DE69804949D1 - Verfahren zum beizen von metallegierungen enthaltenden produkten ohne salpetersäure und zur rückgewinnung gebrauchter beizlösungen und vorrichtung dafür - Google Patents
Verfahren zum beizen von metallegierungen enthaltenden produkten ohne salpetersäure und zur rückgewinnung gebrauchter beizlösungen und vorrichtung dafürInfo
- Publication number
- DE69804949D1 DE69804949D1 DE69804949T DE69804949T DE69804949D1 DE 69804949 D1 DE69804949 D1 DE 69804949D1 DE 69804949 T DE69804949 T DE 69804949T DE 69804949 T DE69804949 T DE 69804949T DE 69804949 D1 DE69804949 D1 DE 69804949D1
- Authority
- DE
- Germany
- Prior art keywords
- ions
- pickling
- niteric
- acid
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910001092 metal group alloy Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 238000010186 staining Methods 0.000 title 1
- 150000002500 ions Chemical class 0.000 abstract 5
- 238000005554 pickling Methods 0.000 abstract 5
- -1 Fe3+ ions Chemical class 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000012071 phase Substances 0.000 abstract 2
- 238000011084 recovery Methods 0.000 abstract 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/36—Regeneration of waste pickling liquors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/106—Other heavy metals refractory metals
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT97RM000102A IT1290947B1 (it) | 1997-02-25 | 1997-02-25 | Metodo e dispositivo per il decapaggio di prodotti in lega metallica in assenza di acido nitrico e per il recupero di soluzioni esauste |
| PCT/IT1998/000038 WO1998038353A1 (en) | 1997-02-25 | 1998-02-25 | Method for pickling products of a metal alloy in absence of nitric and for recovering exhausted pickling solutions and apparatus therefore |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69804949D1 true DE69804949D1 (de) | 2002-05-23 |
| DE69804949T2 DE69804949T2 (de) | 2002-11-28 |
Family
ID=11404789
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69804949T Expired - Fee Related DE69804949T2 (de) | 1997-02-25 | 1998-02-25 | Verfahren zum beizen von metallegierungen enthaltenden produkten ohne salpetersäure und zur rückgewinnung gebrauchter beizlösungen und vorrichtung dafür |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6221234B1 (de) |
| EP (1) | EP0964940B1 (de) |
| JP (1) | JP3282829B2 (de) |
| AT (1) | ATE216438T1 (de) |
| AU (1) | AU6114798A (de) |
| BR (1) | BR9807755A (de) |
| CA (1) | CA2281573A1 (de) |
| DE (1) | DE69804949T2 (de) |
| ES (1) | ES2179454T3 (de) |
| IT (1) | IT1290947B1 (de) |
| WO (1) | WO1998038353A1 (de) |
| ZA (1) | ZA981559B (de) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1297076B1 (it) * | 1997-11-24 | 1999-08-03 | Acciai Speciali Terni Spa | Metodo per il decapaggio di prodotti in acciaio |
| DE19850524C2 (de) * | 1998-11-03 | 2002-04-04 | Eilenburger Elektrolyse & Umwelttechnik Gmbh | Nitratfreies Recycling-Beizverfahren für Edelstähle |
| DE102012111105A1 (de) | 2012-11-19 | 2014-05-22 | Uwe Gräßel | Verfahren zur Rückgewinnung von säurehaltigen Beizlösungen |
| DE102019200832A1 (de) * | 2019-01-24 | 2020-07-30 | MTU Aero Engines AG | VERFAHREN ZUM ENTFERNEN VON Cr(VI)-IONEN AUS EINER WÄSSRIGEN ELEKTROLYTLÖSUNG |
| IT202000005848A1 (it) * | 2020-03-19 | 2021-09-19 | Tenova Spa | Processo per decapare e/o passivare un acciaio inossidabile. |
| WO2023148516A1 (en) * | 2022-02-02 | 2023-08-10 | C.I.E. - Compagnia Italiana Ecologia Srl | Process for free and combinated hydrofluoric acid recovery from stainless steel pickling bath |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50133125A (de) * | 1974-04-10 | 1975-10-22 | ||
| DE3937438C2 (de) * | 1989-02-23 | 1998-01-29 | Wilfried Simmer | Verfahren zum Beizen von Stahl |
| FR2650303B1 (fr) * | 1989-07-26 | 1993-12-10 | Ugine Aciers Chatillon Gueugnon | Procede de decapage en bain acide de produits metalliques contenant du titane ou au moins un element chimique de la famille du titane |
| DE3943142A1 (de) | 1989-12-28 | 1991-07-04 | Metallgesellschaft Ag | Elektrolyseverfahren zur aufbereitung metallionen enthaltender altbeizen oder produktstroeme |
| JP3308345B2 (ja) | 1992-08-21 | 2002-07-29 | ユニチカ株式会社 | 電解槽の操作方法 |
| DE4407448C2 (de) | 1994-03-07 | 1998-02-05 | Mib Metallurg Und Oberflaechen | Elektrolyseverfahren zum Regenerieren einer Eisen-III-Chlorid- oder Eisen-III-Sulfatlösung, insbesondere zum Sprühätzen von Stahl |
| EP0748396B1 (de) | 1994-03-07 | 1998-12-30 | MIB METALLURGIE UND OBERFLÄCHENTECHNIK UND INNOVATION IN BERLIN GmbH & Co | Elektrolyseverfahren zum regenerieren einer eisen-iii-chlorid oder eisen-iii-sulfatlösung, insbesondere zum sprühätzen von stahl |
| DE4435232C2 (de) * | 1994-10-04 | 1997-09-25 | Hahnewald Gmbh Chemisch Physik | Verfahren zur Regenerierung von flußsäurehaltigen Beizlösungen |
| IT1282979B1 (it) | 1996-05-09 | 1998-04-03 | Novamax Itb S R L | Procedimento per il decapaggio dell'acciaio nel quale la ossidazione dello ione ferroso formatosi viene effettuata per via elettrochimica |
-
1997
- 1997-02-25 IT IT97RM000102A patent/IT1290947B1/it active IP Right Grant
-
1998
- 1998-02-25 CA CA002281573A patent/CA2281573A1/en not_active Abandoned
- 1998-02-25 DE DE69804949T patent/DE69804949T2/de not_active Expired - Fee Related
- 1998-02-25 BR BR9807755-4A patent/BR9807755A/pt unknown
- 1998-02-25 AU AU61147/98A patent/AU6114798A/en not_active Abandoned
- 1998-02-25 EP EP98905624A patent/EP0964940B1/de not_active Expired - Lifetime
- 1998-02-25 ES ES98905624T patent/ES2179454T3/es not_active Expired - Lifetime
- 1998-02-25 WO PCT/IT1998/000038 patent/WO1998038353A1/en active IP Right Grant
- 1998-02-25 ZA ZA981559A patent/ZA981559B/xx unknown
- 1998-02-25 JP JP53748498A patent/JP3282829B2/ja not_active Expired - Fee Related
- 1998-02-25 US US09/367,938 patent/US6221234B1/en not_active Expired - Fee Related
- 1998-02-25 AT AT98905624T patent/ATE216438T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA981559B (en) | 1998-08-27 |
| US6221234B1 (en) | 2001-04-24 |
| EP0964940A1 (de) | 1999-12-22 |
| CA2281573A1 (en) | 1998-09-03 |
| JP2000511594A (ja) | 2000-09-05 |
| DE69804949T2 (de) | 2002-11-28 |
| ATE216438T1 (de) | 2002-05-15 |
| WO1998038353A1 (en) | 1998-09-03 |
| ES2179454T3 (es) | 2003-01-16 |
| ITRM970102A1 (it) | 1998-08-25 |
| AU6114798A (en) | 1998-09-18 |
| JP3282829B2 (ja) | 2002-05-20 |
| EP0964940B1 (de) | 2002-04-17 |
| BR9807755A (pt) | 2000-02-22 |
| IT1290947B1 (it) | 1998-12-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ATE321153T1 (de) | Verfahren zur laugung von zinkkonzentat in gegenwart verbrauchter elektrolytlösung mit zugabe von eisen(iii)-rückstand | |
| KR930008197A (ko) | 에칭액의 처리방법 | |
| DE69804949D1 (de) | Verfahren zum beizen von metallegierungen enthaltenden produkten ohne salpetersäure und zur rückgewinnung gebrauchter beizlösungen und vorrichtung dafür | |
| US3975244A (en) | Electrolytic refining | |
| ATE376080T1 (de) | Verfahren zur regeneration von eisenhaltigen ätzlösungen zur verwendung beim ätzen oder beizen von kupfer oder kupferlegierungen und vorrichtung zur durchführung des verfahrens | |
| ATE214436T1 (de) | Verfahren zum beizen von eisen enthaltenden metallegierungen und titan und seinen legierungen | |
| JPH06256999A (ja) | 錫めっき液を回収再生する方法 | |
| GB1196395A (en) | Process for Electrochemically Cleaning and Brightening Copper, Alloy and Brass Strip | |
| WO2000026440A3 (de) | Kreislaufverfahren zum beizen von kupfer und kupferlegierungen | |
| JPS6324098A (ja) | 合金鋼の溶接に伴なうスケ−ルの除去方法 | |
| KR970070244A (ko) | 스테인레스강 및 크롬 및/또는 니켈 합금강의 스케일제거방법, 이에 사용되는 산세조성물 및 산세폐액 재생방법 | |
| JPS5959900A (ja) | ステンレス鋼帯の連続電解脱スケ−ル方法 | |
| JP7217901B2 (ja) | ステンレス鋼の脱スケール液およびステンレス鋼の脱スケール方法 | |
| JPS5959899A (ja) | ステンレス鋼帯の電解脱スケ−ル方法 | |
| JPS5534607A (en) | Recovering and removing method for useless metals from chromate solution by diaphragm electrolysis | |
| JPS6380897A (ja) | 亜リン酸イオンを含む廃めつき液の電解酸化処理法 | |
| Yoshimura et al. | Application of Packed Biopolar Cell to Electrolytic Treatment of Waste Waters,(In Japanese) | |
| RU1807099C (ru) | Способ электрохимического удалени никелевых покрытий со стальных изделий | |
| SU548051A1 (ru) | Способ регенерации железо-меднохлоридны' травильных растворов | |
| JPH0324299A (ja) | ステンレス鋼帯の酸洗方法 | |
| JP2005281827A (ja) | 銀の電解精製方法 | |
| JPS603593A (ja) | 放射性金属廃棄物の電解除染方法 | |
| TH31386A (th) | วิธีสำหรับแช่กรดผลิตภัณฑ์ที่เป็นโลหะอัลลอยในสภาพที่ไม่มีกรดไนตริก และสำหรับนำสารละลายที่ใช้แล้วที่มาจากการแช่กรดและอุปกรณ์ของวิธีการนี้กลับมาใช้ใหม่ | |
| JPS63130800A (ja) | オ−ステナイト系ステンレス冷延鋼帯の脱スケ−ル方法 | |
| JPH02173300A (ja) | ステンレス冷延鋼帯の中性塩電解脱スケール方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |