DE69423027D1 - Verfahren zum Herstellen von Essigsäureestern aus Methanol - Google Patents

Verfahren zum Herstellen von Essigsäureestern aus Methanol

Info

Publication number
DE69423027D1
DE69423027D1 DE69423027T DE69423027T DE69423027D1 DE 69423027 D1 DE69423027 D1 DE 69423027D1 DE 69423027 T DE69423027 T DE 69423027T DE 69423027 T DE69423027 T DE 69423027T DE 69423027 D1 DE69423027 D1 DE 69423027D1
Authority
DE
Germany
Prior art keywords
methanol
acetic acid
acid esters
producing acetic
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69423027T
Other languages
English (en)
Other versions
DE69423027T2 (de
Inventor
Sung Jin Uhm
Sung Hwan Han
Jun Woo Oh
Oh Shim Joo
Kwang Deog Jung
Moon Sang Lee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Institute of Science and Technology KIST
Original Assignee
Korea Institute of Science and Technology KIST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Institute of Science and Technology KIST filed Critical Korea Institute of Science and Technology KIST
Application granted granted Critical
Publication of DE69423027D1 publication Critical patent/DE69423027D1/de
Publication of DE69423027T2 publication Critical patent/DE69423027T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
DE69423027T 1993-07-28 1994-07-26 Verfahren zum Herstellen von Essigsäureestern aus Methanol Expired - Fee Related DE69423027T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019930014392A KR960006546B1 (ko) 1993-07-28 1993-07-28 초산에스테르의 제조 방법

Publications (2)

Publication Number Publication Date
DE69423027D1 true DE69423027D1 (de) 2000-03-23
DE69423027T2 DE69423027T2 (de) 2000-10-19

Family

ID=19360210

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69423027T Expired - Fee Related DE69423027T2 (de) 1993-07-28 1994-07-26 Verfahren zum Herstellen von Essigsäureestern aus Methanol

Country Status (6)

Country Link
US (1) US5430178A (de)
EP (1) EP0640583B1 (de)
JP (1) JP2807176B2 (de)
KR (1) KR960006546B1 (de)
DE (1) DE69423027T2 (de)
ES (1) ES2144472T3 (de)

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KR20000069373A (ko) * 1996-12-12 2000-11-25 마샤 마그달레나 밴 더 메르베 유기 카르복실산 에스테르의 제법
US6127432A (en) * 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
US6458992B1 (en) 1998-03-25 2002-10-01 Sulzer Chemtech Ag Process and apparatus for the production of butylacetate and isobutylacetate
JP2000016966A (ja) * 1998-07-01 2000-01-18 Mitsubishi Gas Chem Co Inc アクリル酸エステルまたはメタクリル酸エステルの製造方法
US6355837B1 (en) * 1999-08-25 2002-03-12 Eastman Chemical Company Vapor phase carbonylation process using group 4 metal promoted iridium catalyst
CZ292620B6 (cs) 1999-10-14 2003-11-12 Sulzer Chemtech Ltd. Způsob výroby etylacetátu a zařízení k provádění tohoto způsobu
US6441222B1 (en) * 2000-05-22 2002-08-27 Eastman Chemical Company Vapor phase carbonylation process using iridium-gold co-catalysts
US6506933B1 (en) * 2000-05-22 2003-01-14 Eastman Chemical Company Vapor phase carbonylation process using gold catalysts
CA2496839A1 (en) 2004-07-19 2006-01-19 Woodland Chemical Systems Inc. Process for producing ethanol from synthesis gas rich in carbon monoxide
JP2009532483A (ja) * 2006-04-05 2009-09-10 ウッドランド バイオフュールズ インコーポレイテッド 合成ガスを介してバイオマスをエタノールに変換するための方法
JP5072251B2 (ja) * 2006-04-06 2012-11-14 三菱重工業株式会社 モノ低級アルキルモノアルカノールアミンの製造方法および装置
EP2637767B1 (de) * 2010-11-12 2017-04-26 Eastman Chemical Company Verarbeitung von gasströmen aus carbonylierungsverfahren
WO2012164573A2 (en) 2011-05-27 2012-12-06 Reliance Industries Ltd., Hydrolysis and esterification with acid catalysts
US9273020B2 (en) * 2012-05-02 2016-03-01 Haldor Topsoe A/S Process for the production of chemical compounds from carbon dioxide
CN106140156A (zh) * 2015-04-20 2016-11-23 中国科学院大连化学物理研究所 一种活性炭负载的铑基催化剂及其制备方法和应用
CN106316846B (zh) * 2016-08-26 2018-12-25 西南化工研究设计院有限公司 一种乙酸甲酯的生产方法
CN108067226A (zh) * 2016-11-15 2018-05-25 中国科学院大连化学物理研究所 一种活性炭负载的铱基催化剂及其制备与应用
CN108069857A (zh) * 2016-11-15 2018-05-25 中国科学院大连化学物理研究所 一种用于甲醇气相羰基化制乙酸甲酯的活性炭负载铱基催化剂及其应用
CN106810450B (zh) * 2017-02-23 2023-08-08 天津大学 一种催化反应精馏制备邻苯二甲酸二丁酯的装置和方法
CN107162257A (zh) * 2017-05-24 2017-09-15 北京师范大学 一种饮用水净化系统及其净化方法
CN108821967A (zh) * 2018-08-07 2018-11-16 中国天辰工程有限公司 一种高纯度酯类物质的合成工艺
CN111195516B (zh) * 2018-11-20 2021-04-23 中国科学院大连化学物理研究所 一种原子级单分散铑基催化剂、其制备方法及在甲醇气相羰基化制备乙酸甲酯中的应用

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA593337A (en) * 1960-03-01 G. Hess Lawrence Synthesis of organic oxygen-containing compounds
GB247050A (en) 1925-05-21 1926-02-11 Basf Ag Improvements in the purification of gases
US1864643A (en) * 1926-01-20 1932-06-28 Celanese Corp Manufacture of aliphatic acids and esters
CH459971A (fr) * 1966-11-01 1968-07-31 Mini Ind Chimice Procédé de transestérification des esters méthyliques des acides organiques inférieurs
SE364255B (de) * 1967-04-05 1974-02-18 Monsanto Co
US3717670A (en) * 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US4690912A (en) * 1968-08-15 1987-09-01 Monsanto Company Rhodium-containing carbonylation catalysts with halogen-containing promoter
US4246195A (en) * 1978-10-06 1981-01-20 Halcon Research And Development Corporation Purification of carbonylation products
JPS56164838A (en) * 1980-05-24 1981-12-18 Unitika Ltd Dipping treatment of polyester fibrous material used for reinforcing rubber
US4810821A (en) * 1981-10-09 1989-03-07 Monsanto Company Preparation of alkylidene diesters
US4514336A (en) * 1982-05-28 1985-04-30 Shell Oil Company Homologous carboxylic acids production
JPS59116115A (ja) * 1982-12-20 1984-07-04 Osaka Gas Co Ltd 一酸化炭素の回収方法
CA1234147A (en) * 1983-07-06 1988-03-15 Eit Drent Process for the preparation of ethanol and/or ethyl acetate
DE3329781A1 (de) * 1983-08-18 1985-02-28 Hoechst Ag, 6230 Frankfurt Verfahren zur abtrennung von jod und dessen verbindungen aus den bei der carbonylierung von dimethylether, methylacetat oder methanol erhaltenen carbonylierungsprodukten
JPS6054334A (ja) * 1983-09-02 1985-03-28 Daicel Chem Ind Ltd カルボン酸の製造法
US5214203A (en) * 1983-09-02 1993-05-25 Daicel Chemical Industries, Ltd. Process for producing carboxylic acids
JPS60199853A (ja) * 1984-03-22 1985-10-09 Daicel Chem Ind Ltd アセチル化合物の製造法
US5144068A (en) * 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US5026908A (en) * 1984-05-03 1991-06-25 Hoechst Celanese Corporation Methanol carbonylation process
US5185462A (en) * 1987-01-08 1993-02-09 Bp Chemicals Limited Production of carboxylic acids and esters thereof
DK158221C (da) * 1987-06-30 1990-09-10 Haldor Topsoe As Fremgangsmaade til fremstilling af eddikesyre, metylacetat, eddikesyreanhydrid eller blandinger deraf
GB8729267D0 (en) * 1987-12-15 1988-01-27 Shell Int Research Process for production of propionate esters
US5218140A (en) * 1988-08-02 1993-06-08 Union Carbide Chemicals & Plastics Technology Corporation Carbonylation reaction and catalyst therefor
JPH06100479A (ja) * 1992-06-30 1994-04-12 Korea Advanced Inst Of Sci Technol 酢酸、酢酸メチル及び無水酢酸の同時製造方法
KR960007736B1 (ko) * 1993-07-27 1996-06-11 한국과학기술연구원 원료 가스 중에 함유된 철 카르보닐 화합물의 제거 방법

Also Published As

Publication number Publication date
KR950003254A (ko) 1995-02-16
JPH07149691A (ja) 1995-06-13
KR960006546B1 (ko) 1996-05-17
EP0640583A3 (de) 1995-08-02
EP0640583B1 (de) 2000-02-16
US5430178A (en) 1995-07-04
JP2807176B2 (ja) 1998-10-08
DE69423027T2 (de) 2000-10-19
EP0640583A2 (de) 1995-03-01
ES2144472T3 (es) 2000-06-16

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee