DE69321899T2 - Herstellung von fliessbarem alkali- oder ammoniumthiosulfat oder -sulfit und produkt nach diesem verfahren - Google Patents
Herstellung von fliessbarem alkali- oder ammoniumthiosulfat oder -sulfit und produkt nach diesem verfahrenInfo
- Publication number
- DE69321899T2 DE69321899T2 DE69321899T DE69321899T DE69321899T2 DE 69321899 T2 DE69321899 T2 DE 69321899T2 DE 69321899 T DE69321899 T DE 69321899T DE 69321899 T DE69321899 T DE 69321899T DE 69321899 T2 DE69321899 T2 DE 69321899T2
- Authority
- DE
- Germany
- Prior art keywords
- mixture
- sulfite
- formaldehyde
- alkali
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 title claims description 55
- 238000000034 method Methods 0.000 title claims description 15
- 230000009969 flowable effect Effects 0.000 title claims description 13
- 230000008569 process Effects 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 title description 15
- 239000000203 mixture Substances 0.000 claims description 75
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 41
- 239000003513 alkali Substances 0.000 claims description 38
- 229910052783 alkali metal Inorganic materials 0.000 claims description 32
- 239000000843 powder Substances 0.000 claims description 31
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 30
- 150000001340 alkali metals Chemical class 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 20
- ASPXBYAQZVXSNS-UHFFFAOYSA-N azane;sulfurous acid;hydrate Chemical compound N.N.O.OS(O)=O ASPXBYAQZVXSNS-UHFFFAOYSA-N 0.000 claims description 12
- -1 alkali metal metabisulfite Chemical class 0.000 claims description 11
- 125000005228 aryl sulfonate group Chemical group 0.000 claims description 11
- 239000007844 bleaching agent Substances 0.000 claims description 10
- AAXJDARXOMHXJR-UHFFFAOYSA-M potassium;formaldehyde;naphthalene-1-sulfonate Chemical compound [K+].O=C.C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 AAXJDARXOMHXJR-UHFFFAOYSA-M 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 4
- 239000007864 aqueous solution Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000003801 milling Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 15
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 11
- 238000009472 formulation Methods 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 235000019256 formaldehyde Nutrition 0.000 description 6
- 239000004570 mortar (masonry) Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 229940043349 potassium metabisulfite Drugs 0.000 description 3
- 235000010263 potassium metabisulphite Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 238000003109 Karl Fischer titration Methods 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000011363 dried mixture Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- WYRIPBMUORTOOJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid;potassium Chemical compound [K].O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 WYRIPBMUORTOOJ-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- GRNVJAJGRSXFFZ-UHFFFAOYSA-N sulfurous acid;hydrate Chemical compound O.OS(O)=O GRNVJAJGRSXFFZ-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000009461 vacuum packaging Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/42—Bleach-fixing or agents therefor ; Desilvering processes
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/264—Supplying of photographic processing chemicals; Preparation or packaging thereof
- G03C5/265—Supplying of photographic processing chemicals; Preparation or packaging thereof of powders, granulates, tablets
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/38—Fixing; Developing-fixing; Hardening-fixing
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Glanulating (AREA)
- Nonmetallic Welding Materials (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/828,672 US5270154A (en) | 1992-01-31 | 1992-01-31 | Method of making flowable alkaline thiosulfate/alkaline sulfite and the product thereof |
| PCT/US1993/000424 WO1993015437A1 (en) | 1992-01-31 | 1993-01-27 | Making flowable alkali or ammonium thiosulfate or sulfite and its product-by-process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69321899D1 DE69321899D1 (de) | 1998-12-10 |
| DE69321899T2 true DE69321899T2 (de) | 1999-05-12 |
Family
ID=25252432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69321899T Expired - Fee Related DE69321899T2 (de) | 1992-01-31 | 1993-01-27 | Herstellung von fliessbarem alkali- oder ammoniumthiosulfat oder -sulfit und produkt nach diesem verfahren |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US5270154A (cg-RX-API-DMAC10.html) |
| EP (1) | EP0583443B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP3048386B2 (cg-RX-API-DMAC10.html) |
| CA (1) | CA2106385A1 (cg-RX-API-DMAC10.html) |
| DE (1) | DE69321899T2 (cg-RX-API-DMAC10.html) |
| WO (1) | WO1993015437A1 (cg-RX-API-DMAC10.html) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0518541B1 (en) * | 1991-05-31 | 2000-09-13 | Konica Corporation | Processing method of black-and-white light-sensitive silver halide photographic material |
| US6317648B1 (en) * | 1996-09-06 | 2001-11-13 | Merck & Co., Inc. | Customer specific packaging line having containers with tag means containing medication order information |
| WO2001087805A1 (en) * | 1998-11-27 | 2001-11-22 | Mitsui & Co., Ltd. | Fertilizers containing ammonium thiosulfate |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2515577A (en) * | 1950-07-18 | Noncaking alkaryl sulfonate | ||
| US2579380A (en) * | 1951-12-18 | nazsox | ||
| US2203903A (en) * | 1938-07-15 | 1940-06-11 | American Cyanamid Co | Stabilized photographic fixing powder |
| US2589108A (en) * | 1943-08-02 | 1952-03-11 | Us Sec War | Chlorinated lime composition |
| US2475616A (en) * | 1945-02-09 | 1949-07-12 | Harold E Ingraham | Thiosulfate salts |
| US2578075A (en) * | 1949-06-18 | 1951-12-11 | Keuffel & Esser Co | Brownprint fixing composition containing alkali thiosulfate, alkali oxalate, and a surface active wetting agent |
| US2782121A (en) * | 1954-02-15 | 1957-02-19 | Goldhammer Jerome Stewart | Combined developer and fixer |
| US2905532A (en) * | 1954-06-24 | 1959-09-22 | Cons Mining & Smelting Co | Method of reducing the caking of ammonium sulphate crystals |
| US2871121A (en) * | 1955-12-14 | 1959-01-27 | Kimura Shuji | Photographic fixer-hardener compositions |
| US2893865A (en) * | 1956-12-26 | 1959-07-07 | Gen Aniline & Film Corp | Single powder photographic developers |
| FR1245937A (fr) * | 1960-01-20 | 1960-11-10 | Mélange sec dosé pour bain fixant photographique | |
| FR1310237A (cg-RX-API-DMAC10.html) * | 1961-01-09 | 1963-03-06 | ||
| US3350168A (en) * | 1963-12-18 | 1967-10-31 | Heico Inc | Methods of preventing decomposition of anhydrous ammonium thiosulfate |
| GB1099790A (en) * | 1966-02-01 | 1968-01-17 | Goldschmidt Ag Th | Flowable ammonium thiosulfate and method for its manufacture |
| JPS6023357A (ja) * | 1983-07-19 | 1985-02-05 | Mitsui Toatsu Chem Inc | ２−メチル−４′−イソプロピル−２−ペンテノイルアニリドおよび選択性殺草剤 |
| NZ216253A (en) * | 1985-05-27 | 1989-07-27 | Mitsui Toatsu Chemicals | N-(3-chloro-4-isopropylphenyl)-carboxamide derivatives and herbicidal compositions |
| JP2647861B2 (ja) * | 1987-10-21 | 1997-08-27 | 花王株式会社 | ナフタレンスルホン酸の製造法 |
| US5030244A (en) * | 1988-06-08 | 1991-07-09 | Ciba-Geigy Corporation | Preparation of granules of dyes, optical whiteners or photoactivators from an aqueous suspension of naphthalene sulfonic acid-formaldehyde condensate dispersant |
| DE3830023A1 (de) * | 1988-09-03 | 1990-03-15 | Agfa Gevaert Ag | Granulierter, farbfotografischer entwickler und seine herstellung |
| US5055384A (en) * | 1989-05-10 | 1991-10-08 | Agfa Gevaert Aktiengesellschaft | Granulated photographic fixative and its preparation |
| DE4009310A1 (de) * | 1990-03-23 | 1991-09-26 | Agfa Gevaert Ag | Granulierte fotochemikalien |
| JP2939639B2 (ja) * | 1990-05-15 | 1999-08-25 | コニカ株式会社 | ハロゲン化銀写真感光材料用固形定着剤及び定着液使用液 |
-
1992
- 1992-01-31 US US07/828,672 patent/US5270154A/en not_active Expired - Fee Related
-
1993
- 1993-01-27 WO PCT/US1993/000424 patent/WO1993015437A1/en not_active Ceased
- 1993-01-27 JP JP5513291A patent/JP3048386B2/ja not_active Expired - Fee Related
- 1993-01-27 DE DE69321899T patent/DE69321899T2/de not_active Expired - Fee Related
- 1993-01-27 CA CA002106385A patent/CA2106385A1/en not_active Abandoned
- 1993-01-27 EP EP93903551A patent/EP0583443B1/en not_active Expired - Lifetime
- 1993-09-10 US US08/118,593 patent/US5328814A/en not_active Expired - Lifetime
-
1996
- 1996-07-05 US US08/676,063 patent/USRE35795E/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0583443B1 (en) | 1998-11-04 |
| US5328814A (en) | 1994-07-12 |
| US5270154A (en) | 1993-12-14 |
| JPH06510144A (ja) | 1994-11-10 |
| JP3048386B2 (ja) | 2000-06-05 |
| EP0583443A1 (en) | 1994-02-23 |
| AU3477593A (en) | 1993-09-01 |
| WO1993015437A1 (en) | 1993-08-05 |
| EP0583443A4 (en) | 1994-07-27 |
| DE69321899D1 (de) | 1998-12-10 |
| AU661895B2 (en) | 1995-08-10 |
| CA2106385A1 (en) | 1993-08-01 |
| USRE35795E (en) | 1998-05-12 |
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