DE60336680D1 - Weitgehend langkettenverzweigungsfreie polymere - Google Patents

Weitgehend langkettenverzweigungsfreie polymere

Info

Publication number
DE60336680D1
DE60336680D1 DE60336680T DE60336680T DE60336680D1 DE 60336680 D1 DE60336680 D1 DE 60336680D1 DE 60336680 T DE60336680 T DE 60336680T DE 60336680 T DE60336680 T DE 60336680T DE 60336680 D1 DE60336680 D1 DE 60336680D1
Authority
DE
Germany
Prior art keywords
long chain
chain branch
free polymers
far long
substantially free
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60336680T
Other languages
English (en)
Inventor
Scott T Milner
Timothy D Shaffer
David Y Chung
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32686080&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE60336680(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Application granted granted Critical
Publication of DE60336680D1 publication Critical patent/DE60336680D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Saccharide Compounds (AREA)
  • Devices For Conveying Motion By Means Of Endless Flexible Members (AREA)
  • Polyamides (AREA)
DE60336680T 2002-12-20 2003-12-19 Weitgehend langkettenverzweigungsfreie polymere Expired - Lifetime DE60336680D1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US43506102P 2002-12-20 2002-12-20
US46418703P 2003-04-21 2003-04-21
US47908103P 2003-06-17 2003-06-17
PCT/US2003/040341 WO2004058835A1 (en) 2002-12-20 2003-12-19 Polymers substantially free of long chain branching

Publications (1)

Publication Number Publication Date
DE60336680D1 true DE60336680D1 (de) 2011-05-19

Family

ID=32686080

Family Applications (4)

Application Number Title Priority Date Filing Date
DE60332866T Expired - Lifetime DE60332866D1 (de) 2002-12-20 2003-12-19 Polymere mit neuen sequenzverteilungen
DE60336680T Expired - Lifetime DE60336680D1 (de) 2002-12-20 2003-12-19 Weitgehend langkettenverzweigungsfreie polymere
DE60332758T Expired - Lifetime DE60332758D1 (de) 2002-12-20 2003-12-19 Polymere mit neuen sequenzverteilungen
DE60333123T Expired - Lifetime DE60333123D1 (de) 2002-12-20 2003-12-19 Polymerisationsverfahren

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE60332866T Expired - Lifetime DE60332866D1 (de) 2002-12-20 2003-12-19 Polymere mit neuen sequenzverteilungen

Family Applications After (2)

Application Number Title Priority Date Filing Date
DE60332758T Expired - Lifetime DE60332758D1 (de) 2002-12-20 2003-12-19 Polymere mit neuen sequenzverteilungen
DE60333123T Expired - Lifetime DE60333123D1 (de) 2002-12-20 2003-12-19 Polymerisationsverfahren

Country Status (9)

Country Link
US (6) US7423100B2 (de)
EP (5) EP1578822B1 (de)
JP (7) JP4690195B2 (de)
AT (4) ATE469178T1 (de)
AU (5) AU2003303313A1 (de)
CA (5) CA2509267C (de)
DE (4) DE60332866D1 (de)
RU (1) RU2341538C2 (de)
WO (4) WO2004058829A1 (de)

Families Citing this family (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006071312A2 (en) 2004-12-29 2006-07-06 Exxonmobil Chemical Patents Inc. Select elastomeric blends and their use in articles
US7714043B2 (en) 2000-10-18 2010-05-11 Exxonmobil Chemical Patents Inc. Tire innerliners having improved cold temperature properties
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
AU2003297458A1 (en) * 2002-12-20 2004-07-22 Exxonmobil Chemical Patents Inc. Polymerization processes
US7425601B2 (en) * 2002-12-20 2008-09-16 Exxonmobil Chemical Patents Inc. Polymers with new sequence distributions
US7723447B2 (en) * 2002-12-20 2010-05-25 Exxonmobil Chemical Patents Inc. Polymerization processes
CA2509267C (en) * 2002-12-20 2010-04-06 Exxonmobil Chemical Patents Inc. Polymerization process utilizing hydrofluorocarbons as diluents
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
RU2366642C2 (ru) 2003-07-15 2009-09-10 Джи Ар Ти, Инк. Синтез углеводородов
US9359481B2 (en) 2003-11-26 2016-06-07 Owens Corning Intellectual Capital, Llc Thermoplastic foams and method of forming them using nano-graphite
US7241398B2 (en) * 2004-01-14 2007-07-10 E.I. Du Pont De Nemours And Company 1,1,1,3,3,-pentafluorobutane refrigerant or heat transfer fluid compositions comprising hydrofluorocarbon and uses thereof
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7683140B2 (en) 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
TW200613326A (en) 2004-05-20 2006-05-01 Exxonmobil Chemical Patents Inc Polymerization process
ATE427980T1 (de) * 2004-06-15 2009-04-15 Exxonmobil Chem Patents Inc Elastomere zusammensetzungen, luftbarrieren und herstellungsverfahren dafur
US7781547B2 (en) 2004-06-25 2010-08-24 Exxonmobil Chemical Patents Inc. Reactor systems for use in polymerization processes
US7758562B2 (en) * 2004-09-09 2010-07-20 Plc Medical Systems, Inc. Patient hydration system with a redundant monitoring of hydration fluid infusion
JP5255842B2 (ja) 2004-12-03 2013-08-07 エクソンモービル・ケミカル・パテンツ・インク ナノ複合組成物を製造するための修飾層状フィラーおよびその使用法
US7906600B2 (en) 2004-12-29 2011-03-15 Exxonmobil Chemical Patents Inc. Processable filled, curable halogenated isoolefin elastomers
CA2505565C (en) * 2005-04-28 2008-09-16 Camco Inc. Apparatus and method for controlling a clothes dryer
US9187608B2 (en) 2005-09-08 2015-11-17 Owens Corning Intellectual Capital, Llc Polystyrene foam containing a modifier-free nanoclay and having improved fire protection performance
EP1772773B1 (de) * 2005-10-06 2011-06-29 STMicroelectronics Srl Methode zur Erzeugung einer mit mehrfachen Linienprofilen umgebenen Struktur, Benutzung einer solchen Struktur als Matrize und Methode zu Herstellung von Schaltkreisstrukturen hiermit
EP2502742B1 (de) 2005-10-27 2017-06-21 ExxonMobil Chemical Patents Inc. Konstruktion mit einer Bindeschicht für Luftreifen
US8287752B2 (en) * 2005-11-01 2012-10-16 E I Du Pont De Nemours And Company Fire extinguishing and fire suppression compositions comprising unsaturated fluorocarbons
EP1966254B1 (de) * 2005-12-28 2011-06-01 ExxonMobil Chemical Patents Inc. Halogenierungsverfahren
CN101395088B (zh) 2006-02-03 2012-04-04 Grt公司 轻气体与卤素的分离方法
EA020442B1 (ru) 2006-02-03 2014-11-28 ДжиАрТи, ИНК. Способ превращения углеводородного сырья (варианты) и система для его осуществления
US7767743B2 (en) 2006-03-10 2010-08-03 Exxonmobil Chemical Patents Inc. Processable branched isoolefin-alkylstyrene elastomers
TW200812938A (en) * 2006-05-31 2008-03-16 Exxonmobil Chem Patents Inc Use of isotopic analysis for determination of aromatic hydrocarbons produced from methane
US8148450B2 (en) * 2006-06-23 2012-04-03 Exxonmobil Chemical Patents Inc. Process to produce a hydrocarbon rubber cement utilizing a hydrofluorocarbon diluent
JP5143835B2 (ja) * 2006-07-03 2013-02-13 ダウ・コーニング・コーポレイション 化学的硬化性一体型ウォームエッジスペーサー及びシール
KR101053817B1 (ko) * 2006-10-11 2011-08-03 야스하라 케미카루 가부시키가이샤 β-피넨 중합체 및 그 제조 방법
JP5046342B2 (ja) 2007-02-09 2012-10-10 エクソンモービル・ケミカル・パテンツ・インク 重合失活方法とシステム
US7402636B1 (en) 2007-03-23 2008-07-22 Exxonmobil Chemical Patents Inc Method and apparatus for decreasing polymer deposition
US7893176B2 (en) * 2007-03-23 2011-02-22 Exxonmobil Chemical Patents Inc. Polydispersity-controlled isoolefin polymerization with polymorphogenates
US7981991B2 (en) * 2007-04-20 2011-07-19 Exxonmobil Chemical Patents Inc. Separation of polymer slurries
WO2008140875A1 (en) 2007-05-16 2008-11-20 Exxonmobil Chemical Patents Inc. Catalyst system for olefin polymerization and polymers produced therefrom
JP2010528054A (ja) 2007-05-24 2010-08-19 ジーアールティー インコーポレイテッド 可逆的なハロゲン化水素の捕捉及び放出を組み込んだ領域反応器
WO2008154612A1 (en) * 2007-06-12 2008-12-18 E.I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of e-1,1,1,4,4,4-hexafluoro-2-butene
DE102007028238A1 (de) * 2007-06-20 2008-12-24 Osram Opto Semiconductors Gmbh Verwendung eines Metallkomplexes als p-Dotand für ein organisches halbleitendes Matrixmaterial, organisches Halbleitermaterial und organische Leuchtdiode
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8415517B2 (en) 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
CN105147759A (zh) 2009-03-04 2015-12-16 瑞吉纳拉制药公司 聚合月桂烯的组合物
PL2403505T3 (pl) 2009-03-04 2017-06-30 Regenera Pharma Ltd. Terapeutyczne zastosowania frakcji gumy mastyksowej
US20100273964A1 (en) * 2009-04-22 2010-10-28 Stewart Lewis Heterogeneous lewis acid catalysts for cationic polymerizations
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US9079990B2 (en) * 2010-06-01 2015-07-14 Exxonmobil Chemical Patents Inc. Methods of production of alkylstyrene/isoolefin polymers
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
JP5774202B2 (ja) 2011-04-21 2015-09-09 横浜ゴム株式会社 熱可塑性エラストマー組成物
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
KR20140056372A (ko) 2011-10-05 2014-05-09 엑손모빌 케미칼 패턴츠 인코포레이티드 타이어 경화 블래더
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
US8592538B2 (en) 2011-12-20 2013-11-26 Honeywell International Inc. Azeotropes of methyl chloride with fluorocarbons
US9963521B2 (en) * 2012-02-17 2018-05-08 Basf Se Process for preparing higher molecular weight polyisobutylene
CA2816776A1 (en) * 2012-05-29 2013-11-29 Tpc Group Llc Adducts of low molecular weight pib with low polydispersity and high vinylidene content
US8927666B2 (en) 2012-11-08 2015-01-06 Honeywell International Inc. Polymerization of monomers using fluorinated propylene solvents
US8987399B2 (en) * 2012-11-08 2015-03-24 Honeywell International Inc. Azeotropes of isobutylene with fluoro-olefins
FR3000093B1 (fr) * 2012-12-26 2015-07-17 Arkema France Composition azeotropique ou quasi-azeotropique de chloromethane
JP6164927B2 (ja) * 2013-05-16 2017-07-19 住友ゴム工業株式会社 空気入りタイヤ
JP6159574B2 (ja) * 2013-05-16 2017-07-05 住友ゴム工業株式会社 分枝共役ジエン共重合体および水添分枝共役ジエン共重合体、ゴム組成物、並びに空気入りタイヤ
EP3087136B1 (de) 2013-12-23 2019-08-14 Arlanxeo Singapore Pte. Ltd. Neuartige anti-agglomerants für elastomere ethylen/-olefincopolymere
CA2934812C (en) * 2013-12-23 2023-07-25 Arlanxeo Singapore Pte. Ltd. Anti-agglomerants for the rubber industry
SG11201604701PA (en) 2013-12-23 2016-07-28 Basf South East Asia Pte Ltd Novel anti-agglomerants for polyisobutylene production
WO2015095961A1 (en) * 2013-12-23 2015-07-02 Lanxess Inc Highly pure halogenated rubbers
KR102394009B1 (ko) * 2013-12-23 2022-05-03 아란세오 싱가포르 프라이빗 리미티드 고순도 고무
WO2015095958A1 (en) 2013-12-23 2015-07-02 Lanxess Inc. Rubbers with tunable levels of metal containing anti-agglomerants
EP2930192A1 (de) * 2014-04-11 2015-10-14 LANXESS Deutschland GmbH Initiator-System zur Herstellung von synthetischen Kautschuken
SG11201608806XA (en) * 2014-04-30 2016-11-29 Arlanxeo Singapore Pte Ltd Highly unsaturated multi-modal polyisoolefin composition and process for preparation thereof
US10077326B2 (en) 2014-04-30 2018-09-18 ARLANXEO Canada Inc. Copolymer having high multiolefin content
RU2695670C2 (ru) * 2014-04-30 2019-07-25 Арланксео Сингапур Пте. Лтд. Бутиловый каучук с новым распределением последовательностей мономерных звеньев
RU2687552C2 (ru) * 2014-04-30 2019-05-15 Арланксео Сингапур Пте. Лтд. Сополимер с низким содержанием изопреноида
EP2940048A1 (de) 2014-04-30 2015-11-04 Lanxess Inc. Copolymer mit niedrigem Isoprenoidanteil
EP2940046A1 (de) 2014-04-30 2015-11-04 Lanxess Inc. Hydrofluorierte Olefine (HFOs) als Verdünnungsmittel zur Butylkautschukherstellung
CN106573996B (zh) * 2014-04-30 2019-11-15 阿朗新科新加坡私人有限公司 作为用于丁基橡胶生产的稀释剂的氢氟烯烃(hfo)
WO2015164971A1 (en) * 2014-04-30 2015-11-05 Lanxess Inc. 2,3,3,3-tetrafluoro-1-propene as diluent for the preparation of novel butyl rubbers
KR20170003946A (ko) 2014-04-30 2017-01-10 아란세오 싱가포르 프라이빗 리미티드 뷰틸 고무의 제조를 위한 희석제
EP2940047A1 (de) 2014-04-30 2015-11-04 Lanxess Inc. Copolymer mit hohem Multiolefingehalt
EP2940050A1 (de) 2014-04-30 2015-11-04 Lanxess Inc. Copolymer mit niedrigem zyklischem Oligomergehalt
SG11201608801SA (en) 2014-04-30 2016-11-29 Arlanxeo Singapore Pte Ltd Copolymer having low cyclic oligomer content
CN106536619B (zh) 2014-06-30 2021-02-12 阿朗新科新加坡私人有限公司 用于橡胶工业的新型防聚剂
KR102424467B1 (ko) 2014-06-30 2022-07-22 바스프 사우쓰 이스트 아시아 피티이. 엘티디. 신규한 폴리이소부틸렌 제조용 응집방지제
US9896525B2 (en) 2015-04-29 2018-02-20 Exxonmobil Chemical Patents Inc. Homogeneous polymerization process using evaporative cooling
CN104844748B (zh) * 2015-05-12 2017-04-05 清华大学 一种丁基橡胶的制备方法
US9771442B2 (en) * 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
RU2690338C1 (ru) 2016-01-29 2019-05-31 Эксонмобил Кемикэл Пейтентс Инк. Система и способ, предназначенные для получения функционализированного полимера на основе олефина
DE102016221346A1 (de) 2016-10-28 2018-05-03 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Herstellung eines Polymerisates durch Nitroxyl-kontrollierte Polymerisation sowie Polymerisat
SG11202000231QA (en) * 2017-07-13 2020-02-27 Arlanxeo Deutschland Gmbh Process for the production of isobutene polymers with improved temperature control
EP3444283B1 (de) * 2017-08-17 2020-02-26 Basf Se Verfahren zur herstellung von hochreaktiven isobuten-homo- oder -copolymeren
CN111315788B (zh) 2017-10-14 2023-08-15 Tpc集团有限责任公司 异丁烯共聚物、制作异丁烯共聚物的方法及异丁烯共聚物产物
EP3999564A1 (de) 2019-07-17 2022-05-25 ExxonMobil Chemical Patents Inc. Druckempfindliche klebstoffe mit propylen-ethylen(-dien)copolymeren
CN110652954A (zh) * 2019-09-19 2020-01-07 贾影丽 一种化妆品釜式反应装置
WO2021262842A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM
WO2021262838A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom
CN114945610A (zh) * 2020-09-18 2022-08-26 株式会社Lg化学 催化剂组合物和使用该催化剂组合物制备异丁烯-异戊二烯共聚物的方法
CN113861323B (zh) * 2021-11-11 2022-11-01 中国科学院长春应用化学研究所 一种高强度、高定伸应力的仿生橡胶及其制备方法和应用
CN113896819B (zh) * 2021-11-11 2022-10-28 中国科学院长春应用化学研究所 一种酮类化合物改性聚丁二烯橡胶及其制备方法和硫化橡胶

Family Cites Families (113)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2356128A (en) † 1939-10-20 1944-08-22 Jasco Inc Mixed olefinic polymerization process and product
US2494585A (en) 1944-09-30 1950-01-17 Standard Oil Dev Co Olefinic polymerization in the presence of fluorine compounds
US2534698A (en) 1944-11-29 1950-12-19 Standard Oil Dev Co Polymerization of olefins in fluorinated diluent
US2474571A (en) 1946-03-28 1949-06-28 Standard Oil Dev Co Low-temperature polymerization process
US2607764A (en) 1947-11-28 1952-08-19 Standard Oil Dev Co Vulcanizable copolymers of isobutylene and 10-70 per cent combined butadiene
US2548415A (en) * 1948-12-08 1951-04-10 Standard Oil Dev Co Boron fluoride in ethylidene fluoride for low-temperature polymerization
US2603626A (en) 1949-03-19 1952-07-15 Standard Oil Dev Co Low-temperature polymerization process employing p2o5 treated alkyl halide catalyst solvent
US2644809A (en) * 1950-01-11 1953-07-07 Standard Oil Dev Co Friedel-crafts isobutylene polymerizations in chlorofluoroalkane solution
US3269972A (en) 1960-10-05 1966-08-30 Exxon Research Engineering Co Butyl rubber compositions comprising methyl hydroxy stearate
BE613858A (de) * 1961-02-13 1900-01-01
US3331822A (en) 1963-08-20 1967-07-18 Thiokol Chemical Corp Production of polytetrafluoroethylene molding powders by the aqueous suspension polymerization of tetrafluoroethylene with small amounts of perfluoroolefins containing from 3 to 4 carbon atoms
DK105619C (da) 1964-02-07 1966-10-17 Henning Kaaber Fremgangsmåde ved suspensions- eller emulsionspolymerisation af ætylenisk umættede forbindelser i lukket beholder.
US3470143A (en) * 1964-03-26 1969-09-30 Dart Ind Inc Highly fluorinated hydrocarbons used as diluents in the polymerization of ethylenically unsaturated monomers
GB1146188A (en) 1965-07-30 1969-03-19 Montedison Spa Polymerization of halogen containing olefins
US3444117A (en) † 1966-04-06 1969-05-13 Exxon Research Engineering Co Polymer blend
GB1200753A (en) 1967-07-12 1970-08-05 Ici Ltd Polymerisation of tetrafluoroethylene
US3616371A (en) 1967-08-05 1971-10-26 Asahi Glass Co Ltd Process for the production of homopolymer of vinylidene fluoride or copolymers thereof in the presence of a fluorine-containing hydrocarbon solvent
US3528954A (en) 1967-10-30 1970-09-15 Du Pont Process for homopolymerization of tetrafluoroethylene and copolymerization of same with fluoro co-monomers in the solvent 1,1,2 - trichloro - 1,2,2 - trifluoroethane
US3642742A (en) 1969-04-22 1972-02-15 Du Pont Tough stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers
US3787379A (en) 1971-10-05 1974-01-22 Pennwalt Corp Copolymers of vinyl fluoride and hexafluoropropene
US4107417A (en) 1971-11-26 1978-08-15 Snamprogetti, S.P.A. Process for the production of polymers and copolymers of isobutylene
CH582719A5 (de) 1973-09-12 1976-12-15 Ciba Geigy Ag
DE2504514A1 (de) 1974-02-12 1975-08-14 Ciba Geigy Ag Fluorierte carbonsaeureamide und ihre polymerisationsprodukte
US4100225A (en) 1974-06-20 1978-07-11 Ciba-Geigy Corporation Stable polymer compositions containing perfluoroalkyl groups and process for making
US4042634A (en) 1976-03-15 1977-08-16 E. I. Du Pont De Nemours And Company Fluorocarbon separation process
US4123602A (en) 1976-05-24 1978-10-31 Asahi Glass Company, Ltd. Terpolymers of tetrafluoroethylene, ethylene and perfluoroalkyl vinyl monomer and process for producing the same
JPS5950162B2 (ja) 1977-05-20 1984-12-06 旭硝子株式会社 改良されたエチレン−四弗化エチレン系共重合体及びその製法
US4194073A (en) 1978-01-04 1980-03-18 Phillips Petroleum Company Olefin polymerization
DE2843157A1 (de) 1978-10-04 1980-04-17 Bayer Ag Verfahren zur herstellung von acrylnitril-polymerisaten in halogenierten aliphatischen kohlenwasserstoffen
US4248988A (en) 1979-10-18 1981-02-03 The Firestone Tire & Rubber Company Process for the preparation of cyclized polymeric dienes
DE3024450A1 (de) 1980-06-28 1982-01-28 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von waessrigen, kolloidalen dispersionen von copolymerisaten des typs tetrafluorethylen-ethylen
US4381387A (en) * 1980-06-28 1983-04-26 Hoechst Aktiengesellschaft Quaterpolymers of the tetrafluoroethylene/ethylene type
DE3139721A1 (de) * 1981-10-06 1983-04-21 Wacker-Chemie GmbH, 8000 München Verfahren zur herstellung von waessrigen copolymerdispersionen und deren verwendung
JPS58189210A (ja) 1982-04-30 1983-11-04 Daikin Ind Ltd テトラフルオロエチレン／フルオロ（アルキルビニルエ−テル）共重合体の製法
US4501865A (en) * 1982-07-08 1985-02-26 Bayer Aktiengesellschaft Polymerization process
US4508881A (en) 1982-09-20 1985-04-02 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene in the presence of polymeric dispersing agents
US4435553A (en) 1982-09-20 1984-03-06 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene in the presence of carbonylated polymeric dispersing agents
US4452960A (en) 1982-09-20 1984-06-05 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene in the presence of polymeric dispersing agents
US4424324A (en) 1982-12-09 1984-01-03 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene
US4626608A (en) 1983-04-05 1986-12-02 Green Cross Corporation Persistent perfluoroalkyl free radicals useful as polymerization catalyst
US4736004A (en) * 1983-04-05 1988-04-05 Green Cross Corporation Persistent perfluoroalkyl free radicals useful as polymerization catalyst
US4588796A (en) 1984-04-23 1986-05-13 E. I. Du Pont De Nemours And Company Fluoroolefin polymerization process using fluoroxy compound solution as initiator
US4535136A (en) * 1984-04-23 1985-08-13 E. I. Du Pont De Nemours And Company Fluoroolefin polymerization process using acyl hypofluorite catalyst
GB8515254D0 (en) 1985-06-17 1985-07-17 Enichem Elastomers Butyl rubber
US5162445A (en) 1988-05-27 1992-11-10 Exxon Chemical Patents Inc. Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof
US5032656A (en) 1987-11-23 1991-07-16 Allied-Signal Inc. Fluorinated copolymer and barrier films
IT1223409B (it) * 1987-12-10 1990-09-19 Ausimont Spa Polimeri e copolimeri fluorurati contenenti blocchi perfluoropolieteri
US4948844A (en) * 1988-04-16 1990-08-14 Tokuyama Soda Kabushiki Kaisha Process for preparation of perfluorinated copolymer
CA1338546C (en) * 1988-05-27 1996-08-20 Kenneth William Powers Para-alkylstyrene/isoolefin copolymers
US4950724A (en) * 1988-09-27 1990-08-21 The Dow Chemical Company Suspension polymerization of vinyl aromatic monomers to polymer having high syndiotacticity
SU1627243A1 (ru) * 1989-02-10 1991-02-15 Советско-итальянское научно-исследовательское общество "Синион" Полимеризатор
US4983528A (en) † 1989-06-06 1991-01-08 Polysar Limited Measurement of unsaturation level in butyl and EPDM rubbers
US5105047A (en) 1989-08-02 1992-04-14 E. I. Du Pont De Nemours And Company Catalysis using blends of perfluorinated ion-exchange polymers with perfluorinated diluents
KR100207346B1 (ko) 1991-07-29 1999-07-15 벤 씨. 카덴헤드 중합 반응기
US5286804A (en) * 1991-09-17 1994-02-15 Exxon Chemical Patents Inc. Halogenation of star-branched butyl rubber with improved neutralization
US5182342A (en) 1992-02-28 1993-01-26 E. I. Du Pont De Nemours And Company Hydrofluorocarbon solvents for fluoromonomer polymerization
US5807977A (en) * 1992-07-10 1998-09-15 Aerojet General Corporation Polymers and prepolymers from mono-substituted fluorinated oxetane monomers
US5310870A (en) * 1992-08-13 1994-05-10 E. I. Du Pont De Nemours And Company Fluoroalkene/hydrofluorocarbon telomers and their synthesis
US5281680A (en) 1993-01-14 1994-01-25 E. I. Du Pont De Nemours And Company Polymerization of fluorinated copolymers
US5506316A (en) * 1993-02-19 1996-04-09 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
DE69421021T2 (de) 1993-03-17 2000-01-20 Asahi Glass Co. Ltd., Tokio/Tokyo Verfahren zur herstellung eines fluorpolymers
JP3272475B2 (ja) * 1993-04-19 2002-04-08 旭硝子株式会社 エチレン−テトラフルオロエチレン系共重合体の製造方法
JP2736938B2 (ja) * 1993-06-24 1998-04-08 ザ ダウ ケミカル カンパニー チタン（▲ｉｉ▼）またはジルコニウム（▲ｉｉ▼）錯体およびそれからなる付加重合触媒
US5990251A (en) 1993-07-13 1999-11-23 Bp Chemicals Limited Process for polymerising olefin with a Ziegler-Natta catalyst
JP2985600B2 (ja) 1993-09-24 1999-12-06 ダイキン工業株式会社 低分子量ポリテトラフルオロエチレンの製造方法
JPH07118596A (ja) 1993-10-25 1995-05-09 Daikin Ind Ltd 撥水撥油剤組成物およびその製法
US5527870A (en) 1994-01-12 1996-06-18 Kanagafuchi Kagaku Kogyo Kabushiki Kaisha Process for the preparation of isobutylene polymer
US5459212A (en) 1994-05-26 1995-10-17 E. I. Du Pont De Nemours And Company Carbon based initiators for polymerization and telomerization of vinyl monomers
DE69513623T2 (de) * 1994-06-09 2000-07-13 Kanegafuchi Kagaku Kogyo K.K., Osaka Verfahren zur herstellung von isobutenpolymer
DE69513526T2 (de) * 1994-07-08 2000-05-04 Minnesota Mining And Mfg. Co., Saint Paul Superatmosphärische reaktion
IT1274711B (it) 1994-08-04 1997-07-24 Ausimont Spa Processo per la preparazione di fluoropolimeri contenenti idrogeno tramite (co)polimerizzazione in sospensione
US5448001A (en) † 1994-10-07 1995-09-05 Queen's University At Kingston Polymerization of iso-butylene
US5811591A (en) * 1994-11-22 1998-09-22 Nippon Shokubai Co., Ltd. Process of producing hydroxyalkanal
US5478905A (en) 1995-02-06 1995-12-26 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene/hexafluoropropylene copolymers
DE69633024T2 (de) 1995-02-06 2005-08-04 E.I. Du Pont De Nemours And Co., Wilmington Amorphe HFP/TFE Copolymere
US6133389A (en) 1995-02-06 2000-10-17 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene-hexafluoropropylene copolymers
US5674957A (en) 1995-03-10 1997-10-07 The University Of North Carolina At Chapel Hill Nonaqueous polymerization of fluoromonomers
US5618894A (en) 1995-03-10 1997-04-08 The University Of North Carolina Nonaqueous polymerization of fluoromonomers
US5552500A (en) 1995-04-24 1996-09-03 E. I. Du Pont De Nemours And Company Fluoroalkene/hydrochlorofluorocarbon telomers and their synthesis
ATE246212T1 (de) 1995-05-26 2003-08-15 Igen Inc Molekular geprägten perl polymere und stabilisierte suspensionspolymerisation von diesen in perfluorkohlstoff flussigkeiten
JPH08333408A (ja) 1995-06-07 1996-12-17 Asahi Glass Co Ltd 含フッ素共重合体の製造方法
IT1276070B1 (it) 1995-10-31 1997-10-24 Siac It Additivi Carburanti Processo per la preparazione di polimeri a base di etilene a basso peso molecolare
CA2174795C (en) * 1996-04-23 2009-11-03 Gabor Kaszas Improved polymer bromination process
RU2097122C1 (ru) * 1996-05-14 1997-11-27 Акционерное общество Научно-производственное предприятие "Ярсинтез" Полимеризатор
US5900251A (en) * 1996-06-10 1999-05-04 Breath Asure, Inc. Internal breath freshener and digestive aid
DE69835649T2 (de) 1997-10-15 2007-09-13 E.I. Dupont De Nemours And Co., Wilmington Copolymere aus Maleinsäure oder dessen Anhydrid und fluorierten Olefinen
JP3818344B2 (ja) 1997-11-20 2006-09-06 旭硝子株式会社 含フッ素脂肪族環構造含有重合体の製造方法
IT1298257B1 (it) 1998-02-17 1999-12-20 Ausimont Spa Perfluorodiossoli
DE19812755A1 (de) 1998-03-23 1999-09-30 Bayer Ag Verfahren zur Herstellung von teilfluorierten Fluorpolymeren
ITMI981506A1 (it) * 1998-06-30 1999-12-30 Ausimont Spa Manufatti di fluoropolimeri amorfi
WO2000004061A1 (en) * 1998-07-17 2000-01-27 Bayer Inc. Process for polymerizing cationically polymerizable olefin
TWI230712B (en) 1998-09-15 2005-04-11 Novartis Ag Polymers
WO2000020472A1 (en) * 1998-10-05 2000-04-13 The B.F. Goodrich Company Catalyst and methods for polymerizing cycloolefins
US6306989B1 (en) * 1999-09-30 2001-10-23 E. I. Du Pont De Nemours And Company Situ fluoropolymer polymerization into porous substrates
EP1141047B1 (de) * 1998-11-30 2009-03-11 E.I. Du Pont De Nemours And Company Fluoromonomerpolymerisation
KR100334163B1 (ko) 1998-12-04 2002-10-25 삼성종합화학주식회사 올레핀중합또는공중합방법
US6337373B1 (en) 1999-07-30 2002-01-08 Montell Technology Company Bv Polyolefin graft copolymers made with fluorinated monomers
IT1313597B1 (it) * 1999-08-04 2002-09-09 Ausimont Spa Lubrificanti perfluoropolieterei contenenti gruppi solfonilfluoruro
US6410982B1 (en) * 1999-11-12 2002-06-25 Intel Corporation Heatpipesink having integrated heat pipe and heat sink
CA2390117A1 (en) * 1999-11-15 2001-05-25 Exxon Chemical Patents, Inc. Production of isobutylene copolymers
US6939933B2 (en) * 2000-12-20 2005-09-06 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
US6538083B2 (en) * 1999-12-21 2003-03-25 E. I. Du Pont De Nemours And Company Chain transfer agents in fluoroolefin polymerization
DE60143635D1 (de) * 2000-02-15 2011-01-27 Asahi Glass Co Ltd Blockpolymer, Verfahren zur Herstellung von Polymer und Festpolymerelektrolytbrennstoffzelle
US6372838B1 (en) 2000-06-28 2002-04-16 3M Innovative Properties Company Fine latex and seed method of making
CN1317328C (zh) * 2000-09-21 2007-05-23 罗姆和哈斯公司 纳米复合材料水分散体：方法、组合物及其用途
GB0026046D0 (en) * 2000-10-24 2000-12-13 Wilde Peter F Improvements to polymerisation processes
DE10061727A1 (de) * 2000-12-12 2002-06-13 Basf Ag Verfahren zur Herstellung von Polyisobutenen
DE10125583A1 (de) * 2001-05-25 2002-11-28 Basf Ag Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens
CA2509267C (en) * 2002-12-20 2010-04-06 Exxonmobil Chemical Patents Inc. Polymerization process utilizing hydrofluorocarbons as diluents
US7425601B2 (en) * 2002-12-20 2008-09-16 Exxonmobil Chemical Patents Inc. Polymers with new sequence distributions
US7723447B2 (en) * 2002-12-20 2010-05-25 Exxonmobil Chemical Patents Inc. Polymerization processes
AU2003297458A1 (en) * 2002-12-20 2004-07-22 Exxonmobil Chemical Patents Inc. Polymerization processes
ATE427980T1 (de) * 2004-06-15 2009-04-15 Exxonmobil Chem Patents Inc Elastomere zusammensetzungen, luftbarrieren und herstellungsverfahren dafur

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