FR2898127B1 - Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine - Google Patents

Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine

Info

Publication number
FR2898127B1
FR2898127B1 FR0601878A FR0601878A FR2898127B1 FR 2898127 B1 FR2898127 B1 FR 2898127B1 FR 0601878 A FR0601878 A FR 0601878A FR 0601878 A FR0601878 A FR 0601878A FR 2898127 B1 FR2898127 B1 FR 2898127B1
Authority
FR
France
Prior art keywords
alcoxyamine
starter
copolymerization
monomers
radical polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0601878A
Other languages
English (en)
Other versions
FR2898127A1 (fr
Inventor
Jean Luc Couturier
Manuel Hidalgo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema SA
Original Assignee
Arkema SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0601878A priority Critical patent/FR2898127B1/fr
Application filed by Arkema SA filed Critical Arkema SA
Priority to JP2008556794A priority patent/JP2009528418A/ja
Priority to PCT/EP2007/052014 priority patent/WO2007099167A1/fr
Priority to CNA2007800072883A priority patent/CN101405337A/zh
Priority to US12/281,234 priority patent/US20090208441A1/en
Priority to KR1020087023011A priority patent/KR20080112242A/ko
Priority to BRPI0708472-2A priority patent/BRPI0708472A2/pt
Priority to EP07726608A priority patent/EP1989256A1/fr
Publication of FR2898127A1 publication Critical patent/FR2898127A1/fr
Application granted granted Critical
Publication of FR2898127B1 publication Critical patent/FR2898127B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/243—Phosphorus-containing polymers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/243—Phosphorus-containing polymers
    • C04B24/246—Phosphorus-containing polymers containing polyether side chains
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641—Polyacrylates; Polymethacrylates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/45—Anti-settling agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
    • C04B2103/302—Water reducers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
    • C04B2103/34—Flow improvers
FR0601878A 2006-03-02 2006-03-02 Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine Expired - Fee Related FR2898127B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR0601878A FR2898127B1 (fr) 2006-03-02 2006-03-02 Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine
PCT/EP2007/052014 WO2007099167A1 (fr) 2006-03-02 2007-03-02 Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine
CNA2007800072883A CN101405337A (zh) 2006-03-02 2007-03-02 在烷氧基胺类引发剂存在下、一种或多种单体的可控自由基聚合或共聚合方法
US12/281,234 US20090208441A1 (en) 2006-03-02 2007-03-02 Process for the controlled radical polymerization or copolymerization of one or more monomers in the presence of an initiator of alkoxyamine type
JP2008556794A JP2009528418A (ja) 2006-03-02 2007-03-02 アルコキシアミン重合開始剤の存在下での一種または複数のモノマーの制御されたラジカル重合または共重合方法
KR1020087023011A KR20080112242A (ko) 2006-03-02 2007-03-02 알콕시아민 개시제 존재 하에 하나 이상의 단량체의 제어된자유라디칼 중합 또는 공중합 공정
BRPI0708472-2A BRPI0708472A2 (pt) 2006-03-02 2007-03-02 processo de polimerização de um ou vários monÈmeros, polìmero ou copolìmero, utilização de um polìmero ou copolìmero, composição cosmética, composição de cimento, composição de betume, composição de gesso e composição de tinta
EP07726608A EP1989256A1 (fr) 2006-03-02 2007-03-02 Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0601878A FR2898127B1 (fr) 2006-03-02 2006-03-02 Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine

Publications (2)

Publication Number Publication Date
FR2898127A1 FR2898127A1 (fr) 2007-09-07
FR2898127B1 true FR2898127B1 (fr) 2008-07-11

Family

ID=36970152

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0601878A Expired - Fee Related FR2898127B1 (fr) 2006-03-02 2006-03-02 Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine

Country Status (8)

Country Link
US (1) US20090208441A1 (fr)
EP (1) EP1989256A1 (fr)
JP (1) JP2009528418A (fr)
KR (1) KR20080112242A (fr)
CN (1) CN101405337A (fr)
BR (1) BRPI0708472A2 (fr)
FR (1) FR2898127B1 (fr)
WO (1) WO2007099167A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2972349B1 (fr) 2011-03-07 2013-04-05 Coatex Sas Formulation cosmetique contenant un copolymere amphiphile non hydrosoluble comme agent epaississant.
CN102351972B (zh) * 2011-07-28 2014-04-23 中山大学 一种含烷氧胺基团的热可逆自修复交联聚合物
CN104334589B (zh) * 2012-04-04 2018-02-06 罗地亚经营管理公司 由丙烯酸、其盐之一或它们的混合物合成聚合物的方法
KR101684649B1 (ko) * 2014-06-13 2016-12-08 주식회사 엘지화학 고흡수성 수지의 제조 방법 및 이를 통해 제조된 고흡수성 수지
FR3030526B1 (fr) * 2014-12-18 2018-06-15 Arkema France Polymerisation radicalaire d'alcoxyamines a basse temperature
FR3080374B1 (fr) * 2018-04-19 2020-11-06 Arkema France Alcoxyamines oligomeres

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2778912B1 (fr) * 1998-05-20 2000-08-11 Total Raffinage Distribution Enrobe bitumineux a base de fraisats de recyclage de materiaux de chaussees, procede de recyclage de ces materiaux et utilisation de l'enrobe
DE19909028A1 (de) * 1999-03-02 2000-09-07 Aventis Res & Tech Gmbh & Co Sulfonierte aromatische Polymere, Membran enthaltend diese Polymeren, Verfahren zu deren Herstellung und deren Verwendung
AU3733800A (en) * 1999-03-09 2000-09-28 Symyx Technologies, Inc. Controlled free radical emulsion and water-based polymerizations and seeded methodologies
FR2807439B1 (fr) * 2000-04-07 2003-06-13 Atofina Polymeres multimodaux par polymerisation radicalaire controlee en presence d'alcoxyamines
EP1468029B1 (fr) * 2002-01-22 2010-06-30 Arkema France Procede de fabrication et utilisation de materiaux renforces au choc contenant des copolymeres blocs obtenus par polymerisation radicalaire controlee en presence de nitroxydes
US6762263B2 (en) * 2002-02-01 2004-07-13 Atofina Chemicals, Inc. High-solids coatings resins via controlled radical polymerization
FR2843394B1 (fr) * 2002-08-07 2005-12-30 Atofina Alcoxyamines issues de nitroxydes b-phosphore, leur utilisation en polymerisation radicalaire
FR2848557B1 (fr) * 2002-12-13 2006-07-07 Atofina Copolymeres a gradient solubles ou du moins dispersibles dans l'eau comme dans les solvants organiques
FR2864455B1 (fr) * 2003-12-24 2006-03-17 Coatex Sas Utilisation de polymeres hydrosolubles structures obtenus par polymerisation radicalaire controlee comme dispersant et agent d'aide au broyage de matieres minerales
FR2866026B1 (fr) * 2004-02-06 2008-05-23 Arkema Procede de polymerisation radicalaire en emulsion mettant en oeuvre des alcoxyamines hydrosolubles

Also Published As

Publication number Publication date
CN101405337A (zh) 2009-04-08
WO2007099167A1 (fr) 2007-09-07
BRPI0708472A2 (pt) 2011-05-31
US20090208441A1 (en) 2009-08-20
JP2009528418A (ja) 2009-08-06
KR20080112242A (ko) 2008-12-24
FR2898127A1 (fr) 2007-09-07
EP1989256A1 (fr) 2008-11-12

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