FR3080374B1 - Alcoxyamines oligomeres - Google Patents

Alcoxyamines oligomeres Download PDF

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Publication number
FR3080374B1
FR3080374B1 FR1853448A FR1853448A FR3080374B1 FR 3080374 B1 FR3080374 B1 FR 3080374B1 FR 1853448 A FR1853448 A FR 1853448A FR 1853448 A FR1853448 A FR 1853448A FR 3080374 B1 FR3080374 B1 FR 3080374B1
Authority
FR
France
Prior art keywords
oligomeric
alcoxyamines
relates
alkoxyamines
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1853448A
Other languages
English (en)
Other versions
FR3080374A1 (fr
Inventor
Anne-Laure Brocas
Sylvain Bourrigaud
Sylvie Cazaumayou
Ilias Iliopoulos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1853448A priority Critical patent/FR3080374B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to KR1020207029722A priority patent/KR20200132955A/ko
Priority to JP2020557225A priority patent/JP2021522174A/ja
Priority to CA3095694A priority patent/CA3095694A1/fr
Priority to CN201980026307.XA priority patent/CN111989310A/zh
Priority to PCT/FR2019/050918 priority patent/WO2019202262A2/fr
Priority to EP19773137.5A priority patent/EP3781546A2/fr
Priority to SG11202010063RA priority patent/SG11202010063RA/en
Priority to US17/046,603 priority patent/US11814336B2/en
Publication of FR3080374A1 publication Critical patent/FR3080374A1/fr
Application granted granted Critical
Publication of FR3080374B1 publication Critical patent/FR3080374B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C239/00—Compounds containing nitrogen-to-halogen bonds; Hydroxylamino compounds or ethers or esters thereof
    • C07C239/08—Hydroxylamino compounds or their ethers or esters
    • C07C239/20—Hydroxylamino compounds or their ethers or esters having oxygen atoms of hydroxylamino groups etherified
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C239/00—Compounds containing nitrogen-to-halogen bonds; Hydroxylamino compounds or ethers or esters thereof
    • C07C239/08—Hydroxylamino compounds or their ethers or esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/32—Compounds containing nitrogen bound to oxygen

Abstract

La présente invention concerne une nouvelle famille d'alcoxyamines présentant une meilleure stabilité au stockage, notamment en présence de monomères et/ou de solvant. En particulier, la présente invention concerne une nouvelle famille d'alcoxyamines oligomères, obtenues par addition d'une ou plusieurs entités monomériques sur une alcoxyamine.
FR1853448A 2018-04-19 2018-04-19 Alcoxyamines oligomeres Active FR3080374B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1853448A FR3080374B1 (fr) 2018-04-19 2018-04-19 Alcoxyamines oligomeres
JP2020557225A JP2021522174A (ja) 2018-04-19 2019-04-17 オリゴマーアルコキサミン
CA3095694A CA3095694A1 (fr) 2018-04-19 2019-04-17 Alcoxyamines oligomeres
CN201980026307.XA CN111989310A (zh) 2018-04-19 2019-04-17 低聚烷氧基胺
KR1020207029722A KR20200132955A (ko) 2018-04-19 2019-04-17 올리고머성 알콕시아민
PCT/FR2019/050918 WO2019202262A2 (fr) 2018-04-19 2019-04-17 Alcoxyamines oligomeres
EP19773137.5A EP3781546A2 (fr) 2018-04-19 2019-04-17 Alcoxyamines oligomeres
SG11202010063RA SG11202010063RA (en) 2018-04-19 2019-04-17 Oligomeric alkoxyamines
US17/046,603 US11814336B2 (en) 2018-04-19 2019-04-17 Oligomeric alkoxy amines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1853448A FR3080374B1 (fr) 2018-04-19 2018-04-19 Alcoxyamines oligomeres
FR1853448 2018-04-19

Publications (2)

Publication Number Publication Date
FR3080374A1 FR3080374A1 (fr) 2019-10-25
FR3080374B1 true FR3080374B1 (fr) 2020-11-06

Family

ID=62874947

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1853448A Active FR3080374B1 (fr) 2018-04-19 2018-04-19 Alcoxyamines oligomeres

Country Status (9)

Country Link
US (1) US11814336B2 (fr)
EP (1) EP3781546A2 (fr)
JP (1) JP2021522174A (fr)
KR (1) KR20200132955A (fr)
CN (1) CN111989310A (fr)
CA (1) CA3095694A1 (fr)
FR (1) FR3080374B1 (fr)
SG (1) SG11202010063RA (fr)
WO (1) WO2019202262A2 (fr)

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1325521A (fr) * 1962-06-20 1963-04-26 American Cyanamid Co Nouveaux dérivés oxygénés nu,nu-disubstitués par des groupes tertiaires et procédés pour les préparer
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス　サイエンテイフイツク　アンド　インダストリアル　リサ−チ　オ−ガニゼ−シヨン 遊離基重合開始用化合物
FR2843393B1 (fr) * 2002-08-07 2005-12-30 Atofina Alcoxyamines issues de nitroxydes b-phosphore, leur utilisation en polymerisation radicalaire
FR2898127B1 (fr) * 2006-03-02 2008-07-11 Arkema Sa Procede de polymerisation ou copolymerisation radicalaire controlee d'un ou plusieurs monomeres en presence d'un amorceur de type alcoxyamine
FR2898126B1 (fr) * 2006-03-02 2008-05-09 Arkema Sa Nouvelles alcoxyamines, leur procede de preparation et leur utilisation en polymerisation radicalaire
FR2974094A1 (fr) * 2011-04-15 2012-10-19 Arkema France Procede de preparation de surfaces
FR3030526B1 (fr) * 2014-12-18 2018-06-15 Arkema France Polymerisation radicalaire d'alcoxyamines a basse temperature

Also Published As

Publication number Publication date
SG11202010063RA (en) 2020-11-27
US20210139415A1 (en) 2021-05-13
EP3781546A2 (fr) 2021-02-24
CA3095694A1 (fr) 2019-10-24
WO2019202262A2 (fr) 2019-10-24
CN111989310A (zh) 2020-11-24
JP2021522174A (ja) 2021-08-30
WO2019202262A3 (fr) 2020-02-27
KR20200132955A (ko) 2020-11-25
FR3080374A1 (fr) 2019-10-25
US11814336B2 (en) 2023-11-14

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