DE60012879T2 - Schlagzähe polyolefinzusammensetzungen - Google Patents
Schlagzähe polyolefinzusammensetzungen Download PDFInfo
- Publication number
- DE60012879T2 DE60012879T2 DE60012879T DE60012879T DE60012879T2 DE 60012879 T2 DE60012879 T2 DE 60012879T2 DE 60012879 T DE60012879 T DE 60012879T DE 60012879 T DE60012879 T DE 60012879T DE 60012879 T2 DE60012879 T2 DE 60012879T2
- Authority
- DE
- Germany
- Prior art keywords
- propylene
- mfr
- fractions
- polyolefin compositions
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 43
- 229920000098 polyolefin Polymers 0.000 title claims description 12
- 229920000642 polymer Polymers 0.000 claims description 24
- -1 polypropylene Polymers 0.000 claims description 23
- 238000006116 polymerization reaction Methods 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 239000004711 α-olefin Substances 0.000 claims description 19
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 18
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 18
- 239000005977 Ethylene Substances 0.000 claims description 15
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- 229920001384 propylene homopolymer Polymers 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 11
- 210000003918 fraction a Anatomy 0.000 claims description 10
- 239000008096 xylene Substances 0.000 claims description 10
- 239000011777 magnesium Substances 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 230000007704 transition Effects 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 150000003609 titanium compounds Chemical class 0.000 claims description 4
- 229920005604 random copolymer Polymers 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 230000000707 stereoselective effect Effects 0.000 claims description 3
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 13
- 239000007789 gas Substances 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 10
- 239000011949 solid catalyst Substances 0.000 description 10
- 239000012071 phase Substances 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 238000000113 differential scanning calorimetry Methods 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 239000002667 nucleating agent Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 238000002083 X-ray spectrum Methods 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
- 239000012632 extractable Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 1
- DKBCURTUXYMRFB-LXTVHRRPSA-N (2r,3r,4s,5r)-7-(3,4-dimethylphenyl)hept-6-ene-1,2,3,4,5,6-hexol Chemical compound CC1=CC=C(C=C(O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO)C=C1C DKBCURTUXYMRFB-LXTVHRRPSA-N 0.000 description 1
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 description 1
- 241000282693 Cercopithecidae Species 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99202974 | 1999-09-14 | ||
| EP99202974 | 1999-09-14 | ||
| PCT/EP2000/008790 WO2001019915A1 (en) | 1999-09-14 | 2000-09-08 | Impact-resitant polyolefin compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60012879D1 DE60012879D1 (de) | 2004-09-16 |
| DE60012879T2 true DE60012879T2 (de) | 2005-08-11 |
Family
ID=8240637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60012879T Expired - Lifetime DE60012879T2 (de) | 1999-09-14 | 2000-09-08 | Schlagzähe polyolefinzusammensetzungen |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US6441094B1 (enExample) |
| EP (1) | EP1135440B1 (enExample) |
| JP (1) | JP4732649B2 (enExample) |
| KR (1) | KR100635888B1 (enExample) |
| CN (1) | CN1132865C (enExample) |
| AR (1) | AR025636A1 (enExample) |
| AT (1) | ATE273347T1 (enExample) |
| AU (1) | AU776743B2 (enExample) |
| BR (1) | BR0007075B1 (enExample) |
| CA (1) | CA2349297C (enExample) |
| CZ (1) | CZ292977B6 (enExample) |
| DE (1) | DE60012879T2 (enExample) |
| ES (1) | ES2225220T3 (enExample) |
| HU (1) | HUP0104592A3 (enExample) |
| ID (1) | ID28962A (enExample) |
| MY (1) | MY120633A (enExample) |
| NO (1) | NO20012326D0 (enExample) |
| PL (1) | PL198071B1 (enExample) |
| RU (1) | RU2232783C2 (enExample) |
| TR (1) | TR200101320T1 (enExample) |
| TW (1) | TW593521B (enExample) |
| WO (1) | WO2001019915A1 (enExample) |
Families Citing this family (53)
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| US6586531B2 (en) * | 2000-10-04 | 2003-07-01 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch and composition suitable for injection molding |
| BR0211324B1 (pt) | 2001-07-31 | 2014-06-10 | Avery Dennison Corp | Material de rótulo conformável, rótulo e rótulo adesivo sensível à pressão |
| CA2465785A1 (en) * | 2001-11-19 | 2003-05-30 | Exxonmobil Chemical Patents Inc. | Impact resistant compositions |
| CN100349929C (zh) * | 2001-11-27 | 2007-11-21 | 巴塞尔聚烯烃意大利有限公司 | 透明和柔性的丙烯聚合物组合物 |
| KR100879490B1 (ko) * | 2001-12-19 | 2009-01-20 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 내충격성 폴리올레핀 조성물 |
| DK1513885T3 (da) * | 2002-04-26 | 2007-01-08 | Total Petrochemicals Res Feluy | Metallocenpolypropylen til rotostöbning |
| CA2487517A1 (en) * | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| CA2487512A1 (en) | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| ATE396472T1 (de) | 2002-06-26 | 2008-06-15 | Avery Dennison Corp | Längsorientierte polymere filme |
| JP2005533920A (ja) | 2002-07-24 | 2005-11-10 | バセル ポリオレフィン ジーエムビーエイチ | プロピレンポリマー組成物の製造の少なくとも２段階方法 |
| EP2261292B1 (en) | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| MY136027A (en) * | 2003-04-02 | 2008-07-31 | Basell Poliolefine Spa | Polyolefin masterbatch and composition suitable for injection molding |
| US6962889B2 (en) * | 2004-01-28 | 2005-11-08 | Engelhard Corporation | Spherical catalyst for olefin polymerization |
| US20050261434A1 (en) * | 2004-05-24 | 2005-11-24 | Piraye Yaras | Thermoplastic elastomeric blends having enhanced surface appearance |
| US7109290B2 (en) | 2004-06-07 | 2006-09-19 | Chevron Phillips Chemical Company Lp | Polymer transfer within a polymerization system |
| KR20070112105A (ko) † | 2004-10-04 | 2007-11-22 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 엘라스토머 폴리올레핀 조성물 |
| ES2398725T3 (es) | 2006-06-14 | 2013-03-21 | Avery Dennison Corporation | Material para etiquetas orientado en la dirección longitudinal que se puede conformar y cortar con troquel y etiquetas y proceso para su preparación |
| BRPI0713492A2 (pt) | 2006-06-20 | 2012-01-24 | Avery Dennison Corp | filme polimérico de multi-camadas para rotulagem de adesivos de derretimento a quente e etiqueta e rótulo dos mesmos |
| WO2008011402A1 (en) | 2006-07-17 | 2008-01-24 | Avery Dennison Corporation | Asymmetric multilayered polymeric film and label stock and label thereof |
| CN101541879B (zh) * | 2006-11-23 | 2012-03-07 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃组合物 |
| RU2323232C1 (ru) * | 2006-12-18 | 2008-04-27 | Георгий Викторович Несын | Ударопрочная морозостойкая композиция полипропилена |
| CN101583663B (zh) * | 2007-01-12 | 2012-05-16 | 陶氏环球技术有限责任公司 | 适用于薄壁注塑制品的组合物 |
| EP2022824A1 (en) | 2007-08-08 | 2009-02-11 | Borealis Technology Oy | Sterilisable and Tough Impact Polypropylene Composition |
| EP2077286A1 (en) * | 2008-01-07 | 2009-07-08 | Total Petrochemicals Research Feluy | Heterophasic propylene copolymer with improved creep behavior |
| KR101580849B1 (ko) * | 2008-02-29 | 2015-12-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 |
| RU2470946C2 (ru) * | 2008-04-24 | 2012-12-27 | Бореалис Аг | Гетерофазные сополимеры пропилена высокой чистоты |
| CN102066478B (zh) * | 2008-06-16 | 2013-04-24 | 博里利斯股份公司 | 通过多级方法生产的具有高流动性和优异的表面质量的热塑性聚烯烃 |
| ES2378290T3 (es) | 2008-10-29 | 2012-04-10 | Borealis Ag | Composición tenaz para aplicaciones alimentarias |
| KR20120093064A (ko) * | 2009-06-26 | 2012-08-22 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 |
| WO2011036014A1 (en) * | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| JP5650229B2 (ja) * | 2009-10-13 | 2015-01-07 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | プロピレンポリマー組成物 |
| RU2548013C2 (ru) * | 2009-11-25 | 2015-04-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Формованное полимерное изделие, характеризующееся низкой мутностью и высокой прозрачностью |
| JP5751539B2 (ja) * | 2010-12-15 | 2015-07-22 | サンアロマー株式会社 | 射出成形用透明ポリプロピレン樹脂組成物および成形品 |
| US8748539B2 (en) * | 2011-05-24 | 2014-06-10 | Braskem America, Inc. | Propylene impact copolymers having good optical properties |
| CN103649208B (zh) * | 2011-07-07 | 2016-08-17 | 巴塞尔聚烯烃意大利有限责任公司 | 聚丙烯组合物 |
| EP2583999A1 (en) * | 2011-10-20 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions |
| US9676532B2 (en) | 2012-08-15 | 2017-06-13 | Avery Dennison Corporation | Packaging reclosure label for high alcohol content products |
| CN105026442A (zh) * | 2013-02-06 | 2015-11-04 | 埃克森美孚化学专利公司 | 提高负载型齐格勒-纳塔催化剂的生产率的初步润湿方法 |
| EP2781548A1 (en) | 2013-03-19 | 2014-09-24 | Basell Poliolefine Italia S.r.l. | Mineral-filled polypropylene composition |
| EP2821434A1 (en) | 2013-07-05 | 2015-01-07 | Basell Poliolefine Italia S.r.l. | Polypropylene compositions containing glass fiber fillers |
| CA2951030C (en) | 2014-06-02 | 2023-03-28 | Christopher J. Blackwell | Films with enhanced scuff resistance, clarity, and conformability |
| JP6594162B2 (ja) * | 2014-10-31 | 2019-10-23 | サンアロマー株式会社 | ポリプロピレン系樹脂組成物及び成形品 |
| JP6633942B2 (ja) * | 2016-02-29 | 2020-01-22 | サンアロマー株式会社 | 中空成形用ポリプロピレン系樹脂組成物及び中空成形品 |
| KR101991218B1 (ko) | 2016-04-14 | 2019-09-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌 중합체 조성물 |
| CN107805340B (zh) * | 2016-09-09 | 2021-07-02 | 中国石油化工股份有限公司 | 一种聚烯烃组合物和聚烯烃材料 |
| CN107805349B (zh) * | 2016-09-09 | 2020-10-23 | 中国石油化工股份有限公司 | 一种聚烯烃组合物及其制备方法和聚烯烃材料 |
| CN112469745B (zh) * | 2018-08-22 | 2023-11-24 | 巴塞尔聚烯烃意大利有限公司 | 无规丙烯-乙烯共聚物 |
| CN113710745A (zh) | 2019-04-05 | 2021-11-26 | 格雷斯公司 | 具有高刚度特性的聚丙烯聚合物组合物 |
| JP7750863B2 (ja) | 2020-04-29 | 2025-10-07 | 中国石油化工股▲ふん▼有限公司 | 無水物基含有ポリプロピレングラフトおよびポリプロピレングラフトの調製方法 |
| AU2021332812A1 (en) | 2020-08-27 | 2023-03-09 | Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation | Polypropylene composition, preparation method therefor, and article made therefrom |
| CN117980398A (zh) | 2021-08-04 | 2024-05-03 | 中国石油化工股份有限公司 | 一种柔性聚丙烯改性绝缘材料及其制备方法与应用 |
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| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1209255B (it) | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| IT1190681B (it) | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1206128B (it) | 1984-07-30 | 1989-04-14 | Himont Inc | Composizioni polipropileniche resistenti all'urto aventi migliorata resistenza allo sbiancamento. |
| US5210139A (en) * | 1988-01-04 | 1993-05-11 | Exxon Chemical Patents Inc. | Thermoplastic olefin alloys and method for producing the same |
| US5023300A (en) * | 1988-01-04 | 1991-06-11 | Exxon Chemical Patents Inc. | Thermoplastic olefin alloys and method for producing the same |
| IT1227260B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
| IT1227893B (it) | 1988-12-14 | 1991-05-14 | Himont Inc Centerville Road Ne | Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto |
| IT1271420B (it) * | 1993-08-30 | 1997-05-28 | Himont Inc | Composizioni poliolefiniche aventi un elevato bilancio di rigidita' e resilienza |
| IT1269914B (it) * | 1994-03-24 | 1997-04-16 | Himonty Inc | Composizioni verniciabili di copolimeri cristallini del propilene aventi bassa temperatura di saldabilita' |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| JP3570797B2 (ja) * | 1995-05-24 | 2004-09-29 | 三井化学株式会社 | プロピレン重合体組成物 |
| JPH09157492A (ja) * | 1995-12-12 | 1997-06-17 | Tonen Chem Corp | 熱可塑性樹脂組成物 |
| JP3270322B2 (ja) * | 1996-02-22 | 2002-04-02 | 三菱化学株式会社 | 金型汚染性の改良された熱可塑性樹脂組成物 |
| US5835518A (en) * | 1997-01-31 | 1998-11-10 | Star Medical Technologies, Inc. | Laser diode array packaging |
| CN1142973C (zh) * | 1998-11-03 | 2004-03-24 | 蒙特克美国有限公司 | 刚性与冲击强度高度平衡的聚烯烃组合物 |
-
2000
- 2000-09-08 ES ES00964147T patent/ES2225220T3/es not_active Expired - Lifetime
- 2000-09-08 EP EP00964147A patent/EP1135440B1/en not_active Expired - Lifetime
- 2000-09-08 TR TR2001/01320T patent/TR200101320T1/xx unknown
- 2000-09-08 DE DE60012879T patent/DE60012879T2/de not_active Expired - Lifetime
- 2000-09-08 JP JP2001523688A patent/JP4732649B2/ja not_active Expired - Fee Related
- 2000-09-08 AU AU75170/00A patent/AU776743B2/en not_active Ceased
- 2000-09-08 CA CA002349297A patent/CA2349297C/en not_active Expired - Fee Related
- 2000-09-08 RU RU2001116116/04A patent/RU2232783C2/ru not_active IP Right Cessation
- 2000-09-08 PL PL347656A patent/PL198071B1/pl not_active IP Right Cessation
- 2000-09-08 KR KR1020017006016A patent/KR100635888B1/ko not_active Expired - Fee Related
- 2000-09-08 US US09/831,712 patent/US6441094B1/en not_active Expired - Lifetime
- 2000-09-08 HU HU0104592A patent/HUP0104592A3/hu unknown
- 2000-09-08 CN CN008019517A patent/CN1132865C/zh not_active Expired - Fee Related
- 2000-09-08 AT AT00964147T patent/ATE273347T1/de not_active IP Right Cessation
- 2000-09-08 ID IDW00200101284A patent/ID28962A/id unknown
- 2000-09-08 CZ CZ20012131A patent/CZ292977B6/cs not_active IP Right Cessation
- 2000-09-08 WO PCT/EP2000/008790 patent/WO2001019915A1/en not_active Ceased
- 2000-09-08 BR BRPI0007075-0A patent/BR0007075B1/pt not_active IP Right Cessation
- 2000-09-11 TW TW089118583A patent/TW593521B/zh not_active IP Right Cessation
- 2000-09-12 AR ARP000104773A patent/AR025636A1/es active IP Right Grant
- 2000-09-13 MY MYPI20004247A patent/MY120633A/en unknown
-
2001
- 2001-05-11 NO NO20012326A patent/NO20012326D0/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU7517000A (en) | 2001-04-17 |
| KR20010086444A (ko) | 2001-09-12 |
| DE60012879D1 (de) | 2004-09-16 |
| US6441094B1 (en) | 2002-08-27 |
| EP1135440B1 (en) | 2004-08-11 |
| BR0007075A (pt) | 2001-07-10 |
| NO20012326L (no) | 2001-05-11 |
| NO20012326D0 (no) | 2001-05-11 |
| KR100635888B1 (ko) | 2006-10-18 |
| PL198071B1 (pl) | 2008-05-30 |
| CA2349297A1 (en) | 2001-03-22 |
| BR0007075B1 (pt) | 2009-05-05 |
| AR025636A1 (es) | 2002-12-04 |
| ES2225220T3 (es) | 2005-03-16 |
| HUP0104592A3 (en) | 2003-08-28 |
| MY120633A (en) | 2005-11-30 |
| CN1132865C (zh) | 2003-12-31 |
| CZ292977B6 (cs) | 2004-01-14 |
| TR200101320T1 (tr) | 2001-12-21 |
| CA2349297C (en) | 2008-11-18 |
| AU776743B2 (en) | 2004-09-23 |
| WO2001019915A1 (en) | 2001-03-22 |
| JP4732649B2 (ja) | 2011-07-27 |
| RU2232783C2 (ru) | 2004-07-20 |
| EP1135440A1 (en) | 2001-09-26 |
| JP2003509562A (ja) | 2003-03-11 |
| CN1321178A (zh) | 2001-11-07 |
| CZ20012131A3 (cs) | 2002-03-13 |
| ATE273347T1 (de) | 2004-08-15 |
| TW593521B (en) | 2004-06-21 |
| ID28962A (id) | 2001-07-19 |
| HUP0104592A2 (hu) | 2002-03-28 |
| PL347656A1 (en) | 2002-04-22 |
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