DE3405431C2 - - Google Patents
Info
- Publication number
- DE3405431C2 DE3405431C2 DE3405431A DE3405431A DE3405431C2 DE 3405431 C2 DE3405431 C2 DE 3405431C2 DE 3405431 A DE3405431 A DE 3405431A DE 3405431 A DE3405431 A DE 3405431A DE 3405431 C2 DE3405431 C2 DE 3405431C2
- Authority
- DE
- Germany
- Prior art keywords
- measuring probe
- neutral salt
- probe according
- polymer
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000523 sample Substances 0.000 claims description 72
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical group [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 46
- 239000003792 electrolyte Substances 0.000 claims description 42
- 150000003839 salts Chemical class 0.000 claims description 42
- 230000007935 neutral effect Effects 0.000 claims description 38
- 239000000243 solution Substances 0.000 claims description 33
- 239000002245 particle Substances 0.000 claims description 31
- 229920000642 polymer Polymers 0.000 claims description 31
- 239000000499 gel Substances 0.000 claims description 25
- 239000001103 potassium chloride Substances 0.000 claims description 23
- 235000011164 potassium chloride Nutrition 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 20
- 238000005259 measurement Methods 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 239000000725 suspension Substances 0.000 claims description 13
- 239000000741 silica gel Substances 0.000 claims description 12
- 229910002027 silica gel Inorganic materials 0.000 claims description 12
- 150000002500 ions Chemical class 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000010419 fine particle Substances 0.000 claims description 8
- 238000012544 monitoring process Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000004886 process control Methods 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000012777 electrically insulating material Substances 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052681 coesite Inorganic materials 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 229910052906 cristobalite Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229910052682 stishovite Inorganic materials 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 2
- 230000032683 aging Effects 0.000 description 17
- 238000009792 diffusion process Methods 0.000 description 6
- 238000002604 ultrasonography Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000872 buffer Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical class [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 239000005486 organic electrolyte Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- AUNGANRZJHBGPY-UHFFFAOYSA-N D-Lyxoflavin Natural products OCC(O)C(O)C(O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010952 in-situ formation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- AYGYHGXUJBFUJU-UHFFFAOYSA-N n-[2-(prop-2-enoylamino)ethyl]prop-2-enamide Chemical compound C=CC(=O)NCCNC(=O)C=C AYGYHGXUJBFUJU-UHFFFAOYSA-N 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000006176 redox buffer Substances 0.000 description 1
- 239000002151 riboflavin Substances 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 235000019192 riboflavin Nutrition 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Analysing Materials By The Use Of Radiation (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH4889/83A CH661128A5 (de) | 1983-09-07 | 1983-09-07 | Messsonde zu potentiometrischer messung von ionenkonzentrationen, verfahren zu deren herstellung und ihre verwendung. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3405431A1 DE3405431A1 (de) | 1985-03-28 |
| DE3405431C2 true DE3405431C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-11-26 |
Family
ID=4284303
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19843405431 Granted DE3405431A1 (de) | 1983-09-07 | 1984-02-15 | Messsonde zu potentiometrischer messung von ionenkonzentrationen, verfahren zu deren herstellung und ihre verwendung |
Country Status (5)
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3818846C1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1988-06-03 | 1988-12-08 | Schott-Geraete Gmbh, 6238 Hofheim, De | |
| DE19515392A1 (de) * | 1995-04-26 | 1996-11-07 | Prominent Dosiertechnik Gmbh | Elektrochemische Meßzelle |
| DE20017268U1 (de) | 2000-10-07 | 2001-03-29 | DECHEMA Gesellschaft für Chemische Technik und Biotechnologie eV, 60486 Frankfurt | Elektrochemische Messzelle zur Bestimmung der Zellzahl und Aktivität von biologischen Systemen |
| DE10036039A1 (de) * | 2000-07-25 | 2002-02-07 | Mettler Toledo Gmbh | Messsonde für potentiometrische Messungen, Verfahren zur Überwachung des Altrungszustandes der Messonde und ihre Verwendung |
| DE10100239A1 (de) * | 2001-01-05 | 2002-07-11 | Mettler Toledo Gmbh | Verfahren zur Bestimmung einer Restbetriebsdauer einer potentiometrischen Messsonde, Vorrichtung zur Durchführung des Verfahrens und ihre Verwendung |
| DE10209318A1 (de) * | 2002-03-02 | 2003-09-25 | Knick Elektronische Mesgeraete | Verfahren zur Ermittlung der verschleißabhängigen Reststandzeit eines elektrochemischen Messsensors |
| DE10243930A1 (de) * | 2002-03-08 | 2003-09-25 | Conducta Endress & Hauser | Vorrichtung zur Messung und Regelung des pH-Wertes eines Mediums |
| DE10233903B3 (de) * | 2002-07-25 | 2004-05-06 | Testo Gmbh & Co | Verfahren zur Herstellung von ph-Sonden |
| DE10239610B3 (de) * | 2002-08-29 | 2004-06-24 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Verfahren zur Funktionsüberwachung von Sensoren |
| DE102006033564B3 (de) * | 2006-07-20 | 2007-09-13 | Schott Instruments Gmbh | Polymerelektrode |
| DE102016107889B4 (de) | 2016-04-28 | 2024-05-08 | Endress+Hauser Conducta Gmbh+Co. Kg | Elektrochemischer Sensor mit Anzeigeelement |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY102855A (en) * | 1986-05-08 | 1993-03-31 | Berger Jenson & Nicholson Ltd | Apparatus and method for measuring resistivity |
| DE3818845C1 (en) * | 1988-06-03 | 1988-12-08 | Schott-Geraete Gmbh, 6238 Hofheim, De | Glass electrode having integrated reference electrode (one-piece electrode) and immobilised electrolytes |
| JPH02268266A (ja) * | 1989-04-10 | 1990-11-01 | Nakagawa Boshoku Kogyo Kk | 基準電極 |
| GB9118300D0 (en) * | 1991-08-24 | 1991-10-09 | Kodak Ltd | Reference half-cell electrode |
| DE4302322C2 (de) * | 1993-01-28 | 1998-09-10 | Inst Chemo Biosensorik | Langlebige miniaturisierbare Referenzelektrode |
| US5419826A (en) * | 1994-03-25 | 1995-05-30 | The United States Of America As Represented By The Secretary Of The Navy | Ion-selective reference probe |
| RU2117281C1 (ru) * | 1994-12-15 | 1998-08-10 | Семен Борисович Ицыгин | Универсальный комбинированный ионоселективный датчик (варианты) |
| DE19533059C2 (de) * | 1995-09-07 | 1999-10-14 | Juchheim Gmbh & Co M K | Bezugselektrode für elektrochemische Messungen und Verfahren zu deren Herstellung |
| US5690808A (en) * | 1996-01-25 | 1997-11-25 | Teledyne Industries, Inc. | Electrochemical gas sensors and methods for sensing electrochemical active gases in gas mixtures |
| US5965299A (en) * | 1997-06-23 | 1999-10-12 | North Carolina State University | Composite electrolyte containing surface modified fumed silica |
| AU749759B2 (en) | 1997-11-07 | 2002-07-04 | Bioquest Llc | Amperometric halogen control system |
| US6328877B1 (en) * | 1998-08-27 | 2001-12-11 | James B. Bushman | Reference electrode improvement |
| US6544689B1 (en) * | 1999-06-30 | 2003-04-08 | North Carolina State University | Composite electrolytes based on smectite clays and high dielectric organic liquids and electrodes |
| AU4830400A (en) * | 1999-08-04 | 2001-03-05 | Orion Research Inc. | Sealed salt bridge |
| DE50015505D1 (de) * | 2000-02-10 | 2009-02-12 | Hamilton Bonaduz Ag | Polymerelektrolyt |
| US20030178305A1 (en) * | 2000-03-31 | 2003-09-25 | Catalano Lauren M. | PH glass membrane and sensor |
| US7544289B2 (en) * | 2003-10-29 | 2009-06-09 | Idex Health & Science Llc | Dosing engine and cartridge apparatus for liquid dispensing and method |
| DE202004002433U1 (de) * | 2004-02-17 | 2005-07-07 | Hamilton Bonaduz Ag | Kalibrierung von elektrochemischen Sensoren, insbesondere von pH-Elektroden |
| DE102004063469B4 (de) * | 2004-12-23 | 2008-05-29 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Verfahren zur Funktionsüberwachung eines potentiometrischen Sensors |
| US20060249386A1 (en) * | 2005-05-05 | 2006-11-09 | Bower Michael M | Use of an osmotic pump to create a flowing reference junction for ionic-activity sensors |
| US7664607B2 (en) | 2005-10-04 | 2010-02-16 | Teledyne Technologies Incorporated | Pre-calibrated gas sensor |
| EP1956368A1 (de) | 2007-02-08 | 2008-08-13 | Hamilton Bonaduz AG | Nano-Hybridgele als Polymer-Elektrolyte |
| US8172999B2 (en) * | 2008-08-14 | 2012-05-08 | Thermo Orion, Inc. | Low maintenance reference electrode for electrochemical measurements |
| EP2278283A1 (de) | 2009-07-23 | 2011-01-26 | Mettler-Toledo AG | Verfahren zur Temperaturkorrektur einer Kraftmessvorrichtung und Kraftmessvorrichtung |
| DE102013101735A1 (de) * | 2012-04-17 | 2013-10-17 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Potentiometrische Sensorvorrichtung |
| FI20126315L (fi) * | 2012-12-14 | 2014-06-15 | Bo Akademi | Referenssielektrodi ja järjestely sähkökemiallista mittausta varten |
| DE102013013601A1 (de) * | 2013-08-19 | 2015-03-12 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Sensor zur Erfassung einer Analytkonzentration |
| DE102014119449A1 (de) * | 2014-12-22 | 2016-06-23 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Elektrochemische Halbzelle und Verfahren zur Herstellung einer Halbzelle |
| DE102015101191A1 (de) * | 2015-01-28 | 2016-07-28 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Potentiometrischer Sensor |
| EP4336177A1 (en) * | 2022-09-06 | 2024-03-13 | InnoME GmbH | Polymer based solid-state electrolyte (sse) for deposition on an ag/agcl reference electrode |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2278248A (en) * | 1939-12-06 | 1942-03-31 | William A Darrah | Process and apparatus for monitoring gases |
| GB729575A (en) * | 1952-09-03 | 1955-05-11 | Jackson Jacob | Improvements relating to reference electrode units |
| US3077446A (en) * | 1959-06-15 | 1963-02-12 | Ca Nat Research Council | Reference electrode for ph meters |
| US3337441A (en) * | 1963-08-19 | 1967-08-22 | Atomic Energy Authority Uk | Phosphoric acid-glycerine electrolyte for hygroscopic cell |
| US3455793A (en) * | 1965-06-18 | 1969-07-15 | Beckman Instruments Inc | Method of providing for liquid junction |
| US3461055A (en) * | 1966-10-06 | 1969-08-12 | Perkin Elmer Corp | Reference electrode and method of making same |
| US4002547A (en) * | 1970-08-21 | 1977-01-11 | Beckman Instruments, Inc. | Electrochemical reference electrode |
| US3705089A (en) * | 1970-09-28 | 1972-12-05 | Gen Electric | Reference electrode half cell |
| US3671414A (en) * | 1971-03-10 | 1972-06-20 | Gen Electric | Hydrogen ion-selective sensor |
| GB1437091A (en) * | 1972-10-02 | 1976-05-26 | Radiometer As | Calcium electrode and membrane and composition for use therein |
| DE2436261B2 (de) * | 1974-07-27 | 1976-11-25 | Bayer Ag, 5090 Leverkusen | Elektrochemische gasdetektoren |
| JPS529490A (en) * | 1975-07-14 | 1977-01-25 | Horiba Ltd | Liquid penetrating portion of reference electrode |
| DE2646314A1 (de) * | 1975-10-28 | 1977-05-05 | Dictaphone Corp | Elektrochemische elektrodenstruktur |
| GB1571282A (en) * | 1976-03-11 | 1980-07-09 | City Tech | Gas sensor |
| JPS5439155A (en) * | 1977-09-01 | 1979-03-26 | Toshiaki Hiratani | Folding large bell |
| US4128456A (en) * | 1977-10-11 | 1978-12-05 | Lee Kai S | Suction electrode for intracellular potential measurement |
| GB1597628A (en) * | 1978-02-15 | 1981-09-09 | Sira Institute | Electrode apparatus |
| US4235688A (en) * | 1978-06-27 | 1980-11-25 | Pennwalt Corporation | Salt bridge reference electrode |
| JPS55101347U (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1979-01-08 | 1980-07-15 | ||
| JPS5663246A (en) * | 1979-10-26 | 1981-05-29 | Hitachi Ltd | Anion selective electrode |
| DE3100302A1 (de) * | 1980-01-11 | 1981-12-10 | List, Hans, Prof. Dipl.-Ing. Dr.Dr.h.c., Graz | Elektrochemische referenzelektrode |
| US4282079A (en) * | 1980-02-13 | 1981-08-04 | Eastman Kodak Company | Planar glass ion-selective electrode |
| DE3033796A1 (de) * | 1980-09-09 | 1982-04-22 | Bayer Ag, 5090 Leverkusen | Elektrochemischer sensor zum nachweis reduzierender gase, insbesondere von kohlenmonoxid, hydrazin und wasserstoff in luft |
| US4390406A (en) * | 1982-07-23 | 1983-06-28 | Allied Corporation | Replaceable outer junction double junction reference electrode |
| DE3228647A1 (de) * | 1982-07-31 | 1984-02-02 | Dr. W. Ingold KG, 6000 Frankfurt | Bezugselektrode oder einstabmesskette |
| FR2541462A1 (fr) * | 1983-02-17 | 1984-08-24 | Texaim | Electrode de reference electrochimique miniature |
-
1983
- 1983-09-07 CH CH4889/83A patent/CH661128A5/de not_active IP Right Cessation
-
1984
- 1984-02-15 DE DE19843405431 patent/DE3405431A1/de active Granted
- 1984-09-06 GB GB08422498A patent/GB2148512B/en not_active Expired
- 1984-09-07 JP JP59186653A patent/JPS6073350A/ja active Granted
-
1988
- 1988-08-15 US US07/232,007 patent/US4959138A/en not_active Expired - Lifetime
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3818846C1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1988-06-03 | 1988-12-08 | Schott-Geraete Gmbh, 6238 Hofheim, De | |
| DE19515392A1 (de) * | 1995-04-26 | 1996-11-07 | Prominent Dosiertechnik Gmbh | Elektrochemische Meßzelle |
| DE10036039A1 (de) * | 2000-07-25 | 2002-02-07 | Mettler Toledo Gmbh | Messsonde für potentiometrische Messungen, Verfahren zur Überwachung des Altrungszustandes der Messonde und ihre Verwendung |
| DE10036039B4 (de) * | 2000-07-25 | 2016-02-25 | Mettler-Toledo Ag | Messsonde für potentiometrische Messungen, Verfahren zur Überwachung des Altrungszustandes der Messonde und ihre Verwendung |
| DE20017268U1 (de) | 2000-10-07 | 2001-03-29 | DECHEMA Gesellschaft für Chemische Technik und Biotechnologie eV, 60486 Frankfurt | Elektrochemische Messzelle zur Bestimmung der Zellzahl und Aktivität von biologischen Systemen |
| DE10100239A1 (de) * | 2001-01-05 | 2002-07-11 | Mettler Toledo Gmbh | Verfahren zur Bestimmung einer Restbetriebsdauer einer potentiometrischen Messsonde, Vorrichtung zur Durchführung des Verfahrens und ihre Verwendung |
| DE10209318B4 (de) * | 2002-03-02 | 2005-07-28 | Knick Elektronische Messgeräte GmbH & Co. KG | Verfahren zur Ermittlung der verschleißabhängigen Reststandzeit eines elektrochemischen Messsensors |
| DE10209318A1 (de) * | 2002-03-02 | 2003-09-25 | Knick Elektronische Mesgeraete | Verfahren zur Ermittlung der verschleißabhängigen Reststandzeit eines elektrochemischen Messsensors |
| DE10243930A1 (de) * | 2002-03-08 | 2003-09-25 | Conducta Endress & Hauser | Vorrichtung zur Messung und Regelung des pH-Wertes eines Mediums |
| DE10233903B3 (de) * | 2002-07-25 | 2004-05-06 | Testo Gmbh & Co | Verfahren zur Herstellung von ph-Sonden |
| US7318273B2 (en) | 2002-07-25 | 2008-01-15 | Testo Ag | Method for producing pH probes |
| DE10239610B3 (de) * | 2002-08-29 | 2004-06-24 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Verfahren zur Funktionsüberwachung von Sensoren |
| DE102006033564B3 (de) * | 2006-07-20 | 2007-09-13 | Schott Instruments Gmbh | Polymerelektrode |
| DE102006033564B9 (de) * | 2006-07-20 | 2008-01-31 | Schott Instruments Gmbh | Polymerelektrode |
| DE102016107889B4 (de) | 2016-04-28 | 2024-05-08 | Endress+Hauser Conducta Gmbh+Co. Kg | Elektrochemischer Sensor mit Anzeigeelement |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2148512B (en) | 1987-01-21 |
| US4959138A (en) | 1990-09-25 |
| GB8422498D0 (en) | 1984-10-10 |
| DE3405431A1 (de) | 1985-03-28 |
| GB2148512A (en) | 1985-05-30 |
| CH661128A5 (de) | 1987-06-30 |
| JPH0449910B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-08-12 |
| JPS6073350A (ja) | 1985-04-25 |
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