DE3201723A1 - Verfahren zur gewinnung von rhodiumkomplexen - Google Patents

Verfahren zur gewinnung von rhodiumkomplexen

Info

Publication number
DE3201723A1
DE3201723A1 DE19823201723 DE3201723A DE3201723A1 DE 3201723 A1 DE3201723 A1 DE 3201723A1 DE 19823201723 DE19823201723 DE 19823201723 DE 3201723 A DE3201723 A DE 3201723A DE 3201723 A1 DE3201723 A1 DE 3201723A1
Authority
DE
Germany
Prior art keywords
rhodium
complex
triarylphosphine
liquid
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19823201723
Other languages
German (de)
English (en)
Other versions
DE3201723C2 (en, 2012
Inventor
Chihiro Kurashiki Okayama Miyazawa
Taisei Okayama Tanimura
Yoshitoshi Komae Tokyo Tsunoda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Industries Ltd filed Critical Mitsubishi Chemical Industries Ltd
Publication of DE3201723A1 publication Critical patent/DE3201723A1/de
Application granted granted Critical
Publication of DE3201723C2 publication Critical patent/DE3201723C2/de
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE19823201723 1981-01-22 1982-01-21 Verfahren zur gewinnung von rhodiumkomplexen Granted DE3201723A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56008419A JPS5923858B2 (ja) 1981-01-22 1981-01-22 ロジウム錯体の取得方法

Publications (2)

Publication Number Publication Date
DE3201723A1 true DE3201723A1 (de) 1982-08-26
DE3201723C2 DE3201723C2 (en, 2012) 1990-03-01

Family

ID=11692599

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19823201723 Granted DE3201723A1 (de) 1981-01-22 1982-01-21 Verfahren zur gewinnung von rhodiumkomplexen

Country Status (7)

Country Link
US (1) US4473655A (en, 2012)
JP (1) JPS5923858B2 (en, 2012)
BR (1) BR8200197A (en, 2012)
DE (1) DE3201723A1 (en, 2012)
GB (1) GB2092907B (en, 2012)
SG (1) SG49287G (en, 2012)
YU (1) YU42453B (en, 2012)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999062895A1 (de) * 1998-06-03 1999-12-09 Basf Aktiengesellschaft Verfahren zur herstellung von butyrolactonen

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4446074A (en) * 1981-12-24 1984-05-01 Union Carbide Corporation Preparation of rhodium complex compounds
US4659682A (en) * 1985-07-08 1987-04-21 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues
US4605541A (en) * 1985-08-26 1986-08-12 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues using immiscible liquids
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts
US4873213A (en) * 1988-08-12 1989-10-10 Puckette Thomas A Low pressure rhodium catalyzed hydroformylation of olefins
DE4135050A1 (de) * 1991-10-24 1993-04-29 Hoechst Ag Verfahren zur reaktivierung wasserloeslicher hydroformylierungskatalysatoren
US5237106A (en) * 1992-01-24 1993-08-17 Union Carbide Chemicals & Plastics Technology Corporation Reactivation of hydroformylation catalysts
FR2743010B1 (fr) * 1995-12-29 1998-02-20 Rhone Poulenc Fibres Procede de preparation par hydrogenation de catalyseurs a base de metal de transition et de phosphine
DE19940250B4 (de) * 1999-08-25 2005-06-16 Celanese Chemicals Europe Gmbh Verfahren zur Regenerierung gebrauchter wasserlöslicher Hydroformylierungskatalysatoren
GB0210143D0 (en) * 2002-05-02 2002-06-12 Davy Process Techn Ltd Process
JP4595495B2 (ja) * 2004-11-08 2010-12-08 三菱化学株式会社 アルデヒドの製造方法
JP4534732B2 (ja) * 2004-11-25 2010-09-01 三菱化学株式会社 ヒドロホルミル化方法
JP4548103B2 (ja) * 2004-11-30 2010-09-22 三菱化学株式会社 ヒドロホルミル化方法
JP2006169131A (ja) * 2004-12-13 2006-06-29 Mitsubishi Chemicals Corp ヒドロホルミル化方法
CN103506166B (zh) * 2012-06-27 2015-08-19 中国石油化工股份有限公司 失活铑膦催化剂的活化方法
CN103769225B (zh) * 2012-10-22 2016-03-02 中国石油化工股份有限公司 羰基化反应失活或部分失活铑膦催化剂的再生方法
JP7269238B2 (ja) 2017-11-13 2023-05-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスからロジウムを回収するためのプロセス
CN111344273B (zh) * 2017-11-15 2023-08-18 三菱化学株式会社 醛制造方法及醇制造方法
CN113816846A (zh) * 2021-09-15 2021-12-21 浙江微通催化新材料有限公司 一种基于氢气还原合成羧酸铑二聚体的方法
CN118414322A (zh) * 2021-12-14 2024-07-30 三菱化学株式会社 醛的制造方法和醇的制造方法、以及催化剂组合物

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
DE2262852A1 (de) * 1972-01-07 1973-07-12 Basf Ag Verfahren zur abscheidung von rhodium aus rhodiumcarbonylkomplexe enthaltenden loesungen und ueberfuehrung des abgeschiedenen rhodiums in loesliche rhodiumcarbonylkomplexe
DE2311388A1 (de) * 1973-03-08 1974-09-12 Erdoelchemie Gmbh Rhodium-katalysatoren
DE2438847A1 (de) * 1973-08-14 1975-02-27 Mitsubishi Chem Ind Verfahren zur wiedergewinnung von edelmetallen der viii. gruppe aus loesungen von edelmetall-organophosphor-komplexen in organischen loesungsmitteln
DE2441515A1 (de) * 1973-08-31 1975-04-03 Fuji Photo Film Co Ltd Farbphotographische diffusionsuebertragungsbehandlungsmasse
DE2448005A1 (de) * 1974-10-09 1976-04-22 Basf Ag Verfahren zur abtrennung und regenerierung von rhodium oder iridium enthaltenden katalysatoren aus bei hydroformylierungen anfallenden destillationsrueckstaenden
US3965192A (en) * 1967-05-29 1976-06-22 Union Oil Company Of California Hydrocarbonylation process
CA1005512A (en) * 1971-07-30 1977-02-15 Rca Corporation Interference suppression circuits
DE2637262A1 (de) * 1976-08-19 1978-02-23 Erdoelchemie Gmbh Rueckgewinnung von in organischen medien homogen geloesten rhodium- katalysatoren
US4218336A (en) * 1977-10-11 1980-08-19 Boehringer Mannheim Gmbh Process for the separation of triphenylphosphine rhodium halide catalysts

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3560539A (en) * 1968-08-21 1971-02-02 Union Oil Co Selective catalyst recovery
JPS5136799B2 (en, 2012) * 1971-10-06 1976-10-12

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3965192A (en) * 1967-05-29 1976-06-22 Union Oil Company Of California Hydrocarbonylation process
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
CA1005512A (en) * 1971-07-30 1977-02-15 Rca Corporation Interference suppression circuits
DE2262852A1 (de) * 1972-01-07 1973-07-12 Basf Ag Verfahren zur abscheidung von rhodium aus rhodiumcarbonylkomplexe enthaltenden loesungen und ueberfuehrung des abgeschiedenen rhodiums in loesliche rhodiumcarbonylkomplexe
US4131640A (en) * 1972-01-07 1978-12-26 Basf Aktiengesellschaft Separating rhodium from solution containing rhodium carbonyl complexes and converting the separated rhodium into soluble rhodium carbonyl complexes
DE2311388A1 (de) * 1973-03-08 1974-09-12 Erdoelchemie Gmbh Rhodium-katalysatoren
DE2438847A1 (de) * 1973-08-14 1975-02-27 Mitsubishi Chem Ind Verfahren zur wiedergewinnung von edelmetallen der viii. gruppe aus loesungen von edelmetall-organophosphor-komplexen in organischen loesungsmitteln
DE2441515A1 (de) * 1973-08-31 1975-04-03 Fuji Photo Film Co Ltd Farbphotographische diffusionsuebertragungsbehandlungsmasse
DE2448005A1 (de) * 1974-10-09 1976-04-22 Basf Ag Verfahren zur abtrennung und regenerierung von rhodium oder iridium enthaltenden katalysatoren aus bei hydroformylierungen anfallenden destillationsrueckstaenden
DE2637262A1 (de) * 1976-08-19 1978-02-23 Erdoelchemie Gmbh Rueckgewinnung von in organischen medien homogen geloesten rhodium- katalysatoren
US4218336A (en) * 1977-10-11 1980-08-19 Boehringer Mannheim Gmbh Process for the separation of triphenylphosphine rhodium halide catalysts

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
N. Almad et al.: J. Chem. Soc., Dalton Trans., 1972, 843-47 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999062895A1 (de) * 1998-06-03 1999-12-09 Basf Aktiengesellschaft Verfahren zur herstellung von butyrolactonen
US6346629B1 (en) 1998-06-03 2002-02-12 Basf Aktiengesellschaft Method for producing butyrolactones

Also Published As

Publication number Publication date
US4473655A (en) 1984-09-25
JPS57122948A (en) 1982-07-31
SG49287G (en) 1987-07-24
YU9082A (en) 1985-04-30
GB2092907B (en) 1984-06-27
YU42453B (en) 1988-08-31
JPS5923858B2 (ja) 1984-06-05
BR8200197A (pt) 1982-11-09
GB2092907A (en) 1982-08-25
DE3201723C2 (en, 2012) 1990-03-01

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Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
8127 New person/name/address of the applicant

Owner name: MITSUBISHI KASEI CORP., TOKIO/TOKYO, JP

D2 Grant after examination
8364 No opposition during term of opposition