DE3141456C2 - - Google Patents

Info

Publication number
DE3141456C2
DE3141456C2 DE3141456A DE3141456A DE3141456C2 DE 3141456 C2 DE3141456 C2 DE 3141456C2 DE 3141456 A DE3141456 A DE 3141456A DE 3141456 A DE3141456 A DE 3141456A DE 3141456 C2 DE3141456 C2 DE 3141456C2
Authority
DE
Germany
Prior art keywords
group viii
complex
rhodium
catalyst
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE3141456A
Other languages
German (de)
English (en)
Other versions
DE3141456A1 (de
Inventor
Yoshitoshi Komae Tokio/Tokyo Jp Tsunoda
Shimpei Tomita
Chihiro Kurashiki Okayama Jp Miyazawa
Yasuro Okayama Jp Omori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Publication of DE3141456A1 publication Critical patent/DE3141456A1/de
Application granted granted Critical
Publication of DE3141456C2 publication Critical patent/DE3141456C2/de
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/85—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE19813141456 1980-10-23 1981-10-19 Verfahren zum abtrennen und gewinnen von festen komplexen von edelmetallen der gruppe viii Granted DE3141456A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55148824A JPS5850234B2 (ja) 1980-10-23 1980-10-23 第８族貴金属固体錯体の取得方法

Publications (2)

Publication Number Publication Date
DE3141456A1 DE3141456A1 (de) 1982-07-08
DE3141456C2 true DE3141456C2 (en, 2012) 1991-01-03

Family

ID=15461538

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19813141456 Granted DE3141456A1 (de) 1980-10-23 1981-10-19 Verfahren zum abtrennen und gewinnen von festen komplexen von edelmetallen der gruppe viii

Country Status (7)

Country Link
US (1) US4396551A (en, 2012)
JP (1) JPS5850234B2 (en, 2012)
BR (1) BR8106702A (en, 2012)
DE (1) DE3141456A1 (en, 2012)
GB (1) GB2085747B (en, 2012)
SG (1) SG49187G (en, 2012)
YU (1) YU42441B (en, 2012)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1338673C (en) * 1988-04-15 1996-10-22 Graham N. Mott Catalyst recycle in the carbonylation of isobutylphenylethanol to ibuprofen
DE3822037A1 (de) * 1988-06-30 1990-01-04 Hoechst Ag Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
US4987242A (en) * 1988-10-28 1991-01-22 Jagmohan Khanna Hydrogenation catalyst useful in the production of alpha-6-deoxytetracyclines
US5099047A (en) * 1989-11-17 1992-03-24 Mitsubishi Kasei Corporation Method for recovering a group viii metal solid complex and hydroformylation method
US5208194A (en) * 1992-02-25 1993-05-04 Arco Chemical Technology, L.P. Recovery of group VIII transition metals from organic solutions using acidic ion-exchange resins
KR0134494B1 (ko) * 1993-10-20 1998-04-20 성재갑 하이드리도카르보닐트리스(트리오가노포스포러스)로듐의 제조방법
US5773665A (en) * 1996-07-01 1998-06-30 Elf Atochem North America, Inc. Hydroformylation process with separation and recycle of active rhodium catalyst
DE19632530C1 (de) * 1996-08-13 1998-02-05 Hoechst Ag Verfahren zur Abtrennung von Phosphinoxiden und Alkylarylphosphinen aus Reaktionsgemischen einer homogenen Hydroformylierung
CZ283697A3 (cs) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Způsob přípravy roztoku komplexu rhodia a jeho použití
FR2765215B1 (fr) * 1997-06-27 1999-08-27 Rhodia Chimie Sa Procede de decoloration d'un produit, notamment d'une huile silicone, comprenant des residus catalytiques colores
GB9806527D0 (en) 1998-03-26 1998-05-27 Bp Chem Int Ltd Process
WO2004065007A1 (en) * 2003-01-17 2004-08-05 Sasol Technology (Proprietary) Limited Recovery of an active catalyst component from a process stream
KR101083351B1 (ko) * 2010-08-17 2011-11-15 한국지질자원연구원 폐ｃｍｂ촉매로부터 코발트 및 망간의 회수방법 및 이를 이용한 ｃｍｂ촉매 제조방법
TWI758353B (zh) * 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
CN111344273B (zh) * 2017-11-15 2023-08-18 三菱化学株式会社 醛制造方法及醇制造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL146830C (en, 2012) * 1960-07-22
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
US3641076A (en) * 1970-08-24 1972-02-08 Union Oil Co Catalyst recovery
DE2045416C3 (de) * 1970-09-15 1979-10-25 Basf Ag, 6700 Ludwigshafen Verfahren zur Elution von Rhodium, das als Rhodiumcarbonylat auf einem basischen Ionenaustauscher gebunden ist
IT1007026B (it) * 1974-01-23 1976-10-30 Montedison Spa Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione
US4135911A (en) * 1977-07-28 1979-01-23 E. I. Du Pont De Nemours And Company Rhodium recovery from hydroformylation still heel with triaryl phosphite ligand
US4224235A (en) * 1978-12-11 1980-09-23 Union Carbide Corporation Rhodium catalyst regeneration by thermal treatment
US4225530A (en) * 1978-12-11 1980-09-30 Union Carbide Corporation Rhodium catalyst regeneration by carbon monoxide treatment
US4260518A (en) * 1979-05-15 1981-04-07 University Of Delaware Process for the regeneration of metallic catalysts

Also Published As

Publication number Publication date
JPS5772995A (en) 1982-05-07
YU252781A (en) 1983-09-30
YU42441B (en) 1988-08-31
SG49187G (en) 1987-07-24
JPS5850234B2 (ja) 1983-11-09
US4396551A (en) 1983-08-02
GB2085747B (en) 1984-07-25
BR8106702A (pt) 1982-07-06
GB2085747A (en) 1982-05-06
DE3141456A1 (de) 1982-07-08

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Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
8127 New person/name/address of the applicant

Owner name: MITSUBISHI KASEI CORP., TOKIO/TOKYO, JP

D2 Grant after examination
8364 No opposition during term of opposition