IT1007026B - Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione - Google Patents

Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione

Info

Publication number
IT1007026B
IT1007026B IT19691/74A IT1969174A IT1007026B IT 1007026 B IT1007026 B IT 1007026B IT 19691/74 A IT19691/74 A IT 19691/74A IT 1969174 A IT1969174 A IT 1969174A IT 1007026 B IT1007026 B IT 1007026B
Authority
IT
Italy
Prior art keywords
hydroformilation
crude
recovery
procedure
catalytic systems
Prior art date
Application number
IT19691/74A
Other languages
English (en)
Inventor
G Guglielmo
Montrasi Giorgio
Original Assignee
Montedison Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison Spa filed Critical Montedison Spa
Priority to IT19691/74A priority Critical patent/IT1007026B/it
Priority to NL7500556A priority patent/NL7500556A/xx
Priority to FR7501591A priority patent/FR2258357B1/fr
Priority to DE19752502233 priority patent/DE2502233A1/de
Priority to US05/543,151 priority patent/US3968134A/en
Priority to CA218,454A priority patent/CA1051854A/en
Priority to ES434027A priority patent/ES434027A1/es
Priority to JP50008800A priority patent/JPS50104790A/ja
Priority to BE152643A priority patent/BE824700A/xx
Priority to GB3046/75A priority patent/GB1495025A/en
Application granted granted Critical
Publication of IT1007026B publication Critical patent/IT1007026B/it

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4023Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4053Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
IT19691/74A 1974-01-23 1974-01-23 Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione IT1007026B (it)

Priority Applications (10)

Application Number Priority Date Filing Date Title
IT19691/74A IT1007026B (it) 1974-01-23 1974-01-23 Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione
NL7500556A NL7500556A (nl) 1974-01-23 1975-01-17 Werkwijze voor de terugwinning van katalysator- systemen uit ruwe reactieprodukten.
FR7501591A FR2258357B1 (it) 1974-01-23 1975-01-20
DE19752502233 DE2502233A1 (de) 1974-01-23 1975-01-21 Verfahren zur rueckgewinnung von rhodium und triphenylphosphin
US05/543,151 US3968134A (en) 1974-01-23 1975-01-22 Process for recovering catalyst systems from raw hydroformylation products
CA218,454A CA1051854A (en) 1974-01-23 1975-01-22 Process for recovering catalyst systems from raw hydroformylation products
ES434027A ES434027A1 (es) 1974-01-23 1975-01-22 Procedimiento para recuperar sistemas catalicos de produc- tos brutos de hidroformilacion.
JP50008800A JPS50104790A (it) 1974-01-23 1975-01-22
BE152643A BE824700A (fr) 1974-01-23 1975-01-23 Procede de recuperation des systemes catalytiques contenus dans des produits bruts d'hydroformylation
GB3046/75A GB1495025A (en) 1974-01-23 1975-01-23 Recovery of the rhodium and triphenyl phosphine components of a catalyst system used in a hydroformylation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT19691/74A IT1007026B (it) 1974-01-23 1974-01-23 Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione

Publications (1)

Publication Number Publication Date
IT1007026B true IT1007026B (it) 1976-10-30

Family

ID=11160412

Family Applications (1)

Application Number Title Priority Date Filing Date
IT19691/74A IT1007026B (it) 1974-01-23 1974-01-23 Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione

Country Status (10)

Country Link
US (1) US3968134A (it)
JP (1) JPS50104790A (it)
BE (1) BE824700A (it)
CA (1) CA1051854A (it)
DE (1) DE2502233A1 (it)
ES (1) ES434027A1 (it)
FR (1) FR2258357B1 (it)
GB (1) GB1495025A (it)
IT (1) IT1007026B (it)
NL (1) NL7500556A (it)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2614799C2 (de) * 1976-04-06 1986-02-27 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium enthaltenden Katalysatoren durch Behandeln von rhodiumhaltigen Destillationsrückständen von Hydroformylierungsgemischen
US4196096A (en) * 1979-02-12 1980-04-01 Eastman Kodak Company Process for regeneration of rhodium hydroformylation catalysts
US4297239A (en) * 1979-07-16 1981-10-27 Union Carbide Corporation Hydroformylation catalyst reactivation
GB2048862B (en) * 1979-05-11 1983-06-15 Mitsubishi Chem Ind Process for the hydroformylation of olefins
US4283304A (en) * 1979-05-21 1981-08-11 Union Carbide Corporation Process for removing triorganophosphine from a liquid composition
US4710587A (en) * 1980-04-16 1987-12-01 Union Carbide Corp. Process for removing triorganophosphine from an organic liquid
JPS5850234B2 (ja) * 1980-10-23 1983-11-09 三菱化学株式会社 第8族貴金属固体錯体の取得方法
US4363764A (en) * 1980-12-30 1982-12-14 Union Carbide Corporation Preparation of rhodium complex compounds
GB2097795B (en) * 1981-05-01 1984-08-01 Johnson Matthey Plc Recovering triaryl phosphine from poisoned thodium catalyst systems
US4459365A (en) * 1981-05-29 1984-07-10 Mitsubishi Gas Chemical Company, Inc. Method of recovering a catalytic metal
DE3235029A1 (de) * 1982-09-22 1984-03-22 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von wasserloeslichen, rhodium enthaltenden hydroformylierungskatalysatoren
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
CZ283697A3 (cs) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Způsob přípravy roztoku komplexu rhodia a jeho použití
KR100969474B1 (ko) * 2006-10-24 2010-07-14 주식회사 엘지화학 하이드로포밀화 반응생성물로부터의 로듐촉매 회수방법
CN102617308B (zh) * 2012-03-13 2013-11-27 青岛科技大学 一种烯烃两相氢甲酰化方法
EP3710161B1 (en) 2017-11-13 2024-10-16 Dow Technology Investments LLC Processes for recovery of rhodium from a hydroformylation process

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3515757A (en) * 1966-04-01 1970-06-02 Ethyl Corp Organic compounds and processes
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
US3560539A (en) * 1968-08-21 1971-02-02 Union Oil Co Selective catalyst recovery
DE2045416C3 (de) * 1970-09-15 1979-10-25 Basf Ag, 6700 Ludwigshafen Verfahren zur Elution von Rhodium, das als Rhodiumcarbonylat auf einem basischen Ionenaustauscher gebunden ist
IT950259B (it) * 1972-03-16 1973-06-20 Montedison Spa Procedimento per il ricupero di si stemi catalitici costituiti da com plessi di metalli di transizione con leganti organici

Also Published As

Publication number Publication date
NL7500556A (nl) 1975-07-25
FR2258357A1 (it) 1975-08-18
GB1495025A (en) 1977-12-14
ES434027A1 (es) 1976-12-01
BE824700A (fr) 1975-07-23
US3968134A (en) 1976-07-06
DE2502233A1 (de) 1975-07-24
CA1051854A (en) 1979-04-03
JPS50104790A (it) 1975-08-19
FR2258357B1 (it) 1979-09-28

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