DE2700339B2 - - Google Patents

Info

Publication number
DE2700339B2
DE2700339B2 DE2700339A DE2700339A DE2700339B2 DE 2700339 B2 DE2700339 B2 DE 2700339B2 DE 2700339 A DE2700339 A DE 2700339A DE 2700339 A DE2700339 A DE 2700339A DE 2700339 B2 DE2700339 B2 DE 2700339B2
Authority
DE
Germany
Prior art keywords
catalyst
carrier
solution
nickel
hours
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE2700339A
Other languages
German (de)
English (en)
Other versions
DE2700339C3 (de
DE2700339A1 (de
Inventor
Donald Charles Charleston W.Va. Best (V.St.A.)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of DE2700339A1 publication Critical patent/DE2700339A1/de
Publication of DE2700339B2 publication Critical patent/DE2700339B2/de
Application granted granted Critical
Publication of DE2700339C3 publication Critical patent/DE2700339C3/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
    • C07C209/28—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds by reduction with other reducing agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE2700339A 1976-01-07 1977-01-05 Katalysator zur Aminierung niedriger aliphatischer Alkanderivate Expired DE2700339C3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/647,065 US4123462A (en) 1976-01-07 1976-01-07 Amination process using nickel-rhenium catalysts

Publications (3)

Publication Number Publication Date
DE2700339A1 DE2700339A1 (de) 1977-08-18
DE2700339B2 true DE2700339B2 (enExample) 1979-08-09
DE2700339C3 DE2700339C3 (de) 1980-06-19

Family

ID=24595557

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2700339A Expired DE2700339C3 (de) 1976-01-07 1977-01-05 Katalysator zur Aminierung niedriger aliphatischer Alkanderivate

Country Status (10)

Country Link
US (2) US4123462A (enExample)
JP (2) JPS6038380B2 (enExample)
BE (1) BE850144A (enExample)
CA (1) CA1083558A (enExample)
DE (1) DE2700339C3 (enExample)
FR (1) FR2337585A1 (enExample)
GB (1) GB1569714A (enExample)
IN (1) IN145670B (enExample)
IT (1) IT1082703B (enExample)
NL (1) NL180914C (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0163253A3 (en) * 1984-05-23 1986-12-30 Union Carbide Corporation Potentiated nickel catalysts for amination

Families Citing this family (81)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2860763D1 (en) * 1977-12-12 1981-09-17 Azote & Prod Chim Catalyst and process for the manufacture of amines from alcohols
FR2411030A1 (fr) * 1977-12-12 1979-07-06 Azote & Prod Chim Catalyseur et procede de fabrication d'amines a partir d'alcools
US4209424A (en) 1977-12-12 1980-06-24 Societe Chimique de la Grande Paroisse, Azote et Products Chimiques Catalyst for manufacturing amines from alcohols
FR2430262A2 (fr) * 1978-07-04 1980-02-01 Azote & Prod Chim Catalyseur et procede de fabrication d'amines a partir d'alcools
US4404405A (en) * 1981-09-30 1983-09-13 Union Carbide Corporation Process for the preparation of polyethylene polyamines
US4400539A (en) * 1981-09-30 1983-08-23 Union Carbide Corporation Process for the manufacture of ethylenediamine
US4929759A (en) * 1983-07-27 1990-05-29 Basf Aktiengesellschaft Production of amines from an olefin and ammonia or a primary or secondary amine
SE461095B (sv) * 1983-09-09 1990-01-08 Berol Kemi Ab Amineringsfoerfarande med anvaendning av en ruteniumdopad nickel och/eller kovoltkatalysator
US4647701A (en) * 1984-05-23 1987-03-03 Union Carbide Corporation Processes for producing diethylenetriamine from monoethanolamine
US4827037A (en) * 1985-04-04 1989-05-02 Union Carbide Corporation Quality of catalytically prepared polyalkylene polyamines
US4772750A (en) * 1985-06-14 1988-09-20 The Dow Chemical Company Method of producing amines
GB8519425D0 (en) * 1985-08-01 1985-09-04 Ici Plc Amine production
US4709034A (en) * 1986-02-14 1987-11-24 Air Products And Chemicals, Inc. Process for the synthesis of hydroxyalkyl amines and hydroxyalkyl piperazines
US4918233A (en) * 1986-07-08 1990-04-17 Air Products And Chemicals, Inc. Production of ethylenediamine from monoethanolamine and ammonia
US4774336A (en) * 1986-10-02 1988-09-27 Texaco Inc. Process for preparing N-substituted piperazines from ethylene glycol and amines
GB8707304D0 (en) * 1987-03-26 1987-04-29 Bp Chem Int Ltd Chemical process
US4795733A (en) * 1987-11-27 1989-01-03 Gaf Corporation Hydrogenation catalyst and process for its preparation
GB8819663D0 (en) * 1988-08-18 1988-09-21 Bp Chem Int Ltd Chemical process
GB8918965D0 (en) * 1989-08-19 1989-10-04 Bp Chem Int Ltd Chemical process
DE4006540A1 (de) * 1990-03-02 1991-09-05 Huels Chemische Werke Ag Katalysatoren fuer die metathese von olefinen und funktionalisierten olefinen
US5321160A (en) * 1991-07-31 1994-06-14 Tosoh Corporation Process for producing an ethylenamine
CA2146903C (en) * 1993-12-22 2000-01-25 Stephen Wayne King Reductive amination catalysts for the selective production of aminoethylethanolamine
CA2146906C (en) * 1993-12-22 1999-03-16 Stephen Wayne King Reductive amination catalysts
US5600000A (en) * 1993-12-22 1997-02-04 Union Carbide Chemicals & Plastics Technology Corporation Reductive amination processes for the selective production of amino-ethylethanolamine
US5475138A (en) * 1994-07-07 1995-12-12 Pharm-Eco Laboratories Incorporated Method preparing amino acid-derived diaminopropanols
US5817593A (en) * 1995-06-02 1998-10-06 The Dow Chemical Company Catalyst and process for producing amines
US6063963A (en) * 1995-07-05 2000-05-16 Pharm-Eco Laboratories, Inc. Amino acid-derived diaminopropanols
JPH11514401A (ja) * 1995-10-04 1999-12-07 ザ ダウ ケミカル カンパニー アミン末端ポリエーテル及びその製造方法
US5679862A (en) * 1996-03-25 1997-10-21 Chemical Research & Licensing Company Amination process
SE513250C2 (sv) * 1997-11-11 2000-08-07 Akzo Nobel Nv Amineringsförfarande för framställning av polyaminer
AU5280999A (en) * 1998-07-21 2000-02-14 Lonza A.G. Method for producing amines
US6534441B1 (en) * 1999-03-06 2003-03-18 Union Carbide Chemicals & Plastics Technology Corporation Nickel-rhenium catalyst for use in reductive amination processes
US6309758B1 (en) * 1999-05-06 2001-10-30 W. R. Grace & Co.-Conn. Promoted porous catalyst
WO2003076883A2 (en) * 2002-03-08 2003-09-18 Sensys Medical, Inc. Compact apparatus for noninvasive measurement of glucose through near-infrared spectroscopy
DE10145119A1 (de) * 2001-09-13 2003-04-03 Basf Ag Verfahren zur Herstellung von Aminen
US7022645B2 (en) * 2003-08-04 2006-04-04 Catalytic Distillation Technologies Ni hydrogenation catalysts, manufacture and use
US7131446B2 (en) * 2004-03-25 2006-11-07 Tang Kenneth Y Light-triggered tattoo process
US7619118B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Process for the conversion of glycerol to propylene glycol and amino alcohols
US7619119B2 (en) * 2006-06-07 2009-11-17 The Procter & Gamble Company Processes for converting glycerol to amino alcohols
ES2442493T3 (es) * 2006-06-07 2014-02-11 The Procter & Gamble Company Proceso para la conversión de glicerol en propilenglicol y aminoalcoholes
EP2231583B1 (en) * 2008-01-03 2015-08-05 Akzo Nobel N.V. Process to prepare ethylene amines
WO2009155466A2 (en) 2008-06-19 2009-12-23 Honda Motor Co. Ltd. Low temperature single-wall carbon nanotube synthesis
ES2433422T3 (es) * 2008-10-06 2013-12-11 Union Carbide Chemicals & Plastics Technology Llc Métodos para preparar triaminas N-aminofuncionales cíclicas
EP2352585B1 (en) 2008-10-06 2020-06-17 Union Carbide Corporation Low metal loaded, alumina supported, catalyst compositions and amination process
EP2344445B1 (en) * 2008-10-06 2017-05-10 Union Carbide Chemicals & Plastics Technology LLC A process to selectively manufacture diethylenetriamine (deta) or other desirable ethylenamines via continuous transamination of ethylenediamine (eda), and other ethyleneamines over a heterogeneous catalyst system
US8383861B2 (en) * 2008-10-06 2013-02-26 Dow Global Technologies Llc Methods for making ethanolamine(s) and ethyleneamine(s) from ethylene oxide and ammonia, and related methods
JP5480276B2 (ja) 2008-10-06 2014-04-23 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー 担体として酸性混合金属酸化物を含む低金属（ニッケル及びレニウム）触媒組成物
EP2346809B1 (en) * 2008-10-06 2016-01-13 Union Carbide Chemicals & Plastics Technology LLC Method of manufacturing ethyleneamines
BRPI0914045A2 (pt) * 2008-10-06 2015-11-03 Union Carbide Chem Plastic método para transferir um grupo hidroxialquila de um composto alcoxilado para um composto nucleofílico, método para transalcoxilar um composto alcoxilado, método para transalcoxilar um composto de alcanolamina e método para transoxilar um composto de alcanolamina
CN101875014B (zh) * 2009-11-17 2012-10-03 中国科学院大连化学物理研究所 一种在临氢条件下一乙醇胺和氨转化为乙二胺的催化剂
EP2571968A1 (en) 2010-05-21 2013-03-27 H R D Corporation Process for upgrading low value renewable oils
DE102011004465A1 (de) 2010-09-10 2012-03-15 Evonik Degussa Gmbh Verfahren zur direkten Aminierung sekundärer Alkohole mit Ammoniak zu primären Aminen
DE102011075162A1 (de) 2010-12-08 2012-06-14 Evonik Degussa Gmbh Verfahren zur homogen-katalysierte, hochselektiven direkten Aminierung von primären Alkoholen mit Ammoniak zu primären Aminen bei hohem Volumenverhältnis von Flüssig- zu Gasphase und/oder hohen Drücken
DE102011003595B4 (de) * 2011-02-03 2014-04-17 Evonik Degussa Gmbh Herstellung von in ihrer Hauptkette linearen primären Diaminen für Polyamidsynthesen
WO2012113475A1 (de) 2011-02-21 2012-08-30 Evonik Degussa Gmbh Verfahren zur direkten aminierung von alkoholen mit ammoniak zu primären aminen mittels eines xantphos katalysatorsystems
EP2794581B1 (en) * 2011-12-22 2016-05-25 Dow Global Technologies LLC Reductive amination of diethanolamine and resulting product mixture
US8952198B2 (en) 2013-01-30 2015-02-10 Ian Williams Amination process for manufacturing amines using catalyst
US9783486B2 (en) 2013-12-02 2017-10-10 Dow Global Technologies Llc Preparation of high molecular weight, branched, acyclic polyalkyleneamines and mixtures thereof
US10428011B2 (en) 2016-02-12 2019-10-01 Nouryon Chemicals International B.V. Process to prepare higher ethylene amines and ethylene amine derivatives
KR101981157B1 (ko) * 2016-02-12 2019-05-22 아크조 노벨 케미칼즈 인터내셔널 비.브이. 고급 에틸렌아민 및 에틸렌아민 유도체의 제조 방법
BR112018014267B1 (pt) 2016-02-12 2021-12-28 Akzo Nobel Chemicals International B.V. Processo de preparação de etilenoaminas
KR102445287B1 (ko) 2016-05-11 2022-09-20 레그 신써틱 퓨얼즈, 엘엘씨 바이오재생 케로신, 제트 연료, 제트 연료 혼합연료, 및 제조 방법
CN109996781A (zh) * 2016-11-30 2019-07-09 巴斯夫欧洲公司 使用沸石催化剂将乙二醇转化为乙二胺的方法
CN110072839A (zh) 2016-12-15 2019-07-30 巴斯夫欧洲公司 生产乙醇胺和/或亚乙基胺的方法
CN110709380A (zh) 2017-06-09 2020-01-17 巴斯夫欧洲公司 制备亚乙基胺的方法
US20210078935A1 (en) 2017-06-09 2021-03-18 Basf Se Method for the production of ethyleneamines
EP3634935B1 (de) 2017-06-09 2022-03-09 Basf Se Verfahren zur herstellung von ethylenaminen
TWI762669B (zh) 2017-07-10 2022-05-01 荷蘭商安科智諾貝爾化學國際公司 製造較高分子量伸乙基胺之方法
WO2019081286A1 (de) 2017-10-27 2019-05-02 Basf Se Verfahren zur herstellung von ethylenaminen
EP3700883B1 (de) 2017-10-27 2022-04-20 Basf Se Verfahren zur herstellung von ethylenaminen
BR112020006435B1 (pt) 2017-10-27 2023-03-21 Basf Se Processo de preparação de etilenoaminas e/ou alcanolaminas
CN111278801B (zh) 2017-10-27 2023-05-26 巴斯夫欧洲公司 从含eda的混合物中分离n-甲基乙二胺
CN107913694A (zh) * 2017-10-31 2018-04-17 山东玉皇化工有限公司 一种胺化催化剂载体的调变方法及其应用
CN109734601B (zh) * 2019-01-25 2021-11-12 浙江师范大学 一种制备1,3-丙二胺的方法
US12221402B2 (en) 2019-03-06 2025-02-11 Basf Se Method for the production of ethyleneamines
US12398090B2 (en) 2019-12-13 2025-08-26 Basf Se Separation of n-methylethylenediamine from EDA-containing mixtures
EP4463435A1 (en) 2022-01-14 2024-11-20 Basf Se Method for the manufacture or conversion of alkanolamines
CN119451938A (zh) 2022-06-29 2025-02-14 巴斯夫欧洲公司 用于制造亚乙基胺的方法
JP2025522656A (ja) 2022-06-29 2025-07-16 ビーエーエスエフ ソシエタス・ヨーロピア エチレンアミンの製造方法
WO2025125094A1 (en) 2023-12-14 2025-06-19 Basf Se Process for preparing diethylenetriamine and/or ethylene glycol
CN118253311A (zh) * 2024-04-08 2024-06-28 卫星化学股份有限公司 一种用于乙二胺和哌嗪制备的催化剂及其制备方法和应用

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FR1360740A (fr) * 1963-02-12 1964-05-15 British Petroleum Co Perfectionnements relatifs à l'hydrogénation des paraffines
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0163253A3 (en) * 1984-05-23 1986-12-30 Union Carbide Corporation Potentiated nickel catalysts for amination

Also Published As

Publication number Publication date
JPS6038380B2 (ja) 1985-08-31
JPS5285991A (en) 1977-07-16
BE850144A (fr) 1977-07-06
FR2337585A1 (fr) 1977-08-05
JPS6241064B2 (enExample) 1987-09-01
DE2700339C3 (de) 1980-06-19
GB1569714A (en) 1980-06-18
US4123462A (en) 1978-10-31
IT1082703B (it) 1985-05-21
NL7700084A (nl) 1977-07-11
JPS56108534A (en) 1981-08-28
CA1083558A (en) 1980-08-12
DE2700339A1 (de) 1977-08-18
IN145670B (enExample) 1978-11-25
FR2337585B1 (enExample) 1983-10-07
US4111840A (en) 1978-09-05
NL180914C (nl) 1987-05-18

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
8327 Change in the person/name/address of the patent owner

Owner name: UNION CARBIDE CORP., 06817 DANBURY, CONN., US

8339 Ceased/non-payment of the annual fee
8328 Change in the person/name/address of the agent

Free format text: BARZ, P., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 80803 MUENCHEN