FR2430262A2 - Catalyseur et procede de fabrication d'amines a partir d'alcools - Google Patents

Catalyseur et procede de fabrication d'amines a partir d'alcools

Info

Publication number
FR2430262A2
FR2430262A2 FR7819875A FR7819875A FR2430262A2 FR 2430262 A2 FR2430262 A2 FR 2430262A2 FR 7819875 A FR7819875 A FR 7819875A FR 7819875 A FR7819875 A FR 7819875A FR 2430262 A2 FR2430262 A2 FR 2430262A2
Authority
FR
France
Prior art keywords
catalyst
piperazine
ethanolamine
metal
esp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7819875A
Other languages
English (en)
Other versions
FR2430262B2 (fr
Inventor
Yannick Le Goff
Michel Senes
Christian Hamon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Azote et Produits Chimiques SA
Original Assignee
Azote et Produits Chimiques SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Azote et Produits Chimiques SA filed Critical Azote et Produits Chimiques SA
Priority to FR7819875A priority Critical patent/FR2430262A2/fr
Priority to DE7878400202T priority patent/DE2860763D1/de
Priority to EP78400202A priority patent/EP0002630B2/fr
Priority to US05/966,736 priority patent/US4209424A/en
Priority to CA317,511A priority patent/CA1106349A/fr
Priority to ES475896A priority patent/ES475896A1/es
Priority to JP15278378A priority patent/JPS5488892A/ja
Publication of FR2430262A2 publication Critical patent/FR2430262A2/fr
Application granted granted Critical
Publication of FR2430262B2 publication Critical patent/FR2430262B2/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Le perfectionnement concerne un catalyseur pour la mise en oeuvre d'un procédé de fabrication d'amines à partir d'alcools. Ce catalyseur selon le brevet principal a une surface spécifique comprise entre 10 et 300 m**2/g; le diamètre des pores étant inférieur à 5 000 Angström. Un stabilisant sous forme d'un composé à base de sodium à une teneur de 0,15 à 20 % exprimée en poids de sodium par rapport au poids du catalyseur, et un promoteur sous forme d'un composé à base de rhodium à une teneur maximale de 0,1 % exprimée en poids de rhodium par rapport au poids du catalyseur, sont associés au métal actif. catalyseur est applicable à la réaction de l'éthanolamine et de l'ammoniac en vue de la production d'éthylène diamine, de pipérazine et de sous-produits intéressants.
FR7819875A 1977-12-12 1978-07-04 Catalyseur et procede de fabrication d'amines a partir d'alcools Granted FR2430262A2 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR7819875A FR2430262A2 (fr) 1978-07-04 1978-07-04 Catalyseur et procede de fabrication d'amines a partir d'alcools
DE7878400202T DE2860763D1 (en) 1977-12-12 1978-12-01 Catalyst and process for the manufacture of amines from alcohols
EP78400202A EP0002630B2 (fr) 1977-12-12 1978-12-01 Catalyseur et procédé de fabrication d'amines à partir d'alcools
US05/966,736 US4209424A (en) 1977-12-12 1978-12-05 Catalyst for manufacturing amines from alcohols
CA317,511A CA1106349A (fr) 1977-12-12 1978-12-06 Catalyseur et procede de fabrication d'amines a partir d'alcools
ES475896A ES475896A1 (es) 1977-12-12 1978-12-11 Un procedimiento de fabricacion de aminas a partir de alco- holes.
JP15278378A JPS5488892A (en) 1977-12-12 1978-12-12 Aminating catalyst and its manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7819875A FR2430262A2 (fr) 1978-07-04 1978-07-04 Catalyseur et procede de fabrication d'amines a partir d'alcools

Publications (2)

Publication Number Publication Date
FR2430262A2 true FR2430262A2 (fr) 1980-02-01
FR2430262B2 FR2430262B2 (fr) 1982-01-22

Family

ID=9210293

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7819875A Granted FR2430262A2 (fr) 1977-12-12 1978-07-04 Catalyseur et procede de fabrication d'amines a partir d'alcools

Country Status (1)

Country Link
FR (1) FR2430262A2 (fr)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2310802A1 (fr) * 1975-05-14 1976-12-10 Exxon Research Engineering Co Composition catalytique au nickel et son procede de fabrication
FR2325427A1 (fr) * 1975-09-29 1977-04-22 British Gas Corp Catalyseur de reformage d'hydrocarbures avec de la vapeur d'eau, et a son application a la production de gaz contenant du methane
FR2337585A1 (fr) * 1976-01-07 1977-08-05 Union Carbide Corp Nouveau catalyseur d'hydrogenation au nickel et au rhenium, sa preparation et ses applications

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2310802A1 (fr) * 1975-05-14 1976-12-10 Exxon Research Engineering Co Composition catalytique au nickel et son procede de fabrication
FR2325427A1 (fr) * 1975-09-29 1977-04-22 British Gas Corp Catalyseur de reformage d'hydrocarbures avec de la vapeur d'eau, et a son application a la production de gaz contenant du methane
FR2337585A1 (fr) * 1976-01-07 1977-08-05 Union Carbide Corp Nouveau catalyseur d'hydrogenation au nickel et au rhenium, sa preparation et ses applications

Also Published As

Publication number Publication date
FR2430262B2 (fr) 1982-01-22

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