ES475896A1 - Un procedimiento de fabricacion de aminas a partir de alco- holes. - Google Patents
Un procedimiento de fabricacion de aminas a partir de alco- holes.Info
- Publication number
- ES475896A1 ES475896A1 ES475896A ES475896A ES475896A1 ES 475896 A1 ES475896 A1 ES 475896A1 ES 475896 A ES475896 A ES 475896A ES 475896 A ES475896 A ES 475896A ES 475896 A1 ES475896 A1 ES 475896A1
- Authority
- ES
- Spain
- Prior art keywords
- degrees
- temperature
- catalyst
- association
- reduction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000001298 alcohols Chemical class 0.000 title 1
- 150000001412 amines Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 229910052723 transition metal Inorganic materials 0.000 abstract 4
- 150000003624 transition metals Chemical class 0.000 abstract 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 238000007669 thermal treatment Methods 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- 239000011149 active material Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000005576 amination reaction Methods 0.000 abstract 1
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 230000000750 progressive effect Effects 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un procedimiento de fabricación de aminas a partir de alcoholes, en el que se obtienen etilendiamina y piperazina por reacción catalítica en fase heterogénea de etanolamina y amoniaco, caracterizado porque la reacción se efectúa en presencia de un catalizador de aminación constituido por un metal activo, de la familia de los metales de transición, cuyo contenido representa el 30 al 70% del peso del catalizador, fijado uniformemente en un edificio poroso refractario de superficie específica comprendida entre 10 y 300 m2/g y de diámetro de poros inferior a 5.000 angstroms.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7737346A FR2411030A1 (fr) | 1977-12-12 | 1977-12-12 | Catalyseur et procede de fabrication d'amines a partir d'alcools |
FR7819875A FR2430262A2 (fr) | 1978-07-04 | 1978-07-04 | Catalyseur et procede de fabrication d'amines a partir d'alcools |
Publications (1)
Publication Number | Publication Date |
---|---|
ES475896A1 true ES475896A1 (es) | 1979-04-16 |
Family
ID=26220337
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES475896A Expired ES475896A1 (es) | 1977-12-12 | 1978-12-11 | Un procedimiento de fabricacion de aminas a partir de alco- holes. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0002630B2 (es) |
JP (1) | JPS5488892A (es) |
CA (1) | CA1106349A (es) |
DE (1) | DE2860763D1 (es) |
ES (1) | ES475896A1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3125662A1 (de) * | 1981-06-30 | 1983-01-13 | Basf Ag, 6700 Ludwigshafen | Verfahren und katalysator zur herstellung von cyclischen iminen |
JPS62149648A (ja) * | 1985-12-25 | 1987-07-03 | Kao Corp | 第2級アミンの製造方法 |
US4973709A (en) * | 1987-12-18 | 1990-11-27 | Union Carbide Chemicals And Plastics Company, Inc. | Process for the production of amines, hydroxyamines and aziridines |
US5120860A (en) * | 1987-12-18 | 1992-06-09 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of aziridines |
US5321160A (en) * | 1991-07-31 | 1994-06-14 | Tosoh Corporation | Process for producing an ethylenamine |
WO2010042157A1 (en) * | 2008-10-06 | 2010-04-15 | Union Carbide Chemicals & Plastics Technology Llc | Low metal loaded, alumina supported, catalyst compositions and amination process |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE381867B (sv) * | 1973-03-07 | 1975-12-22 | Mo Och Domsjoe Ab | Sett att avlegsna vatten fran en blandning av etylendiamin och vatten |
JPS5132601A (en) * | 1974-09-13 | 1976-03-19 | Pioneer Electronic Corp | Cantilever for pickup cartridge |
AU511696B2 (en) * | 1975-05-14 | 1980-09-04 | Exxon Research And Engineering Company | Supported Cuni-Sio2 catalyst for hydrogenation |
GB1525017A (en) * | 1975-09-29 | 1978-09-20 | British Gas Corp | Steam reforming and methanation catalysts methods of making them and processes for the production of fuel gases |
US4123462A (en) * | 1976-01-07 | 1978-10-31 | Union Carbide Corporation | Amination process using nickel-rhenium catalysts |
-
1978
- 1978-12-01 EP EP78400202A patent/EP0002630B2/fr not_active Expired
- 1978-12-01 DE DE7878400202T patent/DE2860763D1/de not_active Expired
- 1978-12-06 CA CA317,511A patent/CA1106349A/fr not_active Expired
- 1978-12-11 ES ES475896A patent/ES475896A1/es not_active Expired
- 1978-12-12 JP JP15278378A patent/JPS5488892A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
EP0002630B1 (fr) | 1981-06-10 |
EP0002630B2 (fr) | 1986-04-16 |
JPS5488892A (en) | 1979-07-14 |
DE2860763D1 (en) | 1981-09-17 |
CA1106349A (fr) | 1981-08-04 |
EP0002630A1 (fr) | 1979-06-27 |
JPS649048B2 (es) | 1989-02-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19971201 |