ES461834A1 - Procedimiento para el reformado catalitico de hidrocarburos. - Google Patents

Procedimiento para el reformado catalitico de hidrocarburos.

Info

Publication number
ES461834A1
ES461834A1 ES461834A ES461834A ES461834A1 ES 461834 A1 ES461834 A1 ES 461834A1 ES 461834 A ES461834 A ES 461834A ES 461834 A ES461834 A ES 461834A ES 461834 A1 ES461834 A1 ES 461834A1
Authority
ES
Spain
Prior art keywords
pore volume
reforming process
catalytic reforming
treated
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES461834A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron Research and Technology Co
Chevron Research Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/716,924 external-priority patent/US4082697A/en
Application filed by Chevron Research and Technology Co, Chevron Research Co filed Critical Chevron Research and Technology Co
Publication of ES461834A1 publication Critical patent/ES461834A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C01B2203/107—Platinum catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Procedimiento para el reformado catalítico de hidrocarburos, caracterizado porque comprende reformar una materia prima de hidrocarburos, en presencia de un catalizador de reformado catalítico que comprende un componente vehículo y un componente catalítico, caracterizado porque dicho componente vehículo comprende fundamentalmente alúmina que tiene: (1) un volumen de poros al menos 0,65 cc/g, (2) un contenido de microporos con un tamaño en la gama de 80 a 150 A de diámetro que constituye al menos el 70% de dicho volumen de poros y (3) un contenido de poros con un diámetro superior a 1000 A que constituye de un 0,1 a un 3% de dicho volumen de poros; siendo dicho componente catalítico por al menos un material seleccionado entre los metales, óxidos y haluros del grupo de elemento formado por el renio, manganeso, germanio, estaño, cinc y titanio; conteniendo dicha composición, sobre base seca y calculado como metal, además de dicha alúmina, una cantidad de un 0,1 a un 3 por ciento en peso aproximadamente del citado metal noble, una cantidad en la misma gama de haluro a una temperatura comprendida entre 316 y 593ºC, preferentemente entre 371 y 566ºC a una presión comprendida entre presión atmosférica y 70,3 atmósferas, preferentemente comprendido entre 3,52 y 52,7 atmósferas, con una correlación entre la temperatura y presión con la velocidad espacial horaria del líquido comprendida entre 0,1 y 10, preferentemente entre 1 y 5, y una relación molar entre el hidrógeno y el hidrocarburo comprendida entre 1 y 10.
ES461834A 1976-08-23 1977-08-23 Procedimiento para el reformado catalitico de hidrocarburos. Expired ES461834A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/716,924 US4082697A (en) 1974-08-12 1976-08-23 Catalyst carrier, its method of preparation and a reforming catalyst supported on the carrier

Publications (1)

Publication Number Publication Date
ES461834A1 true ES461834A1 (es) 1978-12-16

Family

ID=24880011

Family Applications (1)

Application Number Title Priority Date Filing Date
ES461834A Expired ES461834A1 (es) 1976-08-23 1977-08-23 Procedimiento para el reformado catalitico de hidrocarburos.

Country Status (10)

Country Link
US (1) US4129497A (es)
JP (1) JPS585702B2 (es)
AU (1) AU511968B2 (es)
BE (1) BE858011A (es)
CA (1) CA1094533A (es)
DE (1) DE2736996C2 (es)
ES (1) ES461834A1 (es)
FR (1) FR2362916A1 (es)
GB (1) GB1570427A (es)
NL (1) NL179347C (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8334155D0 (en) * 1983-12-22 1984-02-01 Ici Plc Catalytic composition
US5134109A (en) * 1989-07-07 1992-07-28 Idemitsu Kosan Company Limited Catalyst for reforming hydrocarbon with steam
CN1092146C (zh) * 1997-07-15 2002-10-09 日本能源株式会社 催化剂载体用的假勃姆石粉末及其制备方法
US8668824B2 (en) * 2009-12-04 2014-03-11 Exxonmobil Research And Engineering Company Rapid cycle reforming process
EP2841198B1 (en) * 2012-04-26 2023-06-07 Shell Internationale Research Maatschappij B.V. A hydroprocessing catalyst and process for treating heavy hydrocarbon feedstocks

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2973330A (en) * 1957-12-23 1961-02-28 Exxon Research Engineering Co Hydroforming catalyst
US3193348A (en) * 1962-02-19 1965-07-06 Sinclair Research Inc Method of producing boehmite having crystal size in excess of 100 a
US3415737A (en) * 1966-06-24 1968-12-10 Chevron Res Reforming a sulfur-free naphtha with a platinum-rhenium catalyst
FR2076937A5 (es) * 1970-01-30 1971-10-15 Chevron Res
US3846343A (en) * 1970-02-13 1974-11-05 H Erickson Process for preparing a platinum-rhenium catalyst on an alumina support
US3951782A (en) * 1971-04-09 1976-04-20 Chevron Research Company Reforming with a group IIB-containing catalyst
US3743709A (en) * 1971-07-12 1973-07-03 Canadian Patents Dev Preparation of highly porous alumina
BE787953A (fr) * 1971-08-26 1973-02-26 Franc De Comp Procede de regulation de la teneur en halogene des catalyseurs de conversion des hydrocarbures
US3790503A (en) * 1972-03-27 1974-02-05 Universal Oil Prod Co Method of manufacturing a germanium catalyst
US3804781A (en) * 1972-07-28 1974-04-16 American Cyanamid Co Extruded alumina catalyst supports
US4006074A (en) * 1972-09-07 1977-02-01 Atlantic Richfield Company Reforming with a platinum-alumina catalyst
US3977999A (en) * 1972-09-07 1976-08-31 Atlantic Richfield Company Alumina compositions and methods for making and using same
US3884799A (en) * 1972-12-11 1975-05-20 Standard Oil Co Reforming with platinum-rhenium-selenium catalysts
US3900430A (en) * 1973-05-14 1975-08-19 Continental Oil Co Catalytic hydrocarbon conversion process
FR2252394B1 (es) * 1973-11-23 1977-06-10 Raffinage Cie Francaise
US3948804A (en) * 1973-12-10 1976-04-06 Universal Oil Products Company Superactive acidic bimetallic catalytic composite and use thereof in conversion of hydrocarbons
US4008182A (en) * 1973-12-28 1977-02-15 Uop Inc. Low density refractory inorganic oxide particles having high micropore volume
FR2268558A1 (en) * 1974-04-23 1975-11-21 Catalyse Soc Prod Francais Catalysts for hydrocarbon conversion - contg. gp. VIII metal, manganese and germanium, tin or rhenium, on alumina carrier
BE832072A (fr) * 1974-08-12 1975-12-01 Compositions ameliorees pour catalyse et leur procede de preparation
US3972990A (en) * 1975-05-30 1976-08-03 Universal Oil Products Company Method of preparing low density-high micropore volume refractory inorganic oxide particles

Also Published As

Publication number Publication date
NL179347C (nl) 1986-09-01
DE2736996C2 (de) 1986-03-06
AU2815477A (en) 1979-03-01
CA1094533A (en) 1981-01-27
FR2362916A1 (fr) 1978-03-24
NL7709251A (nl) 1978-02-27
BE858011A (fr) 1977-12-16
US4129497A (en) 1978-12-12
JPS5326789A (en) 1978-03-13
DE2736996A1 (de) 1978-03-09
JPS585702B2 (ja) 1983-02-01
NL179347B (nl) 1986-04-01
AU511968B2 (en) 1980-09-18
FR2362916B1 (es) 1982-01-08
GB1570427A (en) 1980-07-02

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