DE2534013C3 - Schlagfeste, thermoplastische Vinylchlorid-Polymer-Formmassen - Google Patents
Schlagfeste, thermoplastische Vinylchlorid-Polymer-FormmassenInfo
- Publication number
- DE2534013C3 DE2534013C3 DE2534013A DE2534013A DE2534013C3 DE 2534013 C3 DE2534013 C3 DE 2534013C3 DE 2534013 A DE2534013 A DE 2534013A DE 2534013 A DE2534013 A DE 2534013A DE 2534013 C3 DE2534013 C3 DE 2534013C3
- Authority
- DE
- Germany
- Prior art keywords
- weight
- parts
- epdm
- graft
- graft polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title claims description 20
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 12
- 150000001875 compounds Chemical class 0.000 title claims description 7
- 238000000465 moulding Methods 0.000 title description 14
- 229920001169 thermoplastic Polymers 0.000 title description 2
- 239000004416 thermosoftening plastic Substances 0.000 title description 2
- 229920000578 graft copolymer Polymers 0.000 claims description 80
- 229920002943 EPDM rubber Polymers 0.000 claims description 56
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 18
- 239000005977 Ethylene Substances 0.000 claims description 18
- 229920001567 vinyl ester resin Polymers 0.000 claims description 17
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 13
- 239000005060 rubber Substances 0.000 claims description 9
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 238000009757 thermoplastic moulding Methods 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 65
- 229920000915 polyvinyl chloride Polymers 0.000 description 65
- 239000000203 mixture Substances 0.000 description 56
- 239000000178 monomer Substances 0.000 description 17
- 229920001577 copolymer Polymers 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 12
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- -1 Ethylene, Propylene, butylene, vinyl Chemical class 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000012969 di-tertiary-butyl peroxide Substances 0.000 description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 241001441571 Hiodontidae Species 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 101100389815 Caenorhabditis elegans eva-1 gene Proteins 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005253 cladding Methods 0.000 description 3
- 238000010559 graft polymerization reaction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000006077 pvc stabilizer Substances 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- OGQVROWWFUXRST-FNORWQNLSA-N (3e)-hepta-1,3-diene Chemical compound CCC\C=C\C=C OGQVROWWFUXRST-FNORWQNLSA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- QTYUSOHYEPOHLV-FNORWQNLSA-N 1,3-Octadiene Chemical compound CCCC\C=C\C=C QTYUSOHYEPOHLV-FNORWQNLSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical class O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- UPUGLJYNCXXUQV-UHFFFAOYSA-N Oxydisulfoton Chemical compound CCOP(=S)(OCC)SCCS(=O)CC UPUGLJYNCXXUQV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- UMGDCJDMYOKAJW-UHFFFAOYSA-N aminothiocarboxamide Natural products NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000006583 body weight regulation Effects 0.000 description 1
- 229940065285 cadmium compound Drugs 0.000 description 1
- 150000001662 cadmium compounds Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 235000013872 montan acid ester Nutrition 0.000 description 1
- 208000030459 obsessive-compulsive personality disease Diseases 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/06—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene-diene terpolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2534013A DE2534013C3 (de) | 1975-07-30 | 1975-07-30 | Schlagfeste, thermoplastische Vinylchlorid-Polymer-Formmassen |
| CH954776A CH606242A5 (enExample) | 1975-07-30 | 1976-07-26 | |
| NL7608378A NL7608378A (nl) | 1975-07-30 | 1976-07-28 | Vormpreparaten op basis van in hoge mate slagvast thermoplastisch vinylchloride- polymeer. |
| BE169298A BE844586A (fr) | 1975-07-30 | 1976-07-28 | Compositions thermoplastiques pour moulage de resilience elevee a base de polymere de chlorure de vinyle |
| IT50633/76A IT1066294B (it) | 1975-07-30 | 1976-07-28 | Composizione da stampaggio termoplastica di polivinilcloruro |
| JP51089260A JPS5217552A (en) | 1975-07-30 | 1976-07-28 | High impact thermoplastic vinyl chloride molding composition |
| AT554576A AT342300B (de) | 1975-07-30 | 1976-07-28 | Schlagfeste, thermoplastische vinylchlorid-polymer-formmassen |
| AU16307/76A AU1630776A (en) | 1975-07-30 | 1976-07-28 | High-impact thermoplastic vinyl chloride polymer moulding compositions |
| ES450267A ES450267A1 (es) | 1975-07-30 | 1976-07-29 | Procedimiento para la obtencion de masas de moldeo termo- pasticas. |
| GB31634/76A GB1508955A (en) | 1975-07-30 | 1976-07-29 | High-impact thermoplastic vinyl chloride polymer moulding compositions |
| FR7623445A FR2319667A1 (fr) | 1975-07-30 | 1976-07-30 | Compositions thermoplastiques pour moulage de resilience elevee a base de polymere de chlorure de vinyle |
| US06/104,183 US4276391A (en) | 1975-07-30 | 1979-12-17 | High-impact thermoplastic vinyl chloride polymer moulding composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2534013A DE2534013C3 (de) | 1975-07-30 | 1975-07-30 | Schlagfeste, thermoplastische Vinylchlorid-Polymer-Formmassen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2534013A1 DE2534013A1 (de) | 1977-02-17 |
| DE2534013B2 DE2534013B2 (de) | 1979-02-01 |
| DE2534013C3 true DE2534013C3 (de) | 1979-10-18 |
Family
ID=5952812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2534013A Expired DE2534013C3 (de) | 1975-07-30 | 1975-07-30 | Schlagfeste, thermoplastische Vinylchlorid-Polymer-Formmassen |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4276391A (enExample) |
| JP (1) | JPS5217552A (enExample) |
| AT (1) | AT342300B (enExample) |
| AU (1) | AU1630776A (enExample) |
| BE (1) | BE844586A (enExample) |
| CH (1) | CH606242A5 (enExample) |
| DE (1) | DE2534013C3 (enExample) |
| ES (1) | ES450267A1 (enExample) |
| FR (1) | FR2319667A1 (enExample) |
| GB (1) | GB1508955A (enExample) |
| IT (1) | IT1066294B (enExample) |
| NL (1) | NL7608378A (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS562154A (en) * | 1979-06-20 | 1981-01-10 | Mitsuboshi Belting Ltd | Manufacture of multirib belt |
| AU7765081A (en) * | 1980-11-20 | 1982-05-27 | Stauffer Chemical Company | Blends of pvc with graft polymers |
| EP0058979B1 (en) * | 1981-02-23 | 1986-11-12 | Sumitomo Naugatuck Co., Ltd. | Thermoplastic resin composition excellent in color development |
| DE3331220A1 (de) * | 1983-08-30 | 1985-03-21 | J.H. Benecke Gmbh, 3000 Hannover | Kunststoffolie auf der basis von polyvinylchlorid-homopolymerisaten und/oder copolymerisaten |
| NL8303140A (nl) * | 1983-09-10 | 1985-04-01 | Stamicarbon | Slagvastheidsverbeteraar op basis van rubber en een werkwijze voor de vervaardiging van een dergelijke slagvastheidsverbeteraar. |
| US4537933A (en) * | 1983-10-12 | 1985-08-27 | Occidental Chemical Corporation | Blends of polyolefin graft polymers and ASA polymers |
| US4808642A (en) * | 1985-04-26 | 1989-02-28 | Takiron Co., Ltd. | Chlorine-containing resin molding and material for use therewith |
| JPS63113060A (ja) * | 1986-06-27 | 1988-05-18 | Shiseido Co Ltd | 真珠光沢を有する樹脂組成物 |
| JPS6395211A (ja) * | 1986-10-09 | 1988-04-26 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物 |
| JPH0669662B2 (ja) * | 1987-11-09 | 1994-09-07 | 三ツ星ベルト株式会社 | 多リブベルトの製造方法および製造装置 |
| JPH069828B2 (ja) * | 1988-08-26 | 1994-02-09 | 三ツ星ベルト株式会社 | 動力伝動用ベルトの製造方法及び該方法に用いる加硫用可撓性ジャケット |
| JPH04151048A (ja) * | 1990-10-09 | 1992-05-25 | Mitsuboshi Belting Ltd | Ｖリブドベルトおよび同ベルトの製造方法 |
| DE4141319A1 (de) * | 1991-12-14 | 1993-10-14 | Roehm Gmbh | Hochschlagzähe Polymermischungen |
| CN104151506A (zh) * | 2014-08-18 | 2014-11-19 | 苏州市盛百威包装设备有限公司 | 一种环十二碳三烯复合包装材料及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2802809A (en) * | 1953-11-30 | 1957-08-13 | Firestone Tire & Rubber Co | Compositions of vinyl chloride resins and graft copolymers of acrylonitrile-type monomer compositions upon diene polymers and articles formed therefrom |
| BE635024A (enExample) * | 1962-08-31 | |||
| DE1203959B (de) * | 1963-05-31 | 1965-10-28 | Hoechst Ag | Verfahren zur Herstellung von modifiziertem, schlagzaehem Vinylchlorid-Polymerisat |
| US3287433A (en) * | 1964-01-15 | 1966-11-22 | Sinclair Research Inc | Process for the separation of mixtures of tertiary butyl chloride and 3, 3-dimethylbutene-1 |
| NL126217C (enExample) * | 1965-08-09 | |||
| US3636138A (en) * | 1968-08-05 | 1972-01-18 | Monsanto Co | Process for impact modification of vinyl halide polymers and impact modifiers and vinyl halide blends produced therewith |
| US3644577A (en) * | 1968-12-11 | 1972-02-22 | Monsanto Co | Vinyl halide polymeric blends |
| JPS4818101B1 (enExample) * | 1969-03-04 | 1973-06-04 | ||
| US3683050A (en) * | 1969-04-24 | 1972-08-08 | Copolymer Rubber & Chem Corp | Process for preparing improved plastic compositions and the resulting products |
| JPS5147039A (en) * | 1974-10-21 | 1976-04-22 | Japan Synthetic Rubber Co Ltd | Taikoseinosugureta netsuseikeikanonashiitozairyo |
-
1975
- 1975-07-30 DE DE2534013A patent/DE2534013C3/de not_active Expired
-
1976
- 1976-07-26 CH CH954776A patent/CH606242A5/xx not_active IP Right Cessation
- 1976-07-28 IT IT50633/76A patent/IT1066294B/it active
- 1976-07-28 BE BE169298A patent/BE844586A/xx unknown
- 1976-07-28 NL NL7608378A patent/NL7608378A/xx unknown
- 1976-07-28 JP JP51089260A patent/JPS5217552A/ja active Pending
- 1976-07-28 AT AT554576A patent/AT342300B/de not_active IP Right Cessation
- 1976-07-28 AU AU16307/76A patent/AU1630776A/en not_active Expired
- 1976-07-29 ES ES450267A patent/ES450267A1/es not_active Expired
- 1976-07-29 GB GB31634/76A patent/GB1508955A/en not_active Expired
- 1976-07-30 FR FR7623445A patent/FR2319667A1/fr active Granted
-
1979
- 1979-12-17 US US06/104,183 patent/US4276391A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5217552A (en) | 1977-02-09 |
| FR2319667B1 (enExample) | 1979-08-31 |
| DE2534013A1 (de) | 1977-02-17 |
| ATA554576A (de) | 1977-07-15 |
| NL7608378A (nl) | 1977-02-01 |
| BE844586A (fr) | 1977-01-28 |
| DE2534013B2 (de) | 1979-02-01 |
| FR2319667A1 (fr) | 1977-02-25 |
| IT1066294B (it) | 1985-03-04 |
| AU1630776A (en) | 1978-02-02 |
| US4276391A (en) | 1981-06-30 |
| GB1508955A (en) | 1978-04-26 |
| CH606242A5 (enExample) | 1978-10-31 |
| ES450267A1 (es) | 1977-09-01 |
| AT342300B (de) | 1978-03-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |