DE2213781C3 - Verfahren zur Phosphatierung von Stahl - Google Patents
Verfahren zur Phosphatierung von StahlInfo
- Publication number
- DE2213781C3 DE2213781C3 DE19722213781 DE2213781A DE2213781C3 DE 2213781 C3 DE2213781 C3 DE 2213781C3 DE 19722213781 DE19722213781 DE 19722213781 DE 2213781 A DE2213781 A DE 2213781A DE 2213781 C3 DE2213781 C3 DE 2213781C3
- Authority
- DE
- Germany
- Prior art keywords
- free
- bath
- manganese
- phosphating
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 17
- 229910000831 Steel Inorganic materials 0.000 title claims description 8
- 239000010959 steel Substances 0.000 title claims description 8
- 239000011572 manganese Substances 0.000 claims description 31
- 239000013589 supplement Substances 0.000 claims description 15
- 239000012141 concentrate Substances 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- AWKHTBXFNVGFRX-UHFFFAOYSA-K iron(2+);manganese(2+);phosphate Chemical compound [Mn+2].[Fe+2].[O-]P([O-])([O-])=O AWKHTBXFNVGFRX-UHFFFAOYSA-K 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 239000010802 sludge Substances 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 238000005554 pickling Methods 0.000 claims description 2
- 239000001205 polyphosphate Substances 0.000 claims description 2
- 235000011176 polyphosphates Nutrition 0.000 claims description 2
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 2
- 230000002411 adverse Effects 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 229940093474 manganese carbonate Drugs 0.000 claims 1
- 235000006748 manganese carbonate Nutrition 0.000 claims 1
- 239000011656 manganese carbonate Substances 0.000 claims 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 claims 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- 239000011435 rock Substances 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 230000001502 supplementing effect Effects 0.000 claims 1
- 229910002651 NO3 Inorganic materials 0.000 description 11
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- -1 ammonium cations Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 1
- 229940012189 methyl orange Drugs 0.000 description 1
- JCYPECIVGRXBMO-FOCLMDBBSA-N methyl yellow Chemical compound C1=CC(N(C)C)=CC=C1\N=N\C1=CC=CC=C1 JCYPECIVGRXBMO-FOCLMDBBSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Removal Of Specific Substances (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE789593D BE789593A (fr) | 1972-03-22 | Procede de phosphatation de l'acier | |
| DE19722213781 DE2213781C3 (de) | 1972-03-22 | 1972-03-22 | Verfahren zur Phosphatierung von Stahl |
| FR7232219A FR2176647B1 (enrdf_load_stackoverflow) | 1972-03-22 | 1972-09-12 | |
| ES407482A ES407482A1 (es) | 1972-03-22 | 1972-10-10 | Procedimient para el fosfato del acero. |
| NL7303791A NL173661C (nl) | 1972-03-22 | 1973-03-19 | Werkwijze voor het fosfateren van staal. |
| CH404273A CH590341A5 (enrdf_load_stackoverflow) | 1972-03-22 | 1973-03-20 | |
| CA167,018A CA980220A (en) | 1972-03-22 | 1973-03-21 | Method for phosphatizing ferrous surfaces |
| IT2190373A IT982575B (it) | 1972-03-22 | 1973-03-21 | Processo per fosfatare l acciato |
| GB1361873A GB1373897A (en) | 1972-03-22 | 1973-03-21 | Processes for phosphating steel |
| SE7303991A SE383537B (sv) | 1972-03-22 | 1973-03-21 | Forfarande for fosfatering av stal med fosfateringslosning baserad pa manganfosfat |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722213781 DE2213781C3 (de) | 1972-03-22 | 1972-03-22 | Verfahren zur Phosphatierung von Stahl |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2213781A1 DE2213781A1 (de) | 1973-09-27 |
| DE2213781B2 DE2213781B2 (de) | 1977-03-17 |
| DE2213781C3 true DE2213781C3 (de) | 1983-12-08 |
Family
ID=5839694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722213781 Expired DE2213781C3 (de) | 1972-03-22 | 1972-03-22 | Verfahren zur Phosphatierung von Stahl |
Country Status (10)
| Country | Link |
|---|---|
| BE (1) | BE789593A (enrdf_load_stackoverflow) |
| CA (1) | CA980220A (enrdf_load_stackoverflow) |
| CH (1) | CH590341A5 (enrdf_load_stackoverflow) |
| DE (1) | DE2213781C3 (enrdf_load_stackoverflow) |
| ES (1) | ES407482A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2176647B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1373897A (enrdf_load_stackoverflow) |
| IT (1) | IT982575B (enrdf_load_stackoverflow) |
| NL (1) | NL173661C (enrdf_load_stackoverflow) |
| SE (1) | SE383537B (enrdf_load_stackoverflow) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2724395B1 (fr) * | 1994-09-12 | 1996-11-22 | Gec Alsthom Transport Sa | Tole magnetique isolee et procede d'isolement de cette tole |
| DE4440300A1 (de) | 1994-11-11 | 1996-05-15 | Metallgesellschaft Ag | Verfahren zum Aufbringen von Phosphatüberzügen |
| US20040221924A1 (en) | 1999-09-30 | 2004-11-11 | Klaus-Dieter Nittel | Method for applying manganese phosphate layers |
| DE202006009624U1 (de) * | 2006-06-19 | 2007-10-31 | Paatz Viernau Gmbh | Verbundstabile Beschichtung |
| US20110165426A1 (en) * | 2008-09-17 | 2011-07-07 | Hoden Seimitsu Kako Kenkyusho Co., Ltd. | Aqueous solution for blackening chemical conversion coating of zinc or zinc alloy surface and method of forming blackened anti-corrosion coating film using the aqueous solution for the chemical conversion coating |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE746470C (de) * | 1935-02-18 | 1944-07-21 | Metallgesellschaft Ag | Verfahren zur Auffrischung zinkphosphathaltiger Rostschutzbaeder |
| FR1073198A (fr) * | 1953-03-23 | 1954-09-20 | Solution pour la protection des métaux ferreux | |
| DE1109484B (de) * | 1956-02-29 | 1961-06-22 | American Chem Paint Co | Manganphosphatueberzuege |
| FR1403267A (fr) * | 1963-07-30 | 1965-06-18 | Parker Ste Continentale | Procédé pour la formation de revêtements de phosphate de manganèse sur le fer et l'acier |
| DE1246356B (de) * | 1963-07-30 | 1967-08-03 | Metallgesellschaft Ag | Verfahren zur Erzeugung von Manganphosphatueberzuegen auf Eisen und Stahl |
| DE1521927B1 (de) * | 1965-01-25 | 1970-07-23 | J Plaut Fa | Verfahrenzur Herstellung von Ueberzügen aus Zinkphosphat auf Gegenständen aus Stahl,Eisen,Zink oder deren Legierungen |
| DE1521889B1 (de) * | 1966-11-30 | 1972-01-13 | Metallgesellschaft Ag | Verfahren zur phosphatierung von eisen und stahl |
-
0
- BE BE789593D patent/BE789593A/xx not_active IP Right Cessation
-
1972
- 1972-03-22 DE DE19722213781 patent/DE2213781C3/de not_active Expired
- 1972-09-12 FR FR7232219A patent/FR2176647B1/fr not_active Expired
- 1972-10-10 ES ES407482A patent/ES407482A1/es not_active Expired
-
1973
- 1973-03-19 NL NL7303791A patent/NL173661C/xx not_active IP Right Cessation
- 1973-03-20 CH CH404273A patent/CH590341A5/xx not_active IP Right Cessation
- 1973-03-21 SE SE7303991A patent/SE383537B/xx unknown
- 1973-03-21 IT IT2190373A patent/IT982575B/it active
- 1973-03-21 GB GB1361873A patent/GB1373897A/en not_active Expired
- 1973-03-21 CA CA167,018A patent/CA980220A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1373897A (en) | 1974-11-13 |
| IT982575B (it) | 1974-10-21 |
| BE789593A (fr) | 1973-02-01 |
| SE383537B (sv) | 1976-03-15 |
| NL173661C (nl) | 1984-02-16 |
| NL173661B (nl) | 1983-09-16 |
| CH590341A5 (enrdf_load_stackoverflow) | 1977-08-15 |
| DE2213781B2 (de) | 1977-03-17 |
| DE2213781A1 (de) | 1973-09-27 |
| FR2176647A1 (enrdf_load_stackoverflow) | 1973-11-02 |
| CA980220A (en) | 1975-12-23 |
| ES407482A1 (es) | 1975-11-01 |
| FR2176647B1 (enrdf_load_stackoverflow) | 1977-06-17 |
| NL7303791A (enrdf_load_stackoverflow) | 1973-09-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8281 | Inventor (new situation) |
Free format text: HANSEN, HANS, DR., 6367 KARBEN, DE HAUFFE, DIETER HEHN, KARL-HEINZ, 6000 FRANKFURT, DE NUSS, KARL-HEINZ, 6078 NEU-ISENBURG, DE RAUSCH, WERNER, DR., 6372 STIERSTADT, DE ROTHKEGEL, JOSEF, 6451 HANAU, DE WIMMERS, PETER, 6000 FRANKFURT, DE |
|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |