DE2213109C2 - - Google Patents
Info
- Publication number
- DE2213109C2 DE2213109C2 DE2213109A DE2213109A DE2213109C2 DE 2213109 C2 DE2213109 C2 DE 2213109C2 DE 2213109 A DE2213109 A DE 2213109A DE 2213109 A DE2213109 A DE 2213109A DE 2213109 C2 DE2213109 C2 DE 2213109C2
- Authority
- DE
- Germany
- Prior art keywords
- zsm
- cation
- product
- crystalline aluminosilicate
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 40
- 239000003054 catalyst Substances 0.000 claims description 37
- 239000010457 zeolite Substances 0.000 claims description 35
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 29
- 150000001768 cations Chemical class 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- -1 alkali metal cation Chemical class 0.000 claims description 22
- 238000002441 X-ray diffraction Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 229910021536 Zeolite Inorganic materials 0.000 claims description 19
- 239000000377 silicon dioxide Substances 0.000 claims description 19
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 18
- 235000012239 silicon dioxide Nutrition 0.000 claims description 16
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 14
- 229910052681 coesite Inorganic materials 0.000 claims description 13
- 229910052593 corundum Inorganic materials 0.000 claims description 13
- 229910052906 cristobalite Inorganic materials 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 229910052682 stishovite Inorganic materials 0.000 claims description 13
- 229910052905 tridymite Inorganic materials 0.000 claims description 13
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 239000011541 reaction mixture Substances 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000013078 crystal Substances 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 238000005336 cracking Methods 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 4
- 238000010586 diagram Methods 0.000 claims description 4
- 150000002500 ions Chemical group 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 239000000047 product Substances 0.000 description 42
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000000463 material Substances 0.000 description 15
- 238000001179 sorption measurement Methods 0.000 description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 238000005342 ion exchange Methods 0.000 description 10
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 229910052697 platinum Inorganic materials 0.000 description 7
- 229910001388 sodium aluminate Inorganic materials 0.000 description 7
- 239000012265 solid product Substances 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000005984 hydrogenation reaction Methods 0.000 description 5
- 238000006317 isomerization reaction Methods 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000000571 coke Substances 0.000 description 4
- 239000008119 colloidal silica Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229940100198 alkylating agent Drugs 0.000 description 3
- 239000002168 alkylating agent Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 3
- 229940008406 diethyl sulfate Drugs 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229940078552 o-xylene Drugs 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 2
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- IUHFWCGCSVTMPG-UHFFFAOYSA-N [C].[C] Chemical class [C].[C] IUHFWCGCSVTMPG-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- KFOLLPUZRCFERL-UHFFFAOYSA-N [O-2].[Mg+2].O=[Si]=O Chemical compound [O-2].[Mg+2].O=[Si]=O KFOLLPUZRCFERL-UHFFFAOYSA-N 0.000 description 1
- HHUIAYDQMNHELC-UHFFFAOYSA-N [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O HHUIAYDQMNHELC-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical group O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229940045985 antineoplastic platinum compound Drugs 0.000 description 1
- 238000005899 aromatization reaction Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229910001649 dickite Inorganic materials 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AZRCNKIZGKJWOA-UHFFFAOYSA-N dioxosilane oxygen(2-) zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4].O=[Si]=O AZRCNKIZGKJWOA-UHFFFAOYSA-N 0.000 description 1
- TVUBDAUPRIFHFN-UHFFFAOYSA-N dioxosilane;oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4].O=[Si]=O TVUBDAUPRIFHFN-UHFFFAOYSA-N 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- XEJKBIHOIJUJFQ-UHFFFAOYSA-N ethyl sulfate triethylazanium Chemical compound CCOS([O-])(=O)=O.CC[NH+](CC)CC XEJKBIHOIJUJFQ-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007863 gel particle Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910001387 inorganic aluminate Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- OJLGDNQSVQHXJH-UHFFFAOYSA-N magnesium dioxosilane oxygen(2-) zirconium(4+) Chemical compound [O-2].[Zr+4].[Mg+2].[Si](=O)=O.[O-2].[O-2] OJLGDNQSVQHXJH-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000005172 methylbenzenes Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/42—Type ZSM-12
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
- C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
- C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/33—MTW, e.g. ZSM-12, NU-13, CZH-5, TPZ-3
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00125749A US3832449A (en) | 1971-03-18 | 1971-03-18 | Crystalline zeolite zsm{14 12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2213109A1 DE2213109A1 (de) | 1972-09-21 |
| DE2213109C2 true DE2213109C2 (en:Method) | 1987-08-20 |
Family
ID=22421226
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722213109 Granted DE2213109A1 (de) | 1971-03-18 | 1972-03-17 | Kristalline Zeolithe und Verfahren zu ihrer Herstellung |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3832449A (en:Method) |
| JP (1) | JPS5216079B1 (en:Method) |
| AU (1) | AU458708B2 (en:Method) |
| CA (1) | CA984366A (en:Method) |
| DE (1) | DE2213109A1 (en:Method) |
| FR (1) | FR2130429B1 (en:Method) |
| GB (1) | GB1365317A (en:Method) |
| IT (1) | IT946386B (en:Method) |
| NL (1) | NL173736C (en:Method) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10314753A1 (de) * | 2003-04-01 | 2004-10-14 | Süd-Chemie AG | Synthetischer Zeolith, insbesondere für die katalytische Hydroisomerisierung von höheren Paraffinen |
Families Citing this family (435)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3950496A (en) * | 1973-05-29 | 1976-04-13 | Mobil Oil Corporation | Synthetic zeolite ZSM-18 |
| US3968024A (en) * | 1973-07-06 | 1976-07-06 | Mobil Oil Corporation | Catalytic hydrodewaxing |
| US3894939A (en) * | 1973-08-24 | 1975-07-15 | Mobil Oil Corp | Production of low pour point gas oil and high octane number gasoline |
| US4016245A (en) * | 1973-09-04 | 1977-04-05 | Mobil Oil Corporation | Crystalline zeolite and method of preparing same |
| CA1040187A (en) * | 1973-09-07 | 1978-10-10 | Mobil Oil Corporation | Method of preparing a crystalline aluminosilicate zeolite |
| CA1051463A (en) * | 1974-01-07 | 1979-03-27 | Mobil Oil Corporation | Disproportionation of toluene |
| CA1062285A (en) * | 1974-04-24 | 1979-09-11 | Mobil Oil Corporation | Conversion of synthesis gas to hydrocarbon mixtures |
| US3972983A (en) * | 1974-11-25 | 1976-08-03 | Mobil Oil Corporation | Crystalline zeolite ZSM-20 and method of preparing same |
| US3928174A (en) * | 1975-01-02 | 1975-12-23 | Mobil Oil Corp | Combination process for producing LPG and aromatic rich material from naphtha |
| US3980550A (en) * | 1975-01-09 | 1976-09-14 | Mobil Oil Corporation | Catalytic hydrodewaxing |
| US4016218A (en) * | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
| US4056575A (en) * | 1975-06-05 | 1977-11-01 | The British Petroleum Company Limited | Chemical process making aromatic hydrocarbons over gallium catalyst |
| CA1064890A (en) * | 1975-06-10 | 1979-10-23 | Mae K. Rubin | Crystalline zeolite, synthesis and use thereof |
| NZ183608A (en) * | 1976-03-31 | 1978-12-18 | Mobil Oil Corp | Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes |
| USRE31781E (en) * | 1976-05-07 | 1984-12-25 | Mobil Oil Corporation | Isomerization of monocyclic alkyl aromatic hydrocarbons |
| US4100214A (en) * | 1976-05-07 | 1978-07-11 | Mobil Oil Corporation | Isomerization of monocyclic alkyl aromatic hydrocarbons |
| US4104151A (en) * | 1976-11-08 | 1978-08-01 | Mobil Oil Corporation | Organic compound conversion over ZSM-23 |
| RO64554A2 (ro) * | 1976-12-07 | 1980-01-15 | Institutul De Inginerie Tehnologica Si Proiectare Pentru Industria Chimica,Ro | Procedeu catalitic de obtinere a olefinelor si diolefinelor inferioare prin piroliza hidrocarburilor |
| GB1561590A (en) * | 1976-12-20 | 1980-02-27 | British Petroleum Co | Zeolites containing gallium |
| US4101596A (en) * | 1977-01-10 | 1978-07-18 | Mobil Oil Company | Low pressure xylene isomerization |
| US4375458A (en) * | 1977-08-17 | 1983-03-01 | Mobil Oil Corporation | Synthesis of large crystallite zeolites |
| US4296083A (en) * | 1977-04-22 | 1981-10-20 | Mobil Oil Corporation | Zeolite synthesis |
| US4146584A (en) * | 1977-04-22 | 1979-03-27 | Mobil Oil Corporation | Catalytic conversion with zsm-35 |
| NZ186957A (en) * | 1977-04-22 | 1979-10-25 | Mobil Oil Corp | Synthesis of crystalline aluminosilicate zeolite and catalytic conversion of organic compounds |
| US4112056A (en) * | 1977-05-02 | 1978-09-05 | Mobil Oil Corporation | Preparation of zeolites |
| US4152363A (en) * | 1977-05-09 | 1979-05-01 | Mobil Oil Corporation | Vapor phase isomerization of methyl-substituted aromatic hydrocarbons improved by using highly diluted zeolite catalyst |
| US4083889A (en) * | 1977-05-26 | 1978-04-11 | Mobil Oil Corporation | Process for manufacturing ethylene |
| US4083888A (en) * | 1977-05-26 | 1978-04-11 | Mobil Oil Corporation | Process for manufacturing ethylene |
| US4269813A (en) * | 1977-09-26 | 1981-05-26 | Standard Oil Company (Indiana) | Crystalline borosilicate and process of preparation |
| US4209499A (en) * | 1977-10-21 | 1980-06-24 | Mobil Oil Corporation | Crystalline zeolite ZSM-43 synthesis thereof |
| CA1113508A (en) * | 1978-05-05 | 1981-12-01 | Clarence D. Chang | Conversion of synthesis gas to aromatic hydrocarbons |
| US4214107A (en) * | 1978-06-26 | 1980-07-22 | Mobil Oil Corporation | Hydration of olefins using zeolite catalysts |
| US4393262A (en) * | 1978-12-14 | 1983-07-12 | Mobil Oil Corporation | Production of isopropylbenzene |
| US4291185A (en) * | 1978-12-14 | 1981-09-22 | Mobil Oil Corporation | Alkylation of benzene in petroleum |
| CA1139731A (en) * | 1979-01-15 | 1983-01-18 | Mae K. Rubin | Zsm-12 composition method of preparing same and catalytic conversion therewith |
| US4205053A (en) * | 1979-02-01 | 1980-05-27 | Mobil Oil Corporation | Manufacture of nitrogenous zeolites |
| US4247416A (en) * | 1979-02-28 | 1981-01-27 | Mobil Oil Corporation | Crystalline zeolite ZSM-25 |
| DE3060988D1 (en) * | 1979-03-21 | 1982-12-02 | Mobil Oil Corp | Method for preparing zeolite zsm12 and zeolite prepared by this method |
| US4452769A (en) * | 1979-03-21 | 1984-06-05 | Mobil Oil Corporation | Method of preparing crystalline zeolite |
| US4537758A (en) * | 1979-03-21 | 1985-08-27 | Mobil Oil Corporation | Process for preparing highly siliceous porous ZSM-12 type crystalline material |
| US4397827A (en) * | 1979-07-12 | 1983-08-09 | Mobil Oil Corporation | Silico-crystal method of preparing same and catalytic conversion therewith |
| US4260839A (en) * | 1979-07-16 | 1981-04-07 | Mobil Oil Corporation | Ethane conversion process |
| US4423021A (en) * | 1979-08-08 | 1983-12-27 | Mobil Oil Corporation | Method of preparing silico-crystal ZSM-48 |
| US4405502A (en) * | 1979-08-23 | 1983-09-20 | Standard Oil Company (Indiana) | Crystalline chromosilicate catalytic compositions |
| US4405504A (en) * | 1979-08-23 | 1983-09-20 | Standard Oil Company (Indiana) | Catalytic compositions |
| US4740651A (en) * | 1979-08-23 | 1988-04-26 | Amoco Corporation | Catalytic compositions and process uses |
| DE3061785D1 (en) * | 1979-08-30 | 1983-03-03 | Mobil Oil Corp | A method for producing olefins and/or ethers of high octane number |
| US4287166A (en) * | 1979-10-15 | 1981-09-01 | Mobil Oil Corporation | Zeolite ZSM-39 |
| US4263126A (en) * | 1979-10-22 | 1981-04-21 | Mobil Oil Corporation | Preparation and use of reactive dispersions |
| US4247728A (en) * | 1979-11-08 | 1981-01-27 | Mobil Oil Corporation | Crystalline zeolite, synthesis and use thereof |
| US4283573A (en) * | 1979-11-20 | 1981-08-11 | Mobil Oil Corporation | Long-chain alkylphenols |
| US4255600A (en) * | 1979-12-05 | 1981-03-10 | Mobil Oil Corporation | ZSM-12 Cycloolefin dimerization |
| US4284529A (en) * | 1979-12-14 | 1981-08-18 | Mobil Oil Corporation | Hydrocarbon conversion catalyst |
| US4439536A (en) * | 1980-04-11 | 1984-03-27 | Phillips Petroleum Company | Hydrocarbon cracking catalyst |
| US4386015A (en) * | 1980-04-11 | 1983-05-31 | Phillips Petroleum Company | Hydrocarbon cracking zeolitic catalyst |
| US4334979A (en) * | 1980-04-11 | 1982-06-15 | Phillips Petroleum Company | Hydrocarbon cracking process using a catalyst containing germanium |
| US4357233A (en) * | 1980-06-06 | 1982-11-02 | Mobil Oil Corporation | Catalytic conversion with zeolite ZSM-39 |
| NZ197291A (en) * | 1980-06-12 | 1984-10-19 | Ici Ltd | Zeolite eu-2,useful in catalytic processes,especially convversion of methanol to hydrocarbons |
| EP0042226B1 (en) * | 1980-06-12 | 1984-08-08 | Imperial Chemical Industries Plc | Zeolite eu-1 |
| EP0055046B1 (en) * | 1980-12-19 | 1984-11-07 | Imperial Chemical Industries Plc | Zeolites |
| US4377503A (en) * | 1980-12-29 | 1983-03-22 | Mobil Oil Corporation | Shape selective metallic catalysis |
| US4368174A (en) * | 1980-12-29 | 1983-01-11 | Mobil Oil Corporation | Apparatus for a continuous down-flow zeolite production |
| US4359421A (en) * | 1981-01-15 | 1982-11-16 | Mobil Oil Corporation | Process for making epsilon-caprolactam |
| US4420561A (en) * | 1981-02-02 | 1983-12-13 | Mobil Oil Corporation | Fermentation process |
| BR8200670A (pt) * | 1981-02-09 | 1982-12-14 | Mobil Oil Corp | Processo para sintetizar uma zeolita |
| EP0059059B2 (en) * | 1981-02-23 | 1990-04-18 | Imperial Chemical Industries Plc | Zeolites |
| DE3274844D1 (en) * | 1981-04-14 | 1987-02-05 | Ici Plc | Zeolites |
| US4419218A (en) * | 1981-07-08 | 1983-12-06 | Mobil Oil Corporation | Catalytic conversion of shale oil |
| US4454365A (en) * | 1981-07-09 | 1984-06-12 | Standard Oil Company (Indiana) | Hydrocarbon conversion with a crystalline chromosilicate catalyst |
| US4391785A (en) * | 1981-12-21 | 1983-07-05 | Mobil Oil Corporation | Preparation of ZSM-12 type zeolites |
| US4452958A (en) * | 1981-12-30 | 1984-06-05 | Mobil Oil Corporation | Olefin polymerization with catalysts derived from chromium exchanged zeolites |
| JPS58145616A (ja) * | 1982-02-22 | 1983-08-30 | Teijin Yuka Kk | 新規結晶性アルミノシリケ−トゼオライト及びその製造法 |
| US4521297A (en) * | 1982-02-22 | 1985-06-04 | Mobil Oil Corporation | Catalytic conversion of shale oil |
| AU559968B2 (en) | 1982-04-29 | 1987-03-26 | Mobil Oil Corp. | Controlled morphology high silica zeolites |
| US4490568A (en) * | 1982-04-30 | 1984-12-25 | Union Carbide Corporation | Conversion of certain hydrocarbons using calcined TEA-silicate catalyst |
| US4902406A (en) * | 1982-04-30 | 1990-02-20 | Mobil Oil Corporation | Synthesis of zeolite ZSM-22 |
| NL8202992A (nl) * | 1982-07-26 | 1984-02-16 | Shell Int Research | Werkwijze voor het ontparaffineren van koolwaterstofolien. |
| CA1209981A (en) * | 1982-09-04 | 1986-08-19 | Dennis Young | Crystalline gallosilicates, a process for producing them and their use as catalysts |
| US4452909A (en) * | 1982-09-13 | 1984-06-05 | E. I. Du Pont De Nemours And Company | Process for coating crystalline silica polymorphs |
| US4508837A (en) * | 1982-09-28 | 1985-04-02 | Chevron Research Company | Zeolite SSZ-16 |
| US4568654A (en) * | 1982-11-03 | 1986-02-04 | Mobil Oil Corporation | Zeolite ZSM-51 composition |
| US4912281A (en) * | 1982-12-15 | 1990-03-27 | Mobil Oil Corporation | Conversion of methanol and methyl ether to light olefins with ZSM-45 in presence of hydrogen |
| DE3368595D1 (en) * | 1982-12-15 | 1987-02-05 | Mobil Oil Corp | Conversion of methanol and methyl ether to light olefins |
| EP0116732A1 (en) * | 1983-02-10 | 1984-08-29 | Mobil Oil Corporation | Shape selective metallic catalysis |
| AU2455484A (en) * | 1983-02-11 | 1984-08-16 | Broken Hill Proprietary Company Limited, The | Diesel fuel production from olefins |
| US4675460A (en) * | 1983-02-11 | 1987-06-23 | The Broken Hill Propietary Company Limited | Process |
| US4474896A (en) * | 1983-03-31 | 1984-10-02 | Union Carbide Corporation | Adsorbent compositions |
| US4557919A (en) * | 1983-04-12 | 1985-12-10 | Teijin Petrochemical Industries Ltd. | Production of crystalline zeolites |
| US4482531A (en) * | 1983-04-29 | 1984-11-13 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
| US4559213A (en) * | 1983-04-29 | 1985-12-17 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
| US4490566A (en) * | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
| US4490565A (en) * | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
| US4507512A (en) * | 1983-05-31 | 1985-03-26 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for hydration of olefins |
| AU572518B2 (en) * | 1983-06-30 | 1988-05-12 | Mobil Oil Corp. | Low sodium porous crystalline zeolite |
| CA1209121A (en) * | 1983-07-12 | 1986-08-05 | Guenter H. Kuehl | Preparation of zeolite zsm-12 |
| AU570258B2 (en) * | 1983-08-29 | 1988-03-10 | Mobil Oil Corp. | Tailoring acid strength of zsm-12 |
| US4554146A (en) * | 1983-11-10 | 1985-11-19 | Exxon Research And Engineering Co. | Process for preparing a zeolite of the L type using organic templates |
| US4495303A (en) * | 1983-11-29 | 1985-01-22 | Mobil Oil Corporation | Process for making zeolite ZSM-45 with a dimethyldiethylammonium directing agent |
| US4552739A (en) * | 1983-12-09 | 1985-11-12 | Mobil Oil Corporation | Method of preparing crystalline zeolite ZSM-12 and product |
| US4736054A (en) * | 1983-12-27 | 1988-04-05 | The Standard Oil Company | Ammoxidation of paraffins to acrylonitrile in the presence of zeolite catalysts |
| AU581637B2 (en) * | 1984-01-04 | 1989-03-02 | Mobil Oil Corporation | Production of para-diisopropylbenzene and production of hydroquinone |
| US4585639A (en) * | 1984-04-16 | 1986-04-29 | Mobil Oil Corporation | Preparation of crystalline silicate ZSM-12 |
| US4539193A (en) * | 1984-05-23 | 1985-09-03 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
| US4552738A (en) * | 1984-05-25 | 1985-11-12 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
| US4585637A (en) * | 1984-06-26 | 1986-04-29 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
| CA1239385A (en) * | 1984-06-26 | 1988-07-19 | Mae K. Rubin | Preparation of zeolite zsm-12 |
| US4557921A (en) * | 1984-06-27 | 1985-12-10 | Ethyl Corporation | Purification of halide |
| US4585746A (en) * | 1984-06-27 | 1986-04-29 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
| GB8423615D0 (en) * | 1984-09-18 | 1984-10-24 | Shell Int Research | Preparation of composite crystalline aluminium silicates |
| US4696732A (en) * | 1984-10-29 | 1987-09-29 | Mobil Oil Corporation | Simultaneous hydrotreating and dewaxing of petroleum feedstocks |
| US4701313A (en) * | 1984-12-19 | 1987-10-20 | Mobil Oil Corporation | Replacing boron with silicon in zeolite beta using SiCl4 |
| US4547618A (en) * | 1984-12-28 | 1985-10-15 | Mobil Oil Corporation | Modified ZSM-12 catalysts and processes for conversion of propane to propylene |
| US5064865A (en) * | 1985-07-01 | 1991-11-12 | Quantum Chemical Corporation | Crystalline aluminosilicate compositions, the preparation thereof and their use in the conversion of synthesis gas to low molecular weight hydrocarbons |
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Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3306922A (en) * | 1961-03-22 | 1967-02-28 | Union Carbide Corp | Molecular sieve adsorbents |
| US3308069A (en) * | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
| GB1161974A (en) * | 1967-04-14 | 1969-08-20 | Mobil Oil Corp | Synthetic Crystalline Aluminosilicate and method of preparing the same |
| US3578398A (en) * | 1968-04-01 | 1971-05-11 | Mobil Oil Corp | Synthetic crystalline zeolite and preparation thereof |
| US3692470A (en) * | 1969-10-09 | 1972-09-19 | Mobil Oil Corp | Crystalline zeolite zsm-10 |
| US3702886A (en) * | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| US3700585A (en) * | 1969-10-10 | 1972-10-24 | Mobil Oil Corp | Dewaxing of oils by shape selective cracking and hydrocracking over zeolites zsm-5 and zsm-8 |
| US3709979A (en) * | 1970-04-23 | 1973-01-09 | Mobil Oil Corp | Crystalline zeolite zsm-11 |
-
1971
- 1971-03-18 US US00125749A patent/US3832449A/en not_active Expired - Lifetime
- 1971-11-15 CA CA127,638A patent/CA984366A/en not_active Expired
- 1971-11-17 GB GB5336671A patent/GB1365317A/en not_active Expired
-
1972
- 1972-01-07 IT IT19141/72A patent/IT946386B/it active
- 1972-01-10 AU AU37769/72A patent/AU458708B2/en not_active Expired
- 1972-01-18 JP JP47007217A patent/JPS5216079B1/ja active Pending
- 1972-03-17 FR FR7209536A patent/FR2130429B1/fr not_active Expired
- 1972-03-17 NL NLAANVRAGE7203645,A patent/NL173736C/xx not_active IP Right Cessation
- 1972-03-17 DE DE19722213109 patent/DE2213109A1/de active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10314753A1 (de) * | 2003-04-01 | 2004-10-14 | Süd-Chemie AG | Synthetischer Zeolith, insbesondere für die katalytische Hydroisomerisierung von höheren Paraffinen |
Also Published As
| Publication number | Publication date |
|---|---|
| IT946386B (it) | 1973-05-21 |
| AU458708B2 (en) | 1975-03-06 |
| GB1365317A (en) | 1974-08-29 |
| FR2130429B1 (en:Method) | 1974-09-13 |
| NL173736C (nl) | 1984-03-01 |
| CA984366A (en) | 1976-02-24 |
| DE2213109A1 (de) | 1972-09-21 |
| JPS5216079B1 (en:Method) | 1977-05-06 |
| NL7203645A (en:Method) | 1972-09-20 |
| FR2130429A1 (en:Method) | 1972-11-03 |
| US3832449A (en) | 1974-08-27 |
| AU3776972A (en) | 1973-07-12 |
| NL173736B (nl) | 1983-10-03 |
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