DE2213109A1 - Kristalline Zeolithe und Verfahren zu ihrer Herstellung - Google Patents

Kristalline Zeolithe und Verfahren zu ihrer Herstellung

Info

Publication number
DE2213109A1
DE2213109A1 DE19722213109 DE2213109A DE2213109A1 DE 2213109 A1 DE2213109 A1 DE 2213109A1 DE 19722213109 DE19722213109 DE 19722213109 DE 2213109 A DE2213109 A DE 2213109A DE 2213109 A1 DE2213109 A1 DE 2213109A1
Authority
DE
Germany
Prior art keywords
zeolite
mixture
zsm
product
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19722213109
Other languages
German (de)
English (en)
Other versions
DE2213109C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html
Inventor
Edward Joseph Deptford N.J.; Rubin Mae Koenig BaIa Cynwyd Pa.; Rosinski (V.StA.)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AS
Original Assignee
Mobil Oil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil AS filed Critical Mobil Oil AS
Publication of DE2213109A1 publication Critical patent/DE2213109A1/de
Application granted granted Critical
Publication of DE2213109C2 publication Critical patent/DE2213109C2/de
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/42—Type ZSM-12
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/33—MTW, e.g. ZSM-12, NU-13, CZH-5, TPZ-3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE19722213109 1971-03-18 1972-03-17 Kristalline Zeolithe und Verfahren zu ihrer Herstellung Granted DE2213109A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00125749A US3832449A (en) 1971-03-18 1971-03-18 Crystalline zeolite zsm{14 12

Publications (2)

Publication Number Publication Date
DE2213109A1 true DE2213109A1 (de) 1972-09-21
DE2213109C2 DE2213109C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1987-08-20

Family

ID=22421226

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19722213109 Granted DE2213109A1 (de) 1971-03-18 1972-03-17 Kristalline Zeolithe und Verfahren zu ihrer Herstellung

Country Status (9)

Country Link
US (1) US3832449A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JPS5216079B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU458708B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA984366A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE2213109A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
FR (1) FR2130429B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
GB (1) GB1365317A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IT (1) IT946386B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NL (1) NL173736C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2442240A1 (de) * 1973-09-07 1975-03-13 Mobil Oil Corp Verfahren zur herstellung eines kristallinen aluminosilicatzeolithen
DE2460539A1 (de) * 1974-01-07 1975-07-17 Mobil Oil Corp Verfahren zur disproportionierung von toluol
DE2518097A1 (de) * 1974-04-24 1975-11-13 Mobil Oil Corp Verfahren zur herstellung von kohlenwasserstoffen
DE2624097A1 (de) * 1975-05-29 1976-12-09 Mobil Oil Corp Verfahren zur alkylierung von aromatischen kohlenwasserstoffen
DE2714239A1 (de) * 1976-03-31 1977-10-20 Mobil Oil Corp Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung
DE2753867A1 (de) * 1977-01-10 1978-07-13 Mobil Oil Corp Verfahren zur dampfphasen-isomerisierung von xylol
DE2819304A1 (de) * 1977-05-09 1978-11-23 Mobil Oil Corp Verfahren zum katalytischen isomerisieren monocyclischen methylsubstituierten aromatischen kohlenwasserstoff-ausgangsmaterials
DE2912067A1 (de) * 1978-05-05 1979-11-15 Mobil Oil Corp Verfahren zur umwandlung von synthesegas in kohlenwasserstoffgemische
EP0013630A1 (en) * 1979-01-15 1980-07-23 Mobil Oil Corporation ZSM-12 zeolite composition, method of preparing same and catalytic conversion therewith
EP0059059A1 (en) * 1981-02-23 1982-09-01 Imperial Chemical Industries Plc Zeolites
EP0135621A1 (en) * 1983-07-12 1985-04-03 Mobil Oil Corporation Preparation of zeolite ZSM-12
US4537758A (en) * 1979-03-21 1985-08-27 Mobil Oil Corporation Process for preparing highly siliceous porous ZSM-12 type crystalline material
DE3723104A1 (de) * 1987-07-13 1989-01-26 Ruetgerswerke Ag Verfahren zur selektiven herstellung von 2-methylnaphthalin

Families Citing this family (423)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3950496A (en) * 1973-05-29 1976-04-13 Mobil Oil Corporation Synthetic zeolite ZSM-18
US3968024A (en) * 1973-07-06 1976-07-06 Mobil Oil Corporation Catalytic hydrodewaxing
US3894939A (en) * 1973-08-24 1975-07-15 Mobil Oil Corp Production of low pour point gas oil and high octane number gasoline
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
US3972983A (en) * 1974-11-25 1976-08-03 Mobil Oil Corporation Crystalline zeolite ZSM-20 and method of preparing same
US3928174A (en) * 1975-01-02 1975-12-23 Mobil Oil Corp Combination process for producing LPG and aromatic rich material from naphtha
US3980550A (en) * 1975-01-09 1976-09-14 Mobil Oil Corporation Catalytic hydrodewaxing
US4056575A (en) * 1975-06-05 1977-11-01 The British Petroleum Company Limited Chemical process making aromatic hydrocarbons over gallium catalyst
CA1064890A (en) * 1975-06-10 1979-10-23 Mae K. Rubin Crystalline zeolite, synthesis and use thereof
USRE31781E (en) * 1976-05-07 1984-12-25 Mobil Oil Corporation Isomerization of monocyclic alkyl aromatic hydrocarbons
US4100214A (en) * 1976-05-07 1978-07-11 Mobil Oil Corporation Isomerization of monocyclic alkyl aromatic hydrocarbons
US4104151A (en) * 1976-11-08 1978-08-01 Mobil Oil Corporation Organic compound conversion over ZSM-23
RO64554A2 (ro) * 1976-12-07 1980-01-15 Institutul De Inginerie Tehnologica Si Proiectare Pentru Industria Chimica,Ro Procedeu catalitic de obtinere a olefinelor si diolefinelor inferioare prin piroliza hidrocarburilor
GB1561590A (en) * 1976-12-20 1980-02-27 British Petroleum Co Zeolites containing gallium
US4375458A (en) * 1977-08-17 1983-03-01 Mobil Oil Corporation Synthesis of large crystallite zeolites
US4296083A (en) * 1977-04-22 1981-10-20 Mobil Oil Corporation Zeolite synthesis
US4146584A (en) * 1977-04-22 1979-03-27 Mobil Oil Corporation Catalytic conversion with zsm-35
NZ186957A (en) * 1977-04-22 1979-10-25 Mobil Oil Corp Synthesis of crystalline aluminosilicate zeolite and catalytic conversion of organic compounds
US4112056A (en) * 1977-05-02 1978-09-05 Mobil Oil Corporation Preparation of zeolites
US4083888A (en) * 1977-05-26 1978-04-11 Mobil Oil Corporation Process for manufacturing ethylene
US4083889A (en) * 1977-05-26 1978-04-11 Mobil Oil Corporation Process for manufacturing ethylene
US4269813A (en) * 1977-09-26 1981-05-26 Standard Oil Company (Indiana) Crystalline borosilicate and process of preparation
US4209499A (en) * 1977-10-21 1980-06-24 Mobil Oil Corporation Crystalline zeolite ZSM-43 synthesis thereof
US4214107A (en) * 1978-06-26 1980-07-22 Mobil Oil Corporation Hydration of olefins using zeolite catalysts
US4393262A (en) * 1978-12-14 1983-07-12 Mobil Oil Corporation Production of isopropylbenzene
US4291185A (en) * 1978-12-14 1981-09-22 Mobil Oil Corporation Alkylation of benzene in petroleum
US4205053A (en) * 1979-02-01 1980-05-27 Mobil Oil Corporation Manufacture of nitrogenous zeolites
US4247416A (en) * 1979-02-28 1981-01-27 Mobil Oil Corporation Crystalline zeolite ZSM-25
EP0018089B1 (en) * 1979-03-21 1982-10-27 Mobil Oil Corporation Method for preparing zeolite zsm12 and zeolite prepared by this method
US4452769A (en) * 1979-03-21 1984-06-05 Mobil Oil Corporation Method of preparing crystalline zeolite
US4397827A (en) * 1979-07-12 1983-08-09 Mobil Oil Corporation Silico-crystal method of preparing same and catalytic conversion therewith
US4260839A (en) * 1979-07-16 1981-04-07 Mobil Oil Corporation Ethane conversion process
US4423021A (en) * 1979-08-08 1983-12-27 Mobil Oil Corporation Method of preparing silico-crystal ZSM-48
US4740651A (en) * 1979-08-23 1988-04-26 Amoco Corporation Catalytic compositions and process uses
US4405504A (en) * 1979-08-23 1983-09-20 Standard Oil Company (Indiana) Catalytic compositions
US4405502A (en) * 1979-08-23 1983-09-20 Standard Oil Company (Indiana) Crystalline chromosilicate catalytic compositions
EP0026041B1 (en) * 1979-08-30 1983-01-26 Mobil Oil Corporation A method for producing olefins and/or ethers of high octane number
US4287166A (en) * 1979-10-15 1981-09-01 Mobil Oil Corporation Zeolite ZSM-39
US4263126A (en) * 1979-10-22 1981-04-21 Mobil Oil Corporation Preparation and use of reactive dispersions
US4247728A (en) * 1979-11-08 1981-01-27 Mobil Oil Corporation Crystalline zeolite, synthesis and use thereof
US4283573A (en) * 1979-11-20 1981-08-11 Mobil Oil Corporation Long-chain alkylphenols
US4255600A (en) * 1979-12-05 1981-03-10 Mobil Oil Corporation ZSM-12 Cycloolefin dimerization
US4284529A (en) * 1979-12-14 1981-08-18 Mobil Oil Corporation Hydrocarbon conversion catalyst
US4334979A (en) * 1980-04-11 1982-06-15 Phillips Petroleum Company Hydrocarbon cracking process using a catalyst containing germanium
US4439536A (en) * 1980-04-11 1984-03-27 Phillips Petroleum Company Hydrocarbon cracking catalyst
US4386015A (en) * 1980-04-11 1983-05-31 Phillips Petroleum Company Hydrocarbon cracking zeolitic catalyst
US4357233A (en) * 1980-06-06 1982-11-02 Mobil Oil Corporation Catalytic conversion with zeolite ZSM-39
AU542052B2 (en) * 1980-06-12 1985-02-07 Imperial Chemical Industries Ltd. Zeoliteeuz and its use as a catalyst
DE3165380D1 (en) * 1980-06-12 1984-09-13 Ici Plc Zeolite eu-1
EP0055046B1 (en) * 1980-12-19 1984-11-07 Imperial Chemical Industries Plc Zeolites
US4377503A (en) * 1980-12-29 1983-03-22 Mobil Oil Corporation Shape selective metallic catalysis
US4368174A (en) * 1980-12-29 1983-01-11 Mobil Oil Corporation Apparatus for a continuous down-flow zeolite production
US4359421A (en) * 1981-01-15 1982-11-16 Mobil Oil Corporation Process for making epsilon-caprolactam
US4420561A (en) * 1981-02-02 1983-12-13 Mobil Oil Corporation Fermentation process
BR8200670A (pt) * 1981-02-09 1982-12-14 Mobil Oil Corp Processo para sintetizar uma zeolita
DE3274844D1 (en) * 1981-04-14 1987-02-05 Ici Plc Zeolites
US4419218A (en) * 1981-07-08 1983-12-06 Mobil Oil Corporation Catalytic conversion of shale oil
US4454365A (en) * 1981-07-09 1984-06-12 Standard Oil Company (Indiana) Hydrocarbon conversion with a crystalline chromosilicate catalyst
US4391785A (en) * 1981-12-21 1983-07-05 Mobil Oil Corporation Preparation of ZSM-12 type zeolites
US4452958A (en) * 1981-12-30 1984-06-05 Mobil Oil Corporation Olefin polymerization with catalysts derived from chromium exchanged zeolites
JPS58145616A (ja) * 1982-02-22 1983-08-30 Teijin Yuka Kk 新規結晶性アルミノシリケ−トゼオライト及びその製造法
US4521297A (en) * 1982-02-22 1985-06-04 Mobil Oil Corporation Catalytic conversion of shale oil
AU559968B2 (en) 1982-04-29 1987-03-26 Mobil Oil Corp. Controlled morphology high silica zeolites
US4902406A (en) * 1982-04-30 1990-02-20 Mobil Oil Corporation Synthesis of zeolite ZSM-22
US4490568A (en) * 1982-04-30 1984-12-25 Union Carbide Corporation Conversion of certain hydrocarbons using calcined TEA-silicate catalyst
NL8202992A (nl) * 1982-07-26 1984-02-16 Shell Int Research Werkwijze voor het ontparaffineren van koolwaterstofolien.
CA1209981A (en) * 1982-09-04 1986-08-19 Dennis Young Crystalline gallosilicates, a process for producing them and their use as catalysts
US4452909A (en) * 1982-09-13 1984-06-05 E. I. Du Pont De Nemours And Company Process for coating crystalline silica polymorphs
US4508837A (en) * 1982-09-28 1985-04-02 Chevron Research Company Zeolite SSZ-16
US4568654A (en) * 1982-11-03 1986-02-04 Mobil Oil Corporation Zeolite ZSM-51 composition
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US4912281A (en) * 1982-12-15 1990-03-27 Mobil Oil Corporation Conversion of methanol and methyl ether to light olefins with ZSM-45 in presence of hydrogen
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US4490565A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
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CA1239385A (en) * 1984-06-26 1988-07-19 Mae K. Rubin Preparation of zeolite zsm-12
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US4557921A (en) * 1984-06-27 1985-12-10 Ethyl Corporation Purification of halide
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CA984366A (en) 1976-02-24
DE2213109C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1987-08-20
FR2130429B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1974-09-13
NL173736B (nl) 1983-10-03
IT946386B (it) 1973-05-21

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