DE2119750C3 - Herstellung von deuteriertem Methanol - Google Patents
Herstellung von deuteriertem MethanolInfo
- Publication number
- DE2119750C3 DE2119750C3 DE19712119750 DE2119750A DE2119750C3 DE 2119750 C3 DE2119750 C3 DE 2119750C3 DE 19712119750 DE19712119750 DE 19712119750 DE 2119750 A DE2119750 A DE 2119750A DE 2119750 C3 DE2119750 C3 DE 2119750C3
- Authority
- DE
- Germany
- Prior art keywords
- methanol
- catalyst
- pressure
- reaction
- deuterium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKKJLVBELUTLKV-MZCSYVLQSA-N Deuterated methanol Chemical compound [2H]OC([2H])([2H])[2H] OKKJLVBELUTLKV-MZCSYVLQSA-N 0.000 title claims description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 27
- 239000003054 catalyst Substances 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims description 5
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 5
- 229910052805 deuterium Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 230000000155 isotopic effect Effects 0.000 claims description 2
- OKKJLVBELUTLKV-VMNATFBRSA-N methanol-d1 Chemical compound [2H]OC OKKJLVBELUTLKV-VMNATFBRSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims 8
- 238000006243 chemical reaction Methods 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 238000003786 synthesis reaction Methods 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 241001465754 Metazoa Species 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 210000003608 fece Anatomy 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000011835 investigation Methods 0.000 claims 1
- 230000007246 mechanism Effects 0.000 claims 1
- 230000002906 microbiologic effect Effects 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 230000003595 spectral effect Effects 0.000 claims 1
- 239000000047 product Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B59/00—Introduction of isotopes of elements into organic compounds ; Labelled organic compounds per se
- C07B59/001—Acyclic or carbocyclic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA80879 | 1970-04-22 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2119750A1 DE2119750A1 (de) | 1971-11-11 |
| DE2119750B2 DE2119750B2 (de) | 1973-03-01 |
| DE2119750C3 true DE2119750C3 (de) | 1973-10-11 |
Family
ID=4086682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712119750 Expired DE2119750C3 (de) | 1970-04-22 | 1971-04-22 | Herstellung von deuteriertem Methanol |
Country Status (6)
| Country | Link |
|---|---|
| CA (1) | CA886045A (enExample) |
| CH (1) | CH549541A (enExample) |
| DE (1) | DE2119750C3 (enExample) |
| FR (1) | FR2090553A5 (enExample) |
| GB (1) | GB1288191A (enExample) |
| SE (1) | SE382207B (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250041B (zh) * | 2018-02-26 | 2021-09-24 | 上海枢炬化工有限公司 | 一种全氘代甲醇的制备方法 |
| CN113072421A (zh) * | 2021-02-24 | 2021-07-06 | 中国船舶重工集团公司第七一八研究所 | 一种氘代乙醇的制备方法 |
| CN114904518B (zh) * | 2022-05-07 | 2023-11-10 | 南京凝氘生物科技有限公司 | 一种由氘气合成氘代乙醇-d6的催化剂、其制备方法及其应用 |
-
1970
- 1970-04-22 CA CA886045A patent/CA886045A/en not_active Expired
-
1971
- 1971-04-16 SE SE494171A patent/SE382207B/xx unknown
- 1971-04-19 GB GB989171A patent/GB1288191A/en not_active Expired
- 1971-04-22 CH CH588371A patent/CH549541A/xx not_active IP Right Cessation
- 1971-04-22 DE DE19712119750 patent/DE2119750C3/de not_active Expired
- 1971-04-22 FR FR7114318A patent/FR2090553A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE382207B (sv) | 1976-01-19 |
| DE2119750B2 (de) | 1973-03-01 |
| CA886045A (en) | 1971-11-16 |
| GB1288191A (enExample) | 1972-09-06 |
| FR2090553A5 (enExample) | 1972-01-14 |
| DE2119750A1 (de) | 1971-11-11 |
| CH549541A (de) | 1974-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1568864C3 (de) | Verfahren zur Synthese von Methanol | |
| DE2455617A1 (de) | Verfahren zur herstellung von butandiol und/oder tetrahydrofuran ueber die zwischenstufe des gamma-butyrolactons | |
| DD157669A5 (de) | Katalysator und verfahren zur herstellung desselben | |
| DE2056612B2 (de) | Verfahren zur Herstellung von Methanol | |
| DE2119750C3 (de) | Herstellung von deuteriertem Methanol | |
| DE1241429B (de) | Verfahren zur Herstellung von Methanol | |
| DE68921251T2 (de) | Verfahren und Vorrichtung zur Herstellung von Cyanwasserstoff. | |
| DE2147591A1 (de) | Verfahren zur Herstellung von Kupfer oxyd oder Zinkhydroxyd | |
| DE2154074B2 (de) | Verfahren zur Herstellung von Methanol durch Umsetzung von Kohlenmonoxid und Wasserstoff an einem Katalysator und Katalysatorzusammensetzung zur Durchführung des Verfahrens | |
| DE856294C (de) | Verfahren zur Herstellung ª‡,ª‰-ungesaettigter Carbonsaeuren und ihrer Abkoemmlinge | |
| DE1257125B (de) | Verfahren zur Herstellung von Alkali- und Erdalkaliniobaten und -tantalaten | |
| DE2209458A1 (de) | Verfahren zur Herstellung von 1,4-Dithiol-2,3-butandiol. ^Anm: AvonProdücts, Inc., New York (V.StA.) | |
| DE2016596C3 (de) | Verfahren zur Herstellung von Katalysatoren und deren Anwendung | |
| DE938014C (de) | Verfahren zur Herstellung kristallisierter Vanillylamide | |
| DE902375C (de) | Verfahren zur Herstellung von Methanol | |
| DE1768600C3 (de) | Verfahren zur Rückführung nicht umgesetzter Ausgangsprodukte bei der Harnstoffsynthese | |
| DE2527650A1 (de) | Verfahren zur herstellung von phenylthiophosphonyl-dichlorid | |
| DE1442626A1 (de) | Verbesserungen fuer die Herstellung von Kupfer-Zink-Katalysatoren | |
| DE2362781B2 (de) | Verfahren zur herstellung von loesungen der 4,4'-diaminostilben-2,2'- disulfonsaeure in form ihrer alkalisalze | |
| DE888240C (de) | Verfahren zur Herstellung von hoeheren Kohlenwasserstoffen | |
| DE2715518C2 (enExample) | ||
| DE846691C (de) | Verfahren zur Herstellung von gegebenenfalls Traegerstoffe, wie Kieselgur oder Aktivkohle, enthaltenden Eisen-Katalysatoren | |
| DE2124145C3 (de) | Verfahren zur Synthese von Diamanten | |
| DE522253C (de) | Verfahren zur Gewinnung von Cyanverbindungen | |
| DE2004099B2 (de) | Verfahren zur herstellung von salzen von n-acylaminocarbonsaeuren |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 |