DE2002249C3 - Schmelzklebefäden und -Folien aus thermoplastischen Acrylnitrtl-Copolymerisaten - Google Patents
Schmelzklebefäden und -Folien aus thermoplastischen Acrylnitrtl-CopolymerisatenInfo
- Publication number
- DE2002249C3 DE2002249C3 DE2002249A DE2002249A DE2002249C3 DE 2002249 C3 DE2002249 C3 DE 2002249C3 DE 2002249 A DE2002249 A DE 2002249A DE 2002249 A DE2002249 A DE 2002249A DE 2002249 C3 DE2002249 C3 DE 2002249C3
- Authority
- DE
- Germany
- Prior art keywords
- parts
- acrylonitrile
- melt adhesive
- threads
- hot melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title claims description 12
- 239000004831 Hot glue Substances 0.000 title claims description 6
- 229920001169 thermoplastic Polymers 0.000 title claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 4
- 239000011888 foil Substances 0.000 title claims 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 12
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 238000007334 copolymerization reaction Methods 0.000 claims description 5
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 6
- 229920002239 polyacrylonitrile Polymers 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 4
- 235000010262 sodium metabisulphite Nutrition 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/42—Nitriles
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/10—Adhesives in the form of films or foils without carriers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Adhesives Or Adhesive Processes (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2002249A DE2002249C3 (de) | 1970-01-20 | 1970-01-20 | Schmelzklebefäden und -Folien aus thermoplastischen Acrylnitrtl-Copolymerisaten |
| CA102813A CA986646A (en) | 1970-01-20 | 1971-01-15 | Melt-adhesive filaments and films of thermoplastic acrylonitrile copolymers |
| NL7100656A NL7100656A (https=) | 1970-01-20 | 1971-01-18 | |
| GB2472/71A GB1294044A (en) | 1970-01-20 | 1971-01-19 | Melt-adhesive filaments and films of thermo-plastic acrylonitrile copolymers |
| BE761798A BE761798A (fr) | 1970-01-20 | 1971-01-20 | Filaments et fils adhesifs a l'etat fondu, en copolymeres d'acrylonitrile thermoplastiques |
| FR7101854A FR2075770A5 (https=) | 1970-01-20 | 1971-01-20 | |
| CH80371A CH514665A (de) | 1970-01-20 | 1971-01-20 | Schmelzklebefäden und -folien aus thermoplastischen Acrylnitril-Copolymerisaten |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2002249A DE2002249C3 (de) | 1970-01-20 | 1970-01-20 | Schmelzklebefäden und -Folien aus thermoplastischen Acrylnitrtl-Copolymerisaten |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2002249A1 DE2002249A1 (de) | 1971-07-29 |
| DE2002249B2 DE2002249B2 (de) | 1978-03-23 |
| DE2002249C3 true DE2002249C3 (de) | 1978-11-23 |
Family
ID=5759986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2002249A Expired DE2002249C3 (de) | 1970-01-20 | 1970-01-20 | Schmelzklebefäden und -Folien aus thermoplastischen Acrylnitrtl-Copolymerisaten |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE761798A (https=) |
| CA (1) | CA986646A (https=) |
| CH (1) | CH514665A (https=) |
| DE (1) | DE2002249C3 (https=) |
| FR (1) | FR2075770A5 (https=) |
| GB (1) | GB1294044A (https=) |
| NL (1) | NL7100656A (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2134823A1 (en) * | 1993-11-10 | 1995-05-11 | Richard C. Smierciak | Process for making a polymer of acrylonitrile, methacrylonitrile and olefinically unsaturated monomers |
| BR112013015899B1 (pt) * | 2010-12-26 | 2020-03-17 | Dow Global Technologies Llc | Sistema adesivo de poliuretano em duas partes e laminado |
| DE102014219707A1 (de) | 2014-09-29 | 2016-03-31 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Schmelzspinnbare Copolymere vom Polyacrylnitril, Verfahren zur Herstellung von Fasern oder Faserprecursoren mittels Schmelzspinnen und entsprechend hergestellte Fasern |
| DE102015222585A1 (de) | 2015-11-16 | 2017-05-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung von thermisch stabilen schmelzspinnbaren PAN-Copolymeren, PAN-Copolymere, hieraus gebildete Formkörper sowie Verfahren zur Herstellung dieser Formkörper |
| EP3433292A1 (de) | 2016-03-22 | 2019-01-30 | Fraunhofer Gesellschaft zur Förderung der angewandten Forschung E.V. | Schmelzspinnbare copolymere vom polyacrylnitril, verfahren zur herstellung von fasern oder faserprecursoren mittels schmelzspinnen und entsprechend hergestellte fasern |
| DE112016006681A5 (de) | 2016-03-29 | 2019-01-03 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Schmelzspinnbare Copolymere vom Polyacrylnitril, Verfahren zur Herstellung von Fasern oder Faserprecursoren mittels Schmelzspinnen und entsprechend hergestellte Fasern |
| EP3872103A1 (en) | 2020-02-25 | 2021-09-01 | DWI - Leibniz-Institut für Interaktive Materialien e.V. | Melt-processable acrylonitrile-based copolymers and their acidic prestabilization for conversion into carbon fibers and workpieces |
| CN113683843A (zh) * | 2021-08-24 | 2021-11-23 | 安徽鸿森塑业科技股份有限公司 | 一种抗老化塑料围网 |
| CN115341315B (zh) * | 2022-09-19 | 2023-09-05 | 罗莱生活科技股份有限公司 | 一种复合纤维包芯纱线及其制备方法 |
-
1970
- 1970-01-20 DE DE2002249A patent/DE2002249C3/de not_active Expired
-
1971
- 1971-01-15 CA CA102813A patent/CA986646A/en not_active Expired
- 1971-01-18 NL NL7100656A patent/NL7100656A/xx unknown
- 1971-01-19 GB GB2472/71A patent/GB1294044A/en not_active Expired
- 1971-01-20 FR FR7101854A patent/FR2075770A5/fr not_active Expired
- 1971-01-20 CH CH80371A patent/CH514665A/de not_active IP Right Cessation
- 1971-01-20 BE BE761798A patent/BE761798A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE2002249A1 (de) | 1971-07-29 |
| GB1294044A (en) | 1972-10-25 |
| FR2075770A5 (https=) | 1971-10-08 |
| NL7100656A (https=) | 1971-07-22 |
| CH514665A (de) | 1971-10-31 |
| CA986646A (en) | 1976-03-30 |
| BE761798A (fr) | 1971-07-01 |
| DE2002249B2 (de) | 1978-03-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| EHV | Ceased/renunciation |