DE1908096C3 - - Google Patents
Info
- Publication number
- DE1908096C3 DE1908096C3 DE19691908096 DE1908096A DE1908096C3 DE 1908096 C3 DE1908096 C3 DE 1908096C3 DE 19691908096 DE19691908096 DE 19691908096 DE 1908096 A DE1908096 A DE 1908096A DE 1908096 C3 DE1908096 C3 DE 1908096C3
- Authority
- DE
- Germany
- Prior art keywords
- printed
- fiber
- process according
- dyes
- reactive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000975 dye Substances 0.000 claims description 23
- 239000004744 fabric Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 18
- 239000000969 carrier Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 238000010023 transfer printing Methods 0.000 claims description 11
- 239000000986 disperse dye Substances 0.000 claims description 8
- 239000000976 ink Substances 0.000 claims description 8
- 210000002268 Wool Anatomy 0.000 claims description 6
- 238000007639 printing Methods 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 239000011528 polyamide (building material) Substances 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 229920002284 Cellulose triacetate Polymers 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 claims description 3
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 3
- 229920002301 Cellulose acetate Polymers 0.000 claims description 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims 1
- 229920003086 cellulose ether Polymers 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 150000003459 sulfonic acid esters Chemical class 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 14
- -1 unsaturated aliphatic acyl radicals Chemical class 0.000 description 9
- 229920002302 Nylon 6,6 Polymers 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- AJDUTMFFZHIJEM-UHFFFAOYSA-N N-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 150000004891 diazines Chemical class 0.000 description 2
- PUSKHXMZPOMNTQ-UHFFFAOYSA-N ethyl 2,1,3-benzoselenadiazole-5-carboxylate Chemical group CCOC(=O)C1=CC=C2N=[Se]=NC2=C1 PUSKHXMZPOMNTQ-UHFFFAOYSA-N 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N methylene dichloride Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000001043 yellow dye Substances 0.000 description 2
- WMDBQMYVAIBBDH-IHWYPQMZSA-N (Z)-2-chlorobut-2-enoic acid Chemical compound C\C=C(/Cl)C(O)=O WMDBQMYVAIBBDH-IHWYPQMZSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 description 1
- QPHAGNNWDZSKJH-UHFFFAOYSA-N 3-chloro-2H-indazole Chemical compound C1=CC=CC2=C(Cl)NN=C21 QPHAGNNWDZSKJH-UHFFFAOYSA-N 0.000 description 1
- IBWYHNOFSKJKKY-UHFFFAOYSA-N 3-chloropyridazine Chemical group ClC1=CC=CN=N1 IBWYHNOFSKJKKY-UHFFFAOYSA-N 0.000 description 1
- DZBUGLKDJFMEHC-UHFFFAOYSA-N Acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 1
- RZVHIXYEVGDQDX-UHFFFAOYSA-N Anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
- 125000006414 CCl Chemical group ClC* 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- XAPRFLSJBSXESP-UHFFFAOYSA-N Oxycinchophen Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=C(O)C=1C1=CC=CC=C1 XAPRFLSJBSXESP-UHFFFAOYSA-N 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N Perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- UORVCLMRJXCDCP-UHFFFAOYSA-N Propiolic acid Chemical compound OC(=O)C#C UORVCLMRJXCDCP-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- JNELGWHKGNBSMD-UHFFFAOYSA-N Xanthone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3OC2=C1 JNELGWHKGNBSMD-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2R,3R,4S,5R,6S)-4,5-diacetyloxy-3-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2R,3R,4S,5R,6S)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 230000002378 acidificating Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atoms Chemical group N* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000004893 oxazines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N oxygen atom Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical class C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-M triacetate(1-) Chemical compound CC(=O)CC(=O)CC([O-])=O ILJSQTXMGCGYMG-UHFFFAOYSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH272468A CH557920A (en) | 1968-02-26 | 1968-02-26 | Process for printing dyeing synthetic fibres and or |
| CH272468 | 1968-02-26 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1908096A1 DE1908096A1 (de) | 1969-09-11 |
| DE1908096B2 DE1908096B2 (de) | 1977-01-20 |
| DE1908096C3 true DE1908096C3 (fi) | 1977-09-22 |
Family
ID=4240169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19691908096 Granted DE1908096B2 (de) | 1968-02-26 | 1969-02-19 | Transferdruck |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US3632291A (fi) |
| JP (1) | JPS5346947B1 (fi) |
| AT (1) | AT287642B (fi) |
| BE (1) | BE728897A (fi) |
| BG (1) | BG17346A3 (fi) |
| BR (1) | BR6906681D0 (fi) |
| CH (1) | CH272468A4 (fi) |
| CS (1) | CS157665B2 (fi) |
| DE (1) | DE1908096B2 (fi) |
| FI (1) | FI47159C (fi) |
| FR (1) | FR2002602A1 (fi) |
| GB (1) | GB1254021A (fi) |
| HK (1) | HK44176A (fi) |
| IE (1) | IE33447B1 (fi) |
| IL (1) | IL31667A (fi) |
| LU (1) | LU58070A1 (fi) |
| NL (1) | NL6902927A (fi) |
| NO (1) | NO132598B (fi) |
| PL (1) | PL76007B1 (fi) |
| RO (1) | RO58672A (fi) |
| SE (1) | SE353748B (fi) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3961965A (en) * | 1967-07-24 | 1976-06-08 | Sublistatic Holding Sa | Dyestuff preparations and printing inks |
| CH488570A4 (fi) * | 1970-04-02 | 1973-03-15 | ||
| GB1376108A (en) * | 1970-11-12 | 1974-12-04 | Glover R D | Method of sublimatic printing on sheet structures |
| GB1399095A (en) * | 1971-06-21 | 1975-06-25 | Ici Ltd | Production of a coloured pile surfaced products |
| JPS4842188A (fi) * | 1971-10-08 | 1973-06-19 | ||
| GB1434202A (en) * | 1972-12-15 | 1976-05-05 | Ici Ltd | Colouration process |
| CH669173A4 (fi) * | 1973-05-11 | 1976-02-13 | ||
| US3874846A (en) * | 1973-06-20 | 1975-04-01 | John M Ashe | Transfer printing method |
| US3949574A (en) * | 1973-07-20 | 1976-04-13 | Richard Donovan Glover | Sublimatic printing machine |
| NL7414822A (nl) * | 1973-11-16 | 1975-05-21 | Zimmer Peter | Werkwijze en inrichting voor het bedrukken van vezelmaterialen. |
| US3994250A (en) * | 1974-03-27 | 1976-11-30 | Champion International Corporation | Transfer printing of textile yarn |
| US4121932A (en) * | 1974-09-28 | 1978-10-24 | Matsushita Electric Industrial Co., Ltd. | Electrophotographic process involving dye transfer imagewise |
| US4062644A (en) * | 1976-03-30 | 1977-12-13 | Graphic Magicians, Inc. | Transfer ink and method of using same |
| US4081277A (en) * | 1976-10-08 | 1978-03-28 | Eastman Kodak Company | Method for making a solid-state color imaging device having an integral color filter and the device |
| US4097230A (en) * | 1976-10-08 | 1978-06-27 | Eastman Kodak Company | Method for transferring heat-transferable dyes |
| US4177750A (en) * | 1977-09-14 | 1979-12-11 | Ted Scarlet | Pennant and method of making a pennant |
| US4121897A (en) * | 1977-11-03 | 1978-10-24 | Koppers Company, Inc. | Process for printing on solid molded articles made from urea formaldehyde resin or melamine formaldehyde resin |
| US4196009A (en) * | 1978-03-08 | 1980-04-01 | Eastman Kodak Company | Color imaging devices having integral color filter arrays |
| US4266017A (en) * | 1978-03-08 | 1981-05-05 | Eastman Kodak Company | Color imaging devices having integral color filter arrays |
| US4196010A (en) * | 1978-06-06 | 1980-04-01 | Eastman Kodak Company | Color filter arrays and color imaging devices |
| US4267961A (en) * | 1978-09-06 | 1981-05-19 | Eastman Kodak Company | Photocrosslinkable, high-temperature-resistant polymers and their use in color imaging devices |
| US4455147A (en) * | 1978-10-09 | 1984-06-19 | I.W.S. Nominee Company, Limited | Transfer printing |
| US4383018A (en) * | 1979-09-04 | 1983-05-10 | Eastman Kodak Company | Color imaging devices having integral color filter arrays |
| US4239842A (en) * | 1979-09-13 | 1980-12-16 | Eastman Kodak Company | Color filter arrays, color imaging devices and methods of making same |
| US4382111A (en) * | 1980-05-07 | 1983-05-03 | Meisei Chemical Works Co., Ltd. | Method of treating fiber |
| JPS58501057A (ja) * | 1981-06-29 | 1983-06-30 | サブリグラフイツクス ソシエテ アノニム | 磁気静電現像剤、それらの調製及び使用 |
| JPH0696308B2 (ja) * | 1983-06-30 | 1994-11-30 | ソニーケミカル株式会社 | 昇華性インクリボン |
| DE3324709A1 (de) * | 1983-07-08 | 1985-01-17 | Röhm GmbH, 6100 Darmstadt | Umform- und transferdruckverfahren |
| US4647945A (en) * | 1986-02-06 | 1987-03-03 | Tokyo Electric Co., Ltd. | Image recording method and its apparatus |
| US5032850A (en) * | 1989-12-18 | 1991-07-16 | Tokyo Electric Co., Ltd. | Method and apparatus for vapor jet printing |
| US5580410A (en) * | 1994-12-14 | 1996-12-03 | Delta Technology, Inc. | Pre-conditioning a substrate for accelerated dispersed dye sublimation printing |
| US5989380A (en) * | 1997-01-08 | 1999-11-23 | Frischer; Paul | Process of dry printing a paper-like non-woven wall covering material |
| DE19848604C2 (de) * | 1997-10-22 | 2001-11-22 | Toyoda Gosei Kk | Lenkrad |
| NL1015260C2 (nl) * | 2000-05-22 | 2001-11-26 | Corus Staal Bv | Werkwijze en inrichting voor het bekleden van een voortbewegende metalen productband. |
| US20060042141A1 (en) * | 2004-09-01 | 2006-03-02 | Juergen Hansen | Frame system |
| CN100463805C (zh) * | 2005-11-23 | 2009-02-25 | 上海迪纺纺织科技有限公司 | 柔版转移印花纸的生产方法 |
| CN117320888A (zh) | 2021-05-17 | 2023-12-29 | 绿色科技复合材料有限责任公司 | 具有染料升华印刷图像的聚合物制品及其形成方法 |
| CN117917978A (zh) | 2021-09-08 | 2024-04-23 | 绿色科技复合材料有限责任公司 | 具有染料升华印刷图像的非极性热塑性复合材料及其形成方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1052625A (fi) * | 1900-01-01 | |||
| FR1223330A (fr) * | 1958-10-29 | 1960-06-16 | Filatures Prouvost & Cie La La | Procédé de coloration de matières diverses, en particulier de matières textiles artificielles |
| US3245796A (en) * | 1962-10-25 | 1966-04-12 | Du Pont | Photopolymerizable elements and processes |
| NL301546A (fi) * | 1962-12-11 | |||
| US3210544A (en) * | 1963-08-01 | 1965-10-05 | Printing Arts Res Lab Inc | Method of thermographic reproduction wherein a vaporizable conditioner changes the physical characteristics of a conversion sheet coating |
| US3280735A (en) * | 1964-04-13 | 1966-10-25 | Minnesota Mining & Mfg | Heat-copying process |
| US3454764A (en) * | 1965-09-10 | 1969-07-08 | Printing Arts Research Lab Inc | Process of making diazo copies by sublimation of reactant materials onto a copy sheet |
| US3363557A (en) * | 1966-01-19 | 1968-01-16 | Martin Marietta Corp | Heat transfer of indicia containing sublimable coloring agent |
-
1968
- 1968-02-26 CH CH272468D patent/CH272468A4/xx unknown
-
1969
- 1969-02-11 BG BG11642A patent/BG17346A3/xx unknown
- 1969-02-19 DE DE19691908096 patent/DE1908096B2/de active Granted
- 1969-02-20 SE SE02345/69A patent/SE353748B/xx unknown
- 1969-02-21 IL IL31667A patent/IL31667A/xx unknown
- 1969-02-21 FI FI690562A patent/FI47159C/fi active
- 1969-02-24 PL PL1969131928A patent/PL76007B1/pl unknown
- 1969-02-24 FR FR6904700A patent/FR2002602A1/fr not_active Withdrawn
- 1969-02-24 LU LU58070D patent/LU58070A1/xx unknown
- 1969-02-25 NL NL6902927A patent/NL6902927A/xx unknown
- 1969-02-25 NO NO776/69A patent/NO132598B/no unknown
- 1969-02-25 IE IE244/69A patent/IE33447B1/xx unknown
- 1969-02-25 US US802224A patent/US3632291A/en not_active Expired - Lifetime
- 1969-02-25 BE BE728897D patent/BE728897A/xx unknown
- 1969-02-25 AT AT190069A patent/AT287642B/de not_active IP Right Cessation
- 1969-02-26 RO RO59202A patent/RO58672A/ro unknown
- 1969-02-26 JP JP1404169A patent/JPS5346947B1/ja active Pending
- 1969-02-26 BR BR206681/69A patent/BR6906681D0/pt unknown
- 1969-02-26 CS CS136669A patent/CS157665B2/cs unknown
- 1969-02-26 GB GB00251/69A patent/GB1254021A/en not_active Expired
-
1976
- 1976-07-15 HK HK441/76*UA patent/HK44176A/xx unknown
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