DE1545251A1 - Verfahren zur Entschwefelung von Straightrun-Erdoelfraktionen - Google Patents
Verfahren zur Entschwefelung von Straightrun-ErdoelfraktionenInfo
- Publication number
- DE1545251A1 DE1545251A1 DE19661545251 DE1545251A DE1545251A1 DE 1545251 A1 DE1545251 A1 DE 1545251A1 DE 19661545251 DE19661545251 DE 19661545251 DE 1545251 A DE1545251 A DE 1545251A DE 1545251 A1 DE1545251 A1 DE 1545251A1
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen
- stage
- nickel
- temperature
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 42
- 238000006477 desulfuration reaction Methods 0.000 title claims description 16
- 230000023556 desulfurization Effects 0.000 title claims description 16
- 239000003208 petroleum Substances 0.000 title claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 67
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 38
- 229910052717 sulfur Inorganic materials 0.000 claims description 38
- 239000011593 sulfur Substances 0.000 claims description 38
- 229910052739 hydrogen Inorganic materials 0.000 claims description 37
- 239000001257 hydrogen Substances 0.000 claims description 37
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 35
- 229910052759 nickel Inorganic materials 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 21
- 229930195733 hydrocarbon Natural products 0.000 claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 claims description 21
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 13
- 239000007789 gas Substances 0.000 claims description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000004113 Sepiolite Substances 0.000 claims description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims description 10
- 235000019355 sepiolite Nutrition 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000000629 steam reforming Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000002407 reforming Methods 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 238000004804 winding Methods 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 description 8
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000009835 boiling Methods 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- 150000003577 thiophenes Chemical class 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000272470 Circus Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- -1 lünkoxyd Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- UJHLGDUCOCXGBW-UHFFFAOYSA-N oxocobalt trioxomolybdenum Chemical compound O=[Co].O=[Mo](=O)=O UJHLGDUCOCXGBW-UHFFFAOYSA-N 0.000 description 1
- 230000001769 paralizing effect Effects 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB41942/65A GB1098698A (en) | 1965-10-04 | 1965-10-04 | Improvements relating to the desulphurisation of petroleum fractions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1545251A1 true DE1545251A1 (de) | 1970-01-08 |
Family
ID=10422081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19661545251 Pending DE1545251A1 (de) | 1965-10-04 | 1966-10-01 | Verfahren zur Entschwefelung von Straightrun-Erdoelfraktionen |
Country Status (9)
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1232393A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1967-07-11 | 1971-05-19 | ||
| DE2240803C3 (de) * | 1972-08-18 | 1982-08-05 | Siemens AG, 1000 Berlin und 8000 München | Schaltungsanordnung zum Empfangen von Gleichstromzeichen |
| FR2908781B1 (fr) | 2006-11-16 | 2012-10-19 | Inst Francais Du Petrole | Procede de desulfuration profonde des essences de craquage avec une faible perte en indice d'octane |
| US7842181B2 (en) | 2006-12-06 | 2010-11-30 | Saudi Arabian Oil Company | Composition and process for the removal of sulfur from middle distillate fuels |
| US8142646B2 (en) | 2007-11-30 | 2012-03-27 | Saudi Arabian Oil Company | Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds |
| WO2009105749A2 (en) | 2008-02-21 | 2009-08-27 | Saudi Arabian Oil Company | Catalyst to attain low sulfur gasoline |
| US9005432B2 (en) | 2010-06-29 | 2015-04-14 | Saudi Arabian Oil Company | Removal of sulfur compounds from petroleum stream |
| US8535518B2 (en) | 2011-01-19 | 2013-09-17 | Saudi Arabian Oil Company | Petroleum upgrading and desulfurizing process |
| US10752847B2 (en) | 2017-03-08 | 2020-08-25 | Saudi Arabian Oil Company | Integrated hydrothermal process to upgrade heavy oil |
| US10703999B2 (en) | 2017-03-14 | 2020-07-07 | Saudi Arabian Oil Company | Integrated supercritical water and steam cracking process |
-
1965
- 1965-10-04 GB GB41942/65A patent/GB1098698A/en not_active Expired
-
1966
- 1966-10-01 DE DE19661545251 patent/DE1545251A1/de active Pending
- 1966-10-02 IL IL26616A patent/IL26616A/xx unknown
- 1966-10-03 FR FR78573A patent/FR1498698A/fr not_active Expired
- 1966-10-04 CH CH1429866A patent/CH482823A/de not_active IP Right Cessation
- 1966-10-04 BE BE687787D patent/BE687787A/xx unknown
- 1966-10-04 NL NL6613969A patent/NL6613969A/xx unknown
- 1966-10-04 AT AT928066A patent/AT265480B/de active
- 1966-10-04 ES ES0332401A patent/ES332401A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1498698A (fr) | 1967-10-20 |
| NL6613969A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1967-04-05 |
| BE687787A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1967-04-04 |
| GB1098698A (en) | 1968-01-10 |
| IL26616A (en) | 1970-03-22 |
| CH482823A (de) | 1969-12-15 |
| AT265480B (de) | 1968-10-10 |
| ES332401A1 (es) | 1967-08-01 |
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