DE1290712B - Gegen den Abbau durch Licht und Waerme stabilisierte Formmassen - Google Patents
Gegen den Abbau durch Licht und Waerme stabilisierte FormmassenInfo
- Publication number
- DE1290712B DE1290712B DEF48174A DEF0048174A DE1290712B DE 1290712 B DE1290712 B DE 1290712B DE F48174 A DEF48174 A DE F48174A DE F0048174 A DEF0048174 A DE F0048174A DE 1290712 B DE1290712 B DE 1290712B
- Authority
- DE
- Germany
- Prior art keywords
- trithio
- acid
- antimony
- ester
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000465 moulding Methods 0.000 title claims description 7
- 150000001875 compounds Chemical class 0.000 title claims description 5
- 230000015556 catabolic process Effects 0.000 title claims description 4
- 238000006731 degradation reaction Methods 0.000 title claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 19
- 229910052787 antimony Inorganic materials 0.000 claims description 17
- 229920000098 polyolefin Polymers 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- KYLIZBIRMBGUOP-UHFFFAOYSA-N Anetholtrithion Chemical group C1=CC(OC)=CC=C1C1=CC(=S)SS1 KYLIZBIRMBGUOP-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000001624 naphthyl group Chemical group 0.000 claims description 2
- 150000007970 thio esters Chemical class 0.000 claims description 2
- -1 polypropylene Polymers 0.000 description 13
- 239000004743 Polypropylene Substances 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 230000000087 stabilizing effect Effects 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 3
- 150000001463 antimony compounds Chemical class 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical class OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 2
- VZWGRQBCURJOMT-UHFFFAOYSA-N Dodecyl acetate Chemical compound CCCCCCCCCCCCOC(C)=O VZWGRQBCURJOMT-UHFFFAOYSA-N 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- RFCQDOVPMUSZMN-UHFFFAOYSA-N 2-Naphthalenethiol Chemical compound C1=CC=CC2=CC(S)=CC=C21 RFCQDOVPMUSZMN-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical class C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- VKJLYEDTHCTCOH-UHFFFAOYSA-N 3-(3-octadecoxy-3-oxopropyl)sulfanylpropanoic acid Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(O)=O VKJLYEDTHCTCOH-UHFFFAOYSA-N 0.000 description 1
- QZHXKQKKEBXYRG-UHFFFAOYSA-N 4-n-(4-aminophenyl)benzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1NC1=CC=C(N)C=C1 QZHXKQKKEBXYRG-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 239000003490 Thiodipropionic acid Substances 0.000 description 1
- XUGISPSHIFXEHZ-GPJXBBLFSA-N [(3r,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical compound C1C=C2C[C@H](OC(C)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XUGISPSHIFXEHZ-GPJXBBLFSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 235000019303 thiodipropionic acid Nutrition 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B7/00—Heating by electric discharge
- H05B7/18—Heating by arc discharge
- H05B7/185—Heating gases for arc discharge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
- B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/80—Processes with the aid of electrical means
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/90—Antimony compounds
- C07F9/902—Compounds without antimony-carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/59—Arsenic- or antimony-containing compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/919—Apparatus considerations
- Y10S585/921—Apparatus considerations using recited apparatus structure
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Plasma Technology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Discharge Heating (AREA)
Priority Applications (16)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF48174A DE1290712B (de) | 1966-01-15 | 1966-01-15 | Gegen den Abbau durch Licht und Waerme stabilisierte Formmassen |
US527787A US3522015A (en) | 1966-01-15 | 1966-02-16 | Direct conversion chemical processing arc heater |
AT1170566A AT270203B (de) | 1966-01-15 | 1966-12-20 | Stabilisierte Polyolefinmischung |
DK674266AA DK114581B (da) | 1966-01-15 | 1966-12-29 | Poly-α-alkenformstof, som er stabiliseret mo indvirkning af lys og varme. |
US607399A US3466261A (en) | 1966-01-15 | 1967-01-05 | Polyolefins stabilized by thioesters of antimonious acid |
NO166312A NO121471B (US20030204162A1-20031030-M00001.png) | 1966-01-15 | 1967-01-09 | |
NL6700414A NL6700414A (US20030204162A1-20031030-M00001.png) | 1966-01-15 | 1967-01-11 | |
GB1679/67A GB1125241A (en) | 1966-01-15 | 1967-01-12 | Direct conversion chemical processing arc heater |
ES335560A ES335560A1 (es) | 1966-01-15 | 1967-01-12 | Procedimiento para estabilizar polimeros de olefinas. |
GB1754/67A GB1110741A (en) | 1966-01-15 | 1967-01-12 | Stabilized polyolefin mixtures and process for their preparation |
CH41967A CH482746A (de) | 1966-01-15 | 1967-01-12 | Verfahren zum Stabilisieren von Polyolefinen |
SE531/67A SE316014B (US20030204162A1-20031030-M00001.png) | 1966-01-15 | 1967-01-13 | |
BE692658D BE692658A (US20030204162A1-20031030-M00001.png) | 1966-01-15 | 1967-01-16 | |
FR91243A FR1507957A (fr) | 1966-01-15 | 1967-01-16 | Stabilisants pour polyoléfines |
DE19671667359 DE1667359A1 (de) | 1966-01-15 | 1967-02-16 | Lichtbogenheizer-Vorrichtung zur direkten chemischen Umsetzung |
FR95212A FR1524161A (fr) | 1966-01-15 | 1967-02-16 | Dispositif de chauffage à arc destiné à effectuer une conversion chimique directe |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF48174A DE1290712B (de) | 1966-01-15 | 1966-01-15 | Gegen den Abbau durch Licht und Waerme stabilisierte Formmassen |
US52778766A | 1966-02-16 | 1966-02-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1290712B true DE1290712B (de) | 1969-03-13 |
Family
ID=25977079
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEF48174A Pending DE1290712B (de) | 1966-01-15 | 1966-01-15 | Gegen den Abbau durch Licht und Waerme stabilisierte Formmassen |
DE19671667359 Pending DE1667359A1 (de) | 1966-01-15 | 1967-02-16 | Lichtbogenheizer-Vorrichtung zur direkten chemischen Umsetzung |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19671667359 Pending DE1667359A1 (de) | 1966-01-15 | 1967-02-16 | Lichtbogenheizer-Vorrichtung zur direkten chemischen Umsetzung |
Country Status (11)
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2765466C1 (ru) * | 2021-04-06 | 2022-01-31 | Акционерное общество "Государственный научный центр Российской Федерации "Исследовательский центр имени М.В. Келдыша" | Способ получения водорода и ацетилена и установка для его реализации |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3629553A (en) * | 1969-01-10 | 1971-12-21 | Westinghouse Electric Corp | Recurrent arc heating process |
US3760145A (en) * | 1971-12-13 | 1973-09-18 | Panelera International Inc | Short gap electric arc heater with opposing gas swirl |
SE366057B (US20030204162A1-20031030-M00001.png) * | 1972-10-06 | 1974-04-08 | Aga Ab | |
US3919168A (en) * | 1974-04-19 | 1975-11-11 | Dart Ind Inc | Vinyl halide resin stabilizer compositions of organotin or antimony organic sulfur-containing compounds and tri-alkali metal phosphates |
US4098578A (en) * | 1975-01-21 | 1978-07-04 | Stanton Anthony A | Ionization of exhaust gases |
US4070412A (en) * | 1976-09-08 | 1978-01-24 | The United States Of America As Represented By The Secretary Of The Navy | Method for production of acetylene by laser irradiation |
US4102764A (en) * | 1976-12-29 | 1978-07-25 | Westinghouse Electric Corp. | High purity silicon production by arc heater reduction of silicon intermediates |
US4102765A (en) * | 1977-01-06 | 1978-07-25 | Westinghouse Electric Corp. | Arc heater production of silicon involving alkali or alkaline-earth metals |
US4102767A (en) * | 1977-04-14 | 1978-07-25 | Westinghouse Electric Corp. | Arc heater method for the production of single crystal silicon |
US4162291A (en) * | 1977-10-12 | 1979-07-24 | Westinghouse Electric Corp. | Liquid silicon casting control mechanism |
US4231895A (en) * | 1979-01-02 | 1980-11-04 | M & T Chemicals Inc. | Synergistic heat stabilizer compositions containing an antimony or a bismuth compound |
US4303578A (en) * | 1979-04-03 | 1981-12-01 | Ciba-Geigy Corporation | Organo-antimony compounds |
US4269731A (en) * | 1979-08-27 | 1981-05-26 | Argus Chemical Corporation | Antimony mercaptocarboxylic acid ester stabilizers for polyvinyl chloride resin compositions and process |
US4517115A (en) * | 1980-08-08 | 1985-05-14 | Plastic Specialties And Technologies, Inc. | Synergistic vinyl halide stabilizer compositions of antimony organic sulfur-containing compounds, alkaline earth carboxylates, and alkali metal carbonates |
US4440674A (en) * | 1980-08-08 | 1984-04-03 | Dart Industries Inc. | Synergistic vinyl halide stabilizer compositions of antimony organic sulfur-containing compounds, alkaline earth carboxylates and alkali metal carbonates |
US4417015A (en) * | 1981-02-06 | 1983-11-22 | Dart Industries Inc. | Low toxic polyvinylchloride stabilizers |
CA1225441A (en) * | 1984-01-23 | 1987-08-11 | Edward S. Fox | Plasma pyrolysis waste destruction |
US4806270A (en) * | 1987-02-06 | 1989-02-21 | Synthetic Products Company | Stain-resistant antimony organic sulfur-containing compounds and vinyl halide resins containing same |
US5095828A (en) * | 1990-12-11 | 1992-03-17 | Environmental Thermal Systems, Corp. | Thermal decomposition of waste material |
EP1768776A2 (fr) * | 2004-07-13 | 2007-04-04 | L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et L'Exploitation des Procédés Georges Claude | Traitement d'effluents gazeux par plasma a pression atmospherique |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB888673A (en) * | 1959-10-28 | 1962-01-31 | Sun Oil Co | Improvements in or relating to the stabilization of polyolefins |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2680726A (en) * | 1951-11-17 | 1954-06-08 | Metal & Thermit Corp | Antimony mercaptoesters and chlorinated organic compounds stabilized therewith |
US2684956A (en) * | 1952-02-25 | 1954-07-27 | Metal & Thermit Corp | Antimony mercaptide compounds and compositions containing same |
US3341464A (en) * | 1962-08-09 | 1967-09-12 | American Cyanamid Co | Heat resistant aminium salt infrared absorbers |
US3182176A (en) * | 1962-12-10 | 1965-05-04 | Edgar A Bunt | Arc plasma generator |
US3309550A (en) * | 1964-03-06 | 1967-03-14 | Westinghouse Electric Corp | Multiple annular electrode gas arc heater with a magnetic arc spinner |
US3389189A (en) * | 1965-04-06 | 1968-06-18 | Westinghouse Electric Corp | Method and equipment for the pyrolysis and synthesis of hydrocarbons and other gasesand arc heater apparatus for use therein |
-
1966
- 1966-01-15 DE DEF48174A patent/DE1290712B/de active Pending
- 1966-02-16 US US527787A patent/US3522015A/en not_active Expired - Lifetime
- 1966-12-29 DK DK674266AA patent/DK114581B/da unknown
-
1967
- 1967-01-05 US US607399A patent/US3466261A/en not_active Expired - Lifetime
- 1967-01-09 NO NO166312A patent/NO121471B/no unknown
- 1967-01-11 NL NL6700414A patent/NL6700414A/xx unknown
- 1967-01-12 CH CH41967A patent/CH482746A/de not_active IP Right Cessation
- 1967-01-12 ES ES335560A patent/ES335560A1/es not_active Expired
- 1967-01-12 GB GB1679/67A patent/GB1125241A/en not_active Expired
- 1967-01-12 GB GB1754/67A patent/GB1110741A/en not_active Expired
- 1967-01-13 SE SE531/67A patent/SE316014B/xx unknown
- 1967-01-16 BE BE692658D patent/BE692658A/xx unknown
- 1967-01-16 FR FR91243A patent/FR1507957A/fr not_active Expired
- 1967-02-16 DE DE19671667359 patent/DE1667359A1/de active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB888673A (en) * | 1959-10-28 | 1962-01-31 | Sun Oil Co | Improvements in or relating to the stabilization of polyolefins |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2765466C1 (ru) * | 2021-04-06 | 2022-01-31 | Акционерное общество "Государственный научный центр Российской Федерации "Исследовательский центр имени М.В. Келдыша" | Способ получения водорода и ацетилена и установка для его реализации |
Also Published As
Publication number | Publication date |
---|---|
GB1110741A (en) | 1968-04-24 |
US3466261A (en) | 1969-09-09 |
SE316014B (US20030204162A1-20031030-M00001.png) | 1969-10-13 |
NL6700414A (US20030204162A1-20031030-M00001.png) | 1967-07-17 |
DK114581B (da) | 1969-07-14 |
US3522015A (en) | 1970-07-28 |
BE692658A (US20030204162A1-20031030-M00001.png) | 1967-07-17 |
DE1667359A1 (de) | 1971-08-12 |
ES335560A1 (es) | 1968-08-16 |
NO121471B (US20030204162A1-20031030-M00001.png) | 1971-03-01 |
GB1125241A (en) | 1968-08-28 |
CH482746A (de) | 1969-12-15 |
FR1507957A (fr) | 1967-12-29 |
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