DE1211168B - Verfahren zur Herstellung von Organoantimon-Verbindungen - Google Patents
Verfahren zur Herstellung von Organoantimon-VerbindungenInfo
- Publication number
- DE1211168B DE1211168B DEF37118A DEF0037118A DE1211168B DE 1211168 B DE1211168 B DE 1211168B DE F37118 A DEF37118 A DE F37118A DE F0037118 A DEF0037118 A DE F0037118A DE 1211168 B DE1211168 B DE 1211168B
- Authority
- DE
- Germany
- Prior art keywords
- water
- mixture
- compounds
- colorless
- mercapto
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 4
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 3
- AEUVIXACNOXTBX-UHFFFAOYSA-N 1-sulfanylpropan-1-ol Chemical compound CCC(O)S AEUVIXACNOXTBX-UHFFFAOYSA-N 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000012230 colorless oil Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001665 trituration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/66—Arsenic compounds
- C07F9/70—Organo-arsenic compounds
- C07F9/72—Aliphatic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/90—Antimony compounds
- C07F9/902—Compounds without antimony-carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/38—Thiocarbonic acids; Derivatives thereof, e.g. xanthates ; i.e. compounds containing -X-C(=X)- groups, X being oxygen or sulfur, at least one X being sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/59—Arsenic- or antimony-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL136482D NL136482C (US07321065-20080122-C00160.png) | 1962-06-20 | ||
| BE633861D BE633861A (US07321065-20080122-C00160.png) | 1962-06-20 | ||
| NL294358D NL294358A (US07321065-20080122-C00160.png) | 1962-06-20 | ||
| DEF37118A DE1211168B (de) | 1962-06-20 | 1962-06-20 | Verfahren zur Herstellung von Organoantimon-Verbindungen |
| DEF37119A DE1295838B (de) | 1962-06-20 | 1962-06-20 | Stabilisatoren fuer chlorhaltige Polymere |
| US288635A US3317576A (en) | 1962-06-20 | 1963-06-18 | Reaction products of antimony halides or oxides with thioglycollic mercapto-hydroxyalkanes |
| GB24438/63A GB1020832A (en) | 1962-06-20 | 1963-06-19 | Organic sulphur-containing derivatives of antimony which can be used as stabilisers for chlorine-containing polymers |
| FR938707A FR1360997A (fr) | 1962-06-20 | 1963-06-20 | Stabilisants pour polymères contenant du chlore |
| US588334A US3347821A (en) | 1962-06-20 | 1966-10-21 | Chlorine-containing polymers stabilized with antimonyl compounds |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF37118A DE1211168B (de) | 1962-06-20 | 1962-06-20 | Verfahren zur Herstellung von Organoantimon-Verbindungen |
| DEF37119A DE1295838B (de) | 1962-06-20 | 1962-06-20 | Stabilisatoren fuer chlorhaltige Polymere |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1211168B true DE1211168B (de) | 1966-02-24 |
Family
ID=25975365
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF37118A Pending DE1211168B (de) | 1962-06-20 | 1962-06-20 | Verfahren zur Herstellung von Organoantimon-Verbindungen |
| DEF37119A Pending DE1295838B (de) | 1962-06-20 | 1962-06-20 | Stabilisatoren fuer chlorhaltige Polymere |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF37119A Pending DE1295838B (de) | 1962-06-20 | 1962-06-20 | Stabilisatoren fuer chlorhaltige Polymere |
Country Status (5)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2640270A1 (fr) * | 1987-06-10 | 1990-06-15 | Sakai Chemical Industry Co | Procede de preparation de mercaptides d'antimoine |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3676477A (en) * | 1970-11-30 | 1972-07-11 | Du Pont | Esters of pentavalent and trivalent antimony with a polyhydroxy compound and the process for making the same |
| US4287118A (en) * | 1978-08-23 | 1981-09-01 | Associated Lead Inc. | Antimony (V) mercaptides as processing stabilizers for vinyl halide resins and method of manufacturing same |
| US4303578A (en) * | 1979-04-03 | 1981-12-01 | Ciba-Geigy Corporation | Organo-antimony compounds |
| DE3063367D1 (en) * | 1979-11-08 | 1983-07-07 | Ciba Geigy Ag | Organic antimony-sulphur compounds, their use as stabilisers in chloric thermoplastics, and thermoplastics so stabilised |
| US4988750A (en) * | 1981-07-17 | 1991-01-29 | Schering Ag | Non-toxic stabilizer for halogenated polymer |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB879155A (en) * | 1959-07-31 | 1961-10-04 | Rhone Poulenc Sa | New antimony derivatives |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2480823A (en) * | 1947-04-23 | 1949-09-06 | Texas Co | Preparation of metal derivatives of organic compounds containing a replaceable hydrogen |
| US2885415A (en) * | 1953-01-22 | 1959-05-05 | Metal & Thermit Corp | Organotin compounds and process of preparation |
-
0
- NL NL136482D patent/NL136482C/xx active
- NL NL294358D patent/NL294358A/xx unknown
- BE BE633861D patent/BE633861A/xx unknown
-
1962
- 1962-06-20 DE DEF37118A patent/DE1211168B/de active Pending
- 1962-06-20 DE DEF37119A patent/DE1295838B/de active Pending
-
1963
- 1963-06-18 US US288635A patent/US3317576A/en not_active Expired - Lifetime
- 1963-06-19 GB GB24438/63A patent/GB1020832A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB879155A (en) * | 1959-07-31 | 1961-10-04 | Rhone Poulenc Sa | New antimony derivatives |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2640270A1 (fr) * | 1987-06-10 | 1990-06-15 | Sakai Chemical Industry Co | Procede de preparation de mercaptides d'antimoine |
Also Published As
| Publication number | Publication date |
|---|---|
| NL294358A (US07321065-20080122-C00160.png) | |
| US3317576A (en) | 1967-05-02 |
| DE1295838B (de) | 1969-05-22 |
| GB1020832A (en) | 1966-02-23 |
| BE633861A (US07321065-20080122-C00160.png) | |
| NL136482C (US07321065-20080122-C00160.png) |
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