DE1107207B - Stabilisierungsmittel fuer Peroxyverbindungen und deren Loesungen - Google Patents
Stabilisierungsmittel fuer Peroxyverbindungen und deren LoesungenInfo
- Publication number
- DE1107207B DE1107207B DEH36547A DEH0036547A DE1107207B DE 1107207 B DE1107207 B DE 1107207B DE H36547 A DEH36547 A DE H36547A DE H0036547 A DEH0036547 A DE H0036547A DE 1107207 B DE1107207 B DE 1107207B
- Authority
- DE
- Germany
- Prior art keywords
- solutions
- acid
- peroxy compounds
- stabilizer
- stabilizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003381 stabilizer Substances 0.000 title claims description 23
- 125000000864 peroxy group Chemical group O(O*)* 0.000 title claims description 11
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 10
- 230000010933 acylation Effects 0.000 claims description 4
- 238000005917 acylation reaction Methods 0.000 claims description 4
- 239000000243 solution Substances 0.000 description 18
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 16
- 239000000047 product Substances 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 5
- 239000012346 acetyl chloride Substances 0.000 description 5
- -1 alkali metal salts Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 4
- ZRCQYAQOWIQUBA-UHFFFAOYSA-N ethyl 2-diethoxyphosphorylsulfanylacetate Chemical compound CCOC(=O)CSP(=O)(OCC)OCC ZRCQYAQOWIQUBA-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000012928 buffer substance Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012084 conversion product Substances 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XUYJLQHKOGNDPB-UHFFFAOYSA-N phosphonoacetic acid Chemical compound OC(=O)CP(O)(O)=O XUYJLQHKOGNDPB-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N 2-propanol Substances CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000012425 OXONE® Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000012345 acetylating agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000003927 aminopyridines Chemical class 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- CCGKOQOJPYTBIH-UHFFFAOYSA-N ethenone Chemical compound C=C=O CCGKOQOJPYTBIH-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002560 ketene acetals Chemical class 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- OKBMCNHOEMXPTM-UHFFFAOYSA-M potassium peroxymonosulfate Chemical compound [K+].OOS([O-])(=O)=O OKBMCNHOEMXPTM-UHFFFAOYSA-M 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ILVXOBCQQYKLDS-UHFFFAOYSA-N pyridine N-oxide Chemical compound [O-][N+]1=CC=CC=C1 ILVXOBCQQYKLDS-UHFFFAOYSA-N 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical compound OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
- C07C407/006—Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/037—Stabilisation by additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3839—Polyphosphonic acids
- C07F9/386—Polyphosphonic acids containing hydroxy substituents in the hydrocarbon radicals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL130828D NL130828C (US07754670-20100713-C00008.png) | 1959-06-03 | ||
| NL252116D NL252116A (US07754670-20100713-C00008.png) | 1959-06-03 | ||
| DEH36547A DE1107207B (de) | 1959-06-03 | 1959-06-03 | Stabilisierungsmittel fuer Peroxyverbindungen und deren Loesungen |
| CH532760A CH396852A (de) | 1959-06-03 | 1960-05-09 | Stabilisierung von Peroxydverbindungen bzw. deren Lösungen |
| US170221A US3122417A (en) | 1959-06-03 | 1962-01-31 | Stabilizing agent for peroxy-compounds and their solutions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH36547A DE1107207B (de) | 1959-06-03 | 1959-06-03 | Stabilisierungsmittel fuer Peroxyverbindungen und deren Loesungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1107207B true DE1107207B (de) | 1961-05-25 |
Family
ID=7153037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEH36547A Pending DE1107207B (de) | 1959-06-03 | 1959-06-03 | Stabilisierungsmittel fuer Peroxyverbindungen und deren Loesungen |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3122417A (US07754670-20100713-C00008.png) |
| CH (1) | CH396852A (US07754670-20100713-C00008.png) |
| DE (1) | DE1107207B (US07754670-20100713-C00008.png) |
| NL (2) | NL252116A (US07754670-20100713-C00008.png) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3159581A (en) * | 1962-04-13 | 1964-12-01 | Procter & Gamble | Detergency composition |
| DE1261850B (de) * | 1965-03-30 | 1968-02-29 | Procter & Gamble | Verfahren zur Herstellung von AEthan-1-hydroxy-1,1-diphosphonsaeure |
| US3392121A (en) * | 1962-11-05 | 1968-07-09 | Procter & Gamble | Built detergent compositions |
| DE1300563B (de) * | 1965-05-13 | 1969-08-07 | Procter & Gamble | Verfahren zur Herstellung von AEthan-1-hydroxy-1, 1-diphosphonsaeure |
| DE2012171A1 (de) * | 1970-03-14 | 1971-10-07 | Benckiser-Knapsack GmbH, 6700 Ludwigshafen | Mittel zur Vorbehandlung von Fasergut aus nativer Cellulose |
| DE2226784A1 (US07754670-20100713-C00008.png) * | 1971-06-03 | 1972-12-14 | ||
| DE2536618A1 (de) * | 1975-08-16 | 1977-02-24 | Henkel & Cie Gmbh | Konzentrate von mikrobiziden mitteln |
| DE2616049A1 (de) * | 1976-04-12 | 1977-10-27 | Henkel & Cie Gmbh | Lagerstabile konzentrate von funktionellen mitteln |
| DE2936551C1 (de) * | 1978-02-17 | 1985-01-17 | Mo och Domsjö AB, Örnsköldsvik | Verfahren zum Bleichen und Extrahieren eines Lignocellulose enthaltenden Materials |
| WO1991003590A1 (de) * | 1989-09-04 | 1991-03-21 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur desinfektion von textilien in waschstrassen |
| US5651793A (en) * | 1993-09-30 | 1997-07-29 | Henkel Kommanditgesellschaft Auf Aktien | Hydrogen peroxide preparations containing foam regulators |
| US7008593B2 (en) | 2002-05-31 | 2006-03-07 | Henkel Kommanditgesellschaft Auf Aktien | Deodorization of cationic acetonitrile derivatives |
| US7316995B2 (en) | 2003-02-10 | 2008-01-08 | Henkel Kommanditgesellschaft Auf Aktien | Detergents or cleaning agents comprising a water-soluble building block system and a cellulose derivative with dirt dissolving properties |
| US7375072B2 (en) | 2003-02-10 | 2008-05-20 | Henkel Kommanditgesellschaft Auf Aktien | Bleach-containing laundry detergents or cleaning compositions comprising water-soluble builder system and soil release-capable cellulose derivative |
| WO2008077688A1 (de) * | 2006-12-21 | 2008-07-03 | Henkel Ag & Co. Kgaa | Stabilisierung von zusammensetzungen, enthaltend wasserstoffperoxid |
| US7456143B2 (en) | 2002-12-20 | 2008-11-25 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Bleach-containing washing or cleaning agents containing a sulfate/silicate coated percarbonate |
| DE10242221B4 (de) * | 2002-09-12 | 2009-10-15 | Henkel Ag & Co. Kgaa | Verfahren zum Bleichen von Aniontensidsäuren |
Families Citing this family (99)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA777769A (en) * | 1963-03-18 | 1968-02-06 | H. Roy Clarence | Substituted methylene diphosphonic acid compounds and detergent compositions |
| DE1297065B (de) * | 1963-07-06 | 1969-06-12 | Degussa | Verfahren zum Waschen und bzw. oder Bleichen von Textilien |
| US3297578A (en) * | 1963-07-26 | 1967-01-10 | Monsanto Co | Bleaching, sterilizing, disinfecting, and deterging compositions |
| US3394083A (en) * | 1963-08-15 | 1968-07-23 | Monsanto Co | Effervescent builder compositions and detergent compositions containing the same |
| US3234140A (en) * | 1964-06-05 | 1966-02-08 | Monsanto Co | Stabilization of peroxy solutions |
| US3458457A (en) * | 1964-08-06 | 1969-07-29 | Albright & Wilson Mfg Ltd | Phosphorus-containing flame retardant polyurethanes |
| CA770172A (en) * | 1965-03-30 | 1967-10-24 | T. Quimby Oscar | Class of organo phosphorous compounds and process for preparing members thereof |
| DE1251759B (de) * | 1965-03-30 | 1967-10-12 | The Procter S. Gamble Company, Cincinnati, Ohio (V St A) | Verfahren zur kontinuierlichen Herstellung von Athan 1 hydroxy - 1 1-diphosphonsaure |
| US3366675A (en) * | 1965-03-30 | 1968-01-30 | Procter & Gamble | Process for the preparation of organo-phosphorus compounds |
| US3400150A (en) * | 1965-07-29 | 1968-09-03 | Procter & Gamble | Process for preparing hydroxydiphosphonic acids from elemental phosphorous, oxygen and carboxylic acids |
| US4440646A (en) * | 1965-08-24 | 1984-04-03 | Plains Chemical Development Co. | Chelation |
| US4188234A (en) * | 1965-08-24 | 1980-02-12 | Plains Chemical Development Co. | Chelation |
| US4020091A (en) * | 1965-10-28 | 1977-04-26 | Plains Chemical Development Co. | Chelation |
| US3504018A (en) * | 1966-12-19 | 1970-03-31 | Monsanto Co | Process for preparing phosphonic acids |
| US3496223A (en) * | 1966-12-19 | 1970-02-17 | Monsanto Co | Process for preparing phosphonic acids |
| US3462480A (en) * | 1967-01-04 | 1969-08-19 | Fmc Corp | Method of producing organic peroxy acids |
| US3496222A (en) * | 1967-12-28 | 1970-02-17 | Procter & Gamble | Diacetylated cyclic dimer of ethane-1-hydroxy - 1,1 - diphosphonic acid and salts thereof |
| US3692841A (en) * | 1969-06-09 | 1972-09-19 | Norac Co | Nonhazardous polymerization initiators |
| US4152358A (en) * | 1971-05-24 | 1979-05-01 | Petro-Tex Chemical Corporation | Preparation of hydroperoxides by autoxidation |
| BE818616A (fr) * | 1973-08-30 | 1975-02-10 | Solutions aqueuses stabilisees de peroxyde d'hydrogene | |
| US3951838A (en) * | 1973-10-10 | 1976-04-20 | E. I. Du Pont De Nemours And Company | Silica sol stabilizers for improving the stability of sodium percarbonate in solid bleaches and detergents |
| US4061721A (en) * | 1975-11-28 | 1977-12-06 | Ppg Industries, Inc. | Hydrogen peroxide stabilization with phenylphosphonic acids |
| US4034064A (en) * | 1976-02-02 | 1977-07-05 | Ppg Industries, Inc. | Hydrogen peroxide stabilization with triamides of phosphorus |
| AT352241B (de) * | 1977-04-22 | 1979-09-10 | Henkel Kgaa | Pulverfoermiges, phosphatfreies textil- waschmittel |
| US4164394A (en) * | 1978-10-10 | 1979-08-14 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| US4496472A (en) * | 1981-12-23 | 1985-01-29 | Ciba-Geigy Corporation | Process for bleaching cellulosic fibre materials using oligomers of phosphonic acid esters as stabilizers in alkaline, peroxide-containing bleaching liquors |
| US4515596A (en) * | 1982-07-27 | 1985-05-07 | Ciba-Geigy Corporation | Process for aftertreating dyed fibrous material made of or containing cellulose |
| US4401509A (en) * | 1982-09-07 | 1983-08-30 | Fmc Corporation | Composition and process for printed circuit etching using a sulfuric acid solution containing hydrogen peroxide |
| US4515597A (en) * | 1982-12-10 | 1985-05-07 | Ciba Geigy Corporation | Magnesium complexes of oligomeric phosphonic acid esters, a process for their preparation and their use as stabilizers in alkaline, peroxide-containing bleach liquors |
| DE3445549A1 (de) * | 1984-12-14 | 1986-06-19 | Henkel KGaA, 4000 Düsseldorf | Acrylatdispersion und deren verwendung zur verdickung von wasserstoffperoxid-zubereitungen |
| US4614646A (en) * | 1984-12-24 | 1986-09-30 | The Dow Chemical Company | Stabilization of peroxide systems in the presence of alkaline earth metal ions |
| EP0222696B1 (de) * | 1985-10-14 | 1990-05-23 | Ciba-Geigy Ag | Verfahren zur Nachbehandlung von mit sulfogruppenhaltigen Farbstoffen gefärbtem Cellulosematerial |
| US4889689A (en) * | 1986-10-14 | 1989-12-26 | Ciba-Geigy Corporation | Method of disinfecting a soft contact lens with a diethylene triamine penta(methylenephosphonic acid) stabilized hydrogen peroxide solution |
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| AU2019222696B2 (en) | 2018-02-14 | 2024-02-29 | Ecolab Usa Inc. | Compositions and methods for the reduction of biofilm and spores from membranes |
| KR102520527B1 (ko) | 2020-12-24 | 2023-04-11 | 군산대학교산학협력단 | 안정성이 향상된 저농도 과초산계 소독제조성물 |
-
0
- NL NL130828D patent/NL130828C/xx active
- NL NL252116D patent/NL252116A/xx unknown
-
1959
- 1959-06-03 DE DEH36547A patent/DE1107207B/de active Pending
-
1960
- 1960-05-09 CH CH532760A patent/CH396852A/de unknown
-
1962
- 1962-01-31 US US170221A patent/US3122417A/en not_active Expired - Lifetime
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3159581A (en) * | 1962-04-13 | 1964-12-01 | Procter & Gamble | Detergency composition |
| US3392121A (en) * | 1962-11-05 | 1968-07-09 | Procter & Gamble | Built detergent compositions |
| DE1261850B (de) * | 1965-03-30 | 1968-02-29 | Procter & Gamble | Verfahren zur Herstellung von AEthan-1-hydroxy-1,1-diphosphonsaeure |
| DE1300563B (de) * | 1965-05-13 | 1969-08-07 | Procter & Gamble | Verfahren zur Herstellung von AEthan-1-hydroxy-1, 1-diphosphonsaeure |
| DE2012171A1 (de) * | 1970-03-14 | 1971-10-07 | Benckiser-Knapsack GmbH, 6700 Ludwigshafen | Mittel zur Vorbehandlung von Fasergut aus nativer Cellulose |
| DE2226784A1 (US07754670-20100713-C00008.png) * | 1971-06-03 | 1972-12-14 | ||
| DE2536618A1 (de) * | 1975-08-16 | 1977-02-24 | Henkel & Cie Gmbh | Konzentrate von mikrobiziden mitteln |
| DE2616049A1 (de) * | 1976-04-12 | 1977-10-27 | Henkel & Cie Gmbh | Lagerstabile konzentrate von funktionellen mitteln |
| DE2936551C1 (de) * | 1978-02-17 | 1985-01-17 | Mo och Domsjö AB, Örnsköldsvik | Verfahren zum Bleichen und Extrahieren eines Lignocellulose enthaltenden Materials |
| WO1991003590A1 (de) * | 1989-09-04 | 1991-03-21 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur desinfektion von textilien in waschstrassen |
| US5651793A (en) * | 1993-09-30 | 1997-07-29 | Henkel Kommanditgesellschaft Auf Aktien | Hydrogen peroxide preparations containing foam regulators |
| US7008593B2 (en) | 2002-05-31 | 2006-03-07 | Henkel Kommanditgesellschaft Auf Aktien | Deodorization of cationic acetonitrile derivatives |
| DE10242221B4 (de) * | 2002-09-12 | 2009-10-15 | Henkel Ag & Co. Kgaa | Verfahren zum Bleichen von Aniontensidsäuren |
| US7456143B2 (en) | 2002-12-20 | 2008-11-25 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Bleach-containing washing or cleaning agents containing a sulfate/silicate coated percarbonate |
| US7316995B2 (en) | 2003-02-10 | 2008-01-08 | Henkel Kommanditgesellschaft Auf Aktien | Detergents or cleaning agents comprising a water-soluble building block system and a cellulose derivative with dirt dissolving properties |
| US7375072B2 (en) | 2003-02-10 | 2008-05-20 | Henkel Kommanditgesellschaft Auf Aktien | Bleach-containing laundry detergents or cleaning compositions comprising water-soluble builder system and soil release-capable cellulose derivative |
| WO2008077688A1 (de) * | 2006-12-21 | 2008-07-03 | Henkel Ag & Co. Kgaa | Stabilisierung von zusammensetzungen, enthaltend wasserstoffperoxid |
Also Published As
| Publication number | Publication date |
|---|---|
| US3122417A (en) | 1964-02-25 |
| CH396852A (de) | 1965-08-15 |
| NL130828C (US07754670-20100713-C00008.png) | |
| NL252116A (US07754670-20100713-C00008.png) |
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