DE1091760B - Verfahren zur Herstellung von linearen, hochmolekularen Polymeren aus Vinylmonomeren, die Silicium-, Germanium-, Zinn- oder Bleiatome enthalten - Google Patents
Verfahren zur Herstellung von linearen, hochmolekularen Polymeren aus Vinylmonomeren, die Silicium-, Germanium-, Zinn- oder Bleiatome enthaltenInfo
- Publication number
- DE1091760B DE1091760B DEM40018A DEM0040018A DE1091760B DE 1091760 B DE1091760 B DE 1091760B DE M40018 A DEM40018 A DE M40018A DE M0040018 A DEM0040018 A DE M0040018A DE 1091760 B DE1091760 B DE 1091760B
- Authority
- DE
- Germany
- Prior art keywords
- monomers
- polymers
- tin
- compounds
- germanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000178 monomer Substances 0.000 title claims description 28
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims description 17
- 229920002554 vinyl polymer Polymers 0.000 title claims description 17
- 229910052718 tin Inorganic materials 0.000 title claims description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title claims description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 10
- 229910052710 silicon Inorganic materials 0.000 title claims description 10
- 239000010703 silicon Substances 0.000 title claims description 10
- 229910052732 germanium Inorganic materials 0.000 title claims description 6
- 230000008569 process Effects 0.000 title claims description 5
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 229920006158 high molecular weight polymer Polymers 0.000 title description 4
- 229920000642 polymer Polymers 0.000 claims description 54
- 238000006116 polymerization reaction Methods 0.000 claims description 22
- 239000003054 catalyst Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 230000000737 periodic effect Effects 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002902 organometallic compounds Chemical class 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 150000002738 metalloids Chemical group 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- -1 Aluminum compound Chemical class 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 150000002611 lead compounds Chemical group 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 239000012442 inert solvent Substances 0.000 claims 1
- 150000003609 titanium compounds Chemical class 0.000 claims 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 37
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 239000000047 product Substances 0.000 description 12
- 238000002844 melting Methods 0.000 description 11
- 230000008018 melting Effects 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000004711 α-olefin Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 6
- 239000000284 extract Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- HYWCXWRMUZYRPH-UHFFFAOYSA-N trimethyl(prop-2-enyl)silane Chemical compound C[Si](C)(C)CC=C HYWCXWRMUZYRPH-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012259 ether extract Substances 0.000 description 3
- DNAJDTIOMGISDS-UHFFFAOYSA-N prop-2-enylsilane Chemical compound [SiH3]CC=C DNAJDTIOMGISDS-UHFFFAOYSA-N 0.000 description 3
- 239000012265 solid product Substances 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical class [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 125000004369 butenyl group Chemical class C(=CCC)* 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229920001580 isotactic polymer Polymers 0.000 description 2
- 229910052752 metalloid Inorganic materials 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 2
- 239000003017 thermal stabilizer Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 229920001585 atactic polymer Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical class C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910000078 germane Inorganic materials 0.000 description 1
- VGRFVJMYCCLWPQ-UHFFFAOYSA-N germanium Chemical compound [Ge].[Ge] VGRFVJMYCCLWPQ-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- GUSQYBRZWHTZGT-UHFFFAOYSA-N hex-1-enylsilane Chemical class CCCCC=C[SiH3] GUSQYBRZWHTZGT-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical group [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 229920005684 linear copolymer Polymers 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- JWBLXUGMIOSKMS-UHFFFAOYSA-N pent-1-enylsilane Chemical class CCCC=C[SiH3] JWBLXUGMIOSKMS-UHFFFAOYSA-N 0.000 description 1
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- SVGQCVJXVAMCPM-UHFFFAOYSA-N triethyl(prop-2-enyl)silane Chemical compound CC[Si](CC)(CC)CC=C SVGQCVJXVAMCPM-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/04—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F30/08—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/04—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1832757 | 1957-12-23 | ||
| IT513458 | 1958-04-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1091760B true DE1091760B (de) | 1960-10-27 |
Family
ID=26325662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEM40018A Pending DE1091760B (de) | 1957-12-23 | 1958-12-22 | Verfahren zur Herstellung von linearen, hochmolekularen Polymeren aus Vinylmonomeren, die Silicium-, Germanium-, Zinn- oder Bleiatome enthalten |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3223686A (en, 2012) |
| BE (1) | BE574128A (en, 2012) |
| CH (1) | CH392889A (en, 2012) |
| DE (1) | DE1091760B (en, 2012) |
| FR (1) | FR1217343A (en, 2012) |
| GB (1) | GB899945A (en, 2012) |
| NL (2) | NL101938C (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2907828A1 (de) * | 1978-03-01 | 1979-09-06 | Ryuichi Sato | Germaniumhaltiges organisches polymer und verfahren zu seiner herstellung |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1125619B (en, 2012) * | 1960-07-08 | |||
| US3322807A (en) * | 1960-07-13 | 1967-05-30 | Monsanto Co | 1, 4-bis-and 2, 4-bis-di-(triorganosilyl) but-1-enes |
| US3240768A (en) * | 1961-06-09 | 1966-03-15 | Exxon Research Engineering Co | Copolymers of alpha olefin and reactive omega alkenyl silanes |
| US3305388A (en) * | 1963-08-28 | 1967-02-21 | Dow Chemical Co | Method of coating metals with organo tin compounds |
| US3415622A (en) * | 1963-08-28 | 1968-12-10 | Dow Chemical Co | Method for inhibiting corrosion |
| US3356616A (en) * | 1964-03-05 | 1967-12-05 | Borden Co | Plastic scintillators |
| US3367902A (en) * | 1965-11-12 | 1968-02-06 | Arthur D. Ketley | 1, 1-dichloro-2-vinyl cyclopropane polymer and a process for polymerizing same |
| GB1183585A (en) * | 1966-06-02 | 1970-03-11 | Midland Silicones Ltd | Organosilicon-Modified Materials |
| US4088670A (en) * | 1974-10-01 | 1978-05-09 | Rhone-Poulenc Industries | Ethylenic silicon compounds and thermoplastic elastomers obtained therefrom |
| FR2295050A1 (fr) * | 1974-10-23 | 1976-07-16 | Inst Neftechimicheskogo Sintez | Copolymeres de silcarbanes a base de vinyltriorganosilanes presentant une permeabilite selective aux gaz |
| US4393113A (en) | 1980-06-05 | 1983-07-12 | Teitin Limited | Novel silicon-containing copolymer, ultrathin solid membrane composed of said copolymer, use of said solid membrane for concentrating a specified gas in a gaseous mixture, and process for producing said solid membrane |
| US4347376A (en) * | 1980-12-24 | 1982-08-31 | Fluorchem Inc. | Method of making and polymerizing perfluoroalkylene acetylene compounds |
| DE3407148A1 (de) * | 1984-02-28 | 1985-08-29 | Basf Ag, 6700 Ludwigshafen | Membrane aus vinylpolymeren und deren verwendung |
| JPS60206806A (ja) * | 1984-03-30 | 1985-10-18 | Japan Synthetic Rubber Co Ltd | エチレン系共重合体の製造方法 |
| US4657841A (en) * | 1985-10-28 | 1987-04-14 | Bell Communications Research, Inc. | Electron beam sensitive positive resist comprising the polymerization product of an ω-alkenyltrimethyl silane monomer with sulfur dioxide |
| EP0301099B1 (en) * | 1987-01-28 | 1996-11-06 | MITSUI TOATSU CHEMICALS, Inc. | Processes for preparing organosilicon compounds and silicon carbide |
| US5508363A (en) * | 1987-01-28 | 1996-04-16 | Mitsui Toatsu Chemicals, Incorporated | Preparation process of organosilicon compounds and production of silicon carbide |
| US4974929A (en) * | 1987-09-22 | 1990-12-04 | Baxter International, Inc. | Fiber optical probe connector for physiologic measurement devices |
| US4996266A (en) * | 1987-10-09 | 1991-02-26 | Minnesota Mining And Manufacturing Company | Method of making condensed phase polymers |
| US5210143A (en) * | 1987-10-09 | 1993-05-11 | Minnesota Mining And Manufacturing Company | Condensed phase polymers |
| US4857618A (en) * | 1987-10-09 | 1989-08-15 | Minnesota Mining And Manufacturing Company | Condensed phase polymers |
| US4857615A (en) * | 1987-10-09 | 1989-08-15 | Minnesota Mining And Manufacturing Company | Method of making condensed phase polymers |
| US5115034A (en) * | 1987-10-09 | 1992-05-19 | Minnesota Mining And Manufacturing Company | Condensed phase polymers |
| JP2713585B2 (ja) * | 1987-11-17 | 1998-02-16 | 三井東圧化学株式会社 | 新規なポリα−オレフィン樹脂組成物及びその用途 |
| CA1312166C (en) * | 1987-12-16 | 1992-12-29 | Mitsui Chemicals, Incorporated | Polyolefin resin composition |
| KR920005671B1 (ko) * | 1987-12-16 | 1992-07-13 | 미쯔이도오아쯔가가꾸 가부시끼가이샤 | 함규소 폴리머의 제조방법 |
| JP2618668B2 (ja) * | 1987-12-24 | 1997-06-11 | 東レ・ダウコーニング・シリコーン株式会社 | β−置換アリルシランの製造方法 |
| JPH0813822B2 (ja) | 1988-02-29 | 1996-02-14 | 三井東圧化学株式会社 | 有機ケイ素化合物 |
| EP0331364B1 (en) * | 1988-03-01 | 1996-01-24 | MITSUI TOATSU CHEMICALS, Inc. | Block copolymer of propylene and a process for the production thereof |
| JP2710788B2 (ja) * | 1988-06-09 | 1998-02-10 | 三井東圧化学株式会社 | 架橋ポリプロピレンの製造方法 |
| EP0363990A3 (en) * | 1988-10-14 | 1991-09-11 | Aristech Chemical Corporation | Incorporation of functional groups in polymers |
| JP3024685B2 (ja) * | 1989-11-28 | 2000-03-21 | 三井化学株式会社 | α―オレフィン―アルケニルシラン共重合体およびその製造方法 |
| JP2974404B2 (ja) * | 1989-12-28 | 1999-11-10 | 三井化学株式会社 | 新規な重合体およびそれを含むポリプロピレン樹脂組成物 |
| JPH0762030A (ja) * | 1993-08-31 | 1995-03-07 | Daicel Chem Ind Ltd | 光学活性アセチレンポリマー及びその膜、並びにそれを用いた光学分割方法 |
| US7348388B2 (en) * | 2001-11-16 | 2008-03-25 | E.I. Du Pont De Nemours And Company | Copolymers of olefins and vinyl- and allylsilanes |
| EP4172247A1 (en) | 2020-06-24 | 2023-05-03 | Dow Global Technologies LLC | Olefin/siloxane interpolymers and olefin/cyclic silane interpolymers |
| WO2021258328A1 (en) * | 2020-06-24 | 2021-12-30 | Dow Global Technologies Llc | Crosslinkable olefin/silane interpolymer compositions |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2388161A (en) * | 1944-07-31 | 1945-10-30 | American Cyanamid Co | Tetra-allyl silicane and process of preparing the same |
| US2438612A (en) * | 1944-09-26 | 1948-03-30 | Montclair Res Corp | Copolymers of tetraallylsilane |
| US2595729A (en) * | 1945-03-09 | 1952-05-06 | Westinghouse Electric Corp | Organosilicon compounds and conductors insulated therewith |
| US2538657A (en) * | 1945-07-10 | 1951-01-16 | Gen Electric | Tetra allyl silane and polymers thereof |
| US2532583A (en) * | 1945-07-24 | 1950-12-05 | Du Pont | Silicon-containing polymer preparation |
| US2448391A (en) * | 1946-10-15 | 1948-08-31 | Gen Electric | Alkenyl silane interpolymers |
| US2512390A (en) * | 1949-06-03 | 1950-06-20 | Dow Corning | Alpha-chlorovinylsilanes |
| US2728785A (en) * | 1952-03-19 | 1955-12-27 | Du Pont | Process for preparing long-chain 4,5-ethylenically unsaturated silanes |
| CH356913A (de) * | 1954-06-08 | 1961-09-15 | Montedison Spa | Verfahren zur Polymerisation von olefinisch ungesättigten Kohlenwasserstoffen |
| US2811541A (en) * | 1955-06-20 | 1957-10-29 | Dow Corning | Polymerization of vinyldihydrocarbylsilanes and products thereof |
| US2958681A (en) * | 1956-11-30 | 1960-11-01 | Du Pont | Crystalline polyallyl-trimethylsilane |
-
0
- NL NL234502D patent/NL234502A/xx unknown
- BE BE574128D patent/BE574128A/xx unknown
- NL NL101938D patent/NL101938C/xx active
-
1958
- 1958-12-17 GB GB40706/58A patent/GB899945A/en not_active Expired
- 1958-12-19 FR FR782117A patent/FR1217343A/fr not_active Expired
- 1958-12-19 US US781425A patent/US3223686A/en not_active Expired - Lifetime
- 1958-12-22 DE DEM40018A patent/DE1091760B/de active Pending
- 1958-12-23 CH CH6761358A patent/CH392889A/de unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2907828A1 (de) * | 1978-03-01 | 1979-09-06 | Ryuichi Sato | Germaniumhaltiges organisches polymer und verfahren zu seiner herstellung |
Also Published As
| Publication number | Publication date |
|---|---|
| NL101938C (en, 2012) | |
| FR1217343A (fr) | 1960-05-03 |
| GB899945A (en) | 1962-06-27 |
| CH392889A (de) | 1965-05-31 |
| BE574128A (en, 2012) | |
| US3223686A (en) | 1965-12-14 |
| NL234502A (en, 2012) |
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