DE1058736B - Verfahren zur Polymerisation und Mischpolymerisation von Olefinen mit mehr als 2 Kohlenstoffatomen - Google Patents
Verfahren zur Polymerisation und Mischpolymerisation von Olefinen mit mehr als 2 KohlenstoffatomenInfo
- Publication number
- DE1058736B DE1058736B DEF24410A DEF0024410A DE1058736B DE 1058736 B DE1058736 B DE 1058736B DE F24410 A DEF24410 A DE F24410A DE F0024410 A DEF0024410 A DE F0024410A DE 1058736 B DE1058736 B DE 1058736B
- Authority
- DE
- Germany
- Prior art keywords
- polymerization
- aluminum
- olefins
- carbon atoms
- interpolymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 7
- 150000001336 alkenes Chemical class 0.000 title claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 title claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 19
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 13
- 239000012190 activator Substances 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000004711 α-olefin Substances 0.000 claims description 5
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 229920001580 isotactic polymer Polymers 0.000 description 4
- -1 Ethylene, propylene Chemical group 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- TVZXZQOUICFFCL-UHFFFAOYSA-M chloro(ethyl)alumane Chemical compound CC[AlH]Cl TVZXZQOUICFFCL-UHFFFAOYSA-M 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000001550 testis Anatomy 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE573034D BE573034A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1957-11-15 | ||
| DEF24410A DE1058736B (de) | 1957-11-15 | 1957-11-15 | Verfahren zur Polymerisation und Mischpolymerisation von Olefinen mit mehr als 2 Kohlenstoffatomen |
| FR1214380D FR1214380A (fr) | 1957-11-15 | 1958-11-15 | Procédé de polymérisation et copolymérisation d'oléfines |
| GB3697458A GB884583A (en) | 1957-11-15 | 1958-11-17 | Process of polymerizing or copolymerizing olefines |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF24410A DE1058736B (de) | 1957-11-15 | 1957-11-15 | Verfahren zur Polymerisation und Mischpolymerisation von Olefinen mit mehr als 2 Kohlenstoffatomen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1058736B true DE1058736B (de) | 1959-06-04 |
Family
ID=7091224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF24410A Pending DE1058736B (de) | 1957-11-15 | 1957-11-15 | Verfahren zur Polymerisation und Mischpolymerisation von Olefinen mit mehr als 2 Kohlenstoffatomen |
Country Status (4)
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1193677B (de) * | 1960-09-07 | 1965-05-26 | Glanzstoff Ag | Verfahren zur Polymerisation von alpha-Olefinen |
| DE1241992B (de) * | 1960-09-07 | 1967-06-08 | Glanzstoff Ag | Verfahren zur Polymerisation von alpha-Olefinen |
| DE1301526B (de) * | 1960-09-07 | 1969-08-21 | Glanzstoff Ag | Verfahren zur Polymerisation von alpha-Olefinen |
| DE102004047157A1 (de) * | 2004-09-29 | 2006-04-06 | Höhne GmbH | Abzweigklemmmuffe |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3275613A (en) * | 1963-02-06 | 1966-09-27 | Standard Oil Co | Process for preparing alpha-olefin polymers which are substantially free of residual catalyst |
| US4048419A (en) | 1973-04-14 | 1977-09-13 | Chemische Werke Huls Aktiengesellschaft | Process for the production of partially crystalline polybutene-1 |
-
0
- BE BE573034D patent/BE573034A/xx unknown
-
1957
- 1957-11-15 DE DEF24410A patent/DE1058736B/de active Pending
-
1958
- 1958-11-15 FR FR1214380D patent/FR1214380A/fr not_active Expired
- 1958-11-17 GB GB3697458A patent/GB884583A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1193677B (de) * | 1960-09-07 | 1965-05-26 | Glanzstoff Ag | Verfahren zur Polymerisation von alpha-Olefinen |
| DE1241992B (de) * | 1960-09-07 | 1967-06-08 | Glanzstoff Ag | Verfahren zur Polymerisation von alpha-Olefinen |
| DE1301526B (de) * | 1960-09-07 | 1969-08-21 | Glanzstoff Ag | Verfahren zur Polymerisation von alpha-Olefinen |
| DE102004047157A1 (de) * | 2004-09-29 | 2006-04-06 | Höhne GmbH | Abzweigklemmmuffe |
Also Published As
| Publication number | Publication date |
|---|---|
| BE573034A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| GB884583A (en) | 1961-12-13 |
| FR1214380A (fr) | 1960-04-08 |
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