DE102015202258A1 - Reduktionsverfahren und Elektrolysesystem zur elektrochemischen Kohlenstoffdioxid-Verwertung - Google Patents
Reduktionsverfahren und Elektrolysesystem zur elektrochemischen Kohlenstoffdioxid-Verwertung Download PDFInfo
- Publication number
- DE102015202258A1 DE102015202258A1 DE102015202258.7A DE102015202258A DE102015202258A1 DE 102015202258 A1 DE102015202258 A1 DE 102015202258A1 DE 102015202258 A DE102015202258 A DE 102015202258A DE 102015202258 A1 DE102015202258 A1 DE 102015202258A1
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- Germany
- Prior art keywords
- cathode
- carbon dioxide
- reduction process
- reduction
- electrolysis system
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 178
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 89
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 89
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 44
- 238000011946 reduction process Methods 0.000 title claims abstract description 21
- 238000011084 recovery Methods 0.000 title description 5
- 239000000463 material Substances 0.000 claims abstract description 62
- 238000006722 reduction reaction Methods 0.000 claims abstract description 37
- 238000012546 transfer Methods 0.000 claims abstract description 27
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 26
- 125000001145 hydrido group Chemical group *[H] 0.000 claims abstract description 10
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 6
- 230000001737 promoting effect Effects 0.000 claims abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 33
- 230000009467 reduction Effects 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000010410 layer Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 150000003624 transition metals Chemical class 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052723 transition metal Inorganic materials 0.000 claims description 8
- 239000004065 semiconductor Substances 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 5
- 239000011241 protective layer Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 150000004696 coordination complex Chemical class 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000003586 protic polar solvent Substances 0.000 claims description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
- 235000019256 formaldehyde Nutrition 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 24
- 239000003426 co-catalyst Substances 0.000 abstract description 4
- 239000003792 electrolyte Substances 0.000 description 48
- 238000006243 chemical reaction Methods 0.000 description 19
- 239000007789 gas Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 12
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000012528 membrane Substances 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 239000003446 ligand Substances 0.000 description 10
- 238000009792 diffusion process Methods 0.000 description 8
- 241000894007 species Species 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229910052702 rhenium Inorganic materials 0.000 description 5
- NBBILGZMKRYCTO-UHFFFAOYSA-N 2-pyridin-2-ylpyridine;rhenium Chemical compound [Re].N1=CC=CC=C1C1=CC=CC=N1 NBBILGZMKRYCTO-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- -1 carbon water compound Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 239000011736 potassium bicarbonate Substances 0.000 description 2
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 2
- 235000015497 potassium bicarbonate Nutrition 0.000 description 2
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- 101100518972 Caenorhabditis elegans pat-6 gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- YSVZGWAJIHWNQK-UHFFFAOYSA-N [3-(hydroxymethyl)-2-bicyclo[2.2.1]heptanyl]methanol Chemical compound C1CC2C(CO)C(CO)C1C2 YSVZGWAJIHWNQK-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 238000004502 linear sweep voltammetry Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003282 rhenium compounds Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
- C25B1/55—Photoelectrolysis
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
- C25B11/077—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Catalysts (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102015202258.7A DE102015202258A1 (de) | 2015-02-09 | 2015-02-09 | Reduktionsverfahren und Elektrolysesystem zur elektrochemischen Kohlenstoffdioxid-Verwertung |
| EP16704413.0A EP3234225A1 (de) | 2015-02-09 | 2016-02-05 | Reduktionsverfahren und elektrolysesystem zur elektrochemischen kohlenstoffdioxid-verwertung |
| JP2017541254A JP2018510262A (ja) | 2015-02-09 | 2016-02-05 | 二酸化炭素の電気化学的利用のための還元方法及び電気分解システム |
| US15/549,778 US20180023198A1 (en) | 2015-02-09 | 2016-02-05 | Reduction Method And Electrolysis System For Electrochemical Carbon Dioxide Utilization |
| PCT/EP2016/052516 WO2016128323A1 (de) | 2015-02-09 | 2016-02-05 | Reduktionsverfahren und elektrolysesystem zur elektrochemischen kohlenstoffdioxid-verwertung |
| CN201680009432.6A CN107208284A (zh) | 2015-02-09 | 2016-02-05 | 用于二氧化碳的电化学利用的还原方法和电解系统 |
| ZA2017/05252A ZA201705252B (en) | 2015-02-09 | 2017-08-03 | Reduction method and electrolysis system for electrochemical carbon dioxide utilization |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102015202258.7A DE102015202258A1 (de) | 2015-02-09 | 2015-02-09 | Reduktionsverfahren und Elektrolysesystem zur elektrochemischen Kohlenstoffdioxid-Verwertung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102015202258A1 true DE102015202258A1 (de) | 2016-08-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102015202258.7A Withdrawn DE102015202258A1 (de) | 2015-02-09 | 2015-02-09 | Reduktionsverfahren und Elektrolysesystem zur elektrochemischen Kohlenstoffdioxid-Verwertung |
Country Status (7)
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12286714B2 (en) * | 2015-10-09 | 2025-04-29 | Rutgers, The State University Of New Jersey | Nickel phosphide catalysts for direct electrochemical CO2 reduction to hydrocarbons |
| US20170268118A1 (en) * | 2016-03-18 | 2017-09-21 | Kabushiki Kaisha Toshiba | Electrochemical reaction device |
| JP2018090838A (ja) * | 2016-11-30 | 2018-06-14 | 昭和シェル石油株式会社 | 二酸化炭素還元装置 |
| DE102017005681A1 (de) | 2017-06-14 | 2018-12-20 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung eines Kohlenmonoxid enthaltenden Gasprodukts |
| DE102017005680A1 (de) | 2017-06-14 | 2018-12-20 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung eines Kohlenmonoxid enthaltenden Gasprodukts |
| DE102017005678A1 (de) | 2017-06-14 | 2018-12-20 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung eines Kohlenmonoxid enthaltenden Gasprodukts |
| DE102017219974A1 (de) * | 2017-11-09 | 2019-05-09 | Siemens Aktiengesellschaft | Herstellung und Abtrennung von Phosgen durch kombinierte CO2 und Chlorid-Elektrolyse |
| DE102018212409A1 (de) * | 2017-11-16 | 2019-05-16 | Siemens Aktiengesellschaft | Kohlenwasserstoff-selektive Elektrode |
| DE102018201287A1 (de) * | 2018-01-29 | 2019-08-01 | Siemens Aktiengesellschaft | Poröse Elektrode zur elektrochemischen Umsetzung organischer Verbindungen in zwei nicht mischbaren Phasen in einem elektrochemischen Flussreaktor |
| DE102018000672A1 (de) * | 2018-01-29 | 2019-08-14 | Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen | Verfahren zur Übertragung eines Zielstoffs zwischen zwei flüssigen Phasen |
| DE102018202344A1 (de) | 2018-02-15 | 2019-08-22 | Siemens Aktiengesellschaft | Elektrochemische Herstellung von Kohlenstoffmonoxid und/oder Synthesegas |
| DE102018202337A1 (de) | 2018-02-15 | 2019-08-22 | Linde Aktiengesellschaft | Elektrochemische Herstellung eines Gases umfassend CO mit Zwischenkühlung des Elektrolytstroms |
| JP6822998B2 (ja) * | 2018-03-20 | 2021-01-27 | 株式会社東芝 | 電気化学反応装置 |
| WO2020005482A1 (en) * | 2018-06-29 | 2020-01-02 | Illinois Institute Of Technology | Transition metal mxene catalysts for conversion of carbon dioxide to hydrocarbons |
| US12214337B2 (en) | 2018-06-29 | 2025-02-04 | Illinois Institute Of Technology | Transition metal MXene catalysts for conversion of carbon dioxide to hydrocarbons |
| JP7262739B2 (ja) * | 2018-11-29 | 2023-04-24 | グローバル・リンク株式会社 | 電気分解装置の陽極及び陰極の製造方法 |
| US10590548B1 (en) * | 2018-12-18 | 2020-03-17 | Prometheus Fuels, Inc | Methods and systems for fuel production |
| NO20190144A1 (en) | 2019-01-31 | 2020-08-03 | Norsk Hydro As | A process for production of aluminium |
| CN110344071B (zh) * | 2019-08-14 | 2020-11-17 | 碳能科技（北京）有限公司 | 电还原co2装置和方法 |
| DE102019007265A1 (de) | 2019-10-18 | 2021-04-22 | Linde Gmbh | Verfahren und Anlage zur Herstellung eines an Kohlenstoffmonoxid reichen Gasprodukts |
| CN110983357A (zh) * | 2019-12-04 | 2020-04-10 | 昆明理工大学 | 一种电解二氧化碳制一氧化碳同时副产氯气、碳酸氢盐的三室隔膜电解方法 |
| US11001549B1 (en) * | 2019-12-06 | 2021-05-11 | Saudi Arabian Oil Company | Electrochemical reduction of carbon dioxide to upgrade hydrocarbon feedstocks |
| US20230002919A1 (en) * | 2019-12-11 | 2023-01-05 | Nippon Telegraph And Telephone Corporation | Carbon Dioxide Gas Phase Reduction Apparatus and Method |
| CN111575732A (zh) * | 2020-05-28 | 2020-08-25 | 昆明理工大学 | 一种光气合成原料的电化学制备方法 |
| DE102020004630A1 (de) | 2020-07-30 | 2022-02-03 | Linde Gmbh | Druckhaltung in einer Elektrolyseanlage |
| DE102020005254A1 (de) | 2020-08-27 | 2022-03-03 | Linde Gmbh | Verfahren und Anlage zur Herstellung von Kohlenstoffmonoxid |
| EP4050126A1 (de) | 2021-02-25 | 2022-08-31 | Linde GmbH | Co2-elektrolyse mit edukt-befeuchtung |
| JP7459848B2 (ja) * | 2021-07-26 | 2024-04-02 | 株式会社豊田中央研究所 | ガス拡散型電解フローセル用のカソード電極、及びガス拡散型電解フローセル |
| JP7730500B2 (ja) * | 2021-08-26 | 2025-08-28 | 三菱重工業株式会社 | 二酸化炭素吸収還元溶液、二酸化炭素吸収還元装置、及び二酸化炭素吸収還元方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61134331A (ja) * | 1984-12-03 | 1986-06-21 | Kotaro Ogura | 二酸化炭素のアセトアルデヒドによる還元固定法 |
| JPS62120489A (ja) * | 1985-11-18 | 1987-06-01 | Kotaro Ogura | 常温・常圧における二酸化炭素の間接電気化学的還元 |
| JPH01205088A (ja) * | 1988-02-10 | 1989-08-17 | Tanaka Kikinzoku Kogyo Kk | 二酸化炭素の電解還元方法 |
| JP2011082144A (ja) * | 2009-09-14 | 2011-04-21 | Toyota Central R&D Labs Inc | 複合光電極および光電気化学反応システム |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4668349A (en) * | 1986-10-24 | 1987-05-26 | The Standard Oil Company | Acid promoted electrocatalytic reduction of carbon dioxide by square planar transition metal complexes |
| JP2013253270A (ja) * | 2012-06-05 | 2013-12-19 | Sharp Corp | 二酸化炭素還元装置 |
-
2015
- 2015-02-09 DE DE102015202258.7A patent/DE102015202258A1/de not_active Withdrawn
-
2016
- 2016-02-05 US US15/549,778 patent/US20180023198A1/en not_active Abandoned
- 2016-02-05 JP JP2017541254A patent/JP2018510262A/ja active Pending
- 2016-02-05 WO PCT/EP2016/052516 patent/WO2016128323A1/de active Application Filing
- 2016-02-05 EP EP16704413.0A patent/EP3234225A1/de not_active Withdrawn
- 2016-02-05 CN CN201680009432.6A patent/CN107208284A/zh active Pending
-
2017
- 2017-08-03 ZA ZA2017/05252A patent/ZA201705252B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61134331A (ja) * | 1984-12-03 | 1986-06-21 | Kotaro Ogura | 二酸化炭素のアセトアルデヒドによる還元固定法 |
| JPS62120489A (ja) * | 1985-11-18 | 1987-06-01 | Kotaro Ogura | 常温・常圧における二酸化炭素の間接電気化学的還元 |
| JPH01205088A (ja) * | 1988-02-10 | 1989-08-17 | Tanaka Kikinzoku Kogyo Kk | 二酸化炭素の電解還元方法 |
| JP2011082144A (ja) * | 2009-09-14 | 2011-04-21 | Toyota Central R&D Labs Inc | 複合光電極および光電気化学反応システム |
Non-Patent Citations (4)
| Title |
|---|
| J. A. Keith et al. |
| J. A. Keith, K. A. Grice, C. P. Kubiak und E. A. Carter bekannt, erschienen in J. Am. Chem. Soc. 2013, 135, Seiten 15823–15829 |
| JIANG, Y. et al.: Catalytic CO2 Activation Assisted by Rhenium Hydride/B(C6F5)3 Frustrated Lewis Pairs-Metal Hydrides Functioning as FLP Bases. In: J. Am. Chem. Soc., 135, 2013, 7751 - 7760. * |
| Y. Jiang, O. Blacque, T. Fox und H. Berke beschrieben werden, erschienen in J. Am. Chem. Soc., 2013, 135 (20), Seiten 7751–7760 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107208284A (zh) | 2017-09-26 |
| US20180023198A1 (en) | 2018-01-25 |
| EP3234225A1 (de) | 2017-10-25 |
| JP2018510262A (ja) | 2018-04-12 |
| ZA201705252B (en) | 2019-06-26 |
| WO2016128323A1 (de) | 2016-08-18 |
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