DE102006049098B4 - Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien - Google Patents
Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien Download PDFInfo
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- DE102006049098B4 DE102006049098B4 DE102006049098.3A DE102006049098A DE102006049098B4 DE 102006049098 B4 DE102006049098 B4 DE 102006049098B4 DE 102006049098 A DE102006049098 A DE 102006049098A DE 102006049098 B4 DE102006049098 B4 DE 102006049098B4
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
- H01M2300/0037—Mixture of solvents
- H01M2300/004—Three solvents
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006049098.3A DE102006049098B4 (de) | 2006-10-13 | 2006-10-13 | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien |
| KR1020097007239A KR101421758B1 (ko) | 2006-10-13 | 2007-10-11 | 미세분말 화합물, 그의 제조 방법 및 리튬 이차 전지에서의 그의 용도 |
| US12/373,950 US8685289B2 (en) | 2006-10-13 | 2007-10-11 | Pulverulent compounds, a process for the preparation thereof and the use thereof in lithium secondary batteries |
| CA2664781A CA2664781C (en) | 2006-10-13 | 2007-10-11 | Pulverulent compounds, a process for the preparation thereof and the use thereof in lithium secondary batteries |
| PCT/EP2007/008848 WO2008043558A1 (en) | 2006-10-13 | 2007-10-11 | Pulverulent compounds, a process for the preparation thereof and the use thereof in lithium secondary batteries |
| EP07818919.8A EP2067196B1 (en) | 2006-10-13 | 2007-10-11 | Pulverulent compounds, a process for the preparation thereof and the use thereof in lithium secondary batteries |
| JP2009531776A JP5458886B2 (ja) | 2006-10-13 | 2007-10-11 | 化合物粉体、その製造方法およびリチウム二次電池へのその使用 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006049098.3A DE102006049098B4 (de) | 2006-10-13 | 2006-10-13 | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE102006049098A1 DE102006049098A1 (de) | 2008-04-17 |
| DE102006049098B4 true DE102006049098B4 (de) | 2023-11-09 |
Family
ID=38823584
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102006049098.3A Active DE102006049098B4 (de) | 2006-10-13 | 2006-10-13 | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8685289B2 (enExample) |
| EP (1) | EP2067196B1 (enExample) |
| JP (1) | JP5458886B2 (enExample) |
| KR (1) | KR101421758B1 (enExample) |
| CA (1) | CA2664781C (enExample) |
| DE (1) | DE102006049098B4 (enExample) |
| WO (1) | WO2008043558A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102362378B (zh) | 2009-02-20 | 2013-12-25 | 尤米科尔公司 | 在锂可充电电池中兼有高安全性和高功率的非均质正极材料 |
| CN106395918A (zh) * | 2009-10-22 | 2017-02-15 | 户田工业株式会社 | 镍-钴-锰类化合物颗粒粉末和锂复合氧化物颗粒粉末及其制造方法和非水电解质二次电池 |
| JP5488008B2 (ja) * | 2010-02-01 | 2014-05-14 | 日産自動車株式会社 | コンタミネーション分離装置 |
| EP2555287B1 (en) | 2010-04-01 | 2018-05-02 | Mitsubishi Chemical Corporation | Positive electrode material for lithium secondary battery, positive electrode for lithium secondary battery, and lithium secondary battery |
| JP5551195B2 (ja) * | 2011-03-16 | 2014-07-16 | 日本化学工業株式会社 | リチウムニッケルマンガンコバルト複合酸化物の製造方法 |
| JP5708277B2 (ja) * | 2011-06-07 | 2015-04-30 | 住友金属鉱山株式会社 | ニッケルマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、ならびに非水系電解質二次電池 |
| KR101446491B1 (ko) | 2012-03-16 | 2014-10-06 | 주식회사 엘지화학 | 리튬 복합 전이금속 산화물 제조용 전구체 및 그 제조방법 |
| JP5959953B2 (ja) * | 2012-06-22 | 2016-08-02 | 株式会社Gsユアサ | 非水電解質二次電池用活物質、非水電解質二次電池用活物質の製造方法、非水電解質二次電池用電極及び非水電解質二次電池 |
| WO2014155990A1 (ja) * | 2013-03-26 | 2014-10-02 | 三洋電機株式会社 | 非水電解質二次電池用正極及び非水電解質二次電池 |
| JP6017364B2 (ja) * | 2013-03-29 | 2016-10-26 | Jx金属株式会社 | リチウムイオン電池用正極活物質、リチウムイオン電池用正極、及び、リチウムイオン電池 |
| JP6469138B2 (ja) * | 2014-06-10 | 2019-02-13 | ユミコア | 優れた硬強度を有する正極材料 |
| US20160156020A1 (en) * | 2014-11-27 | 2016-06-02 | Hitachi Metals, Ltd. | Method for manufacturing cathode electrode materials |
| JP6485232B2 (ja) | 2014-11-27 | 2019-03-20 | 日立金属株式会社 | 正極活物質の製造方法 |
| US10109854B2 (en) * | 2015-09-30 | 2018-10-23 | Panasonic Corporation | Positive electrode active material for nonaqueous electrolyte secondary batteries and nonaqueous electrolyte secondary battery |
| CN105355911B (zh) * | 2015-11-28 | 2018-02-13 | 中信大锰矿业有限责任公司大新锰矿分公司 | 一种氧化铝包覆镍钴锰酸锂正极材料的制备方法 |
| KR102004665B1 (ko) * | 2016-05-30 | 2019-07-26 | 히타치 긴조쿠 가부시키가이샤 | 리튬 이온 이차 전지용 정극 활물질 및 그것을 포함하는 정극, 그리고 그 정극을 구비하는 리튬 이온 이차 전지 |
| US20190207215A1 (en) | 2016-06-23 | 2019-07-04 | Hitachi Metals, Ltd. | Method for producing positive electrode active material for lithium ion secondary batteries, positive electrode active material for lithium ion secondary batteries, and lithium ion secondary battery |
| CN110214388A (zh) * | 2017-02-21 | 2019-09-06 | 松下电器产业株式会社 | 非水电解质二次电池用正极活性物质、和非水电解质二次电池 |
| KR102521605B1 (ko) | 2018-03-02 | 2023-04-12 | 유미코아 | 재충전가능 리튬 이온 배터리용 양극 물질 |
| US12227430B2 (en) * | 2018-12-19 | 2025-02-18 | Umicore | Cobalt oxide as a precursor of positive electrode materials for rechargeable lithium ion batteries |
| JP6640976B1 (ja) * | 2018-12-20 | 2020-02-05 | 住友化学株式会社 | リチウム遷移金属複合酸化物粉末、ニッケル含有遷移金属複合水酸化物粉末、リチウム二次電池用正極活物質、リチウム二次電池用正極及びリチウム二次電池 |
| US12451485B2 (en) | 2018-12-27 | 2025-10-21 | Contemporary Amperex Technology (Hong Kong) Limited | Pressure-resistant positive active material and electrochemical energy storage apparatus |
| CN112447939B (zh) * | 2019-09-02 | 2022-03-15 | 宁德时代新能源科技股份有限公司 | 正极活性材料、正极极片及锂离子二次电池 |
| DE102019218487A1 (de) | 2019-11-28 | 2021-06-02 | Volkswagen Aktiengesellschaft | Sekundärpartikel als Kathodenaktivmaterial für eine Lithium-Ionen-Batteriezelle |
| JP7235650B2 (ja) * | 2019-12-25 | 2023-03-08 | 住友化学株式会社 | リチウム遷移金属複合酸化物粉末、ニッケル含有遷移金属複合水酸化物粉末、リチウム二次電池用正極活物質、リチウム二次電池用正極及びリチウム二次電池 |
| JP7478587B2 (ja) * | 2020-05-14 | 2024-05-07 | 太平洋セメント株式会社 | リチウムイオン二次電池用正極活物質粒子及びその製造方法 |
| KR20220117639A (ko) * | 2021-02-17 | 2022-08-24 | 에스케이온 주식회사 | 리튬 이차 전지용 양극 활물질 및 이를 포함하는 리튬 이차 전지 |
| WO2023147726A1 (zh) * | 2022-09-23 | 2023-08-10 | 北京当升材料科技股份有限公司 | 含锂氧化物正极材料前驱体和含锂氧化物正极材料及其制备方法与应用、正极片及其应用 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5476530A (en) | 1992-05-04 | 1995-12-19 | Hermann C. Starck Gmbh & Co. Kg | Submicron carbonitride powders and their use |
| DE19849343A1 (de) | 1997-10-30 | 1999-06-02 | Samsung Display Devices Co Ltd | Lithiumcompositoxid, dessen Herstellung und sekundäre Lithiumionzelle mit Lithiumcompositoxid als aktives Material der positiven Elektrode |
| JP2001080920A (ja) | 1999-09-07 | 2001-03-27 | Nippon Chem Ind Co Ltd | 凝集粒状リチウム複合酸化物、その製造方法及びリチウム二次電池 |
| US20040023113A1 (en) | 2000-05-30 | 2004-02-05 | Manabu Suhara | Lithium-transition metal composite oxide |
| EP1450423A1 (en) | 2003-02-21 | 2004-08-25 | Toyota Jidosha Kabushiki Kaisha | Active material for positive electrode in non-aqueous electrolyte secondary battery |
| US20050020700A1 (en) | 2001-11-16 | 2005-01-27 | Hans-Joachim Bahnisch | Method for catalytic production of methanol and a device for implementing said method |
| US20050220700A1 (en) | 2003-03-14 | 2005-10-06 | Seimi Chemical Co., Ltd. | Positive electrode active material powder for lithium secondary battery |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3110728B1 (ja) * | 1999-05-06 | 2000-11-20 | 同和鉱業株式会社 | 非水系二次電池用正極活物質および正極 |
| JP3378222B2 (ja) * | 1999-05-06 | 2003-02-17 | 同和鉱業株式会社 | 非水系二次電池用正極活物質および正極並びに二次電池 |
| JP2001273898A (ja) * | 2000-01-20 | 2001-10-05 | Japan Storage Battery Co Ltd | 非水電解質二次電池用正極活物質およびその製造方法並びにそれを使用した非水電解質二次電池 |
| EP2144314B1 (en) * | 2001-04-20 | 2015-01-28 | GS Yuasa International Ltd. | Positive active materials and process for producing the same, positive electrode for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery |
| AU2003266620A1 (en) * | 2002-09-26 | 2004-04-19 | Seimi Chemical Co., Ltd. | Positive electrode active substance for lithium secondary battery and process for producing the same |
| JP4427351B2 (ja) * | 2003-02-21 | 2010-03-03 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質および非水系電解質二次電池 |
| JPWO2004082046A1 (ja) * | 2003-03-14 | 2006-06-15 | セイミケミカル株式会社 | リチウム二次電池用正極活物質粉末 |
| JP4268442B2 (ja) * | 2003-04-30 | 2009-05-27 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質および非水系電解質二次電池 |
| WO2005020354A1 (ja) * | 2003-08-21 | 2005-03-03 | Seimi Chemical Co., Ltd. | リチウム二次電池用の正極活物質粉末 |
| US20060057466A1 (en) | 2003-09-16 | 2006-03-16 | Seimi Chemical Co., Ltd. | Composite oxide containing lithum, nickel, cobalt, manganese, and fluorine, process for producing the same, and lithium secondary cell employing it |
| FI20060993L (fi) * | 2004-05-14 | 2006-11-13 | Seimi Chem Kk | Menetelmä litiumia sisältävän komposiittioksidin valmistamiseksi litiumakkuun tarkoitettua positiivista elektrodia varten |
| JP4996117B2 (ja) * | 2006-03-23 | 2012-08-08 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質およびその製造方法とそれを用いた非水系電解質二次電池 |
-
2006
- 2006-10-13 DE DE102006049098.3A patent/DE102006049098B4/de active Active
-
2007
- 2007-10-11 CA CA2664781A patent/CA2664781C/en active Active
- 2007-10-11 KR KR1020097007239A patent/KR101421758B1/ko active Active
- 2007-10-11 WO PCT/EP2007/008848 patent/WO2008043558A1/en not_active Ceased
- 2007-10-11 EP EP07818919.8A patent/EP2067196B1/en not_active Revoked
- 2007-10-11 JP JP2009531776A patent/JP5458886B2/ja active Active
- 2007-10-11 US US12/373,950 patent/US8685289B2/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5476530A (en) | 1992-05-04 | 1995-12-19 | Hermann C. Starck Gmbh & Co. Kg | Submicron carbonitride powders and their use |
| DE19849343A1 (de) | 1997-10-30 | 1999-06-02 | Samsung Display Devices Co Ltd | Lithiumcompositoxid, dessen Herstellung und sekundäre Lithiumionzelle mit Lithiumcompositoxid als aktives Material der positiven Elektrode |
| JP2001080920A (ja) | 1999-09-07 | 2001-03-27 | Nippon Chem Ind Co Ltd | 凝集粒状リチウム複合酸化物、その製造方法及びリチウム二次電池 |
| US20040023113A1 (en) | 2000-05-30 | 2004-02-05 | Manabu Suhara | Lithium-transition metal composite oxide |
| US20050020700A1 (en) | 2001-11-16 | 2005-01-27 | Hans-Joachim Bahnisch | Method for catalytic production of methanol and a device for implementing said method |
| EP1450423A1 (en) | 2003-02-21 | 2004-08-25 | Toyota Jidosha Kabushiki Kaisha | Active material for positive electrode in non-aqueous electrolyte secondary battery |
| US20050220700A1 (en) | 2003-03-14 | 2005-10-06 | Seimi Chemical Co., Ltd. | Positive electrode active material powder for lithium secondary battery |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090065527A (ko) | 2009-06-22 |
| JP5458886B2 (ja) | 2014-04-02 |
| EP2067196A1 (en) | 2009-06-10 |
| CA2664781A1 (en) | 2008-04-17 |
| KR101421758B1 (ko) | 2014-07-22 |
| DE102006049098A1 (de) | 2008-04-17 |
| CA2664781C (en) | 2015-01-06 |
| WO2008043558A1 (en) | 2008-04-17 |
| JP2010505732A (ja) | 2010-02-25 |
| US8685289B2 (en) | 2014-04-01 |
| EP2067196B1 (en) | 2018-02-21 |
| US20090314985A1 (en) | 2009-12-24 |
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