CS257781B2 - Agent for compensation of phytotoxical effects caused by herbicides and method of its antitoxic active substance production - Google Patents
Agent for compensation of phytotoxical effects caused by herbicides and method of its antitoxic active substance production Download PDFInfo
- Publication number
- CS257781B2 CS257781B2 CS845574A CS557484A CS257781B2 CS 257781 B2 CS257781 B2 CS 257781B2 CS 845574 A CS845574 A CS 845574A CS 557484 A CS557484 A CS 557484A CS 257781 B2 CS257781 B2 CS 257781B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- weight
- parts
- ethyl
- herbicides
- mixture
- Prior art date
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- 239000004009 herbicide Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 238000000034 method Methods 0.000 title abstract description 23
- 239000013543 active substance Substances 0.000 title description 12
- 230000000694 effects Effects 0.000 title description 3
- 230000001147 anti-toxic effect Effects 0.000 title description 2
- 239000003795 chemical substances by application Substances 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 77
- 150000001875 compounds Chemical class 0.000 claims abstract description 67
- 239000000729 antidote Substances 0.000 claims abstract description 43
- 239000004480 active ingredient Substances 0.000 claims description 44
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 27
- 239000001257 hydrogen Substances 0.000 claims description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims description 25
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 230000000885 phytotoxic effect Effects 0.000 claims description 9
- FBCCMZVIWNDFMO-UHFFFAOYSA-N dichloroacetyl chloride Chemical compound ClC(Cl)C(Cl)=O FBCCMZVIWNDFMO-UHFFFAOYSA-N 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- VONWPEXRCLHKRJ-UHFFFAOYSA-N 2-chloro-n-phenylacetamide Chemical compound ClCC(=O)NC1=CC=CC=C1 VONWPEXRCLHKRJ-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 4
- 125000006729 (C2-C5) alkenyl group Chemical group 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- 238000009472 formulation Methods 0.000 claims description 3
- 150000008282 halocarbons Chemical class 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- 125000005059 halophenyl group Chemical group 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 230000002605 anti-dotal effect Effects 0.000 claims 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims 1
- -1 (N-dichloroacetyl)glycine amides Chemical class 0.000 abstract description 52
- 230000002363 herbicidal effect Effects 0.000 abstract description 18
- 229940075522 antidotes Drugs 0.000 abstract description 13
- 230000009471 action Effects 0.000 abstract description 6
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- 239000012141 concentrate Substances 0.000 description 34
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- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 description 14
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
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- 239000002689 soil Substances 0.000 description 6
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 description 5
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 159000000007 calcium salts Chemical class 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000004660 morphological change Effects 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000004563 wettable powder Substances 0.000 description 4
- ZRYCRPNCXLQHPN-UHFFFAOYSA-N 3-hydroxy-2-methylbenzaldehyde Chemical compound CC1=C(O)C=CC=C1C=O ZRYCRPNCXLQHPN-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 244000038559 crop plants Species 0.000 description 3
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 3
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
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- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
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- 239000005909 Kieselgur Substances 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- 102000001708 Protein Isoforms Human genes 0.000 description 2
- 108010029485 Protein Isoforms Proteins 0.000 description 2
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- 239000003513 alkali Substances 0.000 description 2
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 2
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 2
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- BEBCJVAWIBVWNZ-UHFFFAOYSA-N glycinamide Chemical compound NCC(N)=O BEBCJVAWIBVWNZ-UHFFFAOYSA-N 0.000 description 2
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- 239000004546 suspension concentrate Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 229910002029 synthetic silica gel Inorganic materials 0.000 description 1
- 150000003548 thiazolidines Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
- C07C237/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton
- C07C237/22—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton having nitrogen atoms of amino groups bound to the carbon skeleton of the acid part, further acylated
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS858136A CS258134B2 (cs) | 1983-07-21 | 1985-11-12 | Herbicidní prostředek |
| CS858137A CS258135B2 (cs) | 1983-07-21 | 1985-11-12 | Herbicidní prostředek |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU832565A HU193171B (en) | 1983-07-21 | 1983-07-21 | Herbicide preparations containing antidote of n-/dichlor-acetyl/-n-substituted.glycine-n', n-disubstituted-amide-type, or containing agent and antidote, as well as process for the production of the antidote |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS557484A2 CS557484A2 (en) | 1987-11-12 |
| CS257781B2 true CS257781B2 (en) | 1988-06-15 |
Family
ID=10960015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS845574A CS257781B2 (en) | 1983-07-21 | 1984-07-19 | Agent for compensation of phytotoxical effects caused by herbicides and method of its antitoxic active substance production |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US4623383A (en, 2012) |
| AT (1) | AT389625B (en, 2012) |
| BE (1) | BE900183A (en, 2012) |
| BG (3) | BG40962A3 (en, 2012) |
| BR (1) | BR8403602A (en, 2012) |
| CA (1) | CA1236832A (en, 2012) |
| CS (1) | CS257781B2 (en, 2012) |
| DD (2) | DD233064A5 (en, 2012) |
| DE (1) | DE3426541A1 (en, 2012) |
| DK (1) | DK357884A (en, 2012) |
| ES (1) | ES534454A0 (en, 2012) |
| FR (1) | FR2549471B1 (en, 2012) |
| GB (1) | GB2143821B (en, 2012) |
| GR (1) | GR82232B (en, 2012) |
| HU (1) | HU193171B (en, 2012) |
| IT (1) | IT1176429B (en, 2012) |
| LU (1) | LU85455A1 (en, 2012) |
| NL (1) | NL8402269A (en, 2012) |
| PL (3) | PL140584B1 (en, 2012) |
| PT (1) | PT78951A (en, 2012) |
| SU (2) | SU1375628A1 (en, 2012) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HU201445B (en) * | 1987-05-28 | 1990-11-28 | Eszakmagyar Vegyimuevek | Herbicide composition containing sulfonyl-urea derivative as active component and glycinamide derivative as antidotum |
| US4873631A (en) * | 1988-04-25 | 1989-10-10 | Ncr Corporation | Point of sale automatic back-up system and method |
| US4891058A (en) * | 1988-07-18 | 1990-01-02 | Ici Americas Inc. | 1-alkyl-3-aryl imidazolidine-2,4-diones and herbicidal use |
| US5201933A (en) * | 1988-08-01 | 1993-04-13 | Monsanto Company | Safening herbicidal benzoic acid derivatives |
| US4944796A (en) * | 1988-11-14 | 1990-07-31 | Ici Americas Inc. | Certain 2-(disubstituted amino) acetanilide herbicides |
| US5153226A (en) * | 1989-08-31 | 1992-10-06 | Warner-Lambert Company | Acat inhibitors for treating hypocholesterolemia |
| JP6000241B2 (ja) | 2010-05-31 | 2016-09-28 | シンジェンタ パーティシペーションズ アーゲー | 農薬組成物 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA699162A (en) * | 1964-12-01 | Charles E. Frosst And Co. | N-ACYL-.alpha.-AMINO ACID AMIDES | |
| CA527481A (en) * | 1956-07-10 | Gysin Hans | Amino-carboxylic acid amides and a process for making same | |
| CA1174865A (en) * | 1971-04-16 | 1984-09-25 | Ferenc M. Pallos | Thiolcarbamate herbicides containing nitrogen containing antidote |
| US3803181A (en) * | 1971-08-27 | 1974-04-09 | Nippon Kayaku Kk | Reactive anthraquinone dyestuffs |
| US4021224A (en) * | 1971-12-09 | 1977-05-03 | Stauffer Chemical Company | Herbicide compositions |
| CH574207A5 (en, 2012) * | 1973-01-25 | 1976-04-15 | Ciba Geigy Ag | |
| US4231786A (en) * | 1974-12-26 | 1980-11-04 | Monsanto Company | Compositions and methods for reducing herbicidal injury |
| DE2828265A1 (de) * | 1978-06-28 | 1980-01-17 | Bayer Ag | Verwendung von amiden zur verbesserung der kulturpflanzen-vertraeglichkeit von herbizid wirksamen acetaniliden |
| DE2832974A1 (de) * | 1978-07-27 | 1980-02-14 | Basf Ag | Ein thiolcarbamat enthaltende herbizide mittel |
| DE3119077A1 (de) * | 1981-05-14 | 1982-12-02 | Basf Ag, 6700 Ludwigshafen | Heterocyclische dihalogenacetmide, verfahren zu ihrer herstellung und herbizide mittel, die acetanilide als herbizide wirkstoffe und diese dihalogenacetamine als antagonistische mittel enthalten |
| US4509974A (en) * | 1982-10-04 | 1985-04-09 | Stauffer Chemical Company | S-n-Butyl-N,N-diisopropyl thiocarbamate as a selective herbicide in cotton |
-
1983
- 1983-07-21 HU HU832565A patent/HU193171B/hu not_active IP Right Cessation
-
1984
- 1984-07-10 LU LU85455A patent/LU85455A1/de unknown
- 1984-07-12 AT AT0225884A patent/AT389625B/de not_active IP Right Cessation
- 1984-07-16 DE DE19843426541 patent/DE3426541A1/de not_active Withdrawn
- 1984-07-18 DD DD84265398A patent/DD233064A5/de not_active IP Right Cessation
- 1984-07-18 NL NL8402269A patent/NL8402269A/xx not_active Application Discontinuation
- 1984-07-18 DD DD84274247A patent/DD240885A5/de not_active IP Right Cessation
- 1984-07-19 BG BG068402A patent/BG40962A3/xx unknown
- 1984-07-19 BG BG068403A patent/BG40952A3/xx unknown
- 1984-07-19 BG BG066315A patent/BG40951A3/xx unknown
- 1984-07-19 ES ES534454A patent/ES534454A0/es active Granted
- 1984-07-19 CS CS845574A patent/CS257781B2/cs unknown
- 1984-07-19 CA CA000459228A patent/CA1236832A/en not_active Expired
- 1984-07-19 GB GB08418446A patent/GB2143821B/en not_active Expired
- 1984-07-19 BE BE1/11062A patent/BE900183A/fr not_active IP Right Cessation
- 1984-07-19 IT IT21949/84A patent/IT1176429B/it active
- 1984-07-19 BR BR8403602A patent/BR8403602A/pt not_active IP Right Cessation
- 1984-07-20 GR GR75384A patent/GR82232B/el unknown
- 1984-07-20 PT PT78951A patent/PT78951A/pt not_active IP Right Cessation
- 1984-07-20 FR FR8411513A patent/FR2549471B1/fr not_active Expired
- 1984-07-20 DK DK357884A patent/DK357884A/da unknown
- 1984-07-20 PL PL1984248856A patent/PL140584B1/pl unknown
- 1984-07-20 PL PL1984262854A patent/PL144613B1/pl unknown
- 1984-07-20 PL PL1984257576A patent/PL142125B1/pl unknown
- 1984-07-23 US US06/633,382 patent/US4623383A/en not_active Expired - Fee Related
- 1984-11-23 SU SU843814603A patent/SU1375628A1/ru active
- 1984-11-23 SU SU843814616A patent/SU1395138A3/ru active
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