CN1827214A - 不对称(转移)氢化催化剂 - Google Patents

不对称(转移)氢化催化剂 Download PDF

Info

Publication number
CN1827214A
CN1827214A CNA2006100669482A CN200610066948A CN1827214A CN 1827214 A CN1827214 A CN 1827214A CN A2006100669482 A CNA2006100669482 A CN A2006100669482A CN 200610066948 A CN200610066948 A CN 200610066948A CN 1827214 A CN1827214 A CN 1827214A
Authority
CN
China
Prior art keywords
catalyst
group
hydrogenation
asymmetric
atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2006100669482A
Other languages
English (en)
Chinese (zh)
Inventor
M·伯格范登
A·J·明纳尔德
B·费林加
J·G·弗里斯德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DSM IP Assets BV
Original Assignee
DSM IP Assets BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM IP Assets BV filed Critical DSM IP Assets BV
Publication of CN1827214A publication Critical patent/CN1827214A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/1855—Triamide derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/657154—Cyclic esteramides of oxyacids of phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNA2006100669482A 2000-07-07 2001-07-06 不对称(转移)氢化催化剂 Pending CN1827214A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL1015655A NL1015655C2 (nl) 2000-07-07 2000-07-07 Katalysator voor de asymmetrische hydrogenering.
NL1015655 2000-07-07

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CNB018123910A Division CN1289515C (zh) 2000-07-07 2001-07-06 不对称(转移)氢化催化剂

Publications (1)

Publication Number Publication Date
CN1827214A true CN1827214A (zh) 2006-09-06

Family

ID=19771696

Family Applications (3)

Application Number Title Priority Date Filing Date
CNA2006100669482A Pending CN1827214A (zh) 2000-07-07 2001-07-06 不对称(转移)氢化催化剂
CNB018123910A Expired - Fee Related CN1289515C (zh) 2000-07-07 2001-07-06 不对称(转移)氢化催化剂
CN200610149973A Expired - Fee Related CN100584460C (zh) 2000-07-07 2001-07-06 不对称(转移)氢化催化剂

Family Applications After (2)

Application Number Title Priority Date Filing Date
CNB018123910A Expired - Fee Related CN1289515C (zh) 2000-07-07 2001-07-06 不对称(转移)氢化催化剂
CN200610149973A Expired - Fee Related CN100584460C (zh) 2000-07-07 2001-07-06 不对称(转移)氢化催化剂

Country Status (16)

Country Link
US (1) US6989461B2 (https=)
EP (1) EP1325013B1 (https=)
JP (1) JP4958374B2 (https=)
CN (3) CN1827214A (https=)
AT (1) ATE339430T1 (https=)
AU (1) AU2001271145A1 (https=)
CA (1) CA2414202C (https=)
CY (1) CY1106288T1 (https=)
CZ (1) CZ304071B6 (https=)
DE (1) DE60123093T2 (https=)
DK (1) DK1325013T3 (https=)
ES (1) ES2271043T3 (https=)
HU (1) HU229665B1 (https=)
NL (1) NL1015655C2 (https=)
PT (1) PT1325013E (https=)
WO (1) WO2002004466A2 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112789108A (zh) * 2018-10-02 2021-05-11 格拉斯如睦株式会社 用于含有碳双键的化合物的不对称氢化的催化剂

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003006151A1 (en) 2001-07-12 2003-01-23 Avecia Limited Microencapsulated catalyst, methods of preparation and methods of use thereof
EP1364932A1 (en) * 2002-05-23 2003-11-26 DSM IP Assets B.V. Process for the preparation of enantiomerically enriched compounds
US7732365B2 (en) * 2002-09-13 2010-06-08 Yale University Enantioselective amination and etherification
DE10247633A1 (de) * 2002-10-11 2004-04-29 Studiengesellschaft Kohle Mbh Mischungen von chiralen Monophosphor-Verbindungen als Ligandensysteme für die asymmetrische Übergangsmetallkatalyse
JP2004150960A (ja) * 2002-10-30 2004-05-27 Nichirei Corp 物性測定用プローブ
US7446236B2 (en) * 2002-12-02 2008-11-04 Solvias Ag Catalytic hydrogenation of carbon-heteroatom double bonds
WO2004078766A1 (en) * 2003-02-27 2004-09-16 Mitsubishi Chemical Corporation Optically active phosphites and phosphoramides bearing biphenol skeletons with axial chirality, and their use in catalytic asymmetric reactions
CN1309728C (zh) * 2004-07-30 2007-04-11 中国科学院上海有机化学研究所 一类手性有机－无机高分子组装体催化剂、合成方法及用途
CN100482671C (zh) * 2004-09-29 2009-04-29 中国科学院上海有机化学研究所 手性单磷配体、合成方法及其用途
JP5704786B2 (ja) * 2004-11-16 2015-04-22 ヴェロシス，インク． マイクロチャネル技術を用いる多相反応プロセス
AT501193B1 (de) 2004-12-27 2007-03-15 Dsm Fine Chem Austria Gmbh Verfahen zur übergangsmetall - katalysierten asymmetrischen hydrierung von acrylsäurederivaten
EP1846350A2 (en) * 2005-01-27 2007-10-24 University of Nottingham Improved method for the preparation of enantiomerically enriched secondary alcohols by the addition of organoaluminium reagents to carbonyl compounds
DE102005044355A1 (de) * 2005-09-16 2007-03-22 Studiengesellschaft Kohle Mbh Chirale Phosphoramidite
US20070213540A1 (en) * 2006-03-09 2007-09-13 Degussa Ag Process for the hydrogenation of imines
JP2009046452A (ja) * 2007-08-22 2009-03-05 Erick M Carreira ホスホルアミダイト配位子およびそれを用いたアリルアミンの製造方法
CN101508702B (zh) * 2009-03-27 2012-07-04 中国科学院上海有机化学研究所 四氢喹啉和吲哚啉衍生的磷氮配体、合成方法和应用
JP6150179B2 (ja) * 2011-08-19 2017-06-21 パセオン オーストリア ゲーエムベーハー ウント ツェーオー カーゲー Ｒ−ビフェニルアラニノールの合成
GB201307049D0 (en) 2013-04-18 2013-05-29 Isis Innovation Catalysts and use thereof
DE102013107421A1 (de) * 2013-07-12 2015-01-15 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zum asymmetrischen Hydrieren von Enolestern
EP2829546A3 (de) * 2013-07-23 2015-05-06 Evonik Industries AG Isomerisierungsarme Hydroformylierung von Ölsäureester-haltigen Gemischen
WO2015011132A2 (de) * 2013-07-23 2015-01-29 Evonik Industries Ag Phosphoramiditderivate in der hydroformylierung von ungesättigten verbindungen
DE102013214378A1 (de) * 2013-07-23 2015-01-29 Evonik Industries Ag Phosphoramiditderivate in der Hydroformylierung von olefinhaltigen Gemischen
WO2015063790A1 (en) 2013-11-01 2015-05-07 Council Of Scientific And Industrial Research Catalyst for asymmetric transfer hydrogenation of ketones and imines
CN105524111B (zh) * 2016-01-25 2017-10-27 西北农林科技大学 手性亚磷酰胺单齿配体及其合成方法与应用
EP3301087A1 (en) 2016-09-30 2018-04-04 DPx Fine Chemicals Austria GmbH & Co KG Process for preparing chiral amines
CN108101785A (zh) * 2016-11-24 2018-06-01 中国科学院大连化学物理研究所 一种铱催化不对称氢化制备手性β-羟基酯的方法
JP7138106B2 (ja) 2016-12-23 2022-09-15 ノバルティス アーゲー 初期サクビトリル中間体のための新規な方法
CN111454136A (zh) * 2019-01-22 2020-07-28 中国科学院上海高等研究院 用于催化偕二取代芳香烯烃的氢甲酰化反应的催化剂及其制备方法和用途
EP4055025A1 (en) * 2019-11-07 2022-09-14 DSM IP Assets B.V. New transition metal catalyst
CN111333573B (zh) * 2020-04-10 2021-09-28 浙江工业大学 一种右美沙芬中间体的制备工艺
CN111548329B (zh) * 2020-05-27 2022-06-17 浙江乐普药业股份有限公司 一种布瓦西坦的制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2116905A5 (fr) * 1970-12-10 1972-07-21 Inst Francais Du Petrole Nouveaux coordinats bidentes,leur fabrication et leurs applications
EP0005500B1 (de) * 1978-05-18 1981-10-07 Ciba-Geigy Ag Dioxaphosphepine, ihre Herstellung und Verwendung als Stabilisatoren für organisches Material
US4981995A (en) * 1987-03-20 1991-01-01 Varadaraj Elango Method for producing ibuprofen
AU5777300A (en) * 1999-06-30 2001-01-31 Penn State Research Foundation, The Ligands based on chiral 2-amino-2'-hydroxy-1,1'-binaphthyl and related frameworks for asymmetric catalysis
DE19936473A1 (de) * 1999-08-03 2001-02-08 Studiengesellschaft Kohle Mbh Neue chirale Phosphorliganden und ihre Verwendung in der Herstellung optisch aktiver Produkte

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112789108A (zh) * 2018-10-02 2021-05-11 格拉斯如睦株式会社 用于含有碳双键的化合物的不对称氢化的催化剂
CN112789108B (zh) * 2018-10-02 2023-09-19 格拉斯如睦株式会社 用于含有碳双键的化合物的不对称氢化的催化剂

Also Published As

Publication number Publication date
HUP0400519A3 (en) 2005-10-28
NL1015655C2 (nl) 2002-01-08
WO2002004466A2 (en) 2002-01-17
CN1440416A (zh) 2003-09-03
EP1325013A2 (en) 2003-07-09
PT1325013E (pt) 2006-12-29
HUP0400519A2 (hu) 2004-06-28
ATE339430T1 (de) 2006-10-15
US6989461B2 (en) 2006-01-24
EP1325013B1 (en) 2006-09-13
WO2002004466A3 (en) 2002-03-28
AU2001271145A1 (en) 2002-01-21
CY1106288T1 (el) 2011-10-12
DE60123093D1 (de) 2006-10-26
JP4958374B2 (ja) 2012-06-20
ES2271043T3 (es) 2007-04-16
HU229665B1 (hu) 2014-04-28
DE60123093T2 (de) 2007-03-15
CA2414202A1 (en) 2002-01-17
CN1974010A (zh) 2007-06-06
CN100584460C (zh) 2010-01-27
CA2414202C (en) 2010-03-23
CZ200341A3 (cs) 2003-04-16
JP2004502543A (ja) 2004-01-29
US20030199713A1 (en) 2003-10-23
CN1289515C (zh) 2006-12-13
DK1325013T3 (da) 2006-12-04
CZ304071B6 (cs) 2013-09-25

Similar Documents

Publication Publication Date Title
CN1827214A (zh) 不对称(转移)氢化催化剂
Beletskaya et al. Stereodivergent catalysis
Noyori Asymmetric catalysis: science and opportunities (Nobel Lecture 2001)
Zhang et al. Ir-catalyzed regio-and enantioselective hydroalkynylation of trisubstituted alkene to access all-carbon quaternary stereocenters
Ojima et al. Recent advances in catalytic asymmetric reactions promoted by transition metal complexes
Takizawa et al. P-chirogenic organocatalysts: application to the aza-Morita–Baylis–Hillman (aza-MBH) reaction of ketimines
CN100339354C (zh) 通过不对称氢化来制备手性β－氨基酸衍生物的方法
CN1257468A (zh) 转移氢化方法和催化剂
CN1059906C (zh) 水溶性膦衍生物
Akotsi et al. Versatile precursor to ruthenium‐bis (phosphine) hydrogenation catalysts
Watts et al. Catalytic asymmetric transfer hydrogenation of ketones using terpene-based chiral β-amino alcohols
CN1832953A (zh) 作为均相氢化催化剂的取代的二茂铁基二膦
US6583312B2 (en) Process for preparing optically active trimethyllactic acid and its esters
Ito et al. Synthesis and reactivity of 2-aminoethanethiolato-bridged dinuclear Ru (hmb) complexes (hmb= η6-hexamethylbenzene): mechanistic consideration on transfer hydrogenation with bifunctional [RuCl2 (hmb)] 2/2-aminoethanethiol catalyst system
Sumi et al. Rhodium/ruthenium applications
Baran et al. Deracemization of Chiral-at-Ruthenium Catalyst by Diastereoselective Dynamic Resolution
Xie et al. New chiral phosphorus ligands with spirobiindane backbone for asymmetric hydrogenations
CN1223998A (zh) 生产反式－(r,r)－放线菌醇的方法
CN1281460A (zh) 含刚性手性配体的不对称合成用催化剂
CN1376659A (zh) 高选择性地制备手性仲醇的新方法
ES2327705B1 (es) Procedimiento para la hidrogenacion homogenea de cetonas utilizando sistemas cataliticos de rutenio.
CN1281582C (zh) 高光学纯度手性β—氨基醇类化合物、制备方法及其用途
Vinogradov et al. Ruthenium and rhodium complexes with chiral P-donor ligands as catalysts of enantioselective hydrogenation of ketoesters
CN1656047A (zh) 富集了对映异构体的化合物的制备方法
US20040220347A1 (en) Process for reducing ketocarboxylic esters

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication