CN1802326A - 一种包含二氧化钛和氧化铋的微球 - Google Patents

一种包含二氧化钛和氧化铋的微球 Download PDF

Info

Publication number
CN1802326A
CN1802326A CNA2004800160999A CN200480016099A CN1802326A CN 1802326 A CN1802326 A CN 1802326A CN A2004800160999 A CNA2004800160999 A CN A2004800160999A CN 200480016099 A CN200480016099 A CN 200480016099A CN 1802326 A CN1802326 A CN 1802326A
Authority
CN
China
Prior art keywords
microspheres
weight
microsphere
beads
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2004800160999A
Other languages
English (en)
Chinese (zh)
Inventor
马修·H·弗雷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN1802326A publication Critical patent/CN1802326A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C12/00—Powdered glass; Bead compositions
    • C03C12/02—Reflective beads
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00—Other methods of shaping glass
    • C03B19/10—Forming beads
    • C03B19/1005—Forming solid beads
    • C03B19/102—Forming solid beads by blowing a gas onto a stream of molten glass or onto particulate materials, e.g. pulverising
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00—Other methods of shaping glass
    • C03B19/10—Forming beads
    • C03B19/1005—Forming solid beads
    • C03B19/1045—Forming solid beads by bringing hot glass in contact with a liquid, e.g. shattering
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00—Other methods of shaping glass
    • C03B19/10—Forming beads
    • C03B19/1005—Forming solid beads
    • C03B19/1055—Forming solid beads by extruding, e.g. dripping molten glass in a gaseous atmosphere
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/122—Silica-free oxide glass compositions containing oxides of As, Sb, Bi, Mo, W, V, Te as glass formers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/127—Silica-free oxide glass compositions containing TiO2 as glass former
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • C04B35/462—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/653—Processes involving a melting step
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00—Type of glass produced
    • C03B2201/06—Doped silica-based glasses
    • C03B2201/30—Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00—Type of glass produced
    • C03B2201/06—Doped silica-based glasses
    • C03B2201/30—Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi
    • C03B2201/40—Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi doped with transition metals other than rare earth metals, e.g. Zr, Nb, Ta or Zn
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00—Type of glass produced
    • C03B2201/06—Doped silica-based glasses
    • C03B2201/30—Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi
    • C03B2201/40—Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi doped with transition metals other than rare earth metals, e.g. Zr, Nb, Ta or Zn
    • C03B2201/42—Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi doped with transition metals other than rare earth metals, e.g. Zr, Nb, Ta or Zn doped with titanium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00—Type of glass produced
    • C03B2201/60—Silica-free oxide glasses
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3213—Strontium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3215—Barium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3298—Bismuth oxides, bismuthates or oxide forming salts thereof, e.g. zinc bismuthate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52—Constituents or additives characterised by their shapes
    • C04B2235/528—Spheres
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9646—Optical properties
    • C04B2235/9653—Translucent or transparent ceramics other than alumina
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)
CNA2004800160999A 2003-06-11 2004-04-20 一种包含二氧化钛和氧化铋的微球 Pending CN1802326A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/458,955 US20040259713A1 (en) 2003-06-11 2003-06-11 Microspheres comprising titania and bismuth oxide
US10/458,955 2003-06-11

Publications (1)

Publication Number Publication Date
CN1802326A true CN1802326A (zh) 2006-07-12

Family

ID=33516933

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2004800160999A Pending CN1802326A (zh) 2003-06-11 2004-04-20 一种包含二氧化钛和氧化铋的微球

Country Status (6)

Country Link
US (4) US20040259713A1 (enExample)
EP (1) EP1631530A2 (enExample)
JP (1) JP2007501183A (enExample)
KR (1) KR20060023556A (enExample)
CN (1) CN1802326A (enExample)
WO (1) WO2005000756A2 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101679108B (zh) * 2007-05-11 2012-01-11 3M创新有限公司 具有含氧化镧和氧化铝以及氧化锆、二氧化钛或它们的混合物的微球的道路标记和反射元件
CN103964676A (zh) * 2014-05-06 2014-08-06 湖州远光路标涂料有限公司 全天候高折射反光微晶陶珠
CN106082683A (zh) * 2009-08-21 2016-11-09 3M创新有限公司 路面标记、反射元件、微球以及制备微球的方法

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040259713A1 (en) * 2003-06-11 2004-12-23 3M Innovative Properties Company Microspheres comprising titania and bismuth oxide
MXPA06004844A (es) 2003-11-06 2006-07-06 3M Innovative Properties Co Elementos retrorreflejantes que comprenden un nucleo de resina pegado y marcaciones de pavimento.
JP2007022832A (ja) * 2005-07-14 2007-02-01 Nippon Electric Glass Co Ltd ガラス粉末の製造方法
US7513941B2 (en) 2005-11-14 2009-04-07 3M Innovative Properties Company Pavement marking, reflective elements, and methods of making micospheres
JPWO2007129509A1 (ja) * 2006-05-01 2009-09-17 旭硝子株式会社 ガラス製造方法
US8701441B2 (en) 2006-08-21 2014-04-22 3M Innovative Properties Company Method of making inorganic, metal oxide spheres using microstructured molds
US8840956B2 (en) * 2008-10-31 2014-09-23 Potters Industries, Llc Retroreflective coating and method for applying a retroreflective coating on a structure
US7884055B2 (en) * 2008-12-04 2011-02-08 Intevep, S.A. Ceramic microspheres for cementing applications
US20100272962A1 (en) * 2009-04-22 2010-10-28 Potters Industries Inc. Reflective substrate surface system, reflective assembly, and methods of improving the visibility of a substrate surface
BR112012003662A2 (pt) 2009-08-21 2016-03-29 3M Innovative Properties Co demarcações de pavimentos, elementos refletivos, e métodos de preparo de mocroesferas.
CA2730631C (en) * 2010-02-09 2015-03-31 Potters Industries, Inc. Reflective substrate surface system, reflective assembly, and methods of improving the visibility of a substrate surface
US9340934B2 (en) 2011-09-01 2016-05-17 3M Innovative Properties Company Pavement marking materials and methods
US20130105735A1 (en) * 2011-10-27 2013-05-02 Willard Scott Rader Thermally induced flash synthesis of photoluminescent compositions
FR2981952B1 (fr) * 2011-11-02 2015-01-02 Fabien Gaben Procede de realisation de couches minces denses par electrophorese
KR102126363B1 (ko) 2012-10-29 2020-06-24 쓰리엠 이노베이티브 프로퍼티즈 캄파니 도로 표지 조성물
US10259947B2 (en) 2014-04-04 2019-04-16 3M Innovative Properties Company Wet or damp surface preparation compositions
KR20170004982A (ko) 2014-04-29 2017-01-11 쓰리엠 이노베이티브 프로퍼티즈 캄파니 폴리(에틸렌-코-아크릴산)과 폴리다이유기실록산의 공중합체
US10605967B2 (en) 2014-08-08 2020-03-31 3M Innovative Properties Company Retroreflective elements including particles
GB201415005D0 (en) * 2014-08-22 2014-10-08 Univ Nottingham Porous and non-pourous bodies
CN104529381B (zh) * 2014-12-29 2017-01-04 商都中建金马冶金化工有限公司 一种用高温镍铁合金废渣为原料制造微晶石的方法
CN104944774A (zh) * 2015-06-17 2015-09-30 安徽环泰新材料科技有限公司 一种折射率≥1.93的玻璃微珠及其制备方法
CN104944775A (zh) * 2015-06-17 2015-09-30 安徽环泰新材料科技有限公司 一种折射率≥2.2的玻璃微珠及其制备方法
CN104944778A (zh) * 2015-06-17 2015-09-30 安徽环泰新材料科技有限公司 一种反光膜用耐高温玻璃微珠及其制备方法
EP3310966B1 (en) 2015-06-18 2021-01-27 3M Innovative Properties Company Thermoplastic pavement marking tapes
CN104961349A (zh) * 2015-07-01 2015-10-07 合肥鼎亮光学科技有限公司 一种抗老化耐腐蚀反光膜用玻璃微珠及其制备方法
CN104926128A (zh) * 2015-07-01 2015-09-23 合肥鼎亮光学科技有限公司 一种反光膜用高抗压抗裂玻璃微珠及其制备方法
CN104926139A (zh) * 2015-07-01 2015-09-23 合肥鼎亮光学科技有限公司 一种反光膜用抗老化高耐久玻璃微珠及其制备方法
CN104909577A (zh) * 2015-07-01 2015-09-16 合肥鼎亮光学科技有限公司 一种tpu反光膜用玻璃微珠及其制备方法
CN104944773A (zh) * 2015-07-01 2015-09-30 合肥鼎亮光学科技有限公司 一种反光膜用低吸水率高化学稳定玻璃微珠及其制备方法
CN104926142A (zh) * 2015-07-01 2015-09-23 合肥鼎亮光学科技有限公司 一种用于广告级反光膜的玻璃微珠及其制备方法
CN104961344A (zh) * 2015-07-01 2015-10-07 合肥鼎亮光学科技有限公司 一种反光膜用高性能玻璃微珠及其制备方法
CN105060712A (zh) * 2015-07-29 2015-11-18 蚌埠高华电子股份有限公司 一种高亮反光布用抗老化玻璃微珠及其制备方法
JP6899379B2 (ja) 2015-09-11 2021-07-07 スリーエム イノベイティブ プロパティズ カンパニー イオン性コポリマーコアを含む耐久性のある再帰反射素子
CN108025958B (zh) 2015-09-11 2021-04-09 3M创新有限公司 具有小珠共混物的耐用回射元件
CN110997595A (zh) * 2017-07-28 2020-04-10 3M创新有限公司 纳米晶陶瓷氧化物珠
CN109675590B (zh) * 2017-10-18 2021-12-17 封丽娟 一种二氧化钛的制备方法
RU2672890C1 (ru) * 2018-01-14 2018-11-20 Общество с ограниченной ответственностью "Сферастек" Стеклянный микрошарик
RU2692712C1 (ru) * 2018-01-14 2019-06-26 Общество с ограниченной ответственностью "Сферастек" Способ получения микрошариков для световозвращающих покрытий
FR3080957B1 (fr) 2018-05-07 2020-07-10 I-Ten Electrodes mesoporeuses pour dispositifs electrochimiques en couches minces
US11149354B2 (en) * 2019-02-20 2021-10-19 General Electric Company Dense abradable coating with brittle and abradable components
JP7530034B2 (ja) * 2019-04-05 2024-08-07 日本電気硝子株式会社 装飾用ガラス物品
CN111847846B (zh) * 2020-08-05 2024-08-13 延安城投光学材料有限公司 一种折射率大于等于1.7的大尺寸玻璃微珠的制备方法及其成珠装置
WO2024003637A1 (en) 2022-06-29 2024-01-04 3M Innovative Properties Company Curable adhesive and articles for bonding pavement and concrete
WO2025141651A1 (ja) * 2023-12-25 2025-07-03 株式会社ニコン ガラスの製造方法、光学ガラスの製造方法、混合物の製造方法、ガラスセットの製造方法、ガラスセット、光学素子のセット、光学装置のセット、ガラス、光学素子、及び浮遊熔解ガラス

Family Cites Families (106)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE209431C (enExample)
DE242038C (enExample)
US2354018A (en) * 1940-08-03 1944-07-18 Minnesota Mining & Mfg Light reflector sheet
US2713286A (en) * 1949-10-22 1955-07-19 Minnesota Mining & Mfg Reflex light reflectors and glass bead elements thereof
US2853393A (en) * 1951-07-05 1958-09-23 Minnesota Mining & Mfg High-index glass elements
DE1065580B (de) * 1953-08-12 1959-09-17 Minnesota Mining and Manufacturing Company, Saint Paul, Minn. (V. St. A.) Durchsichtiges Glaselement mit einer Stärke von nicht mehr 2 mm
US2726161A (en) * 1953-09-21 1955-12-06 Minnesota Mining & Mfg High-index glass elements
US2842446A (en) * 1954-12-27 1958-07-08 Minnesota Mining & Mfg High-index glass elements
US2873197A (en) * 1955-01-21 1959-02-10 Carborundum Co Refractory fibrous material
US2963378A (en) * 1955-04-25 1960-12-06 Minnesota Mining & Mfg Ass beads hemispherically reflectorled with metallic coating and compositions thereof
US2870030A (en) * 1955-07-18 1959-01-20 Minnesota Mining & Mfg High-index glass elements
US2924533A (en) * 1956-05-28 1960-02-09 Carborundum Co Spheroidal refractory material and method of making
US2960594A (en) * 1958-06-30 1960-11-15 Plasma Flame Corp Plasma flame generator
US3145114A (en) * 1960-10-24 1964-08-18 Prismo Safety Corp Process for increasing the index of refraction of glass and an article made thereby
US3228897A (en) * 1961-10-26 1966-01-11 Minnesota Mining & Mfg Reflective coating compositions containing glass beads, metal flake pigment and binder
US3149016A (en) * 1962-04-02 1964-09-15 Minnesota Mining & Mfg Nucleated glass particle and process for making it
CA919195A (en) * 1963-02-14 1973-01-16 Fang Tung Chi High index glass elements
US3419403A (en) * 1963-03-18 1968-12-31 Cataphote Corp High index of refraction glass compositions
US3294558A (en) * 1963-04-22 1966-12-27 Cataphote Corp Colorless high index glass compositions
DE1250977B (enExample) * 1963-04-22 1967-09-28
US3293051A (en) * 1963-08-22 1966-12-20 Cataphote Corp High titanate glass beads
US3323888A (en) * 1964-03-17 1967-06-06 Cataphote Corp Method for manufacturing glass beads
FR1404190A (fr) 1964-08-10 1965-06-25 Minnesota Mining & Mfg Perles transparentes
US3416936A (en) * 1965-03-01 1968-12-17 Gen Steel Ind Inc Abrasion resistant glass bead with sharp softening range and process for making the same
US3432314A (en) * 1966-08-02 1969-03-11 Us Air Force Transparent zirconia composition and process for making same
US3410185A (en) * 1966-08-08 1968-11-12 Minnesota Mining & Mfg Marking
US3499857A (en) * 1967-04-17 1970-03-10 Cataphote Corp Thermoplastic resinous compositions,particularly using unsaturated triglycerides
US3523029A (en) * 1967-08-21 1970-08-04 Cataphote Corp Hot melt highway marking composition
US3560074A (en) * 1968-10-21 1971-02-02 Cataphote Corp 95% titanium dioxide glass spheroids
US3709706A (en) * 1969-05-16 1973-01-09 Minnesota Mining & Mfg Refractory fibers and other articles of zirconia and silica mixtures
US3645933A (en) * 1969-11-12 1972-02-29 Sherwin Williams Co Coating composition including isocyanate-modified polyester and chlorinated rubber
US3684536A (en) * 1970-11-04 1972-08-15 Du Pont Bismuthate glass-ceramic precursor compositions
US3795524A (en) * 1971-03-01 1974-03-05 Minnesota Mining & Mfg Aluminum borate and aluminum borosilicate articles
US3749763A (en) * 1971-08-03 1973-07-31 Humphreys Corp Processing of silicate ores and product thereof
IT1045437B (it) * 1972-12-28 1980-05-10 Eigenmann Ludwig Perfezionamento ai materiali cata rifrangenti a doppia focalizzazione in particolare per segnaletica strdale
US3864113A (en) * 1973-10-19 1975-02-04 Corning Glass Works Method of Producing Glass by Flame Hydrolysis
US3915771A (en) * 1974-03-04 1975-10-28 Minnesota Mining & Mfg Pavement-marking tape
US3923051A (en) * 1974-03-18 1975-12-02 Samuel Soichet Inflatable intrauterine contraceptive device for postpartum use
US4082427A (en) * 1974-07-02 1978-04-04 Fukuoka Tokushu Garasu Kabushiki Kaisha High refractive index glass compositions
JPS5828210B2 (ja) 1974-11-07 1983-06-14 オノダセメント カブシキガイシヤ コウブツセンイマタハ ビ−ズソセイブツ
US4137086A (en) * 1975-05-13 1979-01-30 Pilkington Brothers Limited Glass compositions for use in curable compositions
FR2320276A1 (fr) * 1975-08-06 1977-03-04 Prod Refractaires Europ Billes ameliorees en matiere ceramique
US4056602A (en) * 1975-08-20 1977-11-01 Thagard Technology Company High temperature chemical reaction processes utilizing fluid-wall reactors
US4095974A (en) * 1975-09-24 1978-06-20 Thagard Technology Company High temperature chemical reaction processes utilizing fluid-wall reactors
JPS5939378B2 (ja) 1976-08-13 1984-09-22 旭硝子株式会社 繊維用ガラス組成物
JPS5388815A (en) 1977-01-18 1978-08-04 Tokyo Shibaura Electric Co High reeractiveeindex glass for glass beads
JPS53102325A (en) 1977-02-18 1978-09-06 Obara Optical Glass Abrasionn and chemicallproof glass
JPS5415919A (en) * 1977-06-07 1979-02-06 Fukuoka Tokushiyu Garasu Kk Glass having high refractive index
JPS546241A (en) 1977-06-13 1979-01-18 Nissan Diesel Motor Co Ltd Automotive parking brake device
US4367919A (en) * 1977-08-01 1983-01-11 Minnesota Mining And Manufacturing Company Durable glass elements
JPS608983B2 (ja) 1978-07-28 1985-03-07 松下電工株式会社 結晶化能を有する低融点ガラスの製法
JPS5520254A (en) 1978-07-28 1980-02-13 Matsushita Electric Works Ltd Production of low melting point crystallized glass
US4192576A (en) * 1978-11-20 1980-03-11 Minnesota Mining And Manufacturing Company Ultra-high-index glass microspheres and products made therefrom
JPS55126547A (en) 1979-03-20 1980-09-30 Ohara Inc Glass for bead
JPS55126548A (en) 1979-03-20 1980-09-30 Ohara Inc Glass for bead
US4248932A (en) * 1979-06-14 1981-02-03 Minnesota Mining And Manufacturing Company Extended-life pavement-marking sheet material
JPS5641852A (en) 1979-09-17 1981-04-18 Ohara Inc Glass for bead
JPS6022656B2 (ja) 1980-08-21 1985-06-03 ホ−ヤ株式会社 光学ガラス
FR2493910A1 (fr) * 1980-11-13 1982-05-14 Produits Refractaires Agent de soutenement a base de zircone et de silice pour fractures geologiques profondes
JPS5815067A (ja) 1981-07-13 1983-01-28 セントラル硝子株式会社 常温においてδ相を主体とするＢｉ↓２Ｏ↓３組成物特定用途とその製造法
DE3216451C2 (de) * 1982-05-03 1984-04-19 Schott Glaswerke, 6500 Mainz Optisches Leichtgewichtglas mit einem Brechwert ≥ 1.70, einer Abbezahl ≥ 22 und einer Dichte ≦ 3,5 g/cm↑3↑
JPS6022656A (ja) 1983-07-18 1985-02-05 Murata Mfg Co Ltd 霜検知装置
US4621936A (en) * 1983-10-14 1986-11-11 Corning Glass Works Zirconia pen balls
JPS60215549A (ja) 1984-04-11 1985-10-28 Toshiba Glass Co Ltd 耐摩耗性ガラスビ−ズ
DE3430906A1 (de) 1984-08-22 1986-02-27 Boehringer Mannheim Gmbh, 6800 Mannheim Verfahren zur bestimmung von fibrinmonomer in plasma
JPS6168349A (ja) 1984-09-07 1986-04-08 Toshiba Glass Co Ltd 耐摩耗性ガラスビ−ズ
US4564556A (en) * 1984-09-24 1986-01-14 Minnesota Mining And Manufacturing Company Transparent non-vitreous ceramic particulate
DE3504625C1 (de) * 1985-02-11 1986-07-03 Schott Glaswerke, 6500 Mainz Hochbrechendes optisches Glas im System SiO2-TiO2-Nb2O5-BaO-Alkalioxid mit Brechwerten ? 1,83 und Abbezahlen ? 25,und mit sehr guter chemischer Bestaendigkeit
US4721743A (en) * 1985-03-25 1988-01-26 The Dow Chemical Company Non-thermoset thermally stable capped epoxy resin compositions
JPS61270235A (ja) 1985-05-24 1986-11-29 Ohara Inc ビ−ズ用ガラス
US4772511A (en) * 1985-11-22 1988-09-20 Minnesota Mining And Manufacturing Company Transparent non-vitreous zirconia microspheres
CA1308845C (en) * 1986-01-13 1992-10-13 Roger W. Lange Pavement markings containing transparent non-vitreous ceramic microspheres
JPS62242038A (ja) 1986-04-14 1987-10-22 苅部　正夫 Ｐｃ鋼材用定着装置
JPS6338721A (ja) 1986-08-01 1988-02-19 Toyota Motor Corp 車両用クラツチレリ−ズ機構
US4837069A (en) * 1987-01-07 1989-06-06 Minnesota Mining And Manufacturing Company Transparent alumina microspheres
JP2610004B2 (ja) 1988-04-28 1997-05-14 東芝硝子株式会社 ガラスビーズ
US5227221A (en) * 1988-06-09 1993-07-13 Minnesota Mining And Manufacturing Company Patterned skid preventative sheet
US4988555A (en) * 1988-06-09 1991-01-29 Minnesota Mining And Manufacturing Company Patterned pavement marking
DE69222189T2 (de) * 1991-02-28 1998-03-12 Minnesota Mining & Mfg Markierungselement mit silikonkleber
JPH0585771A (ja) 1991-03-29 1993-04-06 Nippon Electric Glass Co Ltd 中空ガラス球用組成物
US5268789A (en) * 1992-02-18 1993-12-07 Minnesota Mining And Manufacturing Company Retroreflective assembly and process for making same
JPH0646905B2 (ja) 1992-02-19 1994-06-22 株式会社ナーサリーテクノロジー イネカルスからの植物体再生方法
US5286682A (en) * 1992-02-19 1994-02-15 Minnesota Mining And Manufacturing Company Yellow retroreflective pavement markings
DE4210011C1 (enExample) 1992-03-27 1993-07-15 Schott Glaswerke, 6500 Mainz, De
FR2714905B1 (fr) * 1994-01-11 1996-03-01 Produits Refractaires Billes en matière céramique fondue.
DE4423794C1 (de) * 1994-07-01 1996-02-08 Ivoclar Ag Zr0¶2¶-haltige Glaskeramik, Verfahren zu deren Herstellung sowie deren Verwendung
IT1268814B1 (it) * 1994-12-13 1997-03-06 Calp Spa Miscela vetrificabile per vetri di qualita'
AR000747A1 (es) * 1995-01-18 1997-08-06 Dow Chemical Co Composicion acuosa de recubrimiento de endurecimiento rapido, pinturas y composiciones ligantes de aplicacion en la formulacion de dichas composicionesy pinturas formuladas con dicha composicion de recubrimiento.
US5674616A (en) * 1995-02-06 1997-10-07 Conversion Technologies International, Inc. Glass beads having improved fracture toughness
AU695580B2 (en) 1995-04-18 1998-08-13 Minnesota Mining And Manufacturing Company Acid-resistant glass
US5576097A (en) * 1995-04-24 1996-11-19 Brite-Line Industries, Inc. High brightness durable retro-reflecting microspheres and method of making the same
JPH09142872A (ja) 1995-09-18 1997-06-03 Ohara Inc 高分散光学ガラス
JPH09188544A (ja) 1996-01-10 1997-07-22 Asahi Glass Co Ltd ガラス組成物
WO1997028471A1 (en) * 1996-02-05 1997-08-07 Minnesota Mining And Manufacturing Company Durable retroreflective elements
JP3113591B2 (ja) 1996-02-13 2000-12-04 株式会社オハラ 高屈折率光学ガラス
US5777791A (en) * 1996-11-26 1998-07-07 Minnesota Mining And Manufacturing Company Wet retroreflective pavement marking articles
DE69712194T2 (de) * 1996-12-25 2002-11-14 Nippon Sheet Glass Co., Ltd. Dünnschicht für optik, zusammensetzung zu deren herstellung und damit hergestelltes uv-absorbierendes und wärmereflektierendes glas
US6132132A (en) * 1997-02-26 2000-10-17 Rohm And Haas Company Water-based road marking paint
JP3993269B2 (ja) * 1997-04-18 2007-10-17 スリーエム カンパニー 透明ビーズおよびその製造方法
WO1998047830A1 (en) 1997-04-18 1998-10-29 Minnesota Mining And Manufacturing Company Transparent beads and their production method
EP0988333B1 (en) * 1997-06-13 2006-03-15 Minnesota Mining And Manufacturing Company Liquid pavement marking compositions
US5998482A (en) * 1997-11-10 1999-12-07 David; Sunil A. Use of synthetic polycationic amphiphilic substances with fatty acid or hydrocarbon substituents as anti-sepsis agents
US6365262B1 (en) * 1998-10-20 2002-04-02 3M Innovative Properties Company Pavement marking articles having enhanced retroreflectivity under dry or wet conditions and method for making same
US6245700B1 (en) * 1999-07-27 2001-06-12 3M Innovative Properties Company Transparent microspheres
JP4899249B2 (ja) 2001-04-05 2012-03-21 旭硝子株式会社 無鉛ガラス、ガラスセラミックス組成物およびガラスペースト
US20040259713A1 (en) * 2003-06-11 2004-12-23 3M Innovative Properties Company Microspheres comprising titania and bismuth oxide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101679108B (zh) * 2007-05-11 2012-01-11 3M创新有限公司 具有含氧化镧和氧化铝以及氧化锆、二氧化钛或它们的混合物的微球的道路标记和反射元件
CN106082683A (zh) * 2009-08-21 2016-11-09 3M创新有限公司 路面标记、反射元件、微球以及制备微球的方法
CN103964676A (zh) * 2014-05-06 2014-08-06 湖州远光路标涂料有限公司 全天候高折射反光微晶陶珠

Also Published As

Publication number Publication date
WO2005000756A2 (en) 2005-01-06
JP2007501183A (ja) 2007-01-25
US20090123754A1 (en) 2009-05-14
KR20060023556A (ko) 2006-03-14
US7585799B2 (en) 2009-09-08
EP1631530A2 (en) 2006-03-08
US7524779B2 (en) 2009-04-28
WO2005000756A3 (en) 2005-04-28
US20040259713A1 (en) 2004-12-23
US20050143248A1 (en) 2005-06-30
US20060293161A1 (en) 2006-12-28

Similar Documents

Publication Publication Date Title
CN1802326A (zh) 一种包含二氧化钛和氧化铋的微球
CN1187278C (zh) 透明微球
CN1121990C (zh) 透明微球和它们的制造方法
US6514892B1 (en) Transparent beads and their production method
CN102574729A (zh) 路面标记、反射元件以及制备微球的方法
CN1852869A (zh) 包括Al2O3 ,REO,ZrO2和/或HfO2,和Nb2O5和/或Ta2O5的陶瓷和其制备方法
CN1537082A (zh) 无定形材料和陶瓷的制备方法
CN1852868A (zh) 包括Al2O3、Y2O3、ZrO2和/或HfO2、和Nb2O5和/或Ta2O5的陶瓷和其制备方法
CN1714052A (zh) 从玻璃制备制品的方法以及所制备的玻璃陶瓷制品
CN1675136A (zh) 通过熔纺制备无定形陶瓷材料的方法
KR20200068959A (ko) 중적외선 영역에서 높은 굴절률 분산 특성을 갖는 BaO-GeO2-La2O3-TiO2-ZnO계 산화물 유리 및 그 제조방법
HK1025945A (en) Transparent beads and their production method
CN1583626A (zh) 铋酸盐玻璃及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
AD01 Patent right deemed abandoned
C20 Patent right or utility model deemed to be abandoned or is abandoned