CN1646220A - 烃的部分氧化用催化剂及该催化剂的制造方法、以及使用该从催化剂的含氢气体制造方法、及利用该催化剂制造的含氢气体的使用方法 - Google Patents
烃的部分氧化用催化剂及该催化剂的制造方法、以及使用该从催化剂的含氢气体制造方法、及利用该催化剂制造的含氢气体的使用方法 Download PDFInfo
- Publication number
- CN1646220A CN1646220A CNA038087782A CN03808778A CN1646220A CN 1646220 A CN1646220 A CN 1646220A CN A038087782 A CNA038087782 A CN A038087782A CN 03808778 A CN03808778 A CN 03808778A CN 1646220 A CN1646220 A CN 1646220A
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- catalyst
- partial oxidation
- heat
- platinum group
- resistant inorganic
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0248—Coatings comprising impregnated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1023—Catalysts in the form of a monolith or honeycomb
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP129121/2002 | 2002-04-30 | ||
| JP2002129121A JP3999557B2 (ja) | 2002-04-30 | 2002-04-30 | 炭化水素の部分酸化用触媒及び該触媒を用いた水素含有ガスの製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1646220A true CN1646220A (zh) | 2005-07-27 |
Family
ID=29397293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA038087782A Pending CN1646220A (zh) | 2002-04-30 | 2003-04-28 | 烃的部分氧化用催化剂及该催化剂的制造方法、以及使用该从催化剂的含氢气体制造方法、及利用该催化剂制造的含氢气体的使用方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20050176580A1 (enExample) |
| EP (1) | EP1500433A4 (enExample) |
| JP (1) | JP3999557B2 (enExample) |
| KR (1) | KR100692411B1 (enExample) |
| CN (1) | CN1646220A (enExample) |
| CA (1) | CA2483942A1 (enExample) |
| WO (1) | WO2003092888A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105980048A (zh) * | 2014-02-05 | 2016-09-28 | 三井金属矿业株式会社 | 燃料重整催化剂 |
| CN106999916A (zh) * | 2014-12-01 | 2017-08-01 | 科莱恩产品(德国)有限公司 | 含烃气体的水蒸气重整催化剂、氢制造装置及氢制造方法 |
| TWI611839B (zh) * | 2016-09-07 | 2018-01-21 | 國立清華大學 | 應用於低碳烴之低溫部分氧化產氫之觸媒 |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7316806B2 (en) * | 2003-10-29 | 2008-01-08 | Nippon Shokubai Co., Ltd. | Modifying catalyst for partial oxidation and method for modification |
| US7090043B2 (en) * | 2003-11-19 | 2006-08-15 | Shell Oil Company | Generating syngas for NOx regeneration combined with fuel cell auxiliary power generation |
| CA2555427C (en) * | 2004-02-19 | 2014-07-29 | Idemitsu Kosan Co., Ltd. | Reforming catalyst for hydrocarbon, method for producing hydrogen using such reforming catalyst, and fuel cell system |
| US8062623B2 (en) * | 2004-10-15 | 2011-11-22 | Velocys | Stable, catalyzed, high temperature combustion in microchannel, integrated combustion reactors |
| JP4500628B2 (ja) * | 2004-08-30 | 2010-07-14 | 千代田化工建設株式会社 | 合成ガスを製造するための反応器および合成ガスの製造方法 |
| KR100719484B1 (ko) | 2004-12-31 | 2007-05-18 | 한국에너지기술연구원 | 금속모노리스 촉매를 이용한 컴팩트형 수증기개질구조촉매 및 이를 이용한 수소의 제조방법 |
| KR20080011044A (ko) * | 2006-07-28 | 2008-01-31 | 주식회사 엘지화학 | 산화세륨 분말, 그 제조방법, 및 이를 포함하는cmp슬러리 |
| US8388710B2 (en) * | 2005-01-26 | 2013-03-05 | Lg Chem, Ltd. | Cerium oxide powder, method for preparing the same, and CMP slurry comprising the same |
| US8648006B2 (en) * | 2005-10-13 | 2014-02-11 | Velocys, Inc. | Electroless plating in microchannels |
| BG109348A (bg) * | 2005-11-15 | 2006-02-28 | АНГЕЛОВ Чавдар | Метод за преработване на природен газ в горива |
| US8357311B2 (en) * | 2006-12-28 | 2013-01-22 | Kao Corporation | Polishing liquid composition |
| US8349289B2 (en) * | 2007-03-05 | 2013-01-08 | Regents Of The University Of Minnesota | Reactive flash volatilization of fluid fuels |
| WO2008109129A2 (en) * | 2007-03-05 | 2008-09-12 | Regents Of The University Of Minnesota | Solid fuel volatilization to produce synthesis |
| BRPI0703296A2 (pt) * | 2007-07-19 | 2009-03-10 | Inst Nac De Tecnologia Int | catalisadores para a produÇço de hidrogÊnio para cÉlulas a combustÍvel de baixa temperatura a partir da reforma a vapor e da reforma autotÉrmica de Álcoois |
| US7976784B2 (en) * | 2007-12-18 | 2011-07-12 | Basf Corporation | Methods and systems including CO oxidation catalyst with low NO to NO2 conversion |
| EP2123721B1 (de) | 2008-04-15 | 2013-11-27 | Eckart GmbH | Perlglanzpigmente auf Basis von feinen und dünnen Substraten |
| US8486301B2 (en) * | 2009-04-13 | 2013-07-16 | U.S. Department Of Energy | Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream |
| JP2010279911A (ja) * | 2009-06-05 | 2010-12-16 | Nippon Shokubai Co Ltd | 水素製造用触媒、その触媒の製造方法およびその触媒を用いた水素の製造方法 |
| DE102009049413A1 (de) | 2009-10-14 | 2011-04-21 | Eckart Gmbh | Perlglanzpigmente auf Basis von feinen und dünnen synthetischen Substraten |
| JP5709005B2 (ja) * | 2011-10-26 | 2015-04-30 | トヨタ自動車株式会社 | 排ガス浄化用触媒及びその製造方法 |
| EP2823885A4 (en) * | 2012-03-09 | 2015-11-04 | Oita University | CATALYST, METHOD FOR PRODUCING THE CATALYST, METHOD FOR PRODUCING A HYDROGEN-SAVING GAS WITH THE CATALYST AND HYDROGEN PRODUCING DEVICE, FUEL CELL SYSTEM AND SILICONE-SUPPORTED CEZR-BASED OXIDE |
| JP5788352B2 (ja) * | 2012-03-23 | 2015-09-30 | Jx日鉱日石エネルギー株式会社 | 水素製造用改質触媒、該触媒を用いた水素製造装置及び燃料電池システム |
| RU2532924C1 (ru) * | 2013-07-10 | 2014-11-20 | Общество с ограниченной ответственностью "Газохим Техно" | Катализатор окислительной конверсии углеводородных газов с получением оксида углерода и водорода |
| JP2015120117A (ja) * | 2013-12-24 | 2015-07-02 | 株式会社デンソー | 浄化触媒 |
| JP2015150486A (ja) * | 2014-02-13 | 2015-08-24 | Jx日鉱日石エネルギー株式会社 | 水素製造用触媒、水素製造用触媒の製造方法及び水素製造方法 |
| BR112020026548A2 (pt) | 2018-07-27 | 2021-03-23 | Johnson Matthey Public Limited Company | Composição catalisadora, artigo catalisador para o tratamento de gás de escape, sistema de tratamento de emissão para tratar um fluxo de um gás de escape de combustão, e, método de tratamento de um gás de escape de um motor de combustão interna |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4844837A (en) * | 1982-09-30 | 1989-07-04 | Engelhard Corporation | Catalytic partial oxidation process |
| GB9806199D0 (en) * | 1998-03-24 | 1998-05-20 | Johnson Matthey Plc | Catalytic generation of hydrogen |
| JP3642273B2 (ja) * | 1999-10-21 | 2005-04-27 | 日産自動車株式会社 | 排気ガス浄化システム |
| JP3759406B2 (ja) * | 1999-12-15 | 2006-03-22 | 日産自動車株式会社 | メタノール改質触媒、メタノール改質装置及びメタノール改質方法 |
| JP3744291B2 (ja) * | 1999-12-16 | 2006-02-08 | 日産自動車株式会社 | 燃料改質用触媒及びその使用方法 |
| DE10025032A1 (de) * | 2000-05-20 | 2001-11-29 | Dmc2 Degussa Metals Catalysts | Verfahren zur autothermen, katalytischen Dampfreformierung von Kohlenwasserstoffen |
| US6436363B1 (en) * | 2000-08-31 | 2002-08-20 | Engelhard Corporation | Process for generating hydrogen-rich gas |
-
2002
- 2002-04-30 JP JP2002129121A patent/JP3999557B2/ja not_active Expired - Fee Related
-
2003
- 2003-04-28 CN CNA038087782A patent/CN1646220A/zh active Pending
- 2003-04-28 EP EP03725685A patent/EP1500433A4/en not_active Withdrawn
- 2003-04-28 CA CA002483942A patent/CA2483942A1/en not_active Abandoned
- 2003-04-28 US US10/513,108 patent/US20050176580A1/en not_active Abandoned
- 2003-04-28 WO PCT/JP2003/005421 patent/WO2003092888A1/ja not_active Ceased
- 2003-04-28 KR KR1020047016016A patent/KR100692411B1/ko not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105980048A (zh) * | 2014-02-05 | 2016-09-28 | 三井金属矿业株式会社 | 燃料重整催化剂 |
| CN105980048B (zh) * | 2014-02-05 | 2018-11-20 | 三井金属矿业株式会社 | 燃料重整催化剂 |
| CN106999916A (zh) * | 2014-12-01 | 2017-08-01 | 科莱恩产品(德国)有限公司 | 含烃气体的水蒸气重整催化剂、氢制造装置及氢制造方法 |
| TWI611839B (zh) * | 2016-09-07 | 2018-01-21 | 國立清華大學 | 應用於低碳烴之低溫部分氧化產氫之觸媒 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003320253A (ja) | 2003-11-11 |
| KR20050008676A (ko) | 2005-01-21 |
| EP1500433A4 (en) | 2006-04-26 |
| AU2003231530A1 (en) | 2003-11-17 |
| JP3999557B2 (ja) | 2007-10-31 |
| EP1500433A1 (en) | 2005-01-26 |
| US20050176580A1 (en) | 2005-08-11 |
| CA2483942A1 (en) | 2003-11-13 |
| WO2003092888A1 (fr) | 2003-11-13 |
| KR100692411B1 (ko) | 2007-03-09 |
| AU2003231530B2 (en) | 2007-04-05 |
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