CN1371404A - 含有氰基丙烯酸酯稳定剂化合物的聚碳酸酯树脂组合物 - Google Patents
含有氰基丙烯酸酯稳定剂化合物的聚碳酸酯树脂组合物 Download PDFInfo
- Publication number
- CN1371404A CN1371404A CN00812200A CN00812200A CN1371404A CN 1371404 A CN1371404 A CN 1371404A CN 00812200 A CN00812200 A CN 00812200A CN 00812200 A CN00812200 A CN 00812200A CN 1371404 A CN1371404 A CN 1371404A
- Authority
- CN
- China
- Prior art keywords
- polycarbonate
- resin composition
- poly carbonate
- stablizer
- carbonate resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/02—Aliphatic polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
MFR | Mw | Mn | MWD | 类型 | |
Calibre 600-3: | 3 | 36500 | 13700 | 2.66 | 支化 |
Calibre 200-3: | 3 | 38700 | 14200 | 2.72 | 线形 |
Calibre 200-15: | 15 | 26400 | 10500 | 2.52 | 线形 |
实施例 | UV稳定剂 | P 168 | I 1076 | HP 136 |
1★ | - | - | - | - |
2★ | - | 400ppm | - | - |
3★ | - | 115ppm | 55ppm | 30ppm |
4★ | Tinuvin 3000ppm | - | - | - |
5★ | Tinuvin 3000ppm | 400ppm | - | - |
6★ | LA31 3000ppm | - | - | - |
7★ | LA31 3000ppm | 400ppm | - | - |
8★ | Uvinul 3000ppm | - | - | - |
9 | Uvinul 3000ppm | 400ppm | - | - |
10 | Uvinul 3000ppm | 115ppm | 55ppm | 30ppm |
实施例 | 添加剂 | B★颗粒 | Y1颗粒 | Y1320℃ | Y1380℃ | ΔY1 | Y1 320℃QUV-B(700小时) | ΔY1 |
1★ | 无 | 2.78 | 3.55 | 3.86 | 0.31 | |||
2★ | P 168 | 1.20 | 3.16 | 3.55 | 0.39 | |||
3★ | P 168+I 1076+HP 136 | 1.75 | 3.03 | 3.16 | 0.13 | |||
4★ | Tinuvin | 6.45 | 11.20 | 4.42 | 4.49 | 0.07 | 12.79 | 8.37 |
5★ | Tinuvin+P 168 | 6.25 | 10.69 | 4.10 | 4.28 | 0.18 | 12.99 | 8.89 |
6★ | LA31 | 3.74 | 6.11 | 3.70 | 4.01 | 0.31 | 13.84 | 10.14 |
7★ | LA31+P 168 | 3.94 | 6.55 | 3.52 | 3.65 | 0.13 | 13.68 | 10.16 |
8★ | Uvinul | 3.62 | 6.28 | 2.89 | 3.89 | 1.00 | 14.05 | 11.16 |
9 | Uvinul+P 168 | 3.82 | 6.72 | 2.72 | 3.45 | 0.73 | 13.25 | 10.53 |
10 | Uvinul+P 168+I 1076+HP 136 | 2.40 | 3.66 | 2.43 | 3.00 | 0.57 | 12.01 | 9.58 |
脱附 | 时间(分钟) | ||||
温度(℃) | 0 | 20 | 40 | 60 | 80 |
240 | 4.33 | 4.23 | 4.19 | 4.15 | 4.12 |
260 | 4.33 | 4.19 | 4.12 | 4.08 | 4.02 |
280 | 4.33 | 4.13 | 4.11 | 3.97 | 3.74 |
△=损失 | |||||
240 | 0 | 0.10 | 0.14 | 0.18 | 0.21 |
260 | 0 | 0.14 | 0.19 | 0.25 | 0.31 |
280 | 0 | 0.20 | 0.22 | 0.36 | 0.59 |
脱附 | 时间(分钟) | ||||
温度(℃) | 0 | 20 | 40 | 60 | 80 |
240 | 4.64 | 4.61 | 4.58 | 4.41 | 4.40 |
260 | 4.64 | 4.47 | 4.38 | 4.34 | 4.23 |
280 | 4.64 | 4.45 | 4.34 | 4.22 | 4.09 |
△=损失 | |||||
240 | 0 | 0.03 | 0.06 | 0.23 | 0.24 |
260 | 0 | 0.17 | 0.26 | 0.30 | 0.41 |
280 | 0 | 0.19 | 0.30 | 0.42 | 0.55 |
脱附 | 时间(分钟) | ||||
温度(℃) | 0 | 20 | 40 | 60 | 80 |
240 | 4.31 | 4.29 | 4.26 | 4.24 | 4.15 |
260 | 4.31 | 4.23 | 4.15 | 4.11 | 4.03 |
280 | 4.31 | 4.16 | 4.14 | 4.10 | 3.89 |
△=损失 | |||||
240 | 0 | 0.02 | 0.05 | 0.07 | 0.16 |
260 | 0 | 0.08 | 0.16 | 0.20 | 0.28 |
280 | 0 | 0.15 | 0.17 | 0.21 | 0.42 |
脱附 | 时间(分钟) | ||||
温度(℃) | 0 | 20 | 40 | 60 | 80 |
240 | 4.73 | 4.72 | 4.56 | 4.44 | 4.29 |
260 | 4.73 | 4.59 | 3.92 | 3.86 | 3.54 |
280 | 4.73 | 4.05 | 3.60 | 3.45 | 3.31 |
△=损失 | |||||
240 | 0 | 0.01 | 0.17 | 0.29 | 0.44 |
260 | 0 | 0.14 | 0.81 | 0.87 | 1.19 |
280 | 0 | 0.68 | 1.13 | 1.28 | 1.42 |
脱附 | 时间(分钟) | ||||
温度(℃) | 0 | 20 | 40 | 60 | 80 |
240 | 4.66 | 4.53 | 4.51 | 4.46 | 4.28 |
260 | 4.66 | 4.53 | 4.06 | 3.97 | 3.92 |
280 | 4.66 | 4.12 | 3.85 | 3.73 | 3.09 |
△=损失 | |||||
240 | 0 | 0.13 | 0.15 | 0.20 | 0.38 |
260 | 0 | 0.13 | 0.58 | 0.69 | 0.74 |
280 | 0 | 0.54 | 0.81 | 0.93 | 1.57 |
实施例 | 添加剂 | 颗粒Y1 | 成型品Y1 | UV吸收剂在80分钟内损失% | |||
UV | 其它 | 240℃ | 260℃ | 280℃ | |||
11 | Uvinul | P 168 | 25.44 | 10.88 | 4.9 | 7.2 | 13.6 |
12 | Uvinul | P 168+I 1076 | 24.38 | 11.06 | 5.2 | 8.8 | 11.9 |
13 | Uvinul | P 168+I 1076+HP 136 | 18.75 | 9.25 | 3.7 | 6.5 | 9.7 |
14★ | Tinuvin | P 168 | 39.61 | 21.17 | 9.3 | 25.2 | 30.0 |
15★ | LA-31 | P 168 | 29.02 | 14.97 | 8.2 | 15.9 | 33.7 |
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15201099P | 1999-09-01 | 1999-09-01 | |
US60/152,010 | 1999-09-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1371404A true CN1371404A (zh) | 2002-09-25 |
CN100366678C CN100366678C (zh) | 2008-02-06 |
Family
ID=22541198
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB008122008A Expired - Fee Related CN100366678C (zh) | 1999-09-01 | 2000-08-08 | 含有氰基丙烯酸酯稳定剂化合物的聚碳酸酯树脂组合物 |
Country Status (14)
Country | Link |
---|---|
US (1) | US6441071B1 (zh) |
EP (1) | EP1216272B1 (zh) |
JP (1) | JP5073898B2 (zh) |
KR (1) | KR100712873B1 (zh) |
CN (1) | CN100366678C (zh) |
AT (1) | ATE284918T1 (zh) |
AU (1) | AU6624800A (zh) |
BR (1) | BR0013836A (zh) |
CA (1) | CA2379522C (zh) |
DE (1) | DE60016768T2 (zh) |
IL (2) | IL148251A0 (zh) |
MX (1) | MXPA02002313A (zh) |
TW (1) | TW553988B (zh) |
WO (1) | WO2001016224A2 (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100427544C (zh) * | 2003-11-26 | 2008-10-22 | 株式会社E-Tec | 非卤素类阻燃性基底材料和车辆用或飞机用地毯 |
CN101160330B (zh) * | 2005-05-30 | 2011-07-27 | 东亚合成株式会社 | 2-氰基丙烯酸酯类组合物 |
CN102361843A (zh) * | 2009-03-26 | 2012-02-22 | 朗盛德国有限责任公司 | 多元醇的稳定化 |
CN101796098B (zh) * | 2007-04-17 | 2012-11-14 | 沙伯基础创新塑料知识产权有限公司 | 热塑性组合物、制备方法和由其形成的制品 |
CN103772688A (zh) * | 2013-12-24 | 2014-05-07 | 济南开发区星火科学技术研究院 | 一种聚碳酸酯的制备方法 |
TWI488903B (zh) * | 2007-03-07 | 2015-06-21 | Bayer Materialscience Ag | 含有uv吸收劑之聚碳酸酯組成物 |
CN113321904A (zh) * | 2021-06-09 | 2021-08-31 | 上海朗亿功能材料有限公司 | 改性pet树脂材料、太阳能电池背板膜及紫外吸收剂的应用 |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19943642A1 (de) * | 1999-09-13 | 2001-03-15 | Bayer Ag | Behälter |
EP1274798A1 (en) * | 2000-04-10 | 2003-01-15 | General Electric Company | Polycarbonate having excellent hydrolytic stability |
CA2405835A1 (en) * | 2000-05-19 | 2001-11-29 | Dow Global Technologies Inc. | Carbonate polymer compositions comprising low volatile uv absorbing compounds |
DE10026628A1 (de) * | 2000-05-29 | 2001-12-06 | Bayer Ag | Transparente thermoplastische Zusammensetzungen |
JP2002265766A (ja) * | 2001-03-09 | 2002-09-18 | Unitika Ltd | ポリアリレート樹脂組成物 |
US6753367B2 (en) * | 2001-08-20 | 2004-06-22 | General Electric Company | Flame retardant polycarbonate compositions with improved weathering performance containing cyanoacrylic esters |
EP1507822B1 (en) * | 2002-05-27 | 2007-04-11 | Great Lakes Chemical (Europe) GmbH | Stabilised polypropylene |
US6899866B2 (en) * | 2002-09-06 | 2005-05-31 | Cph Innovations Corporation | Photostabilization of a sunscreen composition with a combination of an α-cyano-β, β-diphenylacrylate compound and a dialkyl naphithalate |
US6919473B2 (en) * | 2002-09-17 | 2005-07-19 | Cph Innovations Corporation | Photostabilizers, UV absorbers, and methods of photostabilizing a sunscreen composition |
US7544350B2 (en) * | 2002-11-22 | 2009-06-09 | Hallstar Innovations Corp. | Method of decreasing the UV light degradation of polymers |
US7799317B2 (en) | 2002-11-22 | 2010-09-21 | Hallstar Innovations Corp. | Photostabilizers, UV absorbers, and methods of photostabilizing compositions |
US7247658B2 (en) * | 2003-07-08 | 2007-07-24 | Milliken & Company | Reduction of discoloration in white polyurethane foams |
WO2005019354A1 (en) * | 2003-08-22 | 2005-03-03 | Sartomer Technology Co., Inc. | High temperature stabilization of uv systems |
DE10360367A1 (de) * | 2003-12-22 | 2005-07-21 | Bayer Materialscience Ag | Stabilisierte thermoplastische Zusammensetzungen |
JP2005264132A (ja) * | 2004-02-17 | 2005-09-29 | Teijin Chem Ltd | ポリカーボネート樹脂組成物 |
US7534420B2 (en) | 2004-02-25 | 2009-05-19 | Hallstar Innovations Corp. | Compounds derived from polyanhydride resins with film-forming, UV-absorbing, and photostablizing properties, compositions containing same, and methods of using the same |
ES2320677T3 (es) * | 2004-02-27 | 2009-05-27 | Mauser-Werke Gmbh | Contenedor paletizado. |
US7094127B2 (en) * | 2004-03-01 | 2006-08-22 | Milliken & Company | Apparel articles including white polyurethane foams that exhibit a reduction in propensity for discoloring |
KR100566910B1 (ko) * | 2004-06-11 | 2006-04-03 | 주식회사 삼양사 | 자외선 흡수제를 포함하는 폴리카보네이트/폴리에스테르수지 조성물 |
US7235587B2 (en) * | 2004-07-01 | 2007-06-26 | Cph Innovations Corporation | Diesters containing two crylene or fluorene moieties, sunscreen compositions containing the same, and methods of photostabilizing a sunscreen compositions containing the same |
DE102004036965A1 (de) * | 2004-07-30 | 2006-02-16 | Basf Ag | Stabilisatorzusammensetzung aus flüssigen und festen UV-Absorbern |
DE102004039963B4 (de) * | 2004-08-18 | 2010-01-28 | Protechna S.A. | Verfahren zur Herstellung von Kunststoffbehältern für Flüssigkeiten |
US8158678B2 (en) * | 2005-04-07 | 2012-04-17 | Cph Innovations Corp. | Photoabsorbing, highly conjugated compounds of cyanoacrylic esters, sunscreen compositions and methods of use |
EP1892266B1 (en) * | 2005-06-15 | 2010-07-21 | Mitsubishi Engineering-Plastics Corporation | Polycarbonate resin composition and molded articles |
CN101389702A (zh) * | 2006-02-21 | 2009-03-18 | 西巴控股有限公司 | 芳族磷酸酯阻燃剂组合物 |
US8759428B2 (en) * | 2007-08-22 | 2014-06-24 | Sabic Innovative Plastics Ip B.V. | Polycarbonate compositions |
KR101636128B1 (ko) * | 2013-07-01 | 2016-07-04 | 주식회사 엘지화학 | 폴리카보네이트 수지 조성물 |
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-
2000
- 2000-08-08 KR KR20027002792A patent/KR100712873B1/ko not_active IP Right Cessation
- 2000-08-08 CA CA002379522A patent/CA2379522C/en not_active Expired - Fee Related
- 2000-08-08 MX MXPA02002313A patent/MXPA02002313A/es unknown
- 2000-08-08 DE DE60016768T patent/DE60016768T2/de not_active Expired - Lifetime
- 2000-08-08 JP JP2001520775A patent/JP5073898B2/ja not_active Expired - Fee Related
- 2000-08-08 EP EP00953875A patent/EP1216272B1/en not_active Expired - Lifetime
- 2000-08-08 IL IL14825100A patent/IL148251A0/xx unknown
- 2000-08-08 BR BR0013836-3A patent/BR0013836A/pt not_active Application Discontinuation
- 2000-08-08 CN CNB008122008A patent/CN100366678C/zh not_active Expired - Fee Related
- 2000-08-08 WO PCT/US2000/021573 patent/WO2001016224A2/en active IP Right Grant
- 2000-08-08 US US09/634,674 patent/US6441071B1/en not_active Expired - Lifetime
- 2000-08-08 AT AT00953875T patent/ATE284918T1/de not_active IP Right Cessation
- 2000-08-08 AU AU66248/00A patent/AU6624800A/en not_active Abandoned
- 2000-08-31 TW TW089117800A patent/TW553988B/zh active
-
2002
- 2002-02-19 IL IL148251A patent/IL148251A/en not_active IP Right Cessation
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100427544C (zh) * | 2003-11-26 | 2008-10-22 | 株式会社E-Tec | 非卤素类阻燃性基底材料和车辆用或飞机用地毯 |
CN101160330B (zh) * | 2005-05-30 | 2011-07-27 | 东亚合成株式会社 | 2-氰基丙烯酸酯类组合物 |
TWI488903B (zh) * | 2007-03-07 | 2015-06-21 | Bayer Materialscience Ag | 含有uv吸收劑之聚碳酸酯組成物 |
CN101796098B (zh) * | 2007-04-17 | 2012-11-14 | 沙伯基础创新塑料知识产权有限公司 | 热塑性组合物、制备方法和由其形成的制品 |
CN102361843A (zh) * | 2009-03-26 | 2012-02-22 | 朗盛德国有限责任公司 | 多元醇的稳定化 |
CN103772688A (zh) * | 2013-12-24 | 2014-05-07 | 济南开发区星火科学技术研究院 | 一种聚碳酸酯的制备方法 |
CN113321904A (zh) * | 2021-06-09 | 2021-08-31 | 上海朗亿功能材料有限公司 | 改性pet树脂材料、太阳能电池背板膜及紫外吸收剂的应用 |
CN113321904B (zh) * | 2021-06-09 | 2023-08-15 | 上海朗亿功能材料有限公司 | 改性pet树脂材料、太阳能电池背板膜及紫外吸收剂的应用 |
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Publication number | Publication date |
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IL148251A0 (en) | 2002-09-12 |
CA2379522C (en) | 2009-06-02 |
DE60016768T2 (de) | 2006-02-23 |
AU6624800A (en) | 2001-03-26 |
EP1216272B1 (en) | 2004-12-15 |
ATE284918T1 (de) | 2005-01-15 |
WO2001016224B1 (en) | 2001-10-11 |
CN100366678C (zh) | 2008-02-06 |
KR20020087042A (ko) | 2002-11-21 |
WO2001016224A3 (en) | 2001-05-17 |
EP1216272A2 (en) | 2002-06-26 |
JP5073898B2 (ja) | 2012-11-14 |
CA2379522A1 (en) | 2001-03-08 |
US6441071B1 (en) | 2002-08-27 |
WO2001016224A2 (en) | 2001-03-08 |
JP2003508568A (ja) | 2003-03-04 |
MXPA02002313A (es) | 2002-07-30 |
IL148251A (en) | 2010-06-16 |
BR0013836A (pt) | 2002-04-23 |
DE60016768D1 (de) | 2005-01-20 |
KR100712873B1 (ko) | 2007-05-02 |
TW553988B (en) | 2003-09-21 |
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