CN1294163C - 制备超支化聚合物的方法 - Google Patents
制备超支化聚合物的方法 Download PDFInfo
- Publication number
- CN1294163C CN1294163C CNB988077205A CN98807720A CN1294163C CN 1294163 C CN1294163 C CN 1294163C CN B988077205 A CNB988077205 A CN B988077205A CN 98807720 A CN98807720 A CN 98807720A CN 1294163 C CN1294163 C CN 1294163C
- Authority
- CN
- China
- Prior art keywords
- monomer
- unsaturated monomer
- reactor
- hyperbranched polymer
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
- B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
- B01J2219/0006—Temperature measurement of the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compounds Of Unknown Constitution (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/906,140 | 1997-08-05 | ||
| US08/906,140 US5986020A (en) | 1997-08-05 | 1997-08-05 | Process for producing hyperbranched polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1265680A CN1265680A (zh) | 2000-09-06 |
| CN1294163C true CN1294163C (zh) | 2007-01-10 |
Family
ID=25421991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB988077205A Expired - Lifetime CN1294163C (zh) | 1997-08-05 | 1998-08-04 | 制备超支化聚合物的方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (4) | US5986020A (https=) |
| EP (1) | EP1001998B1 (https=) |
| JP (1) | JP4538573B2 (https=) |
| KR (1) | KR100551187B1 (https=) |
| CN (1) | CN1294163C (https=) |
| AT (1) | ATE227312T1 (https=) |
| AU (1) | AU747995B2 (https=) |
| CA (1) | CA2295654C (https=) |
| DE (1) | DE69809247T2 (https=) |
| MX (2) | MXPA00001295A (https=) |
| TW (1) | TW505661B (https=) |
| WO (1) | WO1999007754A1 (https=) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5986020A (en) * | 1997-08-05 | 1999-11-16 | Campbell; J. David | Process for producing hyperbranched polymers |
| DE69936408T2 (de) * | 1998-03-12 | 2007-12-06 | Lucite International Uk Ltd., Southampton | Polymerzusammensetzung |
| US6806301B2 (en) * | 1998-11-30 | 2004-10-19 | Flint Ink Corporation | Lithographic printing inks |
| US6638995B1 (en) * | 1998-11-30 | 2003-10-28 | Flint Ink Corporation | Printing inks |
| US6140392A (en) | 1998-11-30 | 2000-10-31 | Flint Ink Corporation | Printing inks |
| FR2791990A1 (fr) * | 1999-04-06 | 2000-10-13 | Oreal | Composition cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation notamment en capillaire |
| FR2791989A1 (fr) | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
| US6946525B2 (en) | 1999-04-06 | 2005-09-20 | L'oreal S.A. | Composition comprising polymers having a star structure, the polymers, and their use |
| FR2791988A1 (fr) * | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique ou pharmaceutique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
| FR2791986A1 (fr) | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
| FR2791987A1 (fr) | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
| CN1198850C (zh) * | 1999-07-14 | 2005-04-27 | 约翰逊聚合物公司 | 连续生产不含凝胶聚合物的方法,及含有不含凝胶聚合物的粉末和液体涂料应用 |
| ES2340174T3 (es) | 1999-07-14 | 2010-05-31 | Basf Corporation | Proceso para la produccion continua de polimeros de epoxi-(met)acrilico estireno y su uso en recubrimientos. |
| US6605680B1 (en) | 2000-04-07 | 2003-08-12 | Eastman Chemical Resins, Inc. | Low color, aromatic modified C5 hydrocarbon resins |
| DE10035119A1 (de) * | 2000-07-19 | 2002-01-31 | Basf Ag | Teilverzweigte Polymere |
| US20020020669A1 (en) * | 2000-07-28 | 2002-02-21 | Kim Yung K. | Silicone derivatized macromolecules |
| EP1367080A1 (en) | 2002-05-29 | 2003-12-03 | Hycail B.V. | Hyperbranched poly(hydroxycarboxylic acid) polymers |
| AU2003204606A1 (en) * | 2002-06-14 | 2004-01-15 | Rohm And Haas Company | Water-based adhesives |
| US6840175B2 (en) | 2002-11-20 | 2005-01-11 | Flint Ink Corporation | Lithographic printing method using a single fluid ink |
| JP3999746B2 (ja) * | 2003-05-19 | 2007-10-31 | ローム アンド ハース カンパニー | ポリマーナノ粒子の高固形分調製方法 |
| US20050080209A1 (en) * | 2003-10-08 | 2005-04-14 | Blankenship Robert Mitchell | Continuous production of crosslinked polymer nanoparticles |
| US6982309B2 (en) * | 2003-12-19 | 2006-01-03 | Fina Technology, Inc. | Synthesis of branched styrenic copolymers with p-t-butylstyrene |
| JP5173406B2 (ja) * | 2004-04-02 | 2013-04-03 | ネクストテツク・ゲー・エム・ベー・ハー | 生体高分子のクロマトグラフ分離のための複合吸収剤材料の製造方法 |
| US7504466B2 (en) * | 2004-11-04 | 2009-03-17 | Rohm And Haas Company | High solids preparation of crosslinked polymer particles |
| KR100789590B1 (ko) * | 2005-01-25 | 2007-12-28 | 주식회사 엘지화학 | 보존 안정성이 우수한 열경화성 수지 조성물 |
| US8192695B2 (en) * | 2005-05-04 | 2012-06-05 | Fina Technology, Inc. | Reactor apparatus having reduced back mixing |
| US7511101B2 (en) * | 2005-05-13 | 2009-03-31 | Fina Technology, Inc. | Plug flow reactor and polymers prepared therewith |
| TWI379849B (en) * | 2005-09-20 | 2012-12-21 | Eternal Chemical Co Ltd | Radiation-curable alkoxy silanized hyperbranched polyester acrylates and preparation thereof |
| US8163443B2 (en) * | 2006-03-09 | 2012-04-24 | Nippon Steel Chemical Co., Ltd. | Photosensitive resin composition for volume phase hologram recording and optical information recording medium using the same |
| US8231973B2 (en) * | 2006-06-13 | 2012-07-31 | 3M Innovative Properties Company | Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film |
| US7615283B2 (en) * | 2006-06-13 | 2009-11-10 | 3M Innovative Properties Company | Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film |
| US8883865B2 (en) | 2006-09-05 | 2014-11-11 | Cerion Technology, Inc. | Cerium-containing nanoparticles |
| EP2066767B1 (en) * | 2006-09-05 | 2015-10-21 | Cerion LLC | Cerium dioxide nanoparticle-containing fuel additive |
| US10435639B2 (en) | 2006-09-05 | 2019-10-08 | Cerion, Llc | Fuel additive containing lattice engineered cerium dioxide nanoparticles |
| WO2008124265A2 (en) * | 2007-04-09 | 2008-10-16 | Dow Global Technologies, Inc. | Capped polyester polyol lubricant composition |
| US20080268140A1 (en) | 2007-04-26 | 2008-10-30 | Csd, Inc. | Temporary removable solvent based protective coating |
| US8221574B2 (en) | 2007-04-26 | 2012-07-17 | Csd, Llc | Top coating for indoor and outdoor temporary removable graphics and system and method for making, applying and removing such graphics |
| CN101939418A (zh) | 2008-01-30 | 2011-01-05 | 杰龙公司 | 用于培养干细胞衍生的心肌细胞的合成表面 |
| CA2714010C (en) | 2008-01-30 | 2020-06-16 | Corning Incorporated | Synthetic surfaces for culturing stem cell derived oligodendrocyte progenitor cells |
| JP5767104B2 (ja) * | 2008-06-06 | 2015-08-19 | エーブリー デニソン コーポレイションAvery Dennison Corporation | 一時的な戸外用グラフィックフィルム |
| US7919640B2 (en) * | 2008-12-30 | 2011-04-05 | Fina Technology, Inc. | Synthesis with metal methacrylates as comonomers |
| US7919641B2 (en) * | 2008-12-30 | 2011-04-05 | Fina Technology, Inc. | Synthesis of styrene-soluble ionic comonomer |
| US20100168357A1 (en) * | 2008-12-30 | 2010-07-01 | Fina Technology, Inc. | Branched Ionomers with Metal Methacrylates as Comonomers |
| JP2012515227A (ja) * | 2009-01-12 | 2012-07-05 | ビーエーエスエフ ソシエタス・ヨーロピア | 高弾性軟質ポリウレタンフォーム |
| KR20120089857A (ko) | 2009-09-30 | 2012-08-14 | 바스프 에스이 | 알콕실화 중합체 |
| JP5658607B2 (ja) * | 2010-03-31 | 2015-01-28 | 新日鉄住金化学株式会社 | 多分岐型超高分子量体を含有するスチレン系樹脂組成物の製造方法およびその組成物 |
| TWI507425B (zh) * | 2010-06-14 | 2015-11-11 | Nippon Steel & Sumikin Chem Co | An ultraviolet-curing resin composition for use in an ink-jet printing method, and an optical element |
| ES2791035T3 (es) * | 2011-08-30 | 2020-10-30 | Chevron Phillips Chemical Co Lp | Polímeros hiperramificados y métodos para preparar y usar los mismos |
| JP5858705B2 (ja) * | 2011-09-26 | 2016-02-10 | 新日鉄住金化学株式会社 | 高分岐型超高分子量体を含有するスチレン系樹脂組成物の製造方法およびその組成物 |
| JP5913918B2 (ja) * | 2011-11-09 | 2016-04-27 | 新日鉄住金化学株式会社 | 高分岐型板状押出発泡体用スチレン系樹脂組成物 |
| JP5930667B2 (ja) * | 2011-11-09 | 2016-06-08 | 新日鉄住金化学株式会社 | 高分岐型フィルム用スチレン系樹脂組成物及びスチレン系樹脂フィルム |
| JP5913917B2 (ja) * | 2011-11-09 | 2016-04-27 | 新日鉄住金化学株式会社 | 高分岐型発泡用スチレン系樹脂組成物 |
| JP5930668B2 (ja) * | 2011-11-09 | 2016-06-08 | 新日鉄住金化学株式会社 | インジェクションブロー成形品の製造方法 |
| JP5930666B2 (ja) * | 2011-11-09 | 2016-06-08 | 新日鉄住金化学株式会社 | 高分岐型二軸延伸シート用スチレン系樹脂組成物及び二軸延伸シート |
| JP5913919B2 (ja) * | 2011-11-09 | 2016-04-27 | 新日鉄住金化学株式会社 | 高分岐型ゴム変性スチレン系樹脂組成物及びシート |
| CN102807631A (zh) * | 2012-08-15 | 2012-12-05 | 罗吉尔 | 管道式连续聚合反应法 |
| WO2014197421A1 (en) | 2013-06-05 | 2014-12-11 | Biotime, Inc. | Compositions and methods for induced tissue regeneration in mammalian species |
| US10143661B2 (en) | 2013-10-17 | 2018-12-04 | Cerion, Llc | Malic acid stabilized nanoceria particles |
| US11078462B2 (en) | 2014-02-18 | 2021-08-03 | ReCyte Therapeutics, Inc. | Perivascular stromal cells from primate pluripotent stem cells |
| US10240127B2 (en) | 2014-07-03 | 2019-03-26 | ReCyte Therapeutics, Inc. | Exosomes from clonal progenitor cells |
| BE1023998B1 (nl) * | 2015-06-09 | 2017-10-26 | P2I Ltd | Coatings |
| CA3202332A1 (en) | 2015-12-07 | 2017-06-15 | Agex Therapeutics, Inc. | Methods for the re-derivation of diverse pluripotent stem cell-derived brown fat cells |
| US9869018B2 (en) * | 2016-04-26 | 2018-01-16 | Taiwan Semiconductor Manufacturing Co., Ltd. | Solid precursor delivery method using liquid solvent for thin film deposition |
| CN106065053A (zh) * | 2016-06-13 | 2016-11-02 | 江苏大学 | 一种超支化聚二乙烯基苯多臂共聚物的合成方法 |
| KR102406946B1 (ko) * | 2020-07-16 | 2022-06-10 | 한국화학연구원 | 항균 하이퍼브랜치드 고분자 및 이를 이용한 항균 구형 활성탄 |
| CN112574428B (zh) * | 2020-12-16 | 2022-04-12 | 济南大学 | 一种超支化型含氟硅耐高温脱模剂及其应用 |
| CN114426675B (zh) * | 2021-12-17 | 2023-04-07 | 湖北康创科技有限公司 | 一种超支化阳离子聚合物乳液及其在污泥脱水上的应用 |
| CN114539642A (zh) * | 2022-01-18 | 2022-05-27 | 宁波伏龙同步带有限公司 | 一种机器人用的高性能双面齿覆带及其制备方法 |
| CN115466358B (zh) * | 2022-09-30 | 2024-12-10 | 中南民族大学 | 一种无溶剂水溶性氯化聚丙烯的制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4414370A (en) * | 1981-01-09 | 1983-11-08 | S. C. Johnson & Son, Inc. | Process for continuous bulk copolymerization of vinyl monomers |
| CN1111648A (zh) * | 1993-12-29 | 1995-11-15 | 埃勒夫阿托化学有限公司 | 乙烯基芳族单体和共轭二烯的星形嵌段共聚物 |
| US5587446A (en) * | 1994-11-08 | 1996-12-24 | Cornell Research Foundation, Inc. | Hyperbranched polymers from AB monomers |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE571473A (https=) * | 1957-12-17 | |||
| FR2435284A1 (fr) * | 1978-09-09 | 1980-04-04 | Asahi Chemical Ind | Garnissage pour chromatographie liquide tres rapide et procede de production et procede d'utilisation |
| DE3026831A1 (de) * | 1980-07-16 | 1982-02-18 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von copolymerisaten auf basis von monovinylaromaten und ethylenisch ungesaettigten carbonsaeuren und deren verwendung von oberflaechenverguetungsmittel |
| EP0068024B2 (en) * | 1981-01-09 | 1996-02-07 | S.C. Johnson & Son, Inc. | Process for continuous bulk copolymerization of vinyl monomers |
| US5631329A (en) * | 1990-08-27 | 1997-05-20 | Dendritech, Inc. | Process for producing hyper-comb-branched polymers |
| SE9103077D0 (sv) * | 1991-10-22 | 1991-10-22 | Neste Oy | Omaettad etensampolymer och saett foer framstaellning daerav |
| DE4306384A1 (de) * | 1993-03-02 | 1994-09-08 | Basf Ag | Chlorfreie, nicht-trocknende Isobuten-Dien-Copolymere |
| WO1995006669A1 (en) * | 1993-09-01 | 1995-03-09 | Mobil Oil Corporation | Novel cyclopolymerization polymers from non-conjugated dienes |
| US5484866A (en) * | 1993-11-09 | 1996-01-16 | Mobil Oil Corporation | Concentrates of a highly branched polymer and functional fluids prepared therefrom |
| US5414062A (en) * | 1994-03-10 | 1995-05-09 | Rohm And Haas Company | Method for reduction of aqueous phase polymer formation in suspension polymerization |
| US5508366A (en) * | 1994-10-18 | 1996-04-16 | S. C. Johnson & Son, Inc. | Continuous production of reduced gel content hydroxylated addition polymers |
| US5767211A (en) * | 1996-05-02 | 1998-06-16 | E. I. Du Pont De Nemours And Company | Synthesis of multi-functional hyperbranched polymers by polymerization of di-or tri-vinyl monomers in the presence of a chain transfer catalyst |
| US5986020A (en) * | 1997-08-05 | 1999-11-16 | Campbell; J. David | Process for producing hyperbranched polymers |
-
1997
- 1997-08-05 US US08/906,140 patent/US5986020A/en not_active Expired - Lifetime
-
1998
- 1998-08-04 CN CNB988077205A patent/CN1294163C/zh not_active Expired - Lifetime
- 1998-08-04 JP JP2000506251A patent/JP4538573B2/ja not_active Expired - Lifetime
- 1998-08-04 KR KR1020007001176A patent/KR100551187B1/ko not_active Expired - Lifetime
- 1998-08-04 DE DE69809247T patent/DE69809247T2/de not_active Expired - Lifetime
- 1998-08-04 CA CA002295654A patent/CA2295654C/en not_active Expired - Fee Related
- 1998-08-04 AU AU87674/98A patent/AU747995B2/en not_active Ceased
- 1998-08-04 EP EP98939197A patent/EP1001998B1/en not_active Expired - Lifetime
- 1998-08-04 AT AT98939197T patent/ATE227312T1/de not_active IP Right Cessation
- 1998-08-04 WO PCT/US1998/016199 patent/WO1999007754A1/en not_active Ceased
-
1999
- 1999-02-04 TW TW087112913A patent/TW505661B/zh active
- 1999-09-03 US US09/389,821 patent/US6265511B1/en not_active Expired - Lifetime
-
2000
- 2000-02-04 MX MXPA00001295 patent/MXPA00001295A/es unknown
-
2001
- 2001-06-04 US US09/873,634 patent/US6627720B2/en not_active Expired - Lifetime
-
2003
- 2003-08-14 MX MXPA03007260A patent/MXPA03007260A/es active IP Right Grant
- 2003-09-09 US US10/658,498 patent/US20040048987A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4414370A (en) * | 1981-01-09 | 1983-11-08 | S. C. Johnson & Son, Inc. | Process for continuous bulk copolymerization of vinyl monomers |
| CN1111648A (zh) * | 1993-12-29 | 1995-11-15 | 埃勒夫阿托化学有限公司 | 乙烯基芳族单体和共轭二烯的星形嵌段共聚物 |
| US5587446A (en) * | 1994-11-08 | 1996-12-24 | Cornell Research Foundation, Inc. | Hyperbranched polymers from AB monomers |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69809247T2 (de) | 2003-07-24 |
| EP1001998A1 (en) | 2000-05-24 |
| MXPA00001295A (es) | 2000-10-31 |
| DE69809247D1 (de) | 2002-12-12 |
| US5986020A (en) | 1999-11-16 |
| MX217863B (https=) | 2003-12-01 |
| AU8767498A (en) | 1999-03-01 |
| WO1999007754A1 (en) | 1999-02-18 |
| US20040048987A1 (en) | 2004-03-11 |
| CA2295654A1 (en) | 1999-02-18 |
| KR100551187B1 (ko) | 2006-02-13 |
| TW505661B (en) | 2002-10-11 |
| ATE227312T1 (de) | 2002-11-15 |
| AU747995B2 (en) | 2002-05-30 |
| US6627720B2 (en) | 2003-09-30 |
| US20010039316A1 (en) | 2001-11-08 |
| EP1001998B1 (en) | 2002-11-06 |
| KR20010022585A (ko) | 2001-03-26 |
| MXPA03007260A (es) | 2005-09-08 |
| JP4538573B2 (ja) | 2010-09-08 |
| CA2295654C (en) | 2006-05-16 |
| JP2001512752A (ja) | 2001-08-28 |
| CN1265680A (zh) | 2000-09-06 |
| US6265511B1 (en) | 2001-07-24 |
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