CN1265677A - 长链的制备方法 - Google Patents
长链的制备方法 Download PDFInfo
- Publication number
- CN1265677A CN1265677A CN98807722A CN98807722A CN1265677A CN 1265677 A CN1265677 A CN 1265677A CN 98807722 A CN98807722 A CN 98807722A CN 98807722 A CN98807722 A CN 98807722A CN 1265677 A CN1265677 A CN 1265677A
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- China
- Prior art keywords
- reaction
- minutes
- reactor
- residence time
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Steroid Compounds (AREA)
- Saccharide Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
实施例 | 停留时间(分钟) | Mn | Mw | DB/chain |
1A | 30 | 1060 | 1831 | 0.555 |
1B | 60 | 872 | 1411 | 0.655 |
1C | 90 | 718 | 1086 | 1.052 |
实施例 | 停留时间(分钟) | Mn | Mw | DB/chain |
1D | 10 | 873 | 1365 | 0.882 |
1E | 15 | 763 | 1108 | 0.858 |
1F | 30 | 614 | 802 | 0.628 |
1G | 60 | 535 | 659 | 0.633 |
实施例 | 停留时间(分钟) | Mn | Mw | DB/chain |
1H | 10 | 532 | 658 | 0.953 |
1I | 15 | 478 | 563 | 0.745 |
1J | 30 | 431 | 484 | 0.477 |
1K | 60 | 399 | 440 | 0.341 |
实施例 | 苯乙烯(%w/w) | DTBP(%w/w) | Mn | Mw | DB/chain |
2A | 100 | 0.0 | 733.6 | 1077 | 0.91 |
2B | 99.5 | 0.5 | 696.6 | 989.4 | 0.816 |
2C | 99.0 | 1.0 | 685.7 | 955.4 | 0.908 |
实施例 | 苯乙烯(%w/w) | DTBP(%w/w) | Mn | Mw | DB/chain |
3A | 100 | 0.0 | 484.7 | 595.9 | 0.775 |
3B | 99.5 | 0.5 | 471.2 | 558.2 | 0.765 |
3C | 99.0 | 1.0 | 470.4 | 556 | 0.743 |
3D | 98.0 | 2.0 | 463 | 544.3 | 0.728 |
实施例 | 温度(℃) | DTBP(%) | Mn | Mw | TDB/chain |
5 | 285 | 0.5 | 1540 | 3000 | 0.71 |
6 | 315 | 0.5 | 1300 | 2570 | 0.95 |
实施例 | 温度(℃) | DTBP(%w/w) | Mn | Mw | TDB/chain |
7 | 315 | 0.04 | 1450 | 2920 | 0.85 |
8 | 295 | 0.04 | 1810 | 3790 | 0.97 |
实施例 | 温度(℃) | 停留时间(分钟) | Mn | Mw | TDB/chain |
9 | 270 | 12 | 1900 | 2920 | 0.75 |
10A | 343 | 6.33 | 794 | 2640 | 1.1 |
10B | 343 | 10.06 | 740 | 2600 | 1.2 |
10C | 343 | 15.1 | 700 | 2675 | 1.2 |
10D | 343 | 15.1 | 706 | 2710 | 0.9 |
10E | 371 | 6.33 | 495 | 1285 | 1.1 |
10F | 371 | 10.06 | 463 | 1190 | 1.0 |
10G | 371 | 15.1 | 447 | 1205 | 0.8 |
10H | 371 | 15.1 | 460 | 1290 | 0.9 |
实施例 | 酸值 | AA转化率 | Mn | Mw | Pd |
11B(i) | 113 | 98% | 940 | 1505 | 1.67 |
11B(ii) | 67.4 | 73.4% | 1130 | 1900 | 1.69 |
11B(iii) | 143.6 | 78.9% | 1375 | 2745 | 2.0 |
Claims (29)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/906,141 | 1997-08-05 | ||
US08/906,141 US6388026B1 (en) | 1997-08-05 | 1997-08-05 | Process for the preparation of macromers |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1265677A true CN1265677A (zh) | 2000-09-06 |
CN1114622C CN1114622C (zh) | 2003-07-16 |
Family
ID=25421992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN98807722A Expired - Lifetime CN1114622C (zh) | 1997-08-05 | 1998-08-04 | 末端不饱和的均聚和共聚长链的制备方法 |
Country Status (13)
Country | Link |
---|---|
US (1) | US6388026B1 (zh) |
EP (1) | EP1001994B1 (zh) |
JP (1) | JP4237935B2 (zh) |
KR (1) | KR100573637B1 (zh) |
CN (1) | CN1114622C (zh) |
AT (1) | ATE235516T1 (zh) |
AU (1) | AU735802B2 (zh) |
CA (1) | CA2295590C (zh) |
DE (1) | DE69812638T2 (zh) |
MX (1) | MX218562B (zh) |
PH (1) | PH11998001991B1 (zh) |
TW (1) | TW550269B (zh) |
WO (1) | WO1999007755A2 (zh) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6730763B1 (en) * | 2000-03-29 | 2004-05-04 | Toagosei Co., Ltd. | Composition |
EP1207173A1 (en) * | 2000-11-15 | 2002-05-22 | Eastman Chemical Company | Waterborne acrylic modified alkyd |
JP2004527595A (ja) * | 2001-01-19 | 2004-09-09 | エクソンモービル・ケミカル・パテンツ・インク | 改良された耐熱性を有するエチレンアルキルアクリレートコポリマー |
US7163992B2 (en) * | 2001-03-15 | 2007-01-16 | Toagosei Co., Ltd. | Methods for manufacturing a copolymer with a high yield by reacting a vinyl monomer and a macromonomer |
WO2003004543A1 (fr) * | 2001-07-03 | 2003-01-16 | Toagosei Co., Ltd. | Procede de preparation de copolymere, copolymere obtenu au moyen de ce procede et produit durci et film de revetement associes |
JP2003301005A (ja) * | 2002-04-09 | 2003-10-21 | Daicel Chem Ind Ltd | 架橋性ビニル重合体及びその製造方法 |
US7585924B2 (en) | 2002-07-11 | 2009-09-08 | E. I. Du Pont De Nemours And Company | Pressurized high temperature polymerization process and polymerization system used therein |
CN100343284C (zh) * | 2002-12-25 | 2007-10-17 | 三菱丽阳株式会社 | 乙烯基类聚合物、乙烯基类聚合物的制造方法、热固化性被覆用组合物和涂料 |
US20050003094A1 (en) * | 2003-07-02 | 2005-01-06 | Grady Michael Charles | Thermally initiated polymerization process |
US20060079624A1 (en) * | 2004-10-08 | 2006-04-13 | Hildeberto Nava | Crosslinkable polymer systems |
US20060173142A1 (en) * | 2005-02-01 | 2006-08-03 | Hildeberto Nava | Functionalized thermosetting resin systems |
US7906598B2 (en) * | 2006-08-30 | 2011-03-15 | Intertape Polymer Corp. | Recirculation loop reactor bulk polymerization process |
US20100105847A1 (en) | 2006-01-24 | 2010-04-29 | Intertape Polymer Corp. | Plug flow bulk polymerization of vinyl monomers |
WO2008027858A1 (en) * | 2006-08-30 | 2008-03-06 | Intertape Polymer Corp. | Recirculation loop reactor bulk polymerization process |
JP5347115B2 (ja) * | 2007-04-24 | 2013-11-20 | 綜研化学株式会社 | 粘着剤の製造方法 |
DE102013226502A1 (de) | 2013-12-18 | 2015-06-18 | Tesa Se | Verfahren zur Herstellung kurzkettiger Makromoleküle auf Styrolbasis |
US11485699B2 (en) | 2016-07-06 | 2022-11-01 | Synthomer Adhesive Technologies Llc | (Meth)acrylic oligomers |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2593399A (en) * | 1949-11-19 | 1952-04-22 | Monsanto Chemicals | Mass polymerization of styrene at 285u deg. c. |
BE571473A (zh) * | 1957-12-17 | |||
FR1206795A (fr) * | 1958-05-16 | 1960-02-11 | Resines Et Vernis Artificiels | Procédé de polymérisation en masse continue de dérivés vinyliques |
US4117235A (en) * | 1971-09-23 | 1978-09-26 | Owens-Illinois, Inc. | Novel preparation of novel low molecular weight, liquid polymer |
US4276432A (en) * | 1973-07-18 | 1981-06-30 | Celanese Corporation | Low molecular weight acrylates or methacrylates and methods for their preparation |
DE3026973A1 (de) * | 1980-07-16 | 1982-01-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von thermoplastisch verarbeitbaren copolymerisaten |
US4414370A (en) | 1981-01-09 | 1983-11-08 | S. C. Johnson & Son, Inc. | Process for continuous bulk copolymerization of vinyl monomers |
US4529787A (en) | 1982-06-15 | 1985-07-16 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
JPS60133007A (ja) | 1983-12-20 | 1985-07-16 | Toagosei Chem Ind Co Ltd | マクロモノマ−の製造方法 |
US4546160A (en) | 1984-02-29 | 1985-10-08 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
US4680352A (en) | 1985-03-01 | 1987-07-14 | E. I. Du Pont De Nemours And Company | Cobalt (II) chelates as chain transfer agents in free radical polymerizations |
US4600755A (en) | 1985-04-03 | 1986-07-15 | Ppg Industries, Inc. | Free radical initiated polymerization of polymerizable ethylenically unsaturated monomer component in the presence of hydrogen peroxide |
US5324879A (en) | 1985-12-03 | 1994-06-28 | Commonwealth Scientific And Industrial Research Organisation | Oligomerization process |
JPS62232408A (ja) | 1986-04-03 | 1987-10-12 | Toagosei Chem Ind Co Ltd | 片末端に官能基を有するアクリル系ポリマ−の製造法 |
US5028677A (en) | 1986-09-23 | 1991-07-02 | E. I. Du Pont De Nemours And Company | Novel macromonomer compositions |
JP2847242B2 (ja) | 1988-04-21 | 1999-01-13 | 東亞合成株式会社 | カルボキシル基含有マクロモノマーの製造方法 |
US5100980A (en) | 1990-02-06 | 1992-03-31 | Rohm And Haas Company | Process for efficient molecular weight control in copolymerization |
JPH04108808A (ja) | 1990-08-28 | 1992-04-09 | Toagosei Chem Ind Co Ltd | マクロモノマーの製造方法 |
JPH04119526A (ja) | 1990-09-10 | 1992-04-21 | Hitachi Electron Eng Co Ltd | ディスク移載装置 |
US5268437A (en) | 1992-01-22 | 1993-12-07 | Rohm And Haas Company | High temperature aqueous polymerization process |
CA2088129A1 (en) * | 1992-02-06 | 1993-08-07 | Fritz Erdmann Kempter | Continuous polymerization of vinyl monomers |
JPH05247117A (ja) | 1992-03-10 | 1993-09-24 | Toagosei Chem Ind Co Ltd | マクロモノマー及びその製造方法 |
JP3087793B2 (ja) | 1992-04-14 | 2000-09-11 | 東亞合成株式会社 | マクロモノマー及びその製造方法 |
US5264530A (en) | 1992-05-01 | 1993-11-23 | E. I. Du Pont De Nemours And Company | Process of polymerization in an aqueous system |
JP3395291B2 (ja) | 1993-11-05 | 2003-04-07 | 住友化学工業株式会社 | メタクリル系重合体の製造方法 |
CA2151112A1 (en) | 1994-06-13 | 1995-12-14 | Michael Bennett Freeman | High temperature polymerization process and products therefrom |
US5587431A (en) | 1995-04-21 | 1996-12-24 | E. I. Du Pont De Nemours And Company | Synthesis of terminally unsaturated oligomers |
-
1997
- 1997-08-05 US US08/906,141 patent/US6388026B1/en not_active Expired - Lifetime
-
1998
- 1998-08-04 DE DE69812638T patent/DE69812638T2/de not_active Expired - Lifetime
- 1998-08-04 EP EP98940784A patent/EP1001994B1/en not_active Expired - Lifetime
- 1998-08-04 WO PCT/US1998/016198 patent/WO1999007755A2/en active IP Right Grant
- 1998-08-04 CA CA002295590A patent/CA2295590C/en not_active Expired - Fee Related
- 1998-08-04 KR KR1020007001175A patent/KR100573637B1/ko not_active IP Right Cessation
- 1998-08-04 AU AU88979/98A patent/AU735802B2/en not_active Expired
- 1998-08-04 AT AT98940784T patent/ATE235516T1/de not_active IP Right Cessation
- 1998-08-04 PH PH11998001991A patent/PH11998001991B1/en unknown
- 1998-08-04 CN CN98807722A patent/CN1114622C/zh not_active Expired - Lifetime
- 1998-08-04 JP JP2000506252A patent/JP4237935B2/ja not_active Expired - Lifetime
-
1999
- 1999-02-06 TW TW087112914A patent/TW550269B/zh not_active IP Right Cessation
-
2000
- 2000-02-04 MX MXPA00001294 patent/MX218562B/es unknown
Also Published As
Publication number | Publication date |
---|---|
MX218562B (es) | 2004-01-09 |
KR20010022584A (ko) | 2001-03-26 |
JP2001512753A (ja) | 2001-08-28 |
AU735802B2 (en) | 2001-07-12 |
AU8897998A (en) | 1999-03-01 |
US6388026B1 (en) | 2002-05-14 |
CA2295590A1 (en) | 1999-02-18 |
WO1999007755A3 (en) | 1999-06-24 |
DE69812638T2 (de) | 2004-03-18 |
KR100573637B1 (ko) | 2006-04-26 |
EP1001994B1 (en) | 2003-03-26 |
PH11998001991B1 (en) | 2003-10-10 |
DE69812638D1 (de) | 2003-04-30 |
WO1999007755A2 (en) | 1999-02-18 |
ATE235516T1 (de) | 2003-04-15 |
JP4237935B2 (ja) | 2009-03-11 |
CN1114622C (zh) | 2003-07-16 |
MXPA00001294A (es) | 2000-10-31 |
EP1001994A2 (en) | 2000-05-24 |
CA2295590C (en) | 2005-07-05 |
TW550269B (en) | 2003-09-01 |
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