FR1206795A - Procédé de polymérisation en masse continue de dérivés vinyliques - Google Patents

Procédé de polymérisation en masse continue de dérivés vinyliques

Info

Publication number
FR1206795A
FR1206795A FR1206795DA FR1206795A FR 1206795 A FR1206795 A FR 1206795A FR 1206795D A FR1206795D A FR 1206795DA FR 1206795 A FR1206795 A FR 1206795A
Authority
FR
France
Prior art keywords
polymerization process
mass polymerization
continuous mass
vinyl derivatives
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Other languages
English (en)
Inventor
Ernest Fivel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resines et Vernis Artificiels
Original Assignee
Resines et Vernis Artificiels
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Resines et Vernis Artificiels filed Critical Resines et Vernis Artificiels
Application granted granted Critical
Publication of FR1206795A publication Critical patent/FR1206795A/fr
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • B01J19/243Tubular reactors spirally, concentrically or zigzag wound
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/27Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices
    • B01F27/272Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed axially between the surfaces of the rotor and the stator, e.g. the stator rotor system formed by conical or cylindrical surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/90Heating or cooling systems
    • B01F35/92Heating or cooling systems for heating the outside of the receptacle, e.g. heated jackets or burners
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/90Heating or cooling systems
    • B01F35/95Heating or cooling systems using heated or cooled stirrers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/36Polymerisation in solid state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/42Nitriles
    • C08F20/44Acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42Nitriles
    • C08F220/44Acrylonitrile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05Stirrers
    • B01F27/11Stirrers characterised by the configuration of the stirrers
    • B01F27/114Helically shaped stirrers, i.e. stirrers comprising a helically shaped band or helically shaped band sections
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00085Plates; Jackets; Cylinders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00159Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00162Controlling or regulating processes controlling the pressure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/918Polymerization reactors for addition polymer preparation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/922Polymerization process of ethylenic monomers using manipulative technique

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
FR1206795D 1958-05-16 1958-05-16 Procédé de polymérisation en masse continue de dérivés vinyliques Expired FR1206795A (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR765708 1958-05-16
FR991999A FR91206E (fr) 1958-05-16 1964-10-20 Procédé de polymérisation en masse continue de dérivés vinyliques

Publications (1)

Publication Number Publication Date
FR1206795A true FR1206795A (fr) 1960-02-11

Family

ID=26183435

Family Applications (2)

Application Number Title Priority Date Filing Date
FR1206795D Expired FR1206795A (fr) 1958-05-16 1958-05-16 Procédé de polymérisation en masse continue de dérivés vinyliques
FR991999A Expired FR91206E (fr) 1958-05-16 1964-10-20 Procédé de polymérisation en masse continue de dérivés vinyliques

Family Applications After (1)

Application Number Title Priority Date Filing Date
FR991999A Expired FR91206E (fr) 1958-05-16 1964-10-20 Procédé de polymérisation en masse continue de dérivés vinyliques

Country Status (6)

Country Link
US (2) US3141868A (fr)
BE (2) BE578371A (fr)
DE (1) DE1155246B (fr)
FR (2) FR1206795A (fr)
GB (2) GB871686A (fr)
NL (2) NL106322C (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1301068B (de) * 1963-06-28 1969-08-14 Michelin & Cie Vorrichtung zur kontinuierlichen Polymerisation einer polymerisierbaren Mischung
EP0009638A1 (fr) * 1978-09-12 1980-04-16 Hoechst Aktiengesellschaft Procédé de polymérisation en masse continue de monomères alkénylaromatiques

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1206795A (fr) * 1958-05-16 1960-02-11 Resines Et Vernis Artificiels Procédé de polymérisation en masse continue de dérivés vinyliques
US3268625A (en) * 1962-12-26 1966-08-23 Standard Oil Co Bulk interpolymerization of monomeric mixture comprising acrylonitrile and alpha-alkyl styrene
GB1056236A (en) * 1963-06-14 1967-01-25 Sumitomo Chemical Co Copolymers of olefins and acrylonitrile and a process for producing the same
NL128227C (fr) * 1963-09-20 1900-01-01
FR1484663A (fr) * 1966-02-11 1967-06-16 Plastugil Interpolymères thermoplastiques de styrène et de méthacrylate de méthyle à résistance au choc exaltée
JPS497568B1 (fr) * 1970-10-23 1974-02-21
US4529787A (en) * 1982-06-15 1985-07-16 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
DE3248602A1 (de) * 1982-12-30 1984-07-12 Röhm GmbH, 6100 Darmstadt Acrylharze mit geringer wasseraufnahme
US4546160A (en) * 1984-02-29 1985-10-08 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
US4619979A (en) * 1984-03-28 1986-10-28 Minnesota Mining And Manufacturing Company Continuous free radial polymerization in a wiped-surface reactor
US4695608A (en) * 1984-03-29 1987-09-22 Minnesota Mining And Manufacturing Company Continuous process for making polymers having pendant azlactone or macromolecular moieties
JPH0684408B2 (ja) * 1985-02-19 1994-10-26 基嗣 須加 ポリメチルメタクリレ−トの製造方法
JPH04300908A (ja) * 1991-03-29 1992-10-23 Nippon Steel Chem Co Ltd 成形材料
CA2088129A1 (fr) * 1992-02-06 1993-08-07 Fritz Erdmann Kempter Polymerisation continue de monomeres vinyliques
US6388026B1 (en) * 1997-08-05 2002-05-14 S. C. Johnson Commercial Markets, Inc. Process for the preparation of macromers
EP1157738B1 (fr) * 2000-05-21 2005-11-30 CPC Cellular Process Chemistry Systems GmbH Module de temps de séjour pour microréacteurs
JP4432104B2 (ja) * 2003-05-30 2010-03-17 富士フイルム株式会社 マイクロリアクター
US7862886B2 (en) * 2005-08-12 2011-01-04 Fujifilm Corporation Optical film, antireflection film, processes for producing the same, and polarizing plate and display employing the same

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE653083C (de) * 1935-06-20 1937-11-13 I G Farbenindustrie Akt Ges Verfahren zur Herstellung von Polymerisationsprodukten des Styrols
US2530409A (en) * 1948-05-27 1950-11-21 Dow Chemical Co Method for polymerizing styrene
CH287223A (de) * 1949-07-26 1952-11-30 Bataafsche Petroleum Verfahren zur Herstellung von Kopolymeren mit vorausbestimmter Zusammensetzung.
US2714101A (en) * 1950-01-06 1955-07-26 Dow Chemical Co Process of conducting exothermic bulk polymerization
GB683329A (en) * 1950-08-25 1952-11-26 Dow Chemical Co Improvements in or relating to the polymerisation of styrene
BE513431A (fr) * 1951-09-10
US2745824A (en) * 1952-11-26 1956-05-15 American Cyanamid Co Process for the polymerization of styrene and acrylonitrile
US2739142A (en) * 1953-08-24 1956-03-20 Dow Chemical Co Method of preparation of moldable copolymers of styrene and acrylonitrile
US3035033A (en) * 1957-12-12 1962-05-15 Dow Chemical Co Molding grade copolymers and process for preparing the same
BE588809A (fr) * 1958-02-06
US3080348A (en) * 1958-04-23 1963-03-05 Dow Chemical Co Copolymers of styrene and methyl methacrylate
FR1206795A (fr) * 1958-05-16 1960-02-11 Resines Et Vernis Artificiels Procédé de polymérisation en masse continue de dérivés vinyliques
FR1225103A (fr) * 1959-02-13 1960-06-29 Dow Chemical Co Copolymères de styrène et de méthyl-méthacrylate
BE592554A (fr) * 1959-07-03 1900-01-01
NL124891C (fr) * 1965-05-07

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1301068B (de) * 1963-06-28 1969-08-14 Michelin & Cie Vorrichtung zur kontinuierlichen Polymerisation einer polymerisierbaren Mischung
EP0009638A1 (fr) * 1978-09-12 1980-04-16 Hoechst Aktiengesellschaft Procédé de polymérisation en masse continue de monomères alkénylaromatiques

Also Published As

Publication number Publication date
GB1046830A (en) 1966-10-26
NL106322C (fr) 1963-10-15
FR91206E (fr) 1968-05-03
NL6513467A (fr) 1966-04-21
GB871686A (en) 1961-06-28
BE671074A (fr) 1966-02-14
US3466269A (en) 1969-09-09
BE578371A (fr) 1959-08-31
US3141868A (en) 1964-07-21
DE1155246B (de) 1963-10-03

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