CN1261442C - 用于制备草胺膦的方法以及中间体 - Google Patents
用于制备草胺膦的方法以及中间体 Download PDFInfo
- Publication number
- CN1261442C CN1261442C CNB988082616A CN98808261A CN1261442C CN 1261442 C CN1261442 C CN 1261442C CN B988082616 A CNB988082616 A CN B988082616A CN 98808261 A CN98808261 A CN 98808261A CN 1261442 C CN1261442 C CN 1261442C
- Authority
- CN
- China
- Prior art keywords
- formula
- alkyl
- compound
- groups
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
- C07F9/657172—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and one oxygen atom being part of a (thio)phosphinic acid ester: (X = O, S)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19736125.0 | 1997-08-20 | ||
| DE19736125A DE19736125A1 (de) | 1997-08-20 | 1997-08-20 | Verfahren zur Herstellung von Glufosinate und phosphorhaltige alpha-Aminonitrile als Zwischenprodukte |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1267305A CN1267305A (zh) | 2000-09-20 |
| CN1261442C true CN1261442C (zh) | 2006-06-28 |
Family
ID=7839559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB988082616A Expired - Lifetime CN1261442C (zh) | 1997-08-20 | 1998-08-08 | 用于制备草胺膦的方法以及中间体 |
Country Status (27)
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584893A (zh) * | 2012-02-07 | 2012-07-18 | 浙江工业大学 | 一种草铵膦的制备方法 |
| CN107236001A (zh) * | 2016-04-06 | 2017-10-10 | 四川省乐山市福华通达农药科技有限公司 | 一种膦醛的合成方法 |
| CN112898338A (zh) * | 2019-12-04 | 2021-06-04 | 利尔化学股份有限公司 | 草铵膦中间体及草铵膦的制备方法 |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2714873A1 (en) * | 2002-03-21 | 2003-10-02 | Schering Aktiengesellschaft | Plasma carboxypeptidase b inhibitors |
| JP5336851B2 (ja) * | 2006-09-20 | 2013-11-06 | Ｍｅｉｊｉ Ｓｅｉｋａファルマ株式会社 | リン含有α−アミノ酸の製造法およびその製造中間体 |
| WO2011129820A1 (en) * | 2010-04-14 | 2011-10-20 | Strategic Enzyme Applications, Inc. | Process for producing phosphinothricin employing nitrilases |
| CN102372738B (zh) * | 2010-08-14 | 2017-11-10 | 武汉工程大学 | Lj反应在制备维蒂希试剂和草铵膦中的应用 |
| TWI546311B (zh) | 2011-09-30 | 2016-08-21 | 明治製菓藥業股份有限公司 | 固殺草ｐ游離酸之製造方法 |
| CN102372739B (zh) * | 2011-12-05 | 2017-06-16 | 河北威远生化农药有限公司 | 一种草铵膦的合成方法 |
| CN102399239A (zh) * | 2011-12-27 | 2012-04-04 | 江苏优士化学有限公司 | 一种草铵膦及类似物的合成方法 |
| CN102399240A (zh) * | 2011-12-27 | 2012-04-04 | 江苏优士化学有限公司 | 一种改进的草铵膦及类似物的合成方法 |
| CN103183707B (zh) * | 2011-12-30 | 2016-06-15 | 中化蓝天集团有限公司 | 一种草胺膦的制备方法 |
| CN103374030B (zh) * | 2012-04-13 | 2016-03-23 | 浙江新安化工集团股份有限公司 | 一种制备草铵膦的方法及其中间体的制备方法 |
| CN103483379A (zh) * | 2013-09-26 | 2014-01-01 | 江苏辉丰农化股份有限公司 | 一种草铵膦酸的制备方法 |
| CN106459110A (zh) * | 2014-05-13 | 2017-02-22 | 拜耳作物科学股份公司 | 制备含磷羟腈的方法 |
| CN104558033B (zh) * | 2014-12-19 | 2016-05-18 | 浙江工业大学 | 一种l-草铵膦-n-羧酸酐及其制备和应用 |
| MX2017013895A (es) | 2015-04-27 | 2018-03-15 | Bayer Cropscience Ag | Combinaciones herbicidas que comprenden glufosinato e indaziflam. |
| MX2018002731A (es) | 2015-09-02 | 2018-04-13 | Bayer Cropscience Ag | Proceso para la elaboracion de esteres de cianohidrina que contienen fosforo. |
| KR20180048894A (ko) | 2015-09-02 | 2018-05-10 | 바이엘 크롭사이언스 악티엔게젤샤프트 | 인 함유 시아노하이드린 에스테르의 제조 방법 |
| US10316048B2 (en) | 2015-09-02 | 2019-06-11 | Bayer Cropscience Aktiengesellschaft | Process for producing phosphorus-containing cyanohydrin esters |
| US10941167B2 (en) | 2015-09-02 | 2021-03-09 | Basf Se | Process for producing phosphorus-containing cyanohydrin esters |
| TWI721019B (zh) | 2015-09-29 | 2021-03-11 | 德商拜耳作物科學股份有限公司 | 製造膦酸酯之方法 |
| CN107417721B (zh) * | 2016-05-24 | 2019-05-28 | 四川福思达生物技术开发有限责任公司 | 一种氢氰酸加成工艺 |
| WO2018108794A1 (de) | 2016-12-15 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von d-glufosinat oder dessen salzen unter verwendung von ephedrin |
| WO2018108797A1 (de) | 2016-12-15 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von l-glufosinat oder dessen salzen unter verwendung von ephedrin |
| EP3392237B1 (de) | 2017-04-21 | 2019-10-02 | Evonik Degussa GmbH | Verfahren zur herstellung von acroleincyanhydrinen |
| CA3070104C (en) * | 2017-07-18 | 2023-08-08 | Agrimetis, Llc | Methods for the purification of l-glufosinate and crystalline l-glufosinate ammonium forms |
| MX393530B (es) | 2017-07-21 | 2025-03-24 | Basf Se | Produccion de glufosinato mediante la reaccion de acetato de 3-[n-butoxi(metil)fosforil]-1-cianopropilo para obtener una mezcla de n-butil (3-amino-3-cianopropil)metilfosfinato y sales de amonio de acido (3-amino-3-cianopropil)metilfosfinico. |
| EP3728278B1 (de) | 2017-12-19 | 2022-11-30 | Basf Se | Verfahren zur herstellung von phosphorhaltigen aminonitrilen und glufosinat |
| CN109134534B (zh) * | 2018-08-08 | 2020-09-08 | 江苏好收成韦恩农化股份有限公司 | 一种3,3-二烷氧基丙基甲基膦酸酯简易制备方法 |
| KR102131687B1 (ko) * | 2018-09-10 | 2020-07-08 | 주식회사 휴런 | 파킨슨 병 진단 장치 및 방법 |
| EP3909962B1 (en) | 2019-01-11 | 2025-05-21 | CJ CheilJedang Corporation | Method of producing l-glufosinate |
| CN111662326B (zh) * | 2019-03-05 | 2023-03-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN111662324B (zh) * | 2019-03-05 | 2023-02-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN111662325B (zh) * | 2019-03-05 | 2023-03-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN110003269B (zh) * | 2019-04-29 | 2022-04-05 | 利尔化学股份有限公司 | 低能耗生产草铵膦的方法 |
| CN110590836B (zh) * | 2019-09-30 | 2022-07-26 | 江苏七洲绿色化工股份有限公司 | 一种草铵膦中间体的合成方法 |
| CN111659330B (zh) * | 2020-04-23 | 2021-05-07 | 河北威远生物化工有限公司 | 一种连续化生产草铵膦的工艺与设备 |
| CN112358499A (zh) * | 2020-11-12 | 2021-02-12 | 江苏春江润田农化有限公司 | 一种草铵膦的合成方法 |
| PE20241062A1 (es) | 2021-04-01 | 2024-05-13 | Evonik Operations Gmbh | Procedimiento enzimatico para la produccion de l-glufosinato y sus fosfoesteres |
| EP4105335A1 (en) | 2021-06-16 | 2022-12-21 | Evonik Operations GmbH | Enzymatic method for the production of l-glufosinate p-alkyl esters |
| JP7503214B2 (ja) * | 2021-07-20 | 2024-06-19 | リアー ケミカル カンパニー リミテッド | グルホシネート又はその類似体を調製するための方法 |
| EP4151643A1 (en) | 2021-09-16 | 2023-03-22 | Evonik Operations GmbH | Improved process for production of phosphoesters of glufosinate precursors |
| CN114163472B (zh) * | 2021-11-27 | 2024-08-09 | 永农生物科学有限公司 | 醇溶剂下合成α-氨基腈的方法及草铵膦的合成方法 |
| EP4493709A1 (en) | 2022-03-14 | 2025-01-22 | Evonik Operations GmbH | Enzymatic method for the production of l-glufosinate p-esters |
| CN116789695B (zh) * | 2022-11-17 | 2024-03-29 | 永农生物科学有限公司 | 一种草铵膦的制备方法 |
| CN120641571A (zh) | 2023-02-23 | 2025-09-12 | 巴斯夫欧洲公司 | 从氰醇或氰醇衍生物制备l-草铵膦的方法 |
| TW202512923A (zh) | 2023-06-13 | 2025-04-01 | 德商巴地斯顏料化工廠 | 使用基於醯胺酶之製程合成固殺草 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5484529A (en) * | 1977-12-19 | 1979-07-05 | Meiji Seika Kaisha Ltd | Production of d,l-2-amino-4-methylphosphinobutyric acid |
| DE2849003A1 (de) * | 1978-11-11 | 1980-08-21 | Hoechst Ag | Phosphorhaltige cyanhydrinderivate und verfahren zu ihrer herstellung |
| DE3508573A1 (de) | 1985-03-11 | 1986-09-11 | Hoechst Ag, 6230 Frankfurt | Phosphorhaltige (alpha)-aminonitrile und verfahren zu ihrer herstellung |
| JP2615777B2 (ja) * | 1987-05-26 | 1997-06-04 | 日産化学工業株式会社 | ホスフィニルアミノ酸誘導体の製造方法 |
| RU2024536C1 (ru) * | 1992-01-09 | 1994-12-15 | Институт элементоорганических соединений РАН | 4-триметилсилоксиметилфосфинил -2- триметилсилокси -2-бутеннитрил в качестве полупродукта синтеза 4-метилгидроксифосфинил-2- кетобутановой кислоты, обладающей гербицидной активностью, и способы его получения |
-
1997
- 1997-08-20 DE DE19736125A patent/DE19736125A1/de not_active Withdrawn
-
1998
- 1998-08-08 CA CA002301181A patent/CA2301181C/en not_active Expired - Fee Related
- 1998-08-08 RU RU2000107139/04A patent/RU2275376C2/ru not_active IP Right Cessation
- 1998-08-08 WO PCT/EP1998/005053 patent/WO1999009039A1/de not_active Ceased
- 1998-08-08 CZ CZ2000593A patent/CZ2000593A3/cs unknown
- 1998-08-08 UA UA2000031510A patent/UA66806C2/uk unknown
- 1998-08-08 PT PT98945195T patent/PT1005475E/pt unknown
- 1998-08-08 PL PL338855A patent/PL191587B1/pl not_active IP Right Cessation
- 1998-08-08 US US09/486,031 patent/US6359162B1/en not_active Expired - Lifetime
- 1998-08-08 HU HU0003501A patent/HUP0003501A3/hu unknown
- 1998-08-08 AU AU92598/98A patent/AU756471B2/en not_active Ceased
- 1998-08-08 ES ES98945195T patent/ES2214727T3/es not_active Expired - Lifetime
- 1998-08-08 CN CNB988082616A patent/CN1261442C/zh not_active Expired - Lifetime
- 1998-08-08 AT AT98945195T patent/ATE258180T1/de not_active IP Right Cessation
- 1998-08-08 TR TR2000/00456T patent/TR200000456T2/xx unknown
- 1998-08-08 DK DK98945195T patent/DK1005475T3/da active
- 1998-08-08 BR BRPI9811971-0A patent/BR9811971B1/pt not_active IP Right Cessation
- 1998-08-08 EP EP98945195A patent/EP1005475B1/de not_active Expired - Lifetime
- 1998-08-08 IL IL13463398A patent/IL134633A0/xx not_active IP Right Cessation
- 1998-08-08 KR KR1020007001687A patent/KR100674326B1/ko not_active Expired - Lifetime
- 1998-08-08 DE DE59810636T patent/DE59810636D1/de not_active Expired - Lifetime
- 1998-08-08 JP JP2000509718A patent/JP4519316B2/ja not_active Expired - Lifetime
- 1998-08-18 TW TW087113567A patent/TW530063B/zh not_active IP Right Cessation
- 1998-08-18 AR ARP980104072A patent/AR015932A1/es active IP Right Grant
- 1998-08-18 CO CO98046950A patent/CO5031316A1/es unknown
- 1998-08-18 MY MYPI98003746A patent/MY132853A/en unknown
- 1998-08-19 ZA ZA987465A patent/ZA987465B/xx unknown
- 1998-08-19 PH PH11998002119A patent/PH11998002119A1/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584893A (zh) * | 2012-02-07 | 2012-07-18 | 浙江工业大学 | 一种草铵膦的制备方法 |
| CN102584893B (zh) * | 2012-02-07 | 2015-03-04 | 浙江工业大学 | 一种草铵膦的制备方法 |
| CN107236001A (zh) * | 2016-04-06 | 2017-10-10 | 四川省乐山市福华通达农药科技有限公司 | 一种膦醛的合成方法 |
| CN112898338A (zh) * | 2019-12-04 | 2021-06-04 | 利尔化学股份有限公司 | 草铵膦中间体及草铵膦的制备方法 |
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Owner name: BAYER CROP SCIENCE GMBH Free format text: FORMER OWNER: HOECHST SCHERING AGREVO GMBH Effective date: 20150505 Owner name: BAYER CROPSCIENCE AG Free format text: FORMER OWNER: BAYER CROP SCIENCE GMBH Effective date: 20150505 Owner name: BAYER INTELLECTUAL PROPERTY GMBH Free format text: FORMER OWNER: BAYER CROPSCIENCE AG Effective date: 20150505 Owner name: HOECHST SCHERING AGREVO GMBH Free format text: FORMER OWNER: HOECHST SCHERING AGREVO GMBH Effective date: 20150505 |
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Effective date of registration: 20150505 Address after: German Monheim Patentee after: BAYER CROPSCIENCE AG Address before: German Monheim Patentee before: Bayer Cropscience AG Effective date of registration: 20150505 Address after: German Monheim Patentee after: BAYER CROPSCIENCE AG Address before: Frankfurt, Germany Patentee before: BAYER CROPSCIENCE GmbH Effective date of registration: 20150505 Address after: Frankfurt, Germany Patentee after: BAYER CROPSCIENCE GmbH Address before: Frankfurt, Germany Patentee before: AVENTIS CROPSCIENCE GmbH Effective date of registration: 20150505 Address after: Frankfurt, Germany Patentee after: AVENTIS CROPSCIENCE GmbH Address before: Berlin Patentee before: Hechester-Sherin Agricultural Development Co.,Ltd. |
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