CN1239676C - 用于聚合物的涂敷粒状阻燃剂 - Google Patents
用于聚合物的涂敷粒状阻燃剂 Download PDFInfo
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- CN1239676C CN1239676C CNB028022602A CN02802260A CN1239676C CN 1239676 C CN1239676 C CN 1239676C CN B028022602 A CNB028022602 A CN B028022602A CN 02802260 A CN02802260 A CN 02802260A CN 1239676 C CN1239676 C CN 1239676C
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- 239000004945 silicone rubber Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000002730 succinyl group Chemical group C(CCC(=O)*)(=O)* 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- WDICADOLCFREFI-UHFFFAOYSA-N trichlorosilyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)O[Si](Cl)(Cl)Cl WDICADOLCFREFI-UHFFFAOYSA-N 0.000 description 1
- ROBPXJWVYLAUFL-UHFFFAOYSA-N trichlorosilylamine Chemical compound N[Si](Cl)(Cl)Cl ROBPXJWVYLAUFL-UHFFFAOYSA-N 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- 229940094989 trimethylsilane Drugs 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 1
- PZRXQXJGIQEYOG-UHFFFAOYSA-N zinc;oxido(oxo)borane Chemical compound [Zn+2].[O-]B=O.[O-]B=O PZRXQXJGIQEYOG-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
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- Chemical & Material Sciences (AREA)
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
组合物 | 组分 | 实施例1 | 对比例1 | 对比例2 | 对比例3 | |
(A) | 无机化合物 | SiO2 | SiO2 | SiO2 | SiO2 | |
数量(重量份) | 0.3 | 0.3 | 0.3 | 0.3 | ||
平均粒径(nm) | 100 | 97 | 104 | 1500 | ||
涂料化合物 | α-羟基聚二甲基硅氧烷 | - | - | - | ||
无机化合物粒子表面上羟基的数目(每nm2) | 0.6 | 2.5 | 2.4 | 2.7 | ||
(B) | 类型 | PC | PC | PC | PC | |
数量(重量份) | 100 | 100 | 100 | 100 | ||
(C) | 聚二甲基硅氧烷数量(重量份) | - | - | 0.3 | - | |
评价 | 通过共价键键合到无机化合物粒子表面上的涂料化合物数量(wt%) | 10.2 | 0 | 0 | 0 | |
阻燃性(HB方法) | 自熄的 | 完全燃烧 | 完全燃烧 | 完全燃烧 | ||
发生发泡 | 不发生发泡 | 不发生发泡 | 不发生发泡 | |||
分散性 | 成形制品的外观 | ◎ | × | △ | × | |
由EPMA方法评价 | 见图2(a)*分布均匀性小 | 见图2(b)*分布均匀性大 | ||||
稳定性(热停留测试)P2/P1的比例 | 0.92 | 0.53 | 0.63 | 0.51 |
组合物 | 组分 | 实施例2 | 对比例3 | 对比例4 | 对比例5 | |
(A) | 无机化合物 | SiO2 | SiO2 | SiO2 | SiO2 | |
数量(重量份) | 0.3 | 0.3 | 0.3 | 0.3 | ||
平均粒径(nm) | 100 | 110 | 90 | 80 | ||
涂料化合物 | 二羟基二氯硅烷 | 六甲基二硅氮烷 | 辛基三氯硅烷 | α-羟基聚二苯基硅氧烷 | ||
(B) | 类型 | PC | PC | PC | PC | |
数量(重量份) | 100 | 100 | 100 | 100 | ||
评价 | 通过共价键键合到无机化合物粒子表面上的涂料化合物数量(wt%) | 3.2 | 2.5 | 5.5 | 18.5 | |
阻燃性(HB方法) | 自熄的 | 自熄的 | 自熄的 | 自熄的 |
组合物 | 组分 | 实施例6 | 实施例7 | 实施例8 | 实施例9 | 实施例10 | 实施例11 | |
(A) | 无机化合物 | SiO2 | SiO2 | SiO2 | SiO2 | SiO2 | SiO2 | |
数量(重量份) | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | ||
平均粒径(nm) | 98 | 105 | 97 | 103 | 97 | 100 | ||
涂料化合物 | α-羟基聚二甲基硅氧烷 | α-羟基聚二甲基硅氧烷 | α-羟基聚二甲基硅氧烷 | α-羟基聚二甲基硅氧烷 | α-羟基聚二甲基硅氧烷 | α-羟基聚二甲基硅氧烷 | ||
(B) | 类型 | PC | PC | PC/ABS | HIPS | HIPS/PPE | ABS | |
数量(重量份) | 100 | 100 | 95/5 | 100 | 80/20 | 100 | ||
(C) | 类型 | SF | SF/PTFE | SF/PTFE | P1 | P1 | P1 | |
数量(重量份) | 0.3 | 0.3/0.3 | 0.3/0.3 | 5 | 5 | 5 | ||
评价 | 通过共价键键合到无机化合物粒子表面上的涂料化合物数量(wt%) | 10.2 | 10.2 | 10.2 | 10.2 | 10.2 | 10.2 | |
阻燃性(VB方法) | ○ | ◎ | ◎ | ○ | ◎ | ○ | ||
分散性 | 成形制品的外观 | ◎ | ○ | ○ | ◎ | ◎ | ◎ | |
稳定性(热停留测试)P2/P1的比例 | 0.91 | 0.93 | 0.91 | 0.85 | 0.87 | 0.82 |
组合物 | 组分 | 实施例12 | 实施例13 | ||
(A) | 无机化合物 | SiO2 | SiO2 | ||
数量(重量份) | 0.3 | 0.3 | |||
平均粒径(nm) | 105 | 100 | |||
涂料化合物 | α-羟基聚二甲基硅氧烷 | α-羟基聚二甲基硅氧烷 | |||
(B) | 类型 | PC | PC | ||
数量(重量份) | 100 | 100 | |||
(C) | 类型 | ASF/PTFE | ASF/PTFE | ||
数量(重量份) | 0.3/0.3 | 0.3/0.3 | |||
(D) | GF的数量(重量份) | 0 | 20 | ||
评价 | 通过共价键键合到无机化合物粒子表面上的涂料化合物数量(wt%) | 10.2 | 10.2 | ||
阻燃性(VB方法) | ◎ | ◎ | |||
分散性 | 成形制品的外观 | ○ | ○-△ | ||
稳定性(热停留测试)P2/P1的比例 | 0.93 | 0.90 | |||
弯曲模量(MPa) | 1800 | 6100 |
组合物 | 组分 | 对比例4 | 实施例14 | 对比例5 | 实施例15 | 对比例6 | 对比例7 | 实施例16 | 对比例8 | |
(A) | 无机化合物 | - | SiO2 | - | SiO2 | SiO2 | - | SiO2 | ||
数量(重量份) | - | 0.5 | - | 0.5 | 0.5 | - | 0.5 | |||
平均粒径(nm) | - | 110 | - | 105 | 1100 | - | 110 | - | ||
涂料化合物 | - | α-羟基聚二甲基硅氧烷 | - | α-羟基聚二甲基硅氧烷 | - | - | α-羟基聚二甲基硅氧烷 | - | ||
(B) | 类型 | HIPS | TPV | |||||||
数量(重量份) | 100 | 100 | ||||||||
(C) | 类型 | - | P1 | - | ||||||
数量(重量份) | - | 5 | - | |||||||
评价 | 通过共价键键合到无机化合物粒子表面上的涂料化合物数量(wt%) | 0 | 10.2 | 0 | 10.2 | 0 | 0 | 10.2 | 0 | |
热稳定性 | ||||||||||
50%重量降低发生的温度(℃) | 415 | 428 | 426 | 438 | 427 | 399 | 495 | 406 | ||
基于其中不加入(A)的情况的改进比(%) | 参考 | 3 | 参考 | 3 | 0 | 参考 | 24 | 2 | ||
见图3 | 见图4 | 见图5 |
Claims (12)
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KR (1) | KR100537594B1 (zh) |
CN (1) | CN1239676C (zh) |
ES (1) | ES2246677B1 (zh) |
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DE60109120T2 (de) * | 2000-12-21 | 2005-12-29 | Mitsubishi Engineering-Plastics Corp. | Polycarbonatharzzusammensetzung und Formteile davon |
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2002
- 2002-06-21 JP JP2003507211A patent/JPWO2003000822A1/ja not_active Withdrawn
- 2002-06-21 US US10/344,275 patent/US20030166757A1/en not_active Abandoned
- 2002-06-21 WO PCT/JP2002/006258 patent/WO2003000822A1/ja active IP Right Grant
- 2002-06-21 CN CNB028022602A patent/CN1239676C/zh not_active Expired - Fee Related
- 2002-06-21 KR KR10-2003-7002594A patent/KR100537594B1/ko active IP Right Grant
- 2002-06-21 TW TW091113810A patent/TWI300424B/zh not_active IP Right Cessation
- 2002-06-21 ES ES200350015A patent/ES2246677B1/es not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
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JPWO2003000822A1 (ja) | 2004-10-07 |
CN1464903A (zh) | 2003-12-31 |
TWI300424B (zh) | 2008-09-01 |
KR100537594B1 (ko) | 2005-12-19 |
ES2246677A1 (es) | 2006-02-16 |
KR20030027964A (ko) | 2003-04-07 |
ES2246677B1 (es) | 2006-12-01 |
US20030166757A1 (en) | 2003-09-04 |
WO2003000822A1 (en) | 2003-01-03 |
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