CN1211842C - 从聚碳硅烷形成的低介电常数聚有机硅涂料 - Google Patents
从聚碳硅烷形成的低介电常数聚有机硅涂料 Download PDFInfo
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- CN1211842C CN1211842C CNB008114218A CN00811421A CN1211842C CN 1211842 C CN1211842 C CN 1211842C CN B008114218 A CNB008114218 A CN B008114218A CN 00811421 A CN00811421 A CN 00811421A CN 1211842 C CN1211842 C CN 1211842C
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- polycarbosilane
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- 238000007254 oxidation reaction Methods 0.000 claims description 20
- 125000000962 organic group Chemical group 0.000 claims description 18
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- 125000003342 alkenyl group Chemical group 0.000 claims description 12
- 125000001118 alkylidene group Chemical group 0.000 claims description 9
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- 230000000694 effects Effects 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 239000012528 membrane Substances 0.000 claims description 9
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 230000008859 change Effects 0.000 claims description 8
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 31
- 239000010410 layer Substances 0.000 description 27
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 23
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
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- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
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- 125000004122 cyclic group Chemical group 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02126—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing Si, O, and at least one of H, N, C, F, or other non-metal elements, e.g. SiOC, SiOC:H or SiONC
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/12—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/16—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02296—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
- H01L21/02318—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment
- H01L21/02345—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment treatment by exposure to radiation, e.g. visible light
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/312—Organic layers, e.g. photoresist
- H01L21/3121—Layers comprising organo-silicon compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02282—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process liquid deposition, e.g. spin-coating, sol-gel techniques, spray coating
Abstract
Description
波数(cm-1) | 谱带归属 |
2958 | CH3不对称伸缩 |
2923 | CH2不对称伸缩 |
2883 | CH3对称伸缩 |
2853 | CH2对称伸缩 |
2131 | Si-H伸缩 |
1357 | Si-CH2-Si变形 |
1254 | Si-CH3对称变形 |
1048 | Si-C-Si摇摆 |
936 | Si-H2剪刀模式 |
846 | SiH2摇摆 |
765 | Si-C-Si不对称伸缩 |
Si-H峰面积(2300-2000cm-1) | C-H峰面积(3050-2700cm-1) | |
旋涂 | 23.97 | 1.953 |
80 | 22.97 | 1.851 |
150 | 19.77 | 1.924 |
250 | 9.13 | 1.813 |
400 | 5.92 | 1.433 |
Si-H峰面积(2300-2000cm-1) | C-H峰面积(3050-2700cm-1) | |
旋涂 | 24.02 | 2.08 |
80 | 22.96 | 2 |
150 | 19.64 | 1.908 |
250 | 13.62 | 1.784 |
400 | 8.47 | 1.527 |
波数(cm-1) | 谱带归属 |
2958 | CH3不对称伸缩 |
2923 | CH2不对称伸缩 |
2883 | CH3对称伸缩 |
2853 | CH2对称伸缩 |
2143 | Si-H伸缩 |
1358 | Si-CH2-Si变形 |
1254 | Si-CH3对称变形 |
1048 | Si-C-Si摇摆 |
932 | Si-H2剪刀模式 |
861 | SiH2摇摆 |
763 | Si-C-Si不对称伸缩 |
Si-H峰面积(2300-2000cm-1) | C-H峰面积(3050-2700cm-1) | |
旋涂 | 19.81 | 0.968 |
80 | 19.09 | 0.931 |
150 | 9.81 | 0.503 |
220 | 7.21 | 0.397 |
400 | 4.62 | 0.387 |
最后烘烤温度(℃) | k | Si-H峰面积 | C-H峰面积 |
250 | 2.4 | 7.09 | 1.53 |
300 | 3.5 | 2.72 | 1.45 |
320 | 3.8 | 1.88 | 1.25 |
Claims (61)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/327,356 US6225238B1 (en) | 1999-06-07 | 1999-06-07 | Low dielectric constant polyorganosilicon coatings generated from polycarbosilanes |
US09/327,356 | 1999-06-07 |
Publications (2)
Publication Number | Publication Date |
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CN1369110A CN1369110A (zh) | 2002-09-11 |
CN1211842C true CN1211842C (zh) | 2005-07-20 |
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CNB008114218A Expired - Fee Related CN1211842C (zh) | 1999-06-07 | 2000-06-07 | 从聚碳硅烷形成的低介电常数聚有机硅涂料 |
Country Status (7)
Country | Link |
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US (2) | US6225238B1 (zh) |
EP (1) | EP1206796A2 (zh) |
JP (1) | JP2003501518A (zh) |
KR (1) | KR20020012265A (zh) |
CN (1) | CN1211842C (zh) |
AU (1) | AU5327200A (zh) |
WO (1) | WO2000075975A2 (zh) |
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-
1999
- 1999-06-07 US US09/327,356 patent/US6225238B1/en not_active Expired - Fee Related
-
2000
- 2000-06-07 AU AU53272/00A patent/AU5327200A/en not_active Abandoned
- 2000-06-07 CN CNB008114218A patent/CN1211842C/zh not_active Expired - Fee Related
- 2000-06-07 KR KR1020017015819A patent/KR20020012265A/ko not_active Application Discontinuation
- 2000-06-07 JP JP2001502153A patent/JP2003501518A/ja not_active Withdrawn
- 2000-06-07 WO PCT/US2000/015637 patent/WO2000075975A2/en not_active Application Discontinuation
- 2000-06-07 EP EP00938196A patent/EP1206796A2/en not_active Withdrawn
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US20020064965A1 (en) | 2002-05-30 |
US6395649B1 (en) | 2002-05-28 |
AU5327200A (en) | 2000-12-28 |
WO2000075975A3 (en) | 2001-08-23 |
US6225238B1 (en) | 2001-05-01 |
CN1369110A (zh) | 2002-09-11 |
KR20020012265A (ko) | 2002-02-15 |
EP1206796A2 (en) | 2002-05-22 |
JP2003501518A (ja) | 2003-01-14 |
WO2000075975A2 (en) | 2000-12-14 |
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