CN1203076C - 可用作烯烃聚合的助催化剂的有机金属化合物 - Google Patents
可用作烯烃聚合的助催化剂的有机金属化合物 Download PDFInfo
- Publication number
- CN1203076C CN1203076C CNB018010636A CN01801063A CN1203076C CN 1203076 C CN1203076 C CN 1203076C CN B018010636 A CNB018010636 A CN B018010636A CN 01801063 A CN01801063 A CN 01801063A CN 1203076 C CN1203076 C CN 1203076C
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- China
- Prior art keywords
- formula
- substituent
- dimethyl
- alkyl
- organometallic compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/603—Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00200649 | 2000-02-24 | ||
| EP00200649.2 | 2000-02-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1366528A CN1366528A (zh) | 2002-08-28 |
| CN1203076C true CN1203076C (zh) | 2005-05-25 |
Family
ID=8171089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018010636A Expired - Fee Related CN1203076C (zh) | 2000-02-24 | 2001-02-12 | 可用作烯烃聚合的助催化剂的有机金属化合物 |
Country Status (15)
| Country | Link |
|---|---|
| US (3) | US6608224B2 (enExample) |
| EP (1) | EP1173445B1 (enExample) |
| JP (1) | JP2003524013A (enExample) |
| KR (1) | KR20010112459A (enExample) |
| CN (1) | CN1203076C (enExample) |
| AR (1) | AR027476A1 (enExample) |
| AT (1) | ATE268779T1 (enExample) |
| AU (1) | AU783058B2 (enExample) |
| BR (1) | BR0105430A (enExample) |
| CA (1) | CA2370799A1 (enExample) |
| DE (1) | DE60103702T2 (enExample) |
| ES (1) | ES2220725T3 (enExample) |
| RU (1) | RU2248980C2 (enExample) |
| WO (1) | WO2001062764A1 (enExample) |
| ZA (1) | ZA200108415B (enExample) |
Families Citing this family (115)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040072975A1 (en) * | 2000-03-17 | 2004-04-15 | Jorg Schottek | Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins |
| US7202315B2 (en) | 2000-09-25 | 2007-04-10 | Basell Polyolefine Gmbh | Process for the preparation of ethylene polymers |
| DE60202524T2 (de) * | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
| JP4571798B2 (ja) | 2001-06-12 | 2010-10-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンの重合方法 |
| WO2002100909A1 (en) | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| DE60210089T2 (de) | 2001-06-22 | 2006-10-19 | Basell Polyolefine Gmbh | Metallocene, verwendung in katalysatoren für olefinpolymerisation |
| WO2003008496A1 (en) | 2001-07-17 | 2003-01-30 | Basell Polyolefine Gmbh | Multistep process for the (co)polymerization of olefins |
| DE60218059T2 (de) | 2001-11-12 | 2007-08-30 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von 1-buten und 1-buten polymeren |
| ES2268126T3 (es) | 2001-11-30 | 2007-03-16 | Basell Polyolefine Gmbh | Compuestos de metaloceno y procedimiento para la preparacion de polimeros de propileno. |
| US6703338B2 (en) * | 2002-06-28 | 2004-03-09 | Univation Technologies, Llc | Polymerization catalyst activators, method of preparing, and their use in polymerization processes |
| US6989341B2 (en) | 2002-01-28 | 2006-01-24 | Univation Technologies, Llc | Halogen substituted catalyst system for olefin polymerization |
| US6841504B2 (en) | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
| US6930070B2 (en) * | 2002-01-28 | 2005-08-16 | Univation Technologies, Llc | Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization |
| EP1492825A1 (en) | 2002-02-25 | 2005-01-05 | Basell Polyolefine GmbH | Process for the copolymerization of ethylene |
| CA2487512A1 (en) | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| CA2487517A1 (en) * | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| EP1611167A2 (en) * | 2002-07-09 | 2006-01-04 | Basell Polyolefine GmbH | Catalyst system for the polymerization of olefins |
| US7285513B2 (en) * | 2002-07-15 | 2007-10-23 | Basell Polyolefine Gmbh | Preparation of catalyst systems |
| US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
| TWI315314B (en) * | 2002-08-29 | 2009-10-01 | Ineos Europe Ltd | Polymerisation process |
| EP1539843B1 (en) | 2002-09-06 | 2009-10-14 | Basell Polyolefine GmbH | Process for the copolymerization of ethylene |
| EP1403293A1 (en) * | 2002-09-27 | 2004-03-31 | ATOFINA Research Société Anonyme | Silicon containing cyclopentadienyl ring for metallocene catalyst component |
| EP1549688A2 (en) | 2002-10-10 | 2005-07-06 | Basell Polyolefine GmbH | Process for the copolymerization of ethylene |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE60329523D1 (de) | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| ATE471332T1 (de) | 2003-05-08 | 2010-07-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von halogenidmetallocenverbindungen |
| US7390862B2 (en) * | 2003-05-12 | 2008-06-24 | Basell Polyolefine Gmbh | Process for polymerizing 1-butene |
| WO2005005495A2 (en) | 2003-07-04 | 2005-01-20 | Basell Polyolefine Gmbh | Olefin polymerization process |
| EP1697427B1 (en) | 2003-12-22 | 2008-12-24 | Basell Polyolefine GmbH | Metallocene compounds |
| US7220695B2 (en) | 2004-01-07 | 2007-05-22 | Exxonmobil Chemical Patents Inc. | Supported activator |
| US7741417B2 (en) | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
| WO2005095473A1 (en) | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| WO2005095474A1 (en) | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| EP1753792B1 (en) | 2004-05-04 | 2009-10-14 | Basell Polyolefine GmbH | Process for the preparation of atactic 1-butene polymers |
| EP1765886A1 (en) | 2004-07-13 | 2007-03-28 | Basell Polyolefine GmbH | Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom |
| DE602005005334T2 (de) | 2004-07-22 | 2009-03-26 | Basell Polyolefine Gmbh | 1-butenpolymerzusammensetzung |
| KR20070043798A (ko) | 2004-07-22 | 2007-04-25 | 바젤 폴리올레핀 게엠베하 | 분획가능한 1-부텐 중합체의 제조방법 |
| CA2584395A1 (en) | 2004-10-18 | 2006-04-27 | Basell Poliolefine Italia S.R.L. | Butene-1 (co)polymers having low isotacticity |
| WO2006045687A1 (en) | 2004-10-21 | 2006-05-04 | Basell Polyolefine Gmbh | 1-butene polymer and process for the preparation thereof |
| EP1655314A1 (en) | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Process for the preparation of 1-butene/propylene copolymers |
| JP2008520793A (ja) | 2004-11-22 | 2008-06-19 | バーゼル・ポリオレフィン・ゲーエムベーハー | プロピレンベースのターポリマー |
| EP1825036A1 (en) * | 2004-12-13 | 2007-08-29 | Basell Poliolefine Italia S.r.l. | Polyolefin composition, fibres and nonwoven fabrics |
| DE602005011181D1 (de) * | 2004-12-23 | 2009-01-02 | Basell Poliolefine Srl | Fasern mit elastischen eigenschaften |
| ATE502080T1 (de) | 2005-02-03 | 2011-04-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von warmgeformten artikeln |
| WO2006097500A1 (en) | 2005-03-18 | 2006-09-21 | Basell Polyolefine Gmbh | Metallocene compounds |
| US7842764B2 (en) | 2005-03-18 | 2010-11-30 | Basell Poliolefine Italia S.R.L. | Metallocene compounds |
| JP2008534705A (ja) | 2005-03-23 | 2008-08-28 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィン類の重合法 |
| JP5294842B2 (ja) | 2005-03-23 | 2013-09-18 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィンの重合プロセス |
| JP2006290889A (ja) * | 2005-04-12 | 2006-10-26 | Rohm & Haas Electronic Materials Llc | 金属含有化合物精製 |
| JP2008540714A (ja) * | 2005-05-03 | 2008-11-20 | バーゼル・ポリオレフィン・ゲーエムベーハー | α−オレフィンの重合方法 |
| JP2008540752A (ja) | 2005-05-11 | 2008-11-20 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィンブレンドを製造するための重合方法 |
| US8051611B2 (en) * | 2005-06-24 | 2011-11-08 | Dryvit Systems, Inc. | Exterior insulation and finish system and method and tool for installing same |
| US20090234084A1 (en) * | 2005-06-30 | 2009-09-17 | Basell Polyolefine Gmbh | Metallocene Compounds |
| JP5584416B2 (ja) * | 2005-10-21 | 2014-09-03 | バーゼル・ポリオレフィン・ゲーエムベーハー | 射出成形及びメルトブロー用途のための高いメルトフローレートを有するポリプロピレンランダムコポリマー |
| JP5379480B2 (ja) | 2005-10-21 | 2013-12-25 | バーゼル・ポリオレフィン・ゲーエムベーハー | プロピレンポリマー |
| JP5379479B2 (ja) | 2005-10-21 | 2013-12-25 | バーゼル・ポリオレフィン・ゲーエムベーハー | 射出成形用のポリプロピレン |
| CA2641818C (en) * | 2006-02-02 | 2012-04-10 | Basell Polyolefine Gmbh | Propylene homopolymer melt blown resins |
| ATE461244T1 (de) | 2006-02-23 | 2010-04-15 | Basell Poliolefine Srl | Propylenpolymere für spritzgiessanwendungen |
| JP2009530341A (ja) | 2006-03-17 | 2009-08-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物類 |
| EP2004664B1 (en) | 2006-04-12 | 2016-12-14 | Basell Polyolefine GmbH | Metallocene compounds |
| JP5295098B2 (ja) | 2006-04-21 | 2013-09-18 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレンコポリマーの製造方法 |
| US8785575B2 (en) | 2006-04-21 | 2014-07-22 | Basell Polyolefine Gmbh | Process for the preparation of ethylene propylene copolymers |
| US8097681B2 (en) | 2006-08-30 | 2012-01-17 | Basell Polyolefine Gmbh | 1-butene propylene copolymer compositions |
| JP5580590B2 (ja) | 2006-08-30 | 2014-08-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンプロピレンコポリマー組成物 |
| US8309659B2 (en) | 2006-12-20 | 2012-11-13 | Basell Poliolefine Italia S.R.L. | Filled polyolefin compositions |
| US8716394B2 (en) | 2006-12-20 | 2014-05-06 | Basell Poliolefine Italia S.R.L. | Polypropylene compositions containing fillers and/or pigments |
| JP5503290B2 (ja) | 2006-12-20 | 2014-05-28 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 充填剤添加ポリオレフィン組成物類 |
| WO2008141915A2 (en) * | 2007-05-23 | 2008-11-27 | Basell Polyolefine Gmbh | Insecticidal composition and articles obtained thereof |
| BRPI0813916B1 (pt) | 2007-06-25 | 2018-09-25 | Basell Polyolefine Gmbh | copolímeros de 1-buteno etileno |
| WO2009050037A1 (en) * | 2007-10-19 | 2009-04-23 | Basell Polyolefine Gmbh | Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands |
| US8022005B2 (en) | 2007-11-08 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| EP2227493B1 (en) | 2007-12-20 | 2011-09-14 | Basell Polyolefine GmbH | Process for obtaining polymers of ethylene and cycloolefins |
| KR101580849B1 (ko) * | 2008-02-29 | 2015-12-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 |
| JP2011515518A (ja) | 2008-03-20 | 2011-05-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 1−ブテン系ポリマー類の組成物類 |
| JP5346075B2 (ja) * | 2008-04-22 | 2013-11-20 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 1−ブテンターポリマー |
| US8580902B2 (en) | 2008-08-01 | 2013-11-12 | Exxonmobil Chemical Patents Inc. | Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom |
| US7799879B2 (en) | 2008-08-01 | 2010-09-21 | Exxonmobil Chemical Patents Inc. | Catalyst system and process for olefin polymerization |
| CN102112499B (zh) | 2008-08-01 | 2014-02-05 | 埃克森美孚化学专利公司 | 催化剂体系和用于烯烃聚合的方法 |
| EP2358809B1 (en) | 2008-12-19 | 2014-01-15 | Basell Poliolefine Italia S.r.l. | Polyolefin fibres |
| EP2358810B1 (en) | 2008-12-19 | 2013-02-27 | Basell Poliolefine Italia S.r.l. | Filled polyolefin compositions |
| WO2010081676A1 (en) | 2009-01-13 | 2010-07-22 | Basell Polyolefine Gmbh | Polyethylene copolymers |
| BRPI1007245A2 (pt) | 2009-01-13 | 2016-10-18 | Bassel Poliolefine Italia S R L | composição polimérica |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| US20130101771A1 (en) | 2010-06-29 | 2013-04-25 | Basell Poliolefine Italia, s.r.l. | Filled Polyolefin Compositions |
| CN103857706B (zh) | 2011-09-30 | 2016-09-28 | 埃克森美孚化学专利公司 | 金属茂催化剂的动力学调制 |
| EP2743000A1 (en) | 2012-12-13 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Catalyst system for the preparation of polyolefins |
| CN105377904B (zh) | 2013-07-17 | 2018-07-10 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
| CN105358589B (zh) | 2013-07-17 | 2018-07-03 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
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| EP0722956B1 (de) | 1990-11-12 | 2001-08-16 | Basell Polyolefine GmbH | Verfahren zur Herstellung eines Olefinpolymers |
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-
2001
- 2001-02-12 JP JP2001562546A patent/JP2003524013A/ja active Pending
- 2001-02-12 CA CA002370799A patent/CA2370799A1/en not_active Abandoned
- 2001-02-12 RU RU2001131727/04A patent/RU2248980C2/ru not_active IP Right Cessation
- 2001-02-12 AU AU37373/01A patent/AU783058B2/en not_active Ceased
- 2001-02-12 WO PCT/EP2001/001467 patent/WO2001062764A1/en not_active Ceased
- 2001-02-12 AT AT01909734T patent/ATE268779T1/de not_active IP Right Cessation
- 2001-02-12 EP EP01909734A patent/EP1173445B1/en not_active Expired - Lifetime
- 2001-02-12 ES ES01909734T patent/ES2220725T3/es not_active Expired - Lifetime
- 2001-02-12 KR KR1020017013628A patent/KR20010112459A/ko not_active Abandoned
- 2001-02-12 DE DE60103702T patent/DE60103702T2/de not_active Expired - Lifetime
- 2001-02-12 CN CNB018010636A patent/CN1203076C/zh not_active Expired - Fee Related
- 2001-02-12 BR BR0105430-9A patent/BR0105430A/pt not_active IP Right Cessation
- 2001-02-22 AR ARP010100797A patent/AR027476A1/es not_active Application Discontinuation
- 2001-02-22 US US09/790,314 patent/US6608224B2/en not_active Expired - Fee Related
- 2001-10-12 ZA ZA200108415A patent/ZA200108415B/xx unknown
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2003
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| US20040030153A1 (en) | 2004-02-12 |
| AR027476A1 (es) | 2003-03-26 |
| AU783058B2 (en) | 2005-09-22 |
| CN1366528A (zh) | 2002-08-28 |
| ES2220725T3 (es) | 2004-12-16 |
| EP1173445A1 (en) | 2002-01-23 |
| AU3737301A (en) | 2001-09-03 |
| ZA200108415B (en) | 2003-01-13 |
| US6608224B2 (en) | 2003-08-19 |
| DE60103702T2 (de) | 2005-06-23 |
| CA2370799A1 (en) | 2001-08-30 |
| EP1173445B1 (en) | 2004-06-09 |
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| RU2248980C2 (ru) | 2005-03-27 |
| JP2003524013A (ja) | 2003-08-12 |
| US20030228976A1 (en) | 2003-12-11 |
| US6878786B2 (en) | 2005-04-12 |
| US6841501B2 (en) | 2005-01-11 |
| WO2001062764A1 (en) | 2001-08-30 |
| ATE268779T1 (de) | 2004-06-15 |
| KR20010112459A (ko) | 2001-12-20 |
| US20020038036A1 (en) | 2002-03-28 |
| DE60103702D1 (de) | 2004-07-15 |
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