DE60103702T2 - Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist - Google Patents
Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist Download PDFInfo
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- DE60103702T2 DE60103702T2 DE60103702T DE60103702T DE60103702T2 DE 60103702 T2 DE60103702 T2 DE 60103702T2 DE 60103702 T DE60103702 T DE 60103702T DE 60103702 T DE60103702 T DE 60103702T DE 60103702 T2 DE60103702 T2 DE 60103702T2
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- 238000006116 polymerization reaction Methods 0.000 title claims description 35
- 150000002902 organometallic compounds Chemical class 0.000 title claims description 29
- 150000001336 alkenes Chemical class 0.000 title claims description 21
- -1 heptafluoronaphthyl Chemical group 0.000 claims description 82
- 125000001424 substituent group Chemical group 0.000 claims description 62
- 239000003054 catalyst Substances 0.000 claims description 52
- 150000001875 compounds Chemical class 0.000 claims description 44
- 229910052739 hydrogen Inorganic materials 0.000 claims description 32
- 229910052710 silicon Inorganic materials 0.000 claims description 31
- 229910052757 nitrogen Inorganic materials 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 28
- 229910052698 phosphorus Inorganic materials 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 26
- 229910052717 sulfur Inorganic materials 0.000 claims description 25
- 229910052736 halogen Inorganic materials 0.000 claims description 24
- 150000002367 halogens Chemical class 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- 229910052760 oxygen Inorganic materials 0.000 claims description 24
- 125000004429 atom Chemical group 0.000 claims description 23
- 229920006395 saturated elastomer Polymers 0.000 claims description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 22
- 239000005977 Ethylene Substances 0.000 claims description 22
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 230000000737 periodic effect Effects 0.000 claims description 17
- 150000002431 hydrogen Chemical class 0.000 claims description 16
- 239000003446 ligand Substances 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 239000002841 Lewis acid Substances 0.000 claims description 12
- 229910052796 boron Inorganic materials 0.000 claims description 12
- 150000007517 lewis acids Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- 229910052723 transition metal Inorganic materials 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- GPTXWRGISTZRIO-UHFFFAOYSA-N chlorquinaldol Chemical compound ClC1=CC(Cl)=C(O)C2=NC(C)=CC=C21 GPTXWRGISTZRIO-UHFFFAOYSA-N 0.000 claims description 10
- 125000005843 halogen group Chemical group 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims description 8
- 239000002168 alkylating agent Substances 0.000 claims description 8
- 229940100198 alkylating agent Drugs 0.000 claims description 8
- 229910052732 germanium Inorganic materials 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 7
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 6
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 6
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 5
- UGHSGZIDZZRZKT-UHFFFAOYSA-N methane;zirconium Chemical compound C.[Zr] UGHSGZIDZZRZKT-UHFFFAOYSA-N 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- ONUFSRWQCKNVSL-UHFFFAOYSA-N 1,2,3,4,5-pentafluoro-6-(2,3,4,5,6-pentafluorophenyl)benzene Chemical group FC1=C(F)C(F)=C(F)C(F)=C1C1=C(F)C(F)=C(F)C(F)=C1F ONUFSRWQCKNVSL-UHFFFAOYSA-N 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 4
- 125000004437 phosphorous atom Chemical group 0.000 claims description 4
- 125000004434 sulfur atom Chemical group 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 229920001198 elastomeric copolymer Polymers 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 125000001153 fluoro group Chemical group F* 0.000 claims description 3
- 150000004291 polyenes Chemical class 0.000 claims description 3
- 239000002879 Lewis base Substances 0.000 claims description 2
- 150000001255 actinides Chemical group 0.000 claims description 2
- 150000001925 cycloalkenes Chemical class 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 2
- 150000002602 lanthanoids Chemical class 0.000 claims description 2
- 150000007527 lewis bases Chemical class 0.000 claims description 2
- 238000009877 rendering Methods 0.000 claims description 2
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 68
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 63
- 239000000243 solution Substances 0.000 description 50
- 229910052726 zirconium Inorganic materials 0.000 description 50
- 239000000460 chlorine Substances 0.000 description 45
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 39
- 238000005160 1H NMR spectroscopy Methods 0.000 description 34
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 30
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 20
- 239000000047 product Substances 0.000 description 19
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
- 239000011541 reaction mixture Substances 0.000 description 18
- 239000002904 solvent Substances 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 17
- 238000003786 synthesis reaction Methods 0.000 description 17
- 239000012299 nitrogen atmosphere Substances 0.000 description 16
- 229930192474 thiophene Natural products 0.000 description 15
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 14
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 14
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 13
- 239000000843 powder Substances 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 10
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 10
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical group C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 10
- 238000001228 spectrum Methods 0.000 description 10
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 10
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 9
- BHNHHSOHWZKFOX-UHFFFAOYSA-N 2-methyl-1H-indole Chemical compound C1=CC=C2NC(C)=CC2=C1 BHNHHSOHWZKFOX-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- PAPNRQCYSFBWDI-UHFFFAOYSA-N DMP Natural products CC1=CC=C(C)N1 PAPNRQCYSFBWDI-UHFFFAOYSA-N 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- ZFRKQXVRDFCRJG-UHFFFAOYSA-N skatole Chemical compound C1=CC=C2C(C)=CNC2=C1 ZFRKQXVRDFCRJG-UHFFFAOYSA-N 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 125000002249 indol-2-yl group Chemical group [H]C1=C([H])C([H])=C2N([H])C([*])=C([H])C2=C1[H] 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- XRPDDDRNQJNHLQ-UHFFFAOYSA-N 2-ethyl-1h-pyrrole Chemical compound CCC1=CC=CN1 XRPDDDRNQJNHLQ-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
- IODCSKWIWMPNQO-UHFFFAOYSA-N B.Fc1cc(F)c(c(F)c1F)-c1c(F)cc(F)c(F)c1F.Fc1cc(F)c(c(F)c1F)-c1c(F)cc(F)c(F)c1F.Fc1cc(F)c(c(F)c1F)-c1c(F)cc(F)c(F)c1F Chemical compound B.Fc1cc(F)c(c(F)c1F)-c1c(F)cc(F)c(F)c1F.Fc1cc(F)c(c(F)c1F)-c1c(F)cc(F)c(F)c1F.Fc1cc(F)c(c(F)c1F)-c1c(F)cc(F)c(F)c1F IODCSKWIWMPNQO-UHFFFAOYSA-N 0.000 description 4
- VWBUVRBELAMDSS-UHFFFAOYSA-N B.Fc1cc(c(F)c(F)c1F)-c1cc(F)c(F)c(F)c1F.Fc1cc(c(F)c(F)c1F)-c1cc(F)c(F)c(F)c1F.Fc1cc(c(F)c(F)c1F)-c1cc(F)c(F)c(F)c1F Chemical compound B.Fc1cc(c(F)c(F)c1F)-c1cc(F)c(F)c(F)c1F.Fc1cc(c(F)c(F)c1F)-c1cc(F)c(F)c(F)c1F.Fc1cc(c(F)c(F)c1F)-c1cc(F)c(F)c(F)c1F VWBUVRBELAMDSS-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910000085 borane Inorganic materials 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 4
- 229910052740 iodine Chemical group 0.000 description 4
- 239000011630 iodine Chemical group 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 4
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 3
- XILIYVSXLSWUAI-UHFFFAOYSA-N 2-(diethylamino)ethyl n'-phenylcarbamimidothioate;dihydrobromide Chemical compound Br.Br.CCN(CC)CCSC(N)=NC1=CC=CC=C1 XILIYVSXLSWUAI-UHFFFAOYSA-N 0.000 description 3
- BWCDLEQTELFBAW-UHFFFAOYSA-N 3h-dioxazole Chemical compound N1OOC=C1 BWCDLEQTELFBAW-UHFFFAOYSA-N 0.000 description 3
- KQBVVLOYXDVATK-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1h-indole Chemical compound C1CCCC2=C1C=CN2 KQBVVLOYXDVATK-UHFFFAOYSA-N 0.000 description 3
- ONYNOPPOVKYGRS-UHFFFAOYSA-N 6-methylindole Natural products CC1=CC=C2C=CNC2=C1 ONYNOPPOVKYGRS-UHFFFAOYSA-N 0.000 description 3
- RRBUXJRLDLHRIQ-UHFFFAOYSA-N B.Fc1cc(F)c(F)c(c1F)-c1c(F)c(F)cc(F)c1F.Fc1cc(F)c(F)c(c1F)-c1c(F)c(F)cc(F)c1F.Fc1cc(F)c(F)c(c1F)-c1c(F)c(F)cc(F)c1F Chemical compound B.Fc1cc(F)c(F)c(c1F)-c1c(F)c(F)cc(F)c1F.Fc1cc(F)c(F)c(c1F)-c1c(F)c(F)cc(F)c1F.Fc1cc(F)c(F)c(c1F)-c1c(F)c(F)cc(F)c1F RRBUXJRLDLHRIQ-UHFFFAOYSA-N 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 239000002516 radical scavenger Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
- ZOICEQJZAWJHSI-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenyl)boron Chemical compound [B]C1=C(F)C(F)=C(F)C(F)=C1F ZOICEQJZAWJHSI-UHFFFAOYSA-N 0.000 description 2
- CHEANNSDVJOIBS-MHZLTWQESA-N (3s)-3-cyclopropyl-3-[3-[[3-(5,5-dimethylcyclopenten-1-yl)-4-(2-fluoro-5-methoxyphenyl)phenyl]methoxy]phenyl]propanoic acid Chemical compound COC1=CC=C(F)C(C=2C(=CC(COC=3C=C(C=CC=3)[C@@H](CC(O)=O)C3CC3)=CC=2)C=2C(CCC=2)(C)C)=C1 CHEANNSDVJOIBS-MHZLTWQESA-N 0.000 description 2
- VUIMBZIZZFSQEE-UHFFFAOYSA-N 1-(1h-indol-3-yl)ethanone Chemical compound C1=CC=C2C(C(=O)C)=CNC2=C1 VUIMBZIZZFSQEE-UHFFFAOYSA-N 0.000 description 2
- CHIFTAQVXHNVRW-UHFFFAOYSA-N 1h-indole-3-carbonitrile Chemical compound C1=CC=C2C(C#N)=CNC2=C1 CHIFTAQVXHNVRW-UHFFFAOYSA-N 0.000 description 2
- MVXVYAKCVDQRLW-UHFFFAOYSA-N 1h-pyrrolo[2,3-b]pyridine Chemical compound C1=CN=C2NC=CC2=C1 MVXVYAKCVDQRLW-UHFFFAOYSA-N 0.000 description 2
- MFFMQGGZCLEMCI-UHFFFAOYSA-N 2,4-dimethyl-1h-pyrrole Chemical compound CC1=CNC(C)=C1 MFFMQGGZCLEMCI-UHFFFAOYSA-N 0.000 description 2
- IGJQUJNPMOYEJY-UHFFFAOYSA-N 2-acetylpyrrole Chemical compound CC(=O)C1=CC=CN1 IGJQUJNPMOYEJY-UHFFFAOYSA-N 0.000 description 2
- PGFVYIIJNFGCFU-UHFFFAOYSA-N 5H-benzo[b][1]benzoborole Chemical class C1=CC=C2BC3=CC=CC=C3C2=C1 PGFVYIIJNFGCFU-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000349731 Afzelia bipindensis Species 0.000 description 2
- UGVVIPAIDGTTNN-UHFFFAOYSA-N C[Zr]C Chemical compound C[Zr]C UGVVIPAIDGTTNN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 229910007926 ZrCl Inorganic materials 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 150000001923 cyclic compounds Chemical class 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- OLNJUISKUQQNIM-UHFFFAOYSA-N indole-3-carbaldehyde Chemical compound C1=CC=C2C(C=O)=CNC2=C1 OLNJUISKUQQNIM-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- IHLVCKWPAMTVTG-UHFFFAOYSA-N lithium;carbanide Chemical compound [Li+].[CH3-] IHLVCKWPAMTVTG-UHFFFAOYSA-N 0.000 description 2
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- OZSRZZRXVAQDET-UHFFFAOYSA-N tris(2,3,4,6,7,8-hexafluoro-5-methylnaphthalen-1-yl)borane Chemical compound FC1=C(F)C(F)=C2C(B(C=3C4=C(F)C(F)=C(F)C(C)=C4C(F)=C(F)C=3F)C3=C4C(F)=C(F)C(F)=C(C4=C(F)C(F)=C3F)C)=C(F)C(F)=C(F)C2=C1C OZSRZZRXVAQDET-UHFFFAOYSA-N 0.000 description 1
- JFPWAJLYPATCJF-UHFFFAOYSA-N tris(2,3,4,6,7,8-hexafluoronaphthalen-1-yl)borane Chemical compound FC1=C(F)C(F)=C2C(B(C=3C4=C(F)C(F)=C(F)C=C4C(F)=C(F)C=3F)C=3C(F)=C(F)C(F)=C4C=C(C(=C(F)C4=3)F)F)=C(F)C(F)=C(F)C2=C1 JFPWAJLYPATCJF-UHFFFAOYSA-N 0.000 description 1
- JPUOPPXUYDSOGM-UHFFFAOYSA-N tris(2,3,4,6-tetrafluoro-5-methylphenyl)borane Chemical compound CC1=C(F)C(F)=C(F)C(B(C=2C(=C(F)C(F)=C(C)C=2F)F)C=2C(=C(F)C(F)=C(C)C=2F)F)=C1F JPUOPPXUYDSOGM-UHFFFAOYSA-N 0.000 description 1
- VGEPZRRRDGHRMI-UHFFFAOYSA-N tris(2,3,4,6-tetrafluorophenyl)borane Chemical compound FC1=C(F)C(F)=CC(F)=C1B(C=1C(=C(F)C(F)=CC=1F)F)C1=C(F)C=C(F)C(F)=C1F VGEPZRRRDGHRMI-UHFFFAOYSA-N 0.000 description 1
- PCYXDFGDAHTQSG-UHFFFAOYSA-N tris(2,3,5,6,7,8-hexafluoro-4-methylnaphthalen-1-yl)borane Chemical compound C12=C(F)C(F)=C(F)C(F)=C2C(C)=C(F)C(F)=C1B(C=1C2=C(F)C(F)=C(F)C(F)=C2C(C)=C(F)C=1F)C1=C(F)C(F)=C(C)C2=C(F)C(F)=C(F)C(F)=C12 PCYXDFGDAHTQSG-UHFFFAOYSA-N 0.000 description 1
- LGFXFZBVVBUABA-UHFFFAOYSA-N tris(2,3,5,6,7,8-hexafluoronaphthalen-1-yl)borane Chemical compound FC1=C(F)C(F)=C2C(B(C=3C4=C(F)C(F)=C(F)C(F)=C4C=C(F)C=3F)C=3C4=C(F)C(F)=C(F)C(F)=C4C=C(C=3F)F)=C(F)C(F)=CC2=C1F LGFXFZBVVBUABA-UHFFFAOYSA-N 0.000 description 1
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- GZQXROYFQLBBPK-UHFFFAOYSA-N tris(2,3,5,6-tetrafluorophenyl)borane Chemical compound FC1=CC(F)=C(F)C(B(C=2C(=C(F)C=C(F)C=2F)F)C=2C(=C(F)C=C(F)C=2F)F)=C1F GZQXROYFQLBBPK-UHFFFAOYSA-N 0.000 description 1
- UIKAMONOVUJDNT-UHFFFAOYSA-N tris(2,3,6-trifluorophenyl)borane Chemical compound FC1=CC=C(F)C(B(C=2C(=C(F)C=CC=2F)F)C=2C(=C(F)C=CC=2F)F)=C1F UIKAMONOVUJDNT-UHFFFAOYSA-N 0.000 description 1
- WUQHZWBZRYUJAA-UHFFFAOYSA-N tris(2,4,5,6,7,8-hexafluoro-3-methylnaphthalen-1-yl)borane Chemical compound FC1=C(F)C(F)=C(F)C2=C(F)C(C)=C(F)C(B(C=3C4=C(F)C(F)=C(F)C(F)=C4C(F)=C(C)C=3F)C=3C4=C(F)C(F)=C(F)C(F)=C4C(F)=C(C)C=3F)=C21 WUQHZWBZRYUJAA-UHFFFAOYSA-N 0.000 description 1
- PGQTUPMJTAQRBJ-UHFFFAOYSA-N tris(2,4,5,6,7,8-hexafluoronaphthalen-1-yl)borane Chemical compound FC1=C(F)C(F)=C2C(B(C=3C4=C(F)C(F)=C(F)C(F)=C4C(F)=CC=3F)C3=C4C(F)=C(F)C(F)=C(F)C4=C(F)C=C3F)=C(F)C=C(F)C2=C1F PGQTUPMJTAQRBJ-UHFFFAOYSA-N 0.000 description 1
- MUDVEGNBCFIRDK-UHFFFAOYSA-N tris(2,4-difluoro-5-methylphenyl)borane Chemical compound C1=C(F)C(C)=CC(B(C=2C(=CC(F)=C(C)C=2)F)C=2C(=CC(F)=C(C)C=2)F)=C1F MUDVEGNBCFIRDK-UHFFFAOYSA-N 0.000 description 1
- BJDZTCMHKGMRPE-UHFFFAOYSA-N tris(2,6-difluoro-3-methylphenyl)borane Chemical compound CC1=CC=C(F)C(B(C=2C(=C(C)C=CC=2F)F)C=2C(=C(C)C=CC=2F)F)=C1F BJDZTCMHKGMRPE-UHFFFAOYSA-N 0.000 description 1
- QCYYJEPQSCUMMQ-UHFFFAOYSA-N tris(3,4,5,6,7,8-hexafluoro-2-methylnaphthalen-1-yl)borane Chemical compound FC1=C(F)C(F)=C2C(B(C=3C4=C(F)C(F)=C(F)C(F)=C4C(F)=C(F)C=3C)C3=C4C(F)=C(F)C(F)=C(F)C4=C(F)C(F)=C3C)=C(C)C(F)=C(F)C2=C1F QCYYJEPQSCUMMQ-UHFFFAOYSA-N 0.000 description 1
- OMGHHEYPEZUJHO-UHFFFAOYSA-N tris(3,4,5,6,7,8-hexafluoronaphthalen-1-yl)borane Chemical compound FC1=C(F)C(F)=C(F)C2=C(F)C(F)=CC(B(C=3C4=C(F)C(F)=C(F)C(F)=C4C(F)=C(F)C=3)C=3C4=C(F)C(F)=C(F)C(F)=C4C(F)=C(F)C=3)=C21 OMGHHEYPEZUJHO-UHFFFAOYSA-N 0.000 description 1
- YITDZFPEFPUBLW-UHFFFAOYSA-N tris(3,5-difluoro-2-methylphenyl)borane Chemical compound CC1=C(F)C=C(F)C=C1B(C=1C(=C(F)C=C(F)C=1)C)C1=CC(F)=CC(F)=C1C YITDZFPEFPUBLW-UHFFFAOYSA-N 0.000 description 1
- RWXIPFGJVVTMMM-UHFFFAOYSA-N tris[2,3,4,5-tetrafluoro-6-(2,3,4,5,6-pentafluorophenyl)phenyl]borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1C1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1C1=C(F)C(F)=C(F)C(F)=C1F RWXIPFGJVVTMMM-UHFFFAOYSA-N 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/603—Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00200649 | 2000-02-24 | ||
| EP00200649 | 2000-02-24 | ||
| PCT/EP2001/001467 WO2001062764A1 (en) | 2000-02-24 | 2001-02-12 | Organometallic compound useful as cocatalyst for polymerizing olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60103702D1 DE60103702D1 (de) | 2004-07-15 |
| DE60103702T2 true DE60103702T2 (de) | 2005-06-23 |
Family
ID=8171089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60103702T Expired - Lifetime DE60103702T2 (de) | 2000-02-24 | 2001-02-12 | Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist |
Country Status (15)
| Country | Link |
|---|---|
| US (3) | US6608224B2 (enExample) |
| EP (1) | EP1173445B1 (enExample) |
| JP (1) | JP2003524013A (enExample) |
| KR (1) | KR20010112459A (enExample) |
| CN (1) | CN1203076C (enExample) |
| AR (1) | AR027476A1 (enExample) |
| AT (1) | ATE268779T1 (enExample) |
| AU (1) | AU783058B2 (enExample) |
| BR (1) | BR0105430A (enExample) |
| CA (1) | CA2370799A1 (enExample) |
| DE (1) | DE60103702T2 (enExample) |
| ES (1) | ES2220725T3 (enExample) |
| RU (1) | RU2248980C2 (enExample) |
| WO (1) | WO2001062764A1 (enExample) |
| ZA (1) | ZA200108415B (enExample) |
Families Citing this family (115)
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| US20040072975A1 (en) * | 2000-03-17 | 2004-04-15 | Jorg Schottek | Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins |
| US7202315B2 (en) | 2000-09-25 | 2007-04-10 | Basell Polyolefine Gmbh | Process for the preparation of ethylene polymers |
| DE60202524T2 (de) * | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
| JP4571798B2 (ja) | 2001-06-12 | 2010-10-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンの重合方法 |
| WO2002100909A1 (en) | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| DE60210089T2 (de) | 2001-06-22 | 2006-10-19 | Basell Polyolefine Gmbh | Metallocene, verwendung in katalysatoren für olefinpolymerisation |
| WO2003008496A1 (en) | 2001-07-17 | 2003-01-30 | Basell Polyolefine Gmbh | Multistep process for the (co)polymerization of olefins |
| DE60218059T2 (de) | 2001-11-12 | 2007-08-30 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von 1-buten und 1-buten polymeren |
| ES2268126T3 (es) | 2001-11-30 | 2007-03-16 | Basell Polyolefine Gmbh | Compuestos de metaloceno y procedimiento para la preparacion de polimeros de propileno. |
| US6703338B2 (en) * | 2002-06-28 | 2004-03-09 | Univation Technologies, Llc | Polymerization catalyst activators, method of preparing, and their use in polymerization processes |
| US6989341B2 (en) | 2002-01-28 | 2006-01-24 | Univation Technologies, Llc | Halogen substituted catalyst system for olefin polymerization |
| US6841504B2 (en) | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
| US6930070B2 (en) * | 2002-01-28 | 2005-08-16 | Univation Technologies, Llc | Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization |
| EP1492825A1 (en) | 2002-02-25 | 2005-01-05 | Basell Polyolefine GmbH | Process for the copolymerization of ethylene |
| CA2487512A1 (en) | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| CA2487517A1 (en) * | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| EP1611167A2 (en) * | 2002-07-09 | 2006-01-04 | Basell Polyolefine GmbH | Catalyst system for the polymerization of olefins |
| US7285513B2 (en) * | 2002-07-15 | 2007-10-23 | Basell Polyolefine Gmbh | Preparation of catalyst systems |
| US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
| TWI315314B (en) * | 2002-08-29 | 2009-10-01 | Ineos Europe Ltd | Polymerisation process |
| EP1539843B1 (en) | 2002-09-06 | 2009-10-14 | Basell Polyolefine GmbH | Process for the copolymerization of ethylene |
| EP1403293A1 (en) * | 2002-09-27 | 2004-03-31 | ATOFINA Research Société Anonyme | Silicon containing cyclopentadienyl ring for metallocene catalyst component |
| EP1549688A2 (en) | 2002-10-10 | 2005-07-06 | Basell Polyolefine GmbH | Process for the copolymerization of ethylene |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE60329523D1 (de) | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| ATE471332T1 (de) | 2003-05-08 | 2010-07-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von halogenidmetallocenverbindungen |
| US7390862B2 (en) * | 2003-05-12 | 2008-06-24 | Basell Polyolefine Gmbh | Process for polymerizing 1-butene |
| WO2005005495A2 (en) | 2003-07-04 | 2005-01-20 | Basell Polyolefine Gmbh | Olefin polymerization process |
| EP1697427B1 (en) | 2003-12-22 | 2008-12-24 | Basell Polyolefine GmbH | Metallocene compounds |
| US7220695B2 (en) | 2004-01-07 | 2007-05-22 | Exxonmobil Chemical Patents Inc. | Supported activator |
| US7741417B2 (en) | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
| WO2005095473A1 (en) | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| WO2005095474A1 (en) | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| EP1753792B1 (en) | 2004-05-04 | 2009-10-14 | Basell Polyolefine GmbH | Process for the preparation of atactic 1-butene polymers |
| EP1765886A1 (en) | 2004-07-13 | 2007-03-28 | Basell Polyolefine GmbH | Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom |
| DE602005005334T2 (de) | 2004-07-22 | 2009-03-26 | Basell Polyolefine Gmbh | 1-butenpolymerzusammensetzung |
| KR20070043798A (ko) | 2004-07-22 | 2007-04-25 | 바젤 폴리올레핀 게엠베하 | 분획가능한 1-부텐 중합체의 제조방법 |
| CA2584395A1 (en) | 2004-10-18 | 2006-04-27 | Basell Poliolefine Italia S.R.L. | Butene-1 (co)polymers having low isotacticity |
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2001
- 2001-02-12 JP JP2001562546A patent/JP2003524013A/ja active Pending
- 2001-02-12 CA CA002370799A patent/CA2370799A1/en not_active Abandoned
- 2001-02-12 RU RU2001131727/04A patent/RU2248980C2/ru not_active IP Right Cessation
- 2001-02-12 AU AU37373/01A patent/AU783058B2/en not_active Ceased
- 2001-02-12 WO PCT/EP2001/001467 patent/WO2001062764A1/en not_active Ceased
- 2001-02-12 AT AT01909734T patent/ATE268779T1/de not_active IP Right Cessation
- 2001-02-12 EP EP01909734A patent/EP1173445B1/en not_active Expired - Lifetime
- 2001-02-12 ES ES01909734T patent/ES2220725T3/es not_active Expired - Lifetime
- 2001-02-12 KR KR1020017013628A patent/KR20010112459A/ko not_active Abandoned
- 2001-02-12 DE DE60103702T patent/DE60103702T2/de not_active Expired - Lifetime
- 2001-02-12 CN CNB018010636A patent/CN1203076C/zh not_active Expired - Fee Related
- 2001-02-12 BR BR0105430-9A patent/BR0105430A/pt not_active IP Right Cessation
- 2001-02-22 AR ARP010100797A patent/AR027476A1/es not_active Application Discontinuation
- 2001-02-22 US US09/790,314 patent/US6608224B2/en not_active Expired - Fee Related
- 2001-10-12 ZA ZA200108415A patent/ZA200108415B/xx unknown
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2003
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- 2003-03-28 US US10/402,303 patent/US6878786B2/en not_active Expired - Fee Related
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| US20040030153A1 (en) | 2004-02-12 |
| AR027476A1 (es) | 2003-03-26 |
| AU783058B2 (en) | 2005-09-22 |
| CN1366528A (zh) | 2002-08-28 |
| ES2220725T3 (es) | 2004-12-16 |
| EP1173445A1 (en) | 2002-01-23 |
| AU3737301A (en) | 2001-09-03 |
| ZA200108415B (en) | 2003-01-13 |
| US6608224B2 (en) | 2003-08-19 |
| CA2370799A1 (en) | 2001-08-30 |
| EP1173445B1 (en) | 2004-06-09 |
| BR0105430A (pt) | 2002-06-04 |
| RU2248980C2 (ru) | 2005-03-27 |
| JP2003524013A (ja) | 2003-08-12 |
| US20030228976A1 (en) | 2003-12-11 |
| US6878786B2 (en) | 2005-04-12 |
| US6841501B2 (en) | 2005-01-11 |
| CN1203076C (zh) | 2005-05-25 |
| WO2001062764A1 (en) | 2001-08-30 |
| ATE268779T1 (de) | 2004-06-15 |
| KR20010112459A (ko) | 2001-12-20 |
| US20020038036A1 (en) | 2002-03-28 |
| DE60103702D1 (de) | 2004-07-15 |
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