CN1167718C - 支化聚丙烯组合物 - Google Patents
支化聚丙烯组合物 Download PDFInfo
- Publication number
- CN1167718C CN1167718C CNB998087238A CN99808723A CN1167718C CN 1167718 C CN1167718 C CN 1167718C CN B998087238 A CNB998087238 A CN B998087238A CN 99808723 A CN99808723 A CN 99808723A CN 1167718 C CN1167718 C CN 1167718C
- Authority
- CN
- China
- Prior art keywords
- branched polypropylene
- reactor
- less
- polypropylene composition
- diluent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14059098A | 1998-08-26 | 1998-08-26 | |
| US09/140,590 | 1998-08-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1309669A CN1309669A (zh) | 2001-08-22 |
| CN1167718C true CN1167718C (zh) | 2004-09-22 |
Family
ID=22491936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB998087238A Expired - Lifetime CN1167718C (zh) | 1998-08-26 | 1999-08-16 | 支化聚丙烯组合物 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6225432B1 (https=) |
| EP (1) | EP1115761B1 (https=) |
| JP (1) | JP5407099B2 (https=) |
| KR (1) | KR100611849B1 (https=) |
| CN (1) | CN1167718C (https=) |
| BR (1) | BR9913647B1 (https=) |
| CA (1) | CA2341167A1 (https=) |
| MX (1) | MXPA01002023A (https=) |
| WO (1) | WO2000012572A1 (https=) |
Families Citing this family (109)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1195388A1 (en) * | 2000-10-04 | 2002-04-10 | ATOFINA Research | Process for producing bimodal polyethylene resins |
| EP1195391A1 (en) * | 2000-10-05 | 2002-04-10 | ATOFINA Research | Production of polypropylene |
| US6770697B2 (en) | 2001-02-20 | 2004-08-03 | Solvay Engineered Polymers | High melt-strength polyolefin composites and methods for making and using same |
| US7193024B2 (en) | 2001-06-15 | 2007-03-20 | Dow Global Technology Inc. | Alpha-Olefin based branched polymer |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| CN100345896C (zh) | 2002-08-12 | 2007-10-31 | 埃克森美孚化学专利公司 | 增塑聚烯烃组合物 |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US8008412B2 (en) * | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
| US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
| US7319125B2 (en) * | 2002-09-20 | 2008-01-15 | Exxonmobil Chemical Patents Inc. | Supercritical polymerization process and polymers produced therefrom |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| WO2004037871A1 (en) * | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| US7439312B2 (en) | 2002-10-24 | 2008-10-21 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| EP1567566A1 (en) * | 2002-12-05 | 2005-08-31 | Exxonmobil Chemical Patents Inc. | High temperature bulk polymerization of branched crystalline polypropylene |
| AU2003294343A1 (en) * | 2002-12-05 | 2004-06-30 | Exxonmobil Chemical Patents Inc. | Diene-modified propylene copolymers |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| WO2005026255A1 (ja) * | 2003-09-12 | 2005-03-24 | Kaneka Corporation | ポリプロピレン系樹脂組成物、それからなる発泡成形体およびその製造方法 |
| US20050218551A1 (en) * | 2004-04-01 | 2005-10-06 | Izhar Halahmi | Process for producing polar polyolefines and modified polyolefines thereof |
| US7645829B2 (en) * | 2004-04-15 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Plasticized functionalized propylene copolymer adhesive composition |
| KR20070039930A (ko) | 2004-07-08 | 2007-04-13 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 초임계 조건에서 중합체의 제조방법 |
| WO2006019494A1 (en) | 2004-07-14 | 2006-02-23 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| ATE502080T1 (de) | 2005-02-03 | 2011-04-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von warmgeformten artikeln |
| US8022142B2 (en) * | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
| US9745461B2 (en) | 2005-06-22 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Vulcanized polymer blends |
| US7951872B2 (en) | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
| US7928164B2 (en) * | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
| US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
| US20060293462A1 (en) * | 2005-06-22 | 2006-12-28 | Sunny Jacob | Heterogeneous polymer blend and process of making the same |
| WO2007001694A1 (en) * | 2005-06-24 | 2007-01-04 | Exxonmobil Chemical Patents Inc. | Functionalized propylene copolymer adheside composition |
| WO2007011530A2 (en) | 2005-07-15 | 2007-01-25 | Exxonmobil Chemical Patents, Inc. | Elastomeric compositions |
| EP1847555A1 (en) * | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Multi-branched Polypropylene |
| JP5186680B2 (ja) * | 2006-05-16 | 2013-04-17 | 国立大学法人福井大学 | 電気化学応答性多孔質体 |
| DE602006002512D1 (de) * | 2006-07-10 | 2008-10-09 | Borealis Tech Oy | Kurzkettig verzweigtes Polypropylen |
| DE602006004987D1 (de) * | 2006-07-10 | 2009-03-12 | Borealis Tech Oy | Elektrischer Isolierfilm |
| EP1886806B1 (en) * | 2006-07-10 | 2010-11-10 | Borealis Technology Oy | Biaxially oriented polypropylene film |
| DE602006011873D1 (de) * | 2006-07-10 | 2010-03-11 | Borealis Tech Oy | Kabelschicht auf der Basis von Polypropylen mit hoher elektrischer Ausfall-Spannungsfestigkeit |
| EP1967547A1 (en) | 2006-08-25 | 2008-09-10 | Borealis Technology OY | Extrusion coated substrate |
| ATE439393T1 (de) * | 2006-08-25 | 2009-08-15 | Borealis Tech Oy | Geblasene polypropylenfolie |
| EP1900764B1 (en) | 2006-08-25 | 2009-04-01 | Borealis Technology Oy | Polypropylene foam |
| ATE462189T1 (de) * | 2006-09-25 | 2010-04-15 | Borealis Tech Oy | Koaxiales kabel |
| US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
| EP1939230B1 (en) | 2006-12-28 | 2009-03-04 | Borealis Technology Oy | Process for the manufacture of branched polypropylene |
| US7872086B2 (en) * | 2008-01-17 | 2011-01-18 | Tonen Chemical Corporation | Polymeric material and its manufacture and use |
| US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
| ES2446294T3 (es) * | 2007-06-04 | 2014-03-07 | Exxonmobil Chemical Patents Inc. | Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución |
| CN101772519B (zh) | 2007-08-06 | 2012-07-04 | 日本聚丙烯公司 | 丙烯类聚合物、其制造方法、使用该丙烯类聚合物的组合物及其用途 |
| EP2201042B1 (en) | 2007-09-13 | 2012-06-27 | ExxonMobil Research and Engineering Company | In-line blending of plasticizers with a base polymer |
| US7928162B2 (en) | 2007-09-13 | 2011-04-19 | Exxonmobil Research And Engineering Company | In-line process for producing plasticized polymers and plasticized polymer blends |
| US7994237B2 (en) * | 2007-12-20 | 2011-08-09 | Exxonmobil Research And Engineering Company | In-line process to produce pellet-stable polyolefins |
| WO2009082468A1 (en) | 2007-12-20 | 2009-07-02 | Exxonmobil Research And Engineering Company | Polypropylene ethylene-propylene copolymer blends and in-line process to produce them |
| US7910679B2 (en) | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
| US8318875B2 (en) * | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US8283428B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
| US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
| US8283419B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
| US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
| US8399725B2 (en) * | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
| US7935740B2 (en) * | 2008-12-30 | 2011-05-03 | Basell Poliolefine Italia S.R.L. | Process for producing high melt strength polypropylene |
| CN101792549B (zh) * | 2009-12-25 | 2011-10-19 | 东莞市峄董塑胶科技有限公司 | 一种改进的聚丙烯再生料改性板材发泡工艺 |
| JP5471629B2 (ja) * | 2010-03-10 | 2014-04-16 | 株式会社島津製作所 | 液体クロマトグラフ用分析システム及び該分析システムの制御プログラム |
| JP5606144B2 (ja) * | 2010-05-12 | 2014-10-15 | 出光興産株式会社 | ポリオレフィンの製造方法 |
| CN102268124A (zh) * | 2010-06-07 | 2011-12-07 | 中国科学院化学研究所 | 一种长链支化聚丙烯及其制备方法 |
| US8669326B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Amine functionalized polyolefin and methods for preparation thereof |
| US8841397B2 (en) | 2011-03-25 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
| US8426659B2 (en) | 2011-03-25 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
| EP2688921B1 (en) | 2011-03-25 | 2019-04-24 | ExxonMobil Chemical Patents Inc. | Diblock copolymers prepared by cross metathesis |
| US8455597B2 (en) | 2011-03-25 | 2013-06-04 | Exxonmobil Chemical Patents Inc. | Catalysts and methods of use thereof to produce vinyl terminated polymers |
| US8501894B2 (en) | 2011-03-25 | 2013-08-06 | Exxonmobil Chemical Patents Inc. | Hydrosilyation of vinyl macromers with metallocenes |
| US8785562B2 (en) | 2011-03-25 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Amphiphilic block polymers prepared by alkene metathesis |
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| US8669330B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Olefin triblock polymers via ring-opening metathesis polymerization |
| US8940839B2 (en) | 2011-03-25 | 2015-01-27 | Exxonmobil Chemical Patents Inc. | Diblock copolymers prepared by cross metathesis |
| US8623974B2 (en) | 2011-03-25 | 2014-01-07 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
| US8318998B2 (en) | 2011-03-25 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers |
| US8399724B2 (en) | 2011-03-25 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin copolymers and methods to produce thereof |
| ES2648254T3 (es) * | 2011-05-02 | 2017-12-29 | Borealis Ag | Polipropileno para espuma y espuma de polipropileno |
| US9181360B2 (en) | 2011-08-12 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Polymers prepared by ring opening / cross metathesis |
| IN2014DN03187A (https=) * | 2011-10-11 | 2015-05-22 | Braskem Sa | |
| US8604148B2 (en) | 2011-11-29 | 2013-12-10 | Exxonmobil Chemical Patents Inc. | Functionalization of vinyl terminated polymers by ring opening cross metathesis |
| EP2785763A4 (en) | 2011-11-29 | 2015-06-03 | Exxonmobil Chem Patents Inc | FUNCTIONALIZATION OF POLYMERS WITH VINYL TERMINATION BY METATHESIS CROSSED BY CYCLE OPENING |
| WO2013125700A1 (ja) | 2012-02-23 | 2013-08-29 | 日本ポリプロ株式会社 | ポリプロピレン系樹脂組成物および発泡シート |
| CN104169356B (zh) | 2012-02-23 | 2016-03-09 | 日本聚丙烯株式会社 | 聚丙烯类树脂组合物和发泡片材 |
| US8796376B2 (en) | 2012-03-26 | 2014-08-05 | Exxonmobil Chemical Patents Inc. | Functionalized polymers and oligomers |
| CN102879267B (zh) * | 2012-09-18 | 2014-07-30 | 华南理工大学 | 基于恒定应变速率的塑料薄膜单向拉伸试验方法与装置 |
| CN104662052B (zh) | 2012-09-24 | 2018-09-21 | 埃克森美孚化学专利公司 | 借助烯烃易位获得的官能化树脂 |
| US9453093B2 (en) * | 2012-10-31 | 2016-09-27 | Exxonmobil Chemical Patents Inc. | Broad molecular weight distribution polypropylene resins |
| US9169334B2 (en) | 2013-01-30 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Preparation of bottlebrush polymers via ring-opening metathesis polymerization |
| US9458260B2 (en) | 2013-07-17 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
| US9382354B2 (en) | 2013-11-22 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyesters containing polyolefin arms |
| CN107683295A (zh) * | 2015-06-05 | 2018-02-09 | 埃克森美孚化学专利公司 | 多孔丙烯聚合物 |
| CN114591523B (zh) | 2016-08-09 | 2024-12-24 | 日本聚丙烯株式会社 | 装饰膜和使用其生产装饰成形体的方法 |
| US10882932B2 (en) | 2016-10-05 | 2021-01-05 | Exxonmobil Chemical Patents Inc. | Sterically hindered metallocenes, synthesis and use |
| EP3715092A4 (en) | 2017-11-20 | 2021-08-11 | Japan Polypropylene Corporation | DECORATIVE FILM AND METHOD OF MANUFACTURING A DECORATIVE MOLDED ARTICLE USING IT |
| KR102405286B1 (ko) * | 2017-12-06 | 2022-06-02 | 주식회사 엘지화학 | 메탈로센 담지 촉매의 제조방법, 상기 제조방법으로 제조된 메탈로센 담지 촉매, 및 이를 제조하여 제조한 폴리프로필렌 |
| CN112851892A (zh) * | 2019-11-12 | 2021-05-28 | 中国石油天然气股份有限公司 | 一种高熔体强度聚丙烯的制备方法 |
| CN111474258B (zh) * | 2020-04-17 | 2022-09-06 | 湖北航天化学技术研究所 | 叠氮缩水甘油聚醚支化程度的测定方法 |
| US20230220179A1 (en) | 2020-05-29 | 2023-07-13 | Exxonmobil Chemical Patents Inc. | Processes for Producing Cyclic Olefins from Polymers and Re-Polymerization Thereof |
| JP7794191B2 (ja) * | 2021-03-29 | 2026-01-06 | 日本ポリプロ株式会社 | 分岐状プロピレン系重合体およびその製造方法 |
| EP4393965B1 (en) | 2021-08-23 | 2025-10-01 | Japan Polypropylene Corporation | Branched propylene-based polymer |
| JP2023143812A (ja) | 2022-03-24 | 2023-10-06 | 日本ポリプロ株式会社 | 分岐状プロピレン系重合体 |
Family Cites Families (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| NO167039C (no) * | 1985-01-31 | 1991-09-25 | Himont Inc | Fremgangsmaate for fremstilling av polypropylen med langkjedede forgreninger og anvendelse av dette |
| DE3508887A1 (de) | 1985-03-13 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von optisch aktiven polyolefinen |
| US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
| US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| EP0279863B1 (en) | 1986-08-26 | 1992-10-14 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefin and polymerization process |
| EP0812862B1 (en) | 1986-09-24 | 2002-11-13 | Mitsui Chemicals, Inc. | Process for polymerizing olefins |
| JPH0780933B2 (ja) | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| JP2618384B2 (ja) | 1986-12-27 | 1997-06-11 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒およびその製法 |
| US4921825A (en) | 1986-12-30 | 1990-05-01 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst for olefin polymerization and processes for its production |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| JPH0742301B2 (ja) | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | 微粒子状アルミノオキサン、その製法およびその用途 |
| JP2538588B2 (ja) | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
| US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
| DE3742934A1 (de) | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
| DE3808267A1 (de) * | 1988-03-12 | 1989-09-21 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| US5149819A (en) | 1988-04-28 | 1992-09-22 | Ricoh Company, Ltd. | Squarylium compounds and optical information recording medium using the same |
| US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| DE68919156T3 (de) | 1988-08-05 | 2002-08-14 | Fina Technology, Inc. | Verfahren zur Herstellung grosser symmetrischer Polymerteilchen. |
| US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
| US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
| US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
| US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
| DE3907964A1 (de) | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
| US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
| US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
| US5763549A (en) | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
| ATE120768T1 (de) | 1989-10-30 | 1995-04-15 | Fina Technology | Herstellung von metallocenkatalysatoren für olefinpolymerisation. |
| IL96810A0 (en) | 1990-01-02 | 1991-09-16 | Exxon Chemical Patents Inc | Supported ionic metallocene catalysts for olefin polymerization and methods for the preparation thereof |
| WO1991017194A1 (en) | 1990-05-07 | 1991-11-14 | Exxon Chemical Patents Inc. | UNSATURATED α-OLEFIN COPOLYMERS AND METHOD FOR PREPARATION THEREOF |
| RU2118203C1 (ru) | 1990-06-22 | 1998-08-27 | Экксон Кэмикал Пейтентс Инк. | Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов |
| JP3115595B2 (ja) | 1990-07-24 | 2000-12-11 | 三井化学株式会社 | α―オレフィンの重合触媒及びそれを用いたポリ―α―オレフィンの製造方法 |
| DE59107926D1 (de) | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| US5239022A (en) | 1990-11-12 | 1993-08-24 | Hoechst Aktiengesellschaft | Process for the preparation of a syndiotactic polyolefin |
| US5243001A (en) * | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
| WO1992012162A1 (en) | 1990-12-27 | 1992-07-23 | Exxon Chemical Patents Inc. | An amido transition metal compound and a catalyst system for the production of isotactic polypropylene |
| US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| DE4120009A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
| US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
| US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| EP0537686B1 (de) | 1991-10-15 | 2005-01-12 | Basell Polyolefine GmbH | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| TW318184B (https=) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
| US5329032A (en) | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| US5434115A (en) | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
| EP0574597B2 (en) | 1992-06-13 | 2002-06-26 | Basell Polyolefine GmbH | Process for the preparation of bridged, chiral metallocene catalysts of the bisindenyl type |
| JPH072936A (ja) * | 1992-07-10 | 1995-01-06 | Fina Technol Inc | アイソタクチツクポリオレフイン製造のための方法及び触媒 |
| JPH07509752A (ja) | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
| US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
| RU95110681A (ru) * | 1992-09-29 | 1997-01-10 | Эксон Кемикэл Пейтентс Инк. (US) | Разветвленные длинноцепочечные полимеры и способ получения разветвленных длинноцепочечных полимеров |
| EP0662979B1 (en) | 1992-10-02 | 1997-07-16 | The Dow Chemical Company | Supported homogeneous catalyst complexes for olefin polymerization |
| US5939346A (en) | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
| JP3077940B2 (ja) | 1993-04-26 | 2000-08-21 | エクソン・ケミカル・パテンツ・インク | 流動層重合法のための安定な操作条件を決定する方法 |
| KR100314971B1 (ko) | 1993-05-25 | 2002-07-03 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀중합을위한지지된메탈로센촉매시스템,그의제조방법및용도 |
| EP0812854B2 (en) * | 1993-06-07 | 2011-04-20 | Mitsui Chemicals, Inc. | Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer |
| US5414027A (en) | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| JP3824664B2 (ja) * | 1993-10-06 | 2006-09-20 | 三井化学株式会社 | プロピレン系エラストマー |
| JP3171422B2 (ja) * | 1994-04-20 | 2001-05-28 | 日本原子力研究所 | 改質ポリプロピレンを製造する方法および成形品 |
| ES2143636T3 (es) | 1994-06-24 | 2000-05-16 | Exxon Chemical Patents Inc | Sistemas de catalizadores de polimerizacion, su produccion y uso. |
| WO1996000245A1 (en) | 1994-06-24 | 1996-01-04 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| EP0775164B1 (en) | 1994-08-03 | 2001-11-07 | ExxonMobil Chemical Patents Inc. | Supported ionic catalyst composition |
| TW383314B (en) * | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer |
| EP0745638A1 (de) * | 1995-05-31 | 1996-12-04 | Hoechst Aktiengesellschaft | Biaxial orientierte Polypropylenfolie mit verbessertem Weiterreisswiderstand |
| AT403376B (de) * | 1995-07-03 | 1998-01-26 | Danubia Petrochem Polymere | Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation |
| ATE245665T1 (de) * | 1995-09-28 | 2003-08-15 | Basell Polyolefine Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
-
1999
- 1999-08-16 WO PCT/US1999/018363 patent/WO2000012572A1/en not_active Ceased
- 1999-08-16 MX MXPA01002023A patent/MXPA01002023A/es not_active IP Right Cessation
- 1999-08-16 EP EP99943689.2A patent/EP1115761B1/en not_active Expired - Lifetime
- 1999-08-16 CN CNB998087238A patent/CN1167718C/zh not_active Expired - Lifetime
- 1999-08-16 KR KR1020017002360A patent/KR100611849B1/ko not_active Expired - Fee Related
- 1999-08-16 BR BRPI9913647-3A patent/BR9913647B1/pt not_active IP Right Cessation
- 1999-08-16 CA CA002341167A patent/CA2341167A1/en not_active Abandoned
- 1999-08-16 JP JP2000567585A patent/JP5407099B2/ja not_active Expired - Lifetime
- 1999-08-17 US US09/375,774 patent/US6225432B1/en not_active Expired - Lifetime
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|---|---|
| BR9913647A (pt) | 2001-06-05 |
| JP5407099B2 (ja) | 2014-02-05 |
| CN1309669A (zh) | 2001-08-22 |
| JP2002523575A (ja) | 2002-07-30 |
| CA2341167A1 (en) | 2000-03-09 |
| KR100611849B1 (ko) | 2006-08-11 |
| MXPA01002023A (es) | 2003-10-14 |
| KR20010072933A (ko) | 2001-07-31 |
| US6225432B1 (en) | 2001-05-01 |
| WO2000012572A1 (en) | 2000-03-09 |
| WO2000012572A8 (en) | 2001-04-05 |
| EP1115761B1 (en) | 2013-09-18 |
| EP1115761A1 (en) | 2001-07-18 |
| BR9913647B1 (pt) | 2008-11-18 |
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