CN114467198A - 负极材料及其制备方法和应用以及锂离子电池 - Google Patents
负极材料及其制备方法和应用以及锂离子电池 Download PDFInfo
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- CN114467198A CN114467198A CN202080070420.0A CN202080070420A CN114467198A CN 114467198 A CN114467198 A CN 114467198A CN 202080070420 A CN202080070420 A CN 202080070420A CN 114467198 A CN114467198 A CN 114467198A
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- silicon
- lithium
- negative electrode
- electrode material
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Abstract
本发明涉及锂离子电池领域。公开了负极材料及其制备方法和应用以及锂离子电池。所述负极材料具有核壳结构,所述核中包括含硅物质,所述壳中包括有机锂盐和多孔碳膜,并且至少一部分锂离子插层在所述多孔碳膜之中。其制备方法包括:(1)将硅源与碳源混合,然后焙烧;(2)将步骤(1)得到的焙烧产物与有机锂盐混合;(3)将步骤(2)混合得到的物料进行真空冷冻干燥。本发明所提供的负极材料具有提高的可逆充电容量,应用于锂离子电池中可以提高锂电池的能量密度。
Description
PCT国内申请,说明书已公开。
Claims (15)
- PCT国内申请,权利要求书已公开。
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CN201910953233.6A CN112635719B (zh) | 2019-10-09 | 2019-10-09 | 电池负极材料及其制备方法和应用以及锂离子电池 |
PCT/CN2020/118720 WO2021068796A1 (zh) | 2019-10-09 | 2020-09-29 | 负极材料及其制备方法和应用以及锂离子电池 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115806290A (zh) * | 2022-12-06 | 2023-03-17 | 广东凯金新能源科技股份有限公司 | 人造石墨锂离子电池负极材料及其制备方法 |
CN117976819A (zh) * | 2024-03-29 | 2024-05-03 | 宁德时代新能源科技股份有限公司 | 负极极片、负极极片的制备方法、电池和用电设备 |
Families Citing this family (6)
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---|---|---|---|---|
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CN114784251B (zh) * | 2022-05-13 | 2024-06-18 | 中国科学技术大学 | 一种磷包覆的负极材料及其制备方法和应用 |
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Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008025188A1 (en) * | 2006-08-22 | 2008-03-06 | Btr Energy Materials Co., Ltd. | A silicon-carbon composite negative material for lithium ion battery and the preparation method of the same |
JP2009076433A (ja) * | 2007-08-30 | 2009-04-09 | Sony Corp | 負極およびその製造方法、ならびに二次電池およびその製造方法 |
US20100009261A1 (en) * | 2008-07-14 | 2010-01-14 | Koichiro Watanabe | Negative electrode material, making method, lithium ion secondary battery, and electrochemical capacitor |
KR20140117013A (ko) * | 2013-03-25 | 2014-10-07 | 한국세라믹기술원 | 리튬이온이차전지용 음극 조성물 |
US20150287989A1 (en) * | 2014-04-02 | 2015-10-08 | Shin-Etsu Chemical Co., Ltd. | Negative electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery |
US20160006024A1 (en) * | 2014-07-03 | 2016-01-07 | GM Global Technology Operations LLC | Negative electrode material for lithium-based batteries |
WO2016153322A1 (ko) * | 2015-03-26 | 2016-09-29 | (주)오렌지파워 | 실리콘계 음극 활물질 및 이의 제조 방법 |
CN106531992A (zh) * | 2016-11-09 | 2017-03-22 | 南方科技大学 | 一种含硅复合材料及其制备方法与应用 |
CN108063216A (zh) * | 2017-11-27 | 2018-05-22 | 浙江衡远新能源科技有限公司 | 一种锂电池负极极片及其制备方法 |
WO2018146865A1 (ja) * | 2017-02-09 | 2018-08-16 | 株式会社村田製作所 | 二次電池、電池パック、電動車両、電動工具および電子機器 |
CN110137485A (zh) * | 2019-06-26 | 2019-08-16 | 珠海冠宇电池有限公司 | 一种含有表面修饰膜的硅负极材料的制备方法 |
CN111146422A (zh) * | 2019-12-26 | 2020-05-12 | 宁德新能源科技有限公司 | 负极材料及包含其的电化学装置和电子装置 |
CN112652755A (zh) * | 2019-10-09 | 2021-04-13 | 中国石油化工股份有限公司 | 硅碳负极材料及其制备方法和应用以及锂离子电池 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004086539A1 (en) | 2003-03-26 | 2004-10-07 | Canon Kabushiki Kaisha | Electrode material for lithium secondary battery and electrode structure having the electrode material |
JP5381364B2 (ja) * | 2009-06-12 | 2014-01-08 | トヨタ自動車株式会社 | 二次電池用負極の製造方法及び電極構造 |
CN103400971B (zh) | 2013-07-29 | 2016-07-06 | 宁德新能源科技有限公司 | 硅基复合材料及其制备方法以及其应用 |
CN106463707A (zh) * | 2014-02-21 | 2017-02-22 | 克雷多斯公司 | 官能化iv a族颗粒框架的纳米硅材料制备 |
CN105047887B (zh) * | 2015-06-19 | 2017-03-15 | 苏州大学 | 一种改善锂离子电池硅负极材料的方法 |
CN106898736A (zh) * | 2015-12-18 | 2017-06-27 | 比亚迪股份有限公司 | 一种锂离子电池用电极活性材料、锂离子电池极片及其制备方法和锂离子电池 |
CN109952670B (zh) * | 2016-04-07 | 2022-09-13 | 存点有限公司 | 锂离子电池及其阳极 |
CN105932284B (zh) * | 2016-07-13 | 2019-01-22 | 盐城工学院 | 一种介孔碳紧密包覆型复合材料及其制备方法和应用 |
US11177471B2 (en) * | 2016-12-16 | 2021-11-16 | Johnson Matthey Public Company Limited | Anode materials for lithium ion batteries and methods of making and using same |
CN108063221A (zh) * | 2017-05-11 | 2018-05-22 | 华为技术有限公司 | 制备负极材料的方法、负极材料、负极极片和锂离子电池 |
CN108172775A (zh) | 2017-11-23 | 2018-06-15 | 合肥国轩高科动力能源有限公司 | 一种锂离子电池用磷掺杂硅碳负极材料及其制备方法 |
CN108461723B (zh) * | 2018-02-11 | 2020-08-18 | 安普瑞斯(南京)有限公司 | 一种用于锂离子电池的硅基复合材料及其制备方法 |
US20200144597A1 (en) * | 2018-11-02 | 2020-05-07 | SiNode Systems, Inc. | Advanced negative electrode architecture for high power applications |
CN111916686B (zh) * | 2019-05-08 | 2022-08-12 | 中国石油化工股份有限公司 | 含磷锂离子电池负极材料及其制备工艺 |
CN112635745B (zh) * | 2019-10-09 | 2022-10-11 | 中国石油化工股份有限公司 | 复合材料及其制备方法和锂电池负极以及锂电池 |
CN111146434A (zh) * | 2019-12-26 | 2020-05-12 | 宁德新能源科技有限公司 | 负极材料及包含其的电化学装置和电子装置 |
CN111653738B (zh) | 2020-04-20 | 2022-01-07 | 万向一二三股份公司 | 一种锂离子电池硅碳负极材料及其制备方法 |
-
2020
- 2020-09-29 US US17/754,742 patent/US20230148348A1/en active Pending
- 2020-09-29 CA CA3157355A patent/CA3157355A1/en active Pending
- 2020-09-29 BR BR112022005774A patent/BR112022005774A2/pt unknown
- 2020-09-29 JP JP2022521414A patent/JP2022552485A/ja active Pending
- 2020-09-29 CA CA3155666A patent/CA3155666A1/en active Pending
- 2020-09-29 WO PCT/CN2020/118704 patent/WO2021068793A1/zh active Application Filing
- 2020-09-29 AU AU2020363051A patent/AU2020363051A1/en active Pending
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- 2020-09-29 AU AU2020363053A patent/AU2020363053A1/en active Pending
- 2020-09-29 JP JP2022521415A patent/JP2022552486A/ja active Pending
- 2020-09-29 US US17/754,393 patent/US20220393152A1/en active Pending
- 2020-09-29 WO PCT/CN2020/118720 patent/WO2021068796A1/zh active Application Filing
- 2020-09-29 KR KR1020227015605A patent/KR20220078683A/ko unknown
- 2020-09-29 CN CN202080070420.0A patent/CN114467198B/zh active Active
- 2020-09-29 EP EP20874397.1A patent/EP4044285A4/en active Pending
- 2020-09-29 KR KR1020227015601A patent/KR20220078682A/ko active Search and Examination
- 2020-09-29 BR BR112022005422A patent/BR112022005422A2/pt unknown
- 2020-09-29 CN CN202080070424.9A patent/CN114467195B/zh active Active
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008025188A1 (en) * | 2006-08-22 | 2008-03-06 | Btr Energy Materials Co., Ltd. | A silicon-carbon composite negative material for lithium ion battery and the preparation method of the same |
JP2009076433A (ja) * | 2007-08-30 | 2009-04-09 | Sony Corp | 負極およびその製造方法、ならびに二次電池およびその製造方法 |
US20100009261A1 (en) * | 2008-07-14 | 2010-01-14 | Koichiro Watanabe | Negative electrode material, making method, lithium ion secondary battery, and electrochemical capacitor |
KR20140117013A (ko) * | 2013-03-25 | 2014-10-07 | 한국세라믹기술원 | 리튬이온이차전지용 음극 조성물 |
US20150287989A1 (en) * | 2014-04-02 | 2015-10-08 | Shin-Etsu Chemical Co., Ltd. | Negative electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery |
US20160006024A1 (en) * | 2014-07-03 | 2016-01-07 | GM Global Technology Operations LLC | Negative electrode material for lithium-based batteries |
WO2016153322A1 (ko) * | 2015-03-26 | 2016-09-29 | (주)오렌지파워 | 실리콘계 음극 활물질 및 이의 제조 방법 |
CN106531992A (zh) * | 2016-11-09 | 2017-03-22 | 南方科技大学 | 一种含硅复合材料及其制备方法与应用 |
WO2018146865A1 (ja) * | 2017-02-09 | 2018-08-16 | 株式会社村田製作所 | 二次電池、電池パック、電動車両、電動工具および電子機器 |
CN108063216A (zh) * | 2017-11-27 | 2018-05-22 | 浙江衡远新能源科技有限公司 | 一种锂电池负极极片及其制备方法 |
CN110137485A (zh) * | 2019-06-26 | 2019-08-16 | 珠海冠宇电池有限公司 | 一种含有表面修饰膜的硅负极材料的制备方法 |
CN112652755A (zh) * | 2019-10-09 | 2021-04-13 | 中国石油化工股份有限公司 | 硅碳负极材料及其制备方法和应用以及锂离子电池 |
CN111146422A (zh) * | 2019-12-26 | 2020-05-12 | 宁德新能源科技有限公司 | 负极材料及包含其的电化学装置和电子装置 |
Non-Patent Citations (2)
Title |
---|
HE, DAN等: "Hierarchical C-P(=O)(-O-)n (n≤2)-linked nano-Si/N-doped C/ graphene porous foam as anodes for high-performance lithium ion batteries", 《CARBON》, vol. 141, 4 October 2018 (2018-10-04), pages 531 - 541, XP085537120, DOI: 10.1016/j.carbon.2018.10.007 * |
殷雅侠: "微纳结构高容量锂离子电池负极材料的研究", 《中国博士学位论文全文数据库 工程科技Ⅱ辑》, no. 3, 15 March 2015 (2015-03-15), pages 042 - 28 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115806290A (zh) * | 2022-12-06 | 2023-03-17 | 广东凯金新能源科技股份有限公司 | 人造石墨锂离子电池负极材料及其制备方法 |
CN117976819A (zh) * | 2024-03-29 | 2024-05-03 | 宁德时代新能源科技股份有限公司 | 负极极片、负极极片的制备方法、电池和用电设备 |
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