CN1141250C - 一种流化床连续化制备碳纳米管的方法及其反应装置 - Google Patents

一种流化床连续化制备碳纳米管的方法及其反应装置 Download PDF

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CN1141250C
CN1141250C CNB011183497A CN01118349A CN1141250C CN 1141250 C CN1141250 C CN 1141250C CN B011183497 A CNB011183497 A CN B011183497A CN 01118349 A CN01118349 A CN 01118349A CN 1141250 C CN1141250 C CN 1141250C
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gas
reactor
catalyst
carbon
fluidized bed
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Chinese (zh)
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CN1327943A (zh
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�κ
魏飞
罗国华
王垚
李志飞
汪展文
骞伟忠
金涌
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Tsinghua University
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Priority to CNB011183497A priority Critical patent/CN1141250C/zh
Publication of CN1327943A publication Critical patent/CN1327943A/zh
Priority to EP02700107A priority patent/EP1391425B1/en
Priority to PCT/CN2002/000044 priority patent/WO2002094713A1/zh
Priority to JP2002591391A priority patent/JP3878555B2/ja
Priority to AT02700107T priority patent/ATE478031T1/de
Priority to US10/478,512 priority patent/US7563427B2/en
Priority to DE60237361T priority patent/DE60237361D1/de
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Publication of CN1141250C publication Critical patent/CN1141250C/zh
Priority to US12/400,713 priority patent/US20090286675A1/en
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836—Heating and cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/164—Preparation involving continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B01J2208/00132—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/84—Manufacture, treatment, or detection of nanostructure
    • Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
    • Y10S977/843—Gas phase catalytic growth, i.e. chemical vapor deposition

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  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Catalysts (AREA)
  • Inorganic Fibers (AREA)
CNB011183497A 2001-05-25 2001-05-25 一种流化床连续化制备碳纳米管的方法及其反应装置 Expired - Lifetime CN1141250C (zh)

Priority Applications (8)

Application Number Priority Date Filing Date Title
CNB011183497A CN1141250C (zh) 2001-05-25 2001-05-25 一种流化床连续化制备碳纳米管的方法及其反应装置
AT02700107T ATE478031T1 (de) 2001-05-25 2002-01-29 Kontinuierliche massenproduktion von kohlenstoffnanoröhren in einer nanoagglomerat- wirbelschicht
PCT/CN2002/000044 WO2002094713A1 (en) 2001-05-25 2002-01-29 Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed and the reactor
JP2002591391A JP3878555B2 (ja) 2001-05-25 2002-01-29 ナノ凝集体流動層を用いたカーボンナノチューブの連続製造方法及びその反応装置
EP02700107A EP1391425B1 (en) 2001-05-25 2002-01-29 Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed
US10/478,512 US7563427B2 (en) 2001-05-25 2002-01-29 Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed and the reactor
DE60237361T DE60237361D1 (de) 2001-05-25 2002-01-29 Kontinuierliche massenproduktion von kohlenstoffnanoröhren in einer nanoagglomerat-wirbelschicht
US12/400,713 US20090286675A1 (en) 2001-05-25 2009-03-09 Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed and the reactor

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Application Number Priority Date Filing Date Title
CNB011183497A CN1141250C (zh) 2001-05-25 2001-05-25 一种流化床连续化制备碳纳米管的方法及其反应装置

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CN1327943A CN1327943A (zh) 2001-12-26
CN1141250C true CN1141250C (zh) 2004-03-10

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US (1) US7563427B2 (https=)
EP (1) EP1391425B1 (https=)
JP (1) JP3878555B2 (https=)
CN (1) CN1141250C (https=)
AT (1) ATE478031T1 (https=)
DE (1) DE60237361D1 (https=)
WO (1) WO2002094713A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI807169B (zh) * 2019-02-28 2023-07-01 南韓商Ｌｇ化學股份有限公司 流化床反應器

Families Citing this family (110)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090286675A1 (en) * 2001-05-25 2009-11-19 Tsinghua University Continuous mass production of carbon nanotubes in a nano-agglomerate fluidized-bed and the reactor
JP4160781B2 (ja) * 2002-05-27 2008-10-08 三菱重工業株式会社 繊維状ナノ炭素の製造方法及び装置
US6905544B2 (en) 2002-06-26 2005-06-14 Mitsubishi Heavy Industries, Ltd. Manufacturing method for a carbon nanomaterial, a manufacturing apparatus for a carbon nanomaterial, and manufacturing facility for a carbon nanomaterial
AU2003291133A1 (en) * 2002-11-26 2004-06-18 Carbon Nanotechnologies, Inc. Carbon nanotube particulates, compositions and use thereof
EP1428573B1 (de) * 2002-12-03 2011-06-22 FutureCarbon GmbH Vorrichtung und Verfahren zum Herstellen von Kohlenstoff-Nanomaterial
EP1445236A1 (fr) * 2003-02-05 2004-08-11 Université de Liège Procédé et installation pour la fabrication de nanotubes de carbone
KR101155057B1 (ko) * 2003-04-09 2012-06-11 삼성코닝정밀소재 주식회사 탄소나노튜브의 제조방법
GB0327169D0 (en) * 2003-11-21 2003-12-24 Statoil Asa Method
JP4613268B2 (ja) * 2004-01-27 2011-01-12 清水建設株式会社 球状カーボンナノチューブ集合体の製造方法
KR100626016B1 (ko) * 2004-09-20 2006-09-20 삼성에스디아이 주식회사 탄소나노케이지 제조 방법
DE102004054959A1 (de) * 2004-11-13 2006-05-18 Bayer Technology Services Gmbh Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator
CN100371241C (zh) * 2004-11-24 2008-02-27 中国科学院金属研究所 一种制备大尺寸机械密封用各向同性热解炭材料的设备
CN1323029C (zh) * 2004-12-10 2007-06-27 中国科学院长春应用化学研究所 燃烧聚烯烃合成碳纳米管的方法
FR2881735B1 (fr) * 2005-02-07 2008-04-18 Arkema Sa Procede de synthese de nanotubes de carbone
JP2006225245A (ja) * 2005-02-21 2006-08-31 Mitsubishi Heavy Ind Ltd ナノカーボン材料
KR100664545B1 (ko) * 2005-03-08 2007-01-03 (주)씨엔티 탄소나노튜브 대량합성장치 및 대량합성방법
FR2895393B1 (fr) * 2005-12-23 2008-03-07 Arkema Sa Procede de synthese de nanotubes de carbone
DE102006007147A1 (de) * 2006-02-16 2007-08-23 Bayer Technology Services Gmbh Verfahren zur kontinuierlichen Herstellung von Katalysatoren
ATE517058T1 (de) * 2006-03-20 2011-08-15 Res Inst Of Petroleum Industry Ripi Kontinuierliches verfahren zur herstellung von kohlenstoffnanoröhren
DE102006017695A1 (de) * 2006-04-15 2007-10-18 Bayer Technology Services Gmbh Verfahren zur Herstellung von Kohlenstoffnanoröhrchen in einer Wirbelschicht
US8268281B2 (en) * 2006-05-12 2012-09-18 Honda Motor Co., Ltd. Dry powder injector for industrial production of carbon single walled nanotubes (SWNTs)
KR100793172B1 (ko) 2006-08-30 2008-01-10 세메스 주식회사 탄소나노튜브 제조 설비 및 이를 이용한 탄소나노튜브의제조 방법
CN100450922C (zh) * 2006-11-10 2009-01-14 清华大学 一种超长定向的碳纳米管丝/薄膜及其制备方法
WO2008064368A2 (en) 2006-11-24 2008-05-29 Honda Motor Co., Ltd. Injector for large amount of aerosol powder for synthesis of carbon nanotubes
US20080135482A1 (en) * 2006-11-27 2008-06-12 Kripal Singh Polyamide nanofiltration membrane useful for the removal of phospholipids
CN101049927B (zh) * 2007-04-18 2010-11-10 清华大学 连续化生产碳纳米管的方法及装置
KR100860013B1 (ko) 2007-06-01 2008-09-25 주식회사 제이오 탄소나노튜브의 대량합성을 위한 회전 다단식 원통형 반응기
KR101359415B1 (ko) * 2007-07-27 2014-02-06 금호석유화학 주식회사 탄소나노튜브 합성 방법 및 장치
KR100910382B1 (ko) * 2007-08-16 2009-08-04 세메스 주식회사 촉매 분산 유동층을 이용한 탄소 나노튜브 합성 장치
KR100916330B1 (ko) * 2007-08-21 2009-09-11 세메스 주식회사 탄소나노튜브 합성 방법 및 장치
DE102007044031A1 (de) * 2007-09-14 2009-03-19 Bayer Materialscience Ag Kohlenstoffnanoröhrchenpulver, Kohlenstoffnanoröhrchen und Verfahren zu ihrer Herstellung
KR100976198B1 (ko) 2007-09-19 2010-08-17 세메스 주식회사 탄소나노튜브 제조장치 및 그 방법
DE102007046160A1 (de) * 2007-09-27 2009-04-02 Bayer Materialscience Ag Verfahren zur Herstellung eines Katalysators für die Herstellung von Kohlenstoffnanoröhrchen
KR100933028B1 (ko) 2007-09-28 2009-12-21 세메스 주식회사 탄소나노튜브 제조 설비 및 이를 이용한 탄소나노튜브의제조 방법
US20090200176A1 (en) 2008-02-07 2009-08-13 Mccutchen Co. Radial counterflow shear electrolysis
KR100977147B1 (ko) * 2007-12-31 2010-08-23 세메스 주식회사 유동층 탄소나노튜브 생성 장치 및 그것을 사용한탄소나노튜브 생성 설비 및 방법
US20120156124A1 (en) * 2008-02-12 2012-06-21 New Jersey Institute Of Technology Single Wall Carbon Nanotubes By Atmospheric Chemical Vapor Deposition
KR100982200B1 (ko) * 2008-03-26 2010-09-15 강흥원 탄소나노선재의 제조장치 및 제조방법
US20110158892A1 (en) * 2008-06-30 2011-06-30 Showa Denko K.K. Process for producing carbon nanomaterial and system for producing carbon nanomaterial
CN101348249B (zh) * 2008-09-05 2011-03-30 清华大学 一种在颗粒内表面制备碳纳米管阵列的方法
JP2010100518A (ja) * 2008-09-25 2010-05-06 Nissin Electric Co Ltd カーボンナノコイルの製造方法および製造装置
US8119074B2 (en) * 2008-12-17 2012-02-21 Centro de Investigacion en Materiales Avanzados, S.C Method and apparatus for the continuous production of carbon nanotubes
PE20121017A1 (es) 2009-04-17 2012-08-08 Seerstone Llc Metodo para la produccion de carbono solido mediante la reduccion de oxidos de carbono
FR2949074B1 (fr) 2009-08-17 2013-02-01 Arkema France Catalyseur bi-couche, son procede de preparation et son utilisation pour la fabrication de nanotubes
FR2949075B1 (fr) 2009-08-17 2013-02-01 Arkema France Catalyseur fe/mo supporte, son procede de preparation et utilisation pour la fabrication de nanotubes
US9061909B2 (en) 2009-09-10 2015-06-23 The University Of Tokyo Method for simultaneously producing carbon nanotubes and hydrogen, and device for simultaneously producing carbon nanotubes and hydrogen
US8293204B2 (en) * 2009-12-19 2012-10-23 Abbas Ali Khodadadi Carbon nanotubes continuous synthesis process using iron floating catalysts and MgO particles for CVD of methane in a fluidized bed reactor
KR101551429B1 (ko) * 2009-12-31 2015-09-21 주식회사 효성 유동층 ｃｎｔ를 적용한 폴리아미드 전도성 복합사 제조 방법
US20110171371A1 (en) * 2010-01-13 2011-07-14 CNano Technology Limited Enhanced Electrode Composition for Li ion Battery
WO2011102433A1 (ja) * 2010-02-19 2011-08-25 国立大学法人東京大学 ナノカーボン材料製造装置及びナノカーボン材料の製造方法
WO2011109421A1 (en) * 2010-03-01 2011-09-09 Auburn University Novel nanocomposite for sustainability of infrastructure
WO2012068782A1 (en) * 2010-11-25 2012-05-31 Ka Chun Kalvin Tse System and method for hydrogen production
CN102120570B (zh) * 2011-01-22 2013-08-28 广州市白云化工实业有限公司 一种连续化生产碳纳米管的工艺方法
DE102011003463A1 (de) * 2011-02-01 2012-08-02 E.G.O. Elektro-Gerätebau GmbH Verfahren zur Herstellung einer elektrischen Spule und elektrische Spule
FR2972942B1 (fr) * 2011-03-21 2017-11-24 Arkema France Procede de fabrication de nanotubes de carbone et appareil pour la mise en oeuvre du procede.
EP2694435B1 (en) 2011-04-04 2020-07-08 LG Chem, Ltd. Apparatus and method for continuously producing carbon nanotubes
JP5807455B2 (ja) * 2011-08-31 2015-11-10 東レ株式会社 カーボンナノチューブ含有組成物の製造方法。
US9087626B2 (en) 2011-10-31 2015-07-21 CNano Technology Limited Measuring moisture in a CNT based fluid or paste
FR2984922B1 (fr) 2011-12-22 2015-04-17 Arkema France Procede de co-production de nanotubes de carbone et de graphene
EP2838844A4 (en) 2012-04-16 2015-10-28 Seerstone Llc METHOD FOR TREATING A GAS CLEARANCE CONTAINING CARBON OXIDES
WO2013158160A1 (en) 2012-04-16 2013-10-24 Seerstone Llc Method for producing solid carbon by reducing carbon dioxide
CN104302576B (zh) 2012-04-16 2017-03-08 赛尔斯通股份有限公司 用于捕捉和封存碳并且用于减少废气流中碳氧化物的质量的方法和系统
EP2838837A4 (en) 2012-04-16 2015-12-23 Seerstone Llc METHOD AND STRUCTURES FOR REDUCING CARBON OXIDES WITH IRON-FREE CATALYSTS
NO2749379T3 (https=) * 2012-04-16 2018-07-28
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
US9604848B2 (en) 2012-07-12 2017-03-28 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
CN107215882A (zh) 2012-07-13 2017-09-29 赛尔斯通股份有限公司 用于形成氨和固体碳产物的方法和系统
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
US10526707B2 (en) * 2012-08-29 2020-01-07 The University Of Tokyo Heat exchanger type reaction tube
WO2014085378A1 (en) 2012-11-29 2014-06-05 Seerstone Llc Reactors and methods for producing solid carbon materials
JP2014125418A (ja) * 2012-12-27 2014-07-07 Mitsubishi Materials Corp カーボンナノファイバーの製造装置及び製造方法
KR101414560B1 (ko) * 2013-01-09 2014-07-04 한화케미칼 주식회사 전도성 필름의 제조방법
US9586823B2 (en) 2013-03-15 2017-03-07 Seerstone Llc Systems for producing solid carbon by reducing carbon oxides
WO2014151138A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Reactors, systems, and methods for forming solid products
WO2014151144A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Carbon oxide reduction with intermetallic and carbide catalysts
WO2014150944A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Methods of producing hydrogen and solid carbon
WO2014151119A2 (en) 2013-03-15 2014-09-25 Seerstone Llc Electrodes comprising nanostructured carbon
CN103253650B (zh) * 2013-05-22 2015-03-25 苏州工业园区日高能源科技有限公司 一种纳米碳材的制备方法
CN103420359B (zh) * 2013-08-08 2016-04-06 山东大展纳米材料有限公司 赤泥催化制备碳纳米管的方法、反应装置及应用
US9657723B1 (en) * 2014-03-26 2017-05-23 Lockheed Martin Corporation Carbon nanotube-based fluidized bed heat transfer media for concentrating solar power applications
WO2016044749A1 (en) 2014-09-19 2016-03-24 Nanosynthesis Plus. Ltd. Methods and apparatuses for producing dispersed nanostructures
KR101797809B1 (ko) 2015-03-09 2017-11-14 주식회사 엘지화학 탄소 나노구조물의 제조방법, 이에 의해 제조된 탄소 나노구조물 및 이를 포함하는 복합재
JP6755029B2 (ja) * 2016-03-08 2020-09-16 学校法人早稲田大学 繊維状炭素ナノ構造体製造装置及び繊維状炭素ナノ構造体製造方法
WO2018022999A1 (en) 2016-07-28 2018-02-01 Seerstone Llc. Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
KR102579608B1 (ko) * 2016-08-04 2023-09-18 에스케이이노베이션 주식회사 탄소나노튜브의 제조방법
CN106395791A (zh) * 2016-08-26 2017-02-15 宁波埃飞化工科技有限公司 一种碳纳米管的喷雾式窑炉及其生产方法
CN106395794B (zh) * 2016-08-31 2019-05-03 潍坊昊晟碳材料有限公司 一种耦合流化床碳纳米管高效连续制备方法
CN106430151B (zh) * 2016-08-31 2018-11-16 潍坊昊晟碳材料有限公司 一种还原活化-反应耦合一体的碳纳米管制备方法
CN106395795A (zh) * 2016-08-31 2017-02-15 潍坊昊晟碳材料有限公司 一种连续的碳纳米管流化床制备方法
CN106395793B (zh) * 2016-08-31 2018-11-16 潍坊昊晟碳材料有限公司 一种还原活化-反应耦合一体的碳纳米管高效制备方法
CN106379885B (zh) * 2016-08-31 2019-11-19 潍坊昊晟碳材料有限公司 一种碳纳米管或石墨烯的高效制备方法
CN106430150B (zh) * 2016-08-31 2019-05-03 潍坊昊晟碳材料有限公司 一种连续高效的碳纳米管流化床制备方法
CN106477556A (zh) * 2016-09-06 2017-03-08 南昌大学 一种全自动碳纳米材料连续生产设备及生产方法
CN106914190A (zh) * 2017-04-14 2017-07-04 青岛科技大学 一种反应时间可控的气固两相反应器
US10537840B2 (en) 2017-07-31 2020-01-21 Vorsana Inc. Radial counterflow separation filter with focused exhaust
CN107311150A (zh) * 2017-08-25 2017-11-03 安徽智博新材料科技有限公司 一种高效连续化流化床制备碳纳米管的方法
CN107697903A (zh) * 2017-09-29 2018-02-16 中山国安火炬科技发展有限公司 一种用流化床生产碳纳米管的设备及其制备方法
CN108467024B (zh) * 2018-05-30 2021-05-11 合肥百思新材料研究院有限公司 一种基于化学气相沉积法批量制备碳纳米管的流化床
CN109592667A (zh) * 2019-01-21 2019-04-09 山东斯恩特纳米材料有限公司 一种采用多级复合流化床大规模连续化生产碳纳米管的装置及方法
CN110330008A (zh) * 2019-06-20 2019-10-15 徐成德 一种碳纳米管的连续生产方法
CN113135562B (zh) * 2020-01-20 2024-02-23 山东大展纳米材料有限公司 一种制备碳纳米管和氢气的方法和装置
CN111232953B (zh) * 2020-02-17 2021-06-25 清华大学 一种将挥发性有机物转化为纳米碳产物的装置及方法
CN111686650B (zh) * 2020-06-16 2022-06-28 哈尔滨万鑫石墨谷科技有限公司 一种碳纳米管制备装置及方法
EP4197969A4 (en) * 2020-08-12 2024-05-29 Lg Chem, Ltd. Low-density carbon nanotubes and composite comprising same
AU2021336098B2 (en) * 2020-09-04 2023-05-18 Hindustan Petroleum Corporation Limited Co-production of hydrogen-enriched compressed natural gas and carbon nanotubes
CN112675790A (zh) * 2020-12-04 2021-04-20 厦门大学 一种自蓄热联产碳纳米管的反应器和方法
CN113336283B (zh) * 2021-05-31 2022-07-12 清华大学 将含氰有机废液转化为氮掺杂碳纳米材料的装置及方法
AU2024357176A1 (en) * 2023-10-06 2026-04-16 Basf Se Exploitation of natural hydrogen deposits using methane pyrolysis
CN117504744B (zh) * 2023-11-09 2025-03-25 清华大学 一种高效制备碳纳米材料的流化床系统与方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4650657A (en) * 1982-01-15 1987-03-17 Trw Inc. Method for making carbonaceous materials
DE3347677C2 (de) * 1983-12-31 1987-02-26 VEG-Gasinstituut N.V., Apeldoorn Verfahren zur Herstellung eines Katalysators
US6375917B1 (en) 1984-12-06 2002-04-23 Hyperion Catalysis International, Inc. Apparatus for the production of carbon fibrils by catalysis and methods thereof
US4663230A (en) 1984-12-06 1987-05-05 Hyperion Catalysis International, Inc. Carbon fibrils, method for producing same and compositions containing same
US5458784A (en) * 1990-10-23 1995-10-17 Catalytic Materials Limited Removal of contaminants from aqueous and gaseous streams using graphic filaments
JPH11310407A (ja) * 1998-04-30 1999-11-09 Osaka Gas Co Ltd 機能性炭素材料の製造法
JP2000203819A (ja) * 1999-01-14 2000-07-25 Osaka Gas Co Ltd 直線状カ―ボンナノチュ―ブの製造方法
EP1059266A3 (en) * 1999-06-11 2000-12-20 Iljin Nanotech Co., Ltd. Mass synthesis method of high purity carbon nanotubes vertically aligned over large-size substrate using thermal chemical vapor deposition
CN1140448C (zh) * 2000-03-07 2004-03-03 天津大学 镍催化裂解甲烷制备碳纳米管的方法
CN1183031C (zh) * 2000-03-23 2005-01-05 中国科学院成都有机化学研究所 一种制备碳纳米管的方法
US6919064B2 (en) * 2000-06-02 2005-07-19 The Board Of Regents Of The University Of Oklahoma Process and apparatus for producing single-walled carbon nanotubes
US6413487B1 (en) 2000-06-02 2002-07-02 The Board Of Regents Of The University Of Oklahoma Method and apparatus for producing carbon nanotubes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI807169B (zh) * 2019-02-28 2023-07-01 南韓商Ｌｇ化學股份有限公司 流化床反應器

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