CN1105599C - 用于乙烷氧化成乙酸的催化剂及其制备方法和用途 - Google Patents

用于乙烷氧化成乙酸的催化剂及其制备方法和用途 Download PDF

Info

Publication number
CN1105599C
CN1105599C CN98801493A CN98801493A CN1105599C CN 1105599 C CN1105599 C CN 1105599C CN 98801493 A CN98801493 A CN 98801493A CN 98801493 A CN98801493 A CN 98801493A CN 1105599 C CN1105599 C CN 1105599C
Authority
CN
China
Prior art keywords
catalyst
scope
ethane
mixture
elements
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN98801493A
Other languages
English (en)
Chinese (zh)
Other versions
CN1241146A (zh
Inventor
K·卡利姆
M·H·艾尔－哈兹米
E·玛米多夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
Original Assignee
Saudi Basic Industries Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Publication of CN1241146A publication Critical patent/CN1241146A/zh
Application granted granted Critical
Publication of CN1105599C publication Critical patent/CN1105599C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN98801493A 1997-09-17 1998-09-15 用于乙烷氧化成乙酸的催化剂及其制备方法和用途 Expired - Lifetime CN1105599C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/932,075 US6013597A (en) 1997-09-17 1997-09-17 Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same
US08/932,075 1997-09-17

Publications (2)

Publication Number Publication Date
CN1241146A CN1241146A (zh) 2000-01-12
CN1105599C true CN1105599C (zh) 2003-04-16

Family

ID=25461731

Family Applications (1)

Application Number Title Priority Date Filing Date
CN98801493A Expired - Lifetime CN1105599C (zh) 1997-09-17 1998-09-15 用于乙烷氧化成乙酸的催化剂及其制备方法和用途

Country Status (6)

Country Link
US (2) US6013597A (enExample)
EP (1) EP0938378B1 (enExample)
JP (1) JP4596377B2 (enExample)
CN (1) CN1105599C (enExample)
DE (1) DE69828026T2 (enExample)
WO (1) WO1999013980A1 (enExample)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9807142D0 (en) * 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
CA2271397A1 (en) * 1998-05-21 1999-11-21 Rohm And Haas Company A process for preparing a catalyst
US6087297A (en) * 1998-06-29 2000-07-11 Saudi Basic Industries Corporation Catalysts for gas phase production of acetic acid from ethane, processes of making the same and methods of using same
US6514902B1 (en) * 1998-08-28 2003-02-04 Asahi Kasei Kogyo Kabushiki Kaisha Method for producing an oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane
US6143921A (en) 1999-05-14 2000-11-07 Saudi Basic Industries Corporation Method for producing vinyl acetate monomer from ethane or ethylene oxidation
US6258992B1 (en) * 1999-09-17 2001-07-10 Saudi Basic Industries Corporation Gas phase catalytic oxidation of hydrocarbons to carboxylic acids and dehydrogenated products
US6693059B2 (en) * 2000-02-09 2004-02-17 Rohm And Haas Company Process for preparing a catalyst and catalytic oxidation therewith
US6531631B1 (en) 2000-04-28 2003-03-11 Saudi Basic Industries Corporation Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts
US6337424B1 (en) * 2000-04-28 2002-01-08 Saudi Basic Industries Corporation Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same
US6444845B1 (en) * 2000-04-28 2002-09-03 Saudia Basic Industries Corporation Process for the oxidation of unsaturated aldehydes to produce carboxylic acids using Mo-V based catalysts
US6977064B1 (en) 2000-05-05 2005-12-20 Saudi Basic Industries Corporation Apparatus for the controlled optimized addition of reactants in continuous flow reaction systems
ES2192983B1 (es) * 2002-01-31 2004-09-16 Universidad Politecnica De Valencia. Un catalizador para la deshidrogenacion oxidativa de etano a eteno.
JP2007529294A (ja) * 2003-12-18 2007-10-25 アヴァンティウム　インターナショナル　ベー．フェー． アルカン又はアルケンの酸化及びアンモ酸化のための触媒
JP2008545743A (ja) * 2005-06-01 2008-12-18 セラニーズ・インターナショナル・コーポレーション エタンを選択的に酸化してエチレンを製造する方法
US7795469B2 (en) * 2006-12-21 2010-09-14 Rohm And Haas Company Process for the selective (AMM) oxidation of lower molecular weight alkanes and alkenes
EP2179793A1 (en) * 2008-10-21 2010-04-28 Sued-Chemie AG Phosphorous-containing mixed oxide catalysts
JP6068617B2 (ja) * 2012-03-28 2017-01-25 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ エチレン及び酢酸の製造工程
US9409156B2 (en) 2012-10-19 2016-08-09 Instituto Mexicano Del Petroleo Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
CN105209418B (zh) * 2013-05-13 2017-03-08 沙特基础工业公司 通过乙烷氧化制备乙酸的方法
EP3038747B1 (en) * 2013-08-30 2020-04-08 SABIC Global Technologies B.V. Transesterification of aromatic alcohols using a heterogeneous catalyst
CN103920516B (zh) * 2014-04-15 2016-03-16 高丽娜 可用于烷烃氧化的催化剂制备方法
CN105727978B (zh) * 2014-12-06 2018-01-16 中国石油化工股份有限公司 一种用于乙烷氧化脱氢制乙烯的催化剂制备方法
CN108114731A (zh) * 2016-11-26 2018-06-05 中国科学院大连化学物理研究所 用于氧化反应的催化剂组合物
WO2018116143A1 (en) 2016-12-19 2018-06-28 Sabic Global Technologies B.V. Method of purifying acetic acid
US11986805B2 (en) 2019-03-26 2024-05-21 Sabic Global Technologies B.V. Method of reactivating catalyst
EP4059916A1 (de) 2021-03-15 2022-09-21 Linde GmbH Verfahren und anlage zur erzeugung eines produktkohlenwasserstoffs
CN116328755B (zh) * 2021-12-22 2025-02-28 中国石油天然气股份有限公司 复合氧化物催化剂及其制备方法与应用
CN116408061A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 乙烷选择氧化制乙酸和乙烯的催化剂及其制备方法与应用
EP4342873A1 (de) 2022-09-26 2024-03-27 Linde GmbH Verfahren und anlage zur herstellung von ethylen und essigsäure, verfahren und anlage zur herstellung einer zielverbindung unter verwendung von ethylen und essigsäure
CN119702065B (zh) * 2023-09-28 2025-11-18 中国石油天然气股份有限公司 一种乙烷氧化脱氢的复合型催化剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2836309A1 (de) * 1977-08-19 1979-02-22 Union Carbide Corp Verfahren zur umwandlung gesaettigter aliphatischer saeuren und deren derivate mit mindestens 4 c-atomen in die entsprechenden ungesaettigten verbindungen
US4250346A (en) * 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
EP0294845A1 (en) * 1987-06-12 1988-12-14 Union Carbide Corporation Acetic acid from ethane, ethylene and oxygen
CN1042901A (zh) * 1987-11-25 1990-06-13 三菱化成株式会社 生产腈的方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1129469B (de) * 1957-09-28 1962-05-17 Hoechst Ag Verfahren zur Herstellung von Aldehyden, Ketonen oder den Aldehyden entsprechenden Saeuren
US3057915A (en) * 1957-09-14 1962-10-09 Hoechst Ag Process for oxidizing olefins to aldehydes, ketones and acids
US3240805A (en) * 1961-10-13 1966-03-15 Halcon International Inc Process for producing acetic acid
US4339355A (en) * 1975-10-09 1982-07-13 Union Carbide Corporation Catalytic oxide of molybdenum, vanadium, niobium and optional 4th metal
US4250054A (en) * 1976-06-01 1981-02-10 The Standard Oil Company (Ohio) Catalysts for producing unsaturated aliphatic acids
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
GB8915410D0 (en) * 1989-07-05 1989-08-23 Bp Chem Int Ltd Chemical process
US4568790A (en) * 1984-06-28 1986-02-04 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
US4524236A (en) * 1984-06-28 1985-06-18 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
US4596787A (en) * 1985-04-11 1986-06-24 Union Carbide Corporation Process for preparing a supported catalyst for the oxydehydrogenation of ethane to ethylene
US4899003A (en) * 1985-07-11 1990-02-06 Union Carbide Chemicals And Plastics Company Inc. Process for oxydehydrogenation of ethane to ethylene
JP2608768B2 (ja) * 1987-11-25 1997-05-14 三菱化学株式会社 ニトリルの製造法
US5049692A (en) * 1987-11-25 1991-09-17 Mitsubishi Kasei Corporation Catalytic conversion of alkanes to nitriles, and a catalyst therefor
ES2067774T3 (es) * 1990-02-08 1995-04-01 Nippon Catalytic Chem Ind Procedimiento para producir acido metacrilico.
JP2574948B2 (ja) * 1990-02-08 1997-01-22 株式会社日本触媒 メタクリル酸の製造方法
GB9022127D0 (en) * 1990-10-11 1990-11-21 Bp Chem Int Ltd Process
US5300682A (en) * 1991-06-10 1994-04-05 The Standard Oil Co. Catalytic oxidation of ethane to acetic acid
US5198580A (en) * 1991-11-18 1993-03-30 The Standard Oil Company Process for oxidation of propane
TW295579B (enExample) * 1993-04-06 1997-01-11 Showa Denko Kk
FR2705668B1 (fr) * 1993-05-28 1995-08-25 Rhone Poulenc Chimie Procédé de préparation d'acide acétique par oxydation ménagée de l'éthane.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2836309A1 (de) * 1977-08-19 1979-02-22 Union Carbide Corp Verfahren zur umwandlung gesaettigter aliphatischer saeuren und deren derivate mit mindestens 4 c-atomen in die entsprechenden ungesaettigten verbindungen
US4250346A (en) * 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
EP0294845A1 (en) * 1987-06-12 1988-12-14 Union Carbide Corporation Acetic acid from ethane, ethylene and oxygen
CN1042901A (zh) * 1987-11-25 1990-06-13 三菱化成株式会社 生产腈的方法

Also Published As

Publication number Publication date
CN1241146A (zh) 2000-01-12
EP0938378B1 (en) 2004-12-08
DE69828026T2 (de) 2005-04-07
JP4596377B2 (ja) 2010-12-08
WO1999013980A1 (en) 1999-03-25
JP2001505129A (ja) 2001-04-17
US5907056A (en) 1999-05-25
DE69828026D1 (de) 2005-01-13
US6013597A (en) 2000-01-11
EP0938378A1 (en) 1999-09-01

Similar Documents

Publication Publication Date Title
CN1105599C (zh) 用于乙烷氧化成乙酸的催化剂及其制备方法和用途
CN1145527C (zh) 丙烷催化氧化成丙烯酸的催化剂及其制造和使用方法
CN1027060C (zh) 制取乙烯和乙酸的方法及所用的催化剂
CN1227194C (zh) 生产链烯烃和羧酸的氧化方法
CN1241895C (zh) 乙酸乙烯酯的生产方法
CN1087734C (zh) 由丙烷或异丁烷经氨氧化作用制备丙烯腈或甲基丙烯腈的改进的方法
CN1029843C (zh) 生产丙烯酸的方法
CN1188387C (zh) 通过乙烷或乙烯氧化生产乙酸乙烯酯单体的方法
CN1292832C (zh) 混合金属氧化物催化剂
CN1092633C (zh) 用于制备甲基丙烯酸的催化剂以及使用该催化剂制备甲基丙烯酸的方法
CN1028752C (zh) 生产腈的工艺
CN1123561C (zh) 乙烷催化氧化选择性生产乙酸的方法
CN1188214C (zh) 卤素促进的多金属氧化物催化剂
CN1147358C (zh) 中空圆柱形催化剂及生产马来酸酐的方法
CN1138596C (zh) 乙烷和/或乙烯氧化的催化剂和方法
CN1060154C (zh) 用于生产不饱和醛和不饱和羧酸的催化剂及用此催化剂生产不饱和醛和不饱和羧酸的方法
CN1795160A (zh) 通过含有氧化钒、二氧化钛和氧化锑的催化剂制备醛、羧酸和/或羧酸酐的方法
CN1422833A (zh) 由烷烃制备烯烃、不饱和羧酸和不饱和腈的改进方法
CN1575203A (zh) 多氧金属化物催化剂以及通过催化的烷烃部分氧化制备羧酸的方法
CN1452607A (zh) 乙酸乙烯酯的综合生产方法
CN1131657A (zh) 通过控制氧化相应烷烃制备羧酸的方法
CN1374936A (zh) 烷烃氧化脱氢方法的含硫促进剂
CN1375487A (zh) 在无分子氧条件下由丙烷制备丙烯酸的方法
CN1109802A (zh) 多金属氧化物组合物
CN1183760A (zh) 采用多相催化剂氧化烃、醇或酮的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20030416