JP4596377B2 - エタンから酢酸への酸化用触媒と、その形成方法およびその使用方法 - Google Patents

エタンから酢酸への酸化用触媒と、その形成方法およびその使用方法 Download PDF

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JP4596377B2
JP4596377B2 JP51755399A JP51755399A JP4596377B2 JP 4596377 B2 JP4596377 B2 JP 4596377B2 JP 51755399 A JP51755399 A JP 51755399A JP 51755399 A JP51755399 A JP 51755399A JP 4596377 B2 JP4596377 B2 JP 4596377B2
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catalyst
ethane
acetic acid
oxygen
selectivity
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Expired - Lifetime
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JP51755399A
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Japanese (ja)
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JP2001505129A5 (enExample
JP2001505129A (ja
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カリム，カリド
アル―ハツミ，モハメッド，ハッサン
マメドフ，エドアード
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サウディ ベーシック インダストリーズ コーポレーション
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP51755399A 1997-09-17 1998-09-15 エタンから酢酸への酸化用触媒と、その形成方法およびその使用方法 Expired - Lifetime JP4596377B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/932,075 US6013597A (en) 1997-09-17 1997-09-17 Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same
US08/932,075 1997-09-17
PCT/GB1998/002791 WO1999013980A1 (en) 1997-09-17 1998-09-15 Catalysts for the oxidation of ethane to acetic acid, processes of making same and processes of using same

Publications (3)

Publication Number Publication Date
JP2001505129A JP2001505129A (ja) 2001-04-17
JP2001505129A5 JP2001505129A5 (enExample) 2006-01-05
JP4596377B2 true JP4596377B2 (ja) 2010-12-08

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JP51755399A Expired - Lifetime JP4596377B2 (ja) 1997-09-17 1998-09-15 エタンから酢酸への酸化用触媒と、その形成方法およびその使用方法

Country Status (6)

Country Link
US (2) US6013597A (enExample)
EP (1) EP0938378B1 (enExample)
JP (1) JP4596377B2 (enExample)
CN (1) CN1105599C (enExample)
DE (1) DE69828026T2 (enExample)
WO (1) WO1999013980A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20140137390A (ko) * 2012-03-28 2014-12-02 롬 앤드 하스 캄파니 에틸렌 및 아세트산의 제조 방법

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9807142D0 (en) * 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
CA2271397A1 (en) * 1998-05-21 1999-11-21 Rohm And Haas Company A process for preparing a catalyst
US6087297A (en) * 1998-06-29 2000-07-11 Saudi Basic Industries Corporation Catalysts for gas phase production of acetic acid from ethane, processes of making the same and methods of using same
US6514902B1 (en) * 1998-08-28 2003-02-04 Asahi Kasei Kogyo Kabushiki Kaisha Method for producing an oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane
US6143921A (en) 1999-05-14 2000-11-07 Saudi Basic Industries Corporation Method for producing vinyl acetate monomer from ethane or ethylene oxidation
US6258992B1 (en) * 1999-09-17 2001-07-10 Saudi Basic Industries Corporation Gas phase catalytic oxidation of hydrocarbons to carboxylic acids and dehydrogenated products
US6693059B2 (en) * 2000-02-09 2004-02-17 Rohm And Haas Company Process for preparing a catalyst and catalytic oxidation therewith
US6531631B1 (en) 2000-04-28 2003-03-11 Saudi Basic Industries Corporation Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts
US6337424B1 (en) * 2000-04-28 2002-01-08 Saudi Basic Industries Corporation Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same
US6444845B1 (en) * 2000-04-28 2002-09-03 Saudia Basic Industries Corporation Process for the oxidation of unsaturated aldehydes to produce carboxylic acids using Mo-V based catalysts
US6977064B1 (en) 2000-05-05 2005-12-20 Saudi Basic Industries Corporation Apparatus for the controlled optimized addition of reactants in continuous flow reaction systems
ES2192983B1 (es) * 2002-01-31 2004-09-16 Universidad Politecnica De Valencia. Un catalizador para la deshidrogenacion oxidativa de etano a eteno.
JP2007529294A (ja) * 2003-12-18 2007-10-25 アヴァンティウム　インターナショナル　ベー．フェー． アルカン又はアルケンの酸化及びアンモ酸化のための触媒
JP2008545743A (ja) * 2005-06-01 2008-12-18 セラニーズ・インターナショナル・コーポレーション エタンを選択的に酸化してエチレンを製造する方法
US7795469B2 (en) * 2006-12-21 2010-09-14 Rohm And Haas Company Process for the selective (AMM) oxidation of lower molecular weight alkanes and alkenes
EP2179793A1 (en) * 2008-10-21 2010-04-28 Sued-Chemie AG Phosphorous-containing mixed oxide catalysts
US9409156B2 (en) 2012-10-19 2016-08-09 Instituto Mexicano Del Petroleo Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
CN105209418B (zh) * 2013-05-13 2017-03-08 沙特基础工业公司 通过乙烷氧化制备乙酸的方法
EP3038747B1 (en) * 2013-08-30 2020-04-08 SABIC Global Technologies B.V. Transesterification of aromatic alcohols using a heterogeneous catalyst
CN103920516B (zh) * 2014-04-15 2016-03-16 高丽娜 可用于烷烃氧化的催化剂制备方法
CN105727978B (zh) * 2014-12-06 2018-01-16 中国石油化工股份有限公司 一种用于乙烷氧化脱氢制乙烯的催化剂制备方法
CN108114731A (zh) * 2016-11-26 2018-06-05 中国科学院大连化学物理研究所 用于氧化反应的催化剂组合物
WO2018116143A1 (en) 2016-12-19 2018-06-28 Sabic Global Technologies B.V. Method of purifying acetic acid
US11986805B2 (en) 2019-03-26 2024-05-21 Sabic Global Technologies B.V. Method of reactivating catalyst
EP4059916A1 (de) 2021-03-15 2022-09-21 Linde GmbH Verfahren und anlage zur erzeugung eines produktkohlenwasserstoffs
CN116328755B (zh) * 2021-12-22 2025-02-28 中国石油天然气股份有限公司 复合氧化物催化剂及其制备方法与应用
CN116408061A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 乙烷选择氧化制乙酸和乙烯的催化剂及其制备方法与应用
EP4342873A1 (de) 2022-09-26 2024-03-27 Linde GmbH Verfahren und anlage zur herstellung von ethylen und essigsäure, verfahren und anlage zur herstellung einer zielverbindung unter verwendung von ethylen und essigsäure
CN119702065B (zh) * 2023-09-28 2025-11-18 中国石油天然气股份有限公司 一种乙烷氧化脱氢的复合型催化剂及其制备方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1129469B (de) * 1957-09-28 1962-05-17 Hoechst Ag Verfahren zur Herstellung von Aldehyden, Ketonen oder den Aldehyden entsprechenden Saeuren
US3057915A (en) * 1957-09-14 1962-10-09 Hoechst Ag Process for oxidizing olefins to aldehydes, ketones and acids
US3240805A (en) * 1961-10-13 1966-03-15 Halcon International Inc Process for producing acetic acid
US4339355A (en) * 1975-10-09 1982-07-13 Union Carbide Corporation Catalytic oxide of molybdenum, vanadium, niobium and optional 4th metal
US4250054A (en) * 1976-06-01 1981-02-10 The Standard Oil Company (Ohio) Catalysts for producing unsaturated aliphatic acids
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
US4249020A (en) * 1977-08-19 1981-02-03 Union Carbide Corporation Oxydehydrogenation of certain≧C4 saturated oxyhydrocarbon compounds
US4250346A (en) * 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
GB8915410D0 (en) * 1989-07-05 1989-08-23 Bp Chem Int Ltd Chemical process
US4568790A (en) * 1984-06-28 1986-02-04 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
US4524236A (en) * 1984-06-28 1985-06-18 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
US4596787A (en) * 1985-04-11 1986-06-24 Union Carbide Corporation Process for preparing a supported catalyst for the oxydehydrogenation of ethane to ethylene
US4899003A (en) * 1985-07-11 1990-02-06 Union Carbide Chemicals And Plastics Company Inc. Process for oxydehydrogenation of ethane to ethylene
US5162578A (en) * 1987-06-12 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Acetic acid from ethane, ethylene and oxygen
CN1020597C (zh) * 1987-11-25 1993-05-12 三菱化成株式会社 生产腈的方法
JP2608768B2 (ja) * 1987-11-25 1997-05-14 三菱化学株式会社 ニトリルの製造法
US5049692A (en) * 1987-11-25 1991-09-17 Mitsubishi Kasei Corporation Catalytic conversion of alkanes to nitriles, and a catalyst therefor
ES2067774T3 (es) * 1990-02-08 1995-04-01 Nippon Catalytic Chem Ind Procedimiento para producir acido metacrilico.
JP2574948B2 (ja) * 1990-02-08 1997-01-22 株式会社日本触媒 メタクリル酸の製造方法
GB9022127D0 (en) * 1990-10-11 1990-11-21 Bp Chem Int Ltd Process
US5300682A (en) * 1991-06-10 1994-04-05 The Standard Oil Co. Catalytic oxidation of ethane to acetic acid
US5198580A (en) * 1991-11-18 1993-03-30 The Standard Oil Company Process for oxidation of propane
TW295579B (enExample) * 1993-04-06 1997-01-11 Showa Denko Kk
FR2705668B1 (fr) * 1993-05-28 1995-08-25 Rhone Poulenc Chimie Procédé de préparation d'acide acétique par oxydation ménagée de l'éthane.

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20140137390A (ko) * 2012-03-28 2014-12-02 롬 앤드 하스 캄파니 에틸렌 및 아세트산의 제조 방법
KR102121079B1 (ko) * 2012-03-28 2020-06-09 롬 앤드 하스 캄파니 에틸렌 및 아세트산의 제조 방법

Also Published As

Publication number Publication date
CN1241146A (zh) 2000-01-12
EP0938378B1 (en) 2004-12-08
DE69828026T2 (de) 2005-04-07
WO1999013980A1 (en) 1999-03-25
JP2001505129A (ja) 2001-04-17
US5907056A (en) 1999-05-25
DE69828026D1 (de) 2005-01-13
US6013597A (en) 2000-01-11
EP0938378A1 (en) 1999-09-01
CN1105599C (zh) 2003-04-16

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