DE69828026D1 - Katalysatoren für die oxidation von ethan zu essigsäure, verfahren zu ihrer herstellung und verwendung - Google Patents

Katalysatoren für die oxidation von ethan zu essigsäure, verfahren zu ihrer herstellung und verwendung

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Publication number
DE69828026D1
DE69828026D1 DE1998628026 DE69828026T DE69828026D1 DE 69828026 D1 DE69828026 D1 DE 69828026D1 DE 1998628026 DE1998628026 DE 1998628026 DE 69828026 T DE69828026 T DE 69828026T DE 69828026 D1 DE69828026 D1 DE 69828026D1
Authority
DE
Germany
Prior art keywords
ethanic
catalysts
oxidation
production
acetic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE1998628026
Other languages
English (en)
Other versions
DE69828026T2 (de
Inventor
Khalid Karim
Hassan Al-Hazmi
Edouard Mamedov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
Original Assignee
Saudi Basic Industries Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Publication of DE69828026D1 publication Critical patent/DE69828026D1/de
Application granted granted Critical
Publication of DE69828026T2 publication Critical patent/DE69828026T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69828026T 1997-09-17 1998-09-15 Katalysatoren für die oxidation von ethan zu essigsäure, verfahren zu ihrer herstellung und verwendung Expired - Lifetime DE69828026T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US932075 1997-09-17
US08/932,075 US6013597A (en) 1997-09-17 1997-09-17 Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same
PCT/GB1998/002791 WO1999013980A1 (en) 1997-09-17 1998-09-15 Catalysts for the oxidation of ethane to acetic acid, processes of making same and processes of using same

Publications (2)

Publication Number Publication Date
DE69828026D1 true DE69828026D1 (de) 2005-01-13
DE69828026T2 DE69828026T2 (de) 2005-04-07

Family

ID=25461731

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69828026T Expired - Lifetime DE69828026T2 (de) 1997-09-17 1998-09-15 Katalysatoren für die oxidation von ethan zu essigsäure, verfahren zu ihrer herstellung und verwendung

Country Status (6)

Country Link
US (2) US6013597A (de)
EP (1) EP0938378B1 (de)
JP (1) JP4596377B2 (de)
CN (1) CN1105599C (de)
DE (1) DE69828026T2 (de)
WO (1) WO1999013980A1 (de)

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GB9807142D0 (en) * 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
CA2271397A1 (en) * 1998-05-21 1999-11-21 Rohm And Haas Company A process for preparing a catalyst
US6087297A (en) * 1998-06-29 2000-07-11 Saudi Basic Industries Corporation Catalysts for gas phase production of acetic acid from ethane, processes of making the same and methods of using same
DE19983250T1 (de) * 1998-08-28 2001-08-09 Asahi Chemical Ind Verfahren zur Herstellung eines Oxidkatalysators für die Verwendung bei der Herstellung von Acrylnitril oder Methacrylnitril aus Propan oder Isobutan
US6143921A (en) 1999-05-14 2000-11-07 Saudi Basic Industries Corporation Method for producing vinyl acetate monomer from ethane or ethylene oxidation
US6258992B1 (en) * 1999-09-17 2001-07-10 Saudi Basic Industries Corporation Gas phase catalytic oxidation of hydrocarbons to carboxylic acids and dehydrogenated products
US6693059B2 (en) * 2000-02-09 2004-02-17 Rohm And Haas Company Process for preparing a catalyst and catalytic oxidation therewith
US6444845B1 (en) * 2000-04-28 2002-09-03 Saudia Basic Industries Corporation Process for the oxidation of unsaturated aldehydes to produce carboxylic acids using Mo-V based catalysts
US6337424B1 (en) * 2000-04-28 2002-01-08 Saudi Basic Industries Corporation Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same
US6531631B1 (en) 2000-04-28 2003-03-11 Saudi Basic Industries Corporation Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts
US6977064B1 (en) 2000-05-05 2005-12-20 Saudi Basic Industries Corporation Apparatus for the controlled optimized addition of reactants in continuous flow reaction systems
ES2192983B1 (es) * 2002-01-31 2004-09-16 Universidad Politecnica De Valencia. Un catalizador para la deshidrogenacion oxidativa de etano a eteno.
EP1691921A1 (de) * 2003-12-18 2006-08-23 Avantium International B.V. Katalysatoren zur oxidation und ammoxidation von alkanen oder alkenen
MX2007015298A (es) * 2005-06-01 2008-02-21 Celanese Int Corp Procedimiento para selectivamente oxidar el etano al etileno.
US7795469B2 (en) * 2006-12-21 2010-09-14 Rohm And Haas Company Process for the selective (AMM) oxidation of lower molecular weight alkanes and alkenes
EP2179793A1 (de) * 2008-10-21 2010-04-28 Sued-Chemie AG Mischoxidkatalysator enthaltend Phosphor
CN104203401B (zh) * 2012-03-28 2016-08-17 罗门哈斯公司 制造乙烯和乙酸的方法
US9409156B2 (en) 2012-10-19 2016-08-09 Instituto Mexicano Del Petroleo Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
CA2907955A1 (en) * 2013-05-13 2014-11-20 Saudi Basic Industries Corporation Methods for preparing acetic acid via ethane oxidation
EP3038747B1 (de) * 2013-08-30 2020-04-08 SABIC Global Technologies B.V. Umesterung von aromatischen alkoholen im gegenwart eines heterogenen katalysators
CN103920516B (zh) * 2014-04-15 2016-03-16 高丽娜 可用于烷烃氧化的催化剂制备方法
CN105727978B (zh) * 2014-12-06 2018-01-16 中国石油化工股份有限公司 一种用于乙烷氧化脱氢制乙烯的催化剂制备方法
CN108114731A (zh) * 2016-11-26 2018-06-05 中国科学院大连化学物理研究所 用于氧化反应的催化剂组合物
CN110072836A (zh) 2016-12-19 2019-07-30 沙特基础工业全球技术有限公司 纯化乙酸的方法
US11986805B2 (en) 2019-03-26 2024-05-21 Sabic Global Technologies B.V. Method of reactivating catalyst
CN116328755A (zh) * 2021-12-22 2023-06-27 中国石油天然气股份有限公司 复合氧化物催化剂及其制备方法与应用
CN116408061A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 乙烷选择氧化制乙酸和乙烯的催化剂及其制备方法与应用
EP4342873A1 (de) 2022-09-26 2024-03-27 Linde GmbH Verfahren und anlage zur herstellung von ethylen und essigsäure, verfahren und anlage zur herstellung einer zielverbindung unter verwendung von ethylen und essigsäure

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US3057915A (en) * 1957-09-14 1962-10-09 Hoechst Ag Process for oxidizing olefins to aldehydes, ketones and acids
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US4250054A (en) * 1976-06-01 1981-02-10 The Standard Oil Company (Ohio) Catalysts for producing unsaturated aliphatic acids
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
US4249020A (en) * 1977-08-19 1981-02-03 Union Carbide Corporation Oxydehydrogenation of certain≧C4 saturated oxyhydrocarbon compounds
US4250346A (en) * 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
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US4596787A (en) * 1985-04-11 1986-06-24 Union Carbide Corporation Process for preparing a supported catalyst for the oxydehydrogenation of ethane to ethylene
US4899003A (en) * 1985-07-11 1990-02-06 Union Carbide Chemicals And Plastics Company Inc. Process for oxydehydrogenation of ethane to ethylene
US5162578A (en) * 1987-06-12 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Acetic acid from ethane, ethylene and oxygen
US5049692A (en) * 1987-11-25 1991-09-17 Mitsubishi Kasei Corporation Catalytic conversion of alkanes to nitriles, and a catalyst therefor
CN1020597C (zh) * 1987-11-25 1993-05-12 三菱化成株式会社 生产腈的方法
JP2608768B2 (ja) * 1987-11-25 1997-05-14 三菱化学株式会社 ニトリルの製造法
EP0441312B1 (de) * 1990-02-08 1995-02-01 Nippon Shokubai Kagaku Kogyo Co. Ltd. Verfahren zur Herstellung von Methacrylsäure
JP2574948B2 (ja) * 1990-02-08 1997-01-22 株式会社日本触媒 メタクリル酸の製造方法
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US5300682A (en) * 1991-06-10 1994-04-05 The Standard Oil Co. Catalytic oxidation of ethane to acetic acid
US5198580A (en) * 1991-11-18 1993-03-30 The Standard Oil Company Process for oxidation of propane
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FR2705668B1 (fr) * 1993-05-28 1995-08-25 Rhone Poulenc Chimie Procédé de préparation d'acide acétique par oxydation ménagée de l'éthane.

Also Published As

Publication number Publication date
EP0938378A1 (de) 1999-09-01
WO1999013980A1 (en) 1999-03-25
JP2001505129A (ja) 2001-04-17
EP0938378B1 (de) 2004-12-08
JP4596377B2 (ja) 2010-12-08
CN1105599C (zh) 2003-04-16
US5907056A (en) 1999-05-25
US6013597A (en) 2000-01-11
DE69828026T2 (de) 2005-04-07
CN1241146A (zh) 2000-01-12

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