CN110343413B - 氮磷膨胀型阻燃剂及在水性聚氨酯涂料应用的制备方法 - Google Patents
氮磷膨胀型阻燃剂及在水性聚氨酯涂料应用的制备方法 Download PDFInfo
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- CN110343413B CN110343413B CN201910643179.5A CN201910643179A CN110343413B CN 110343413 B CN110343413 B CN 110343413B CN 201910643179 A CN201910643179 A CN 201910643179A CN 110343413 B CN110343413 B CN 110343413B
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
- C07F9/4883—Amides or esteramides thereof, e.g. RP(NR'2)2 or RP(XR')(NR''2) (X = O, S)
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07K—PEPTIDES
- C07K1/00—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length
- C07K1/14—Extraction; Separation; Purification
- C07K1/30—Extraction; Separation; Purification by precipitation
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Molecular Biology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Biophysics (AREA)
- Genetics & Genomics (AREA)
- Medicinal Chemistry (AREA)
- Analytical Chemistry (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
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| CN202011516311.5A CN112409405A (zh) | 2019-07-17 | 2019-07-17 | 氮磷膨胀型阻燃剂及在水性聚氨酯涂料应用的制备方法 |
| JP2019236699A JP6773351B1 (ja) | 2019-07-17 | 2019-12-26 | 窒素−リン系膨張性難燃剤、及び水性ポリウレタン塗料の調整方法への応用 |
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| CN111040612A (zh) * | 2019-12-30 | 2020-04-21 | 烟台大学 | 碳纳米管改性耐光性水性聚氨酯涂料与胶粘剂的制备方法 |
| CN111117467B (zh) * | 2019-12-30 | 2021-07-09 | 烟台大学 | 石墨烯改性阻燃性水性聚氨酯涂料的制备方法 |
| CN112342786A (zh) * | 2020-11-20 | 2021-02-09 | 静宁县恒达有限责任公司 | 一种磷硼杂链预聚物嵌段聚氨酯织物阻燃水性上浆剂及其制备方法与应用 |
| CN112646269B (zh) * | 2020-12-17 | 2023-04-28 | 安徽强旭塑业科技有限公司 | 一种环保高阻燃电瓶壳及其制备方法 |
| CN114317842B (zh) * | 2020-12-31 | 2023-09-08 | 江苏科美新材料有限公司 | 阻燃防粘着低voc的汽车坐垫革制造工艺 |
| CN112646475B (zh) * | 2020-12-31 | 2021-10-15 | 烟台大学 | 阻燃耐磨耗低voc聚氨酯涂料的制备及应用方法 |
| CN113861776A (zh) * | 2021-09-29 | 2021-12-31 | 安徽坤涂新材料科技有限公司 | 一种聚碳酸酯板材用防火涂料及其制备方法 |
| CN113956776B (zh) * | 2021-12-06 | 2022-12-13 | 烟台大学 | 可粉末化自修复阻燃低voc聚氨酯涂料的制备方法及汽车革中应用 |
| CN114369334B (zh) * | 2022-01-11 | 2024-01-23 | 广东和润新材料股份有限公司 | 一种磷-氮阻燃剂的制备方法 |
| CN114716896A (zh) * | 2022-03-10 | 2022-07-08 | 浙江中聚材料有限公司 | 一种高隔热性阻燃漆料及其制备方法和应用 |
| CN114605832A (zh) * | 2022-04-07 | 2022-06-10 | 粟诗寒 | 一种防火堵料及其制备方法 |
| CN114958123A (zh) * | 2022-05-10 | 2022-08-30 | 单俊昊 | 一种水性生物基膨胀阻燃隔热材料 |
| CN115286747A (zh) * | 2022-08-31 | 2022-11-04 | 中国科学技术大学 | 一种阻燃树脂及其制备方法和古建筑用饰面型防火涂料 |
| CN115466369A (zh) * | 2022-11-02 | 2022-12-13 | 山东一诺威聚氨酯股份有限公司 | 阻燃型热塑性聚氨酯弹性体及其制备方法 |
| CN116120700B (zh) * | 2022-11-23 | 2023-08-04 | 东莞市瑞能塑胶科技有限公司 | 一种高耐磨tpe材料及其制备方法 |
| CN115716985B (zh) * | 2022-11-24 | 2023-07-14 | 上海皆利新材料科技有限公司 | 一种无卤阻燃聚氨酯弹性体及其制备方法 |
| CN115820068B (zh) * | 2022-12-05 | 2023-10-17 | 广东呈美新材料科技有限公司 | 一种水性防腐防火涂料及制备方法 |
| CN115896967B (zh) * | 2022-12-13 | 2023-06-13 | 泰安亚荣生物科技有限公司 | 一种可降解环保阻燃剂及其制备方法 |
| CN115821587A (zh) * | 2022-12-23 | 2023-03-21 | 太仓宝霓实业有限公司 | 织物耐久阻燃剂及其制备方法 |
| CN116023663B (zh) * | 2023-01-09 | 2023-12-29 | 无锡东润电子材料科技有限公司 | 一种含磷氮聚硅氧烷及其制备方法与应用 |
| CN116253951B (zh) * | 2023-02-20 | 2023-09-29 | 江苏骅腾电力科技有限公司 | 一种阻燃型聚丙烯塑料 |
| CN116330793B (zh) * | 2023-03-14 | 2023-09-26 | 南通北风橡塑制品有限公司 | 一种耐高温阻燃聚氨酯复合板及其加工工艺 |
| CN116239752B (zh) * | 2023-03-24 | 2024-04-30 | 浙江梅盛新材料有限公司 | 一种生物基水性聚氨酯、纺织品的制备方法及皮革 |
| CN117343596B (zh) * | 2023-07-12 | 2024-05-03 | 增城市柏雅化工有限公司 | 一种高分子嵌段共聚物-丙烯酸酯涂料及其制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US4026838A (en) * | 1976-08-06 | 1977-05-31 | Armstrong Cork Company | Smoke-suppressant additives for polyphosphazenes |
| JPS6211792A (ja) * | 1985-02-27 | 1987-01-20 | Dainippon Ink & Chem Inc | 難燃剤及び難燃木質物 |
| AU3708593A (en) * | 1992-04-29 | 1993-11-04 | Avco Corporation | Fire resistive coating |
| DE59506142D1 (de) * | 1994-07-29 | 1999-07-15 | Ciba Sc Pfersee Gmbh | Verfahren zur Herstellung von Diestern von Phosphonocarbonsäurederivaten |
| AU2002952373A0 (en) * | 2002-10-31 | 2002-11-14 | Commonwealth Scientific And Industrial Research Organisation | Fire resistant material |
| CN1910263B (zh) * | 2003-12-26 | 2010-05-05 | 东洋纺织株式会社 | 含磷阻燃剂的制造方法、含磷阻燃剂和阻燃性聚酯 |
| WO2006036891A2 (en) * | 2004-09-22 | 2006-04-06 | Indspec Chemical Corporation | Benzoylresorcinol-based phosphate ester compouds as flame retardants |
| JP2009019184A (ja) * | 2006-11-20 | 2009-01-29 | Nankyou Efunika Kk | 水性難燃剤及び消臭性を有する水性難燃剤、並びに難燃性シート、難燃性ポリウレタン発泡体及び該難燃性ポリウレタン発泡体の製造方法 |
| DE102007035417A1 (de) * | 2007-07-28 | 2009-01-29 | Chemische Fabrik Budenheim Kg | Halogenfreies Flammschutzmittel |
| CN103525574A (zh) * | 2013-10-24 | 2014-01-22 | 山东全杰皮革研究所有限公司 | 一种利用制革废弃物铬革屑制备洗涤用表面活性剂的方法 |
| CN104046224B (zh) * | 2014-07-09 | 2016-05-18 | 段宝荣 | 一种阻燃性水性聚氨酯涂料的制备方法 |
| JP2018002812A (ja) * | 2016-06-29 | 2018-01-11 | 日本ペイント・インダストリアルコ−ティングス株式会社 | 粉体耐火塗料組成物の製造方法および粉体耐火塗料組成物 |
| CN108715729B (zh) * | 2018-06-26 | 2021-06-08 | 浙江伟涛包装材料有限公司 | 阻燃、抗菌性水性聚氨酯涂料和胶黏剂的制备方法 |
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